CN106299140A - A kind of new molded breadth spectrum solar cell material - Google Patents
A kind of new molded breadth spectrum solar cell material Download PDFInfo
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- CN106299140A CN106299140A CN201610837250.XA CN201610837250A CN106299140A CN 106299140 A CN106299140 A CN 106299140A CN 201610837250 A CN201610837250 A CN 201610837250A CN 106299140 A CN106299140 A CN 106299140A
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Abstract
The invention discloses a kind of new molded breadth spectrum solar cell material, including following raw material: β chloromethyl thiophene, 2 amino 5 sulfydryls 1, 3, 4 thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst, graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass fibre, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane, 701 powder, aluminium polychlorid, EP rubbers, decanedioic acid double (2, 2, 6, 6 tetramethyl 4 piperidine esters), dibasic lead stearate, 2 hydroxyl 4 methoxy benzophenones, APP.The solar cell material of the present invention can effectively utilize sunlight to include, and ultraviolet and infrared band, at interior energy, improve photoelectric transformation efficiency, carrier transmission efficiency and carrier mobility.
Description
Technical field
The invention belongs to battery material preparing technical field, be specifically related to a kind of new molded breadth spectrum solar cell material.
Background technology
The energy of shortage has had a strong impact on life and the development of restriction society of people.Abundant solar energy is important clear
The clean energy, is the energy that can freely utilize of inexhaustible, nexhaustible, pollution-free, cheap, the mankind.The first oil crisis
Afterwards, various countries competitively carry out cleaning and the applied researcies of regenerative resource, especially solar energy such as solar energy, water energy, wind energy
Applied research is the most extensive.
Solar energy does not has any nonstaining property as a kind of green energy resource to environment, and its source is simple, it may be said that
It is that it is inexhaustible in the existence time limit of the mankind.Solar energy is not only the disposable energy, or cleaning energy
Source, its aboundresources, generally exist, without transporting, also can freely use, the most important thing is environment is not had any pollution.Too
Sun also can have the advantage not available for other generation modes many because of the particularity of solar energy by battery: without geographical restrictions, no
Consume fuel, scale is changeable, motility is big, pollution-free, noiselessness, safe and reliable, the construction period is short, safeguard simply,
There is the probability of large-scale application.So a lot of experts go solar energy to exploitation as the alternative energy, it is desirable to too
Sun can be brought benefit to the mankind.Nowadays the solar energy used have greatly by solar cell conversion get.Because
Solaode has sensing to light, it is possible to the luminous energy being radiated at its surface is converted to electric energy.At present, exerting relevant expert
Under power, solaode is own through having moved towards commercialization and industrialization.
The most crucial part of solaode is the p-n junction being made up of quasiconductor.Solar irradiation on semiconductor p-n junctions,
Forming hole-electron pair, under the effect of p-n junction internal electric field, hole is flowed to n district by p district, and electronics is flowed to p district by n district, connects
Electric current it is formed for after circuit.Owing to quasiconductor has certain bandwidth, solaode can only be by close to quasiconductor bandwidth, energy
Photon for hv is effectively converted into electric energy.Energy cannot be absorbed by battery less than the photon of bandwidth, and energy is more than bandwidth
Photon then only has part energy to be utilized by battery, and the part beyond bandwidth is converted into heat by interactions such as electronics-phonons
Can thus cause energy loss.More than the 99% of solar radiation spectrum is at wavelength 150-4000nm, the sunlight of the most about 50%
For visible ray, remaining is ultraviolet light or infrared light.Due to the semi-conducting material difference used, outside different solaodes
Portion's quantum efficiency is the most different.But for fixing semi-conducting material, the solaode all only sun to specific band
Light effectively utilizes.Even the unijunction silica-based solar cell that spectral response range is wider at present is also only with visible ray
The energy in district, ultraviolet and infrared band are the current sun at interior wide spectral energy the most effectively to utilize sunlight to include
An important problem in energy battery research.
Summary of the invention
The present invention provides a kind of new molded breadth spectrum solar cell material, to solve existing solar cell material only to spy
The sunlight of standing wave section effectively utilizes, and ultraviolet and infrared band are at interior wide light cannot effectively to utilize sunlight to include
Spectrum energy, causes the problems such as photoelectric transformation efficiency, carrier transmission efficiency and carrier mobility are low.The new molded breadth light of the present invention
Spectrum solar cell material has good electronics bulk property, and higher carrier mobility, in the range of 150-4000nm
All having absworption peak, ultraviolet and infrared band, at interior wide spectral energy, can be effectively improved too effectively to utilize sunlight to include
The photoelectric transformation efficiency of sun energy battery, has broad application prospects.
For solve above technical problem, the present invention by the following technical solutions:
A kind of new molded breadth spectrum solar cell material, in units of weight, including following raw material: β-chloromethyl thiophene 36-50
Part, 2-amino-5-sulfydryl-1,3,4-thiadiazoles 19-25 parts, trimethylolpropane 4-8 part, epoxy silane class coupling agent 1-2 part,
Maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-0.2 part, graphite 15-24
Part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, aluminium sesquioxide 7-9 part, silicon dioxide
4-8 part, bentonite 3-6 part, carbon fiber 4-7 part, glass fibre 3-5 part, methylcellulose 5-9 part, dibasic lead phosphite
0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4 part, 701 powder 0.8-
1.6 parts, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester)
3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP 2-4 part；
The preparation method of described new molded breadth spectrum solar cell material, comprises the following steps:
S1: by β-chloromethyl thiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling
Agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200-300W at microwave power, temperature
Degree is for 240-280 DEG C, and rotating speed is stirring 2-4h under 400-600r/min, prepares mixture A；
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass
Glass fiber, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane,
701 powder, aluminium polychlorid, EP rubbers mix, and are 250-360W at microwave power, and temperature is 82-90 DEG C, and rotating speed is 500-
Stir 1-2h under 700r/min, prepare mixture B；
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, heats up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is 150-240W,
Prepare mixture C；
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepares new molded breadth spectrum solar cell material.
Preferably, microwave power described in step S1 is 250-300W, and temperature is 260-280 DEG C, and rotating speed is 500-600r/
2-3h is stirred under min.
It is highly preferred that described microwave power is 300W, temperature is 280 DEG C, and rotating speed is stirring 2h under 600r/min.
Preferably, microwave power described in step S2 is 300-360W, and temperature is 85-90 DEG C, and rotating speed is 600-700r/
1-1.5h is stirred under min.
It is highly preferred that described microwave power is 360W, temperature is 90 DEG C, and rotating speed is stirring 1h under 700r/min.
Preferably, 1.5-2h is stirred under microwave power described in step S3 is 200-240W.
It is highly preferred that described microwave power is stirring 1.5h under 240W.
Preferably, temperature described in step S4 is 250-285 DEG C, and rotating speed is stirring 1-1.2h under 350-400r/min.
It is highly preferred that described temperature is 285 DEG C, rotating speed is stirring 1h under 400r/min.
The method have the advantages that
(1) the new molded breadth spectrum solar cell material of the present invention has good electronics bulk property, and higher carrier moves
Shifting rate, all has absworption peak in the range of 150-4000nm, and ultraviolet and infrared band are interior effectively to utilize sunlight to include
Wide spectral energy, can be effectively improved the photoelectric transformation efficiency of solaode, have broad application prospects；
(2) present invention prepares new molded breadth spectrum solar cell material environmental protection, preparation cost are low.
Detailed description of the invention
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the present invention's
Protection domain, but it is not intended to protection scope of the present invention.
In an embodiment, described new molded breadth spectrum solar cell material, in units of weight, including following raw material: β-
Chloromethyl thiophene 36-50 part, 2-amino-5-sulfydryl-1,3,4-thiadiazoles 19-25 parts, trimethylolpropane 4-8 part, epoxy silicon
Alkanes coupling agent 1-2 part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-
0.2 part, graphite 15-24 part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, three oxidation two
Aluminum 7-9 part, silicon dioxide 4-8 part, bentonite 3-6 part, carbon fiber 4-7 part, glass fibre 3-5 part, methylcellulose 5-9 part,
Dibasic lead phosphite 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4
Part, 701 powder 0.8-1.6 parts, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, double (2,2,6, the 6-tetramethyls of decanedioic acid
Base-4-piperidine ester) 3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP
2-4 part；
The preparation method of described new molded breadth spectrum solar cell material, comprises the following steps:
S1: by β-chloromethyl thiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling
Agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200-300W at microwave power, temperature
Degree is for 240-280 DEG C, and rotating speed is stirring 2-4h under 400-600r/min, prepares mixture A；
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass
Glass fiber, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane,
701 powder, aluminium polychlorid, EP rubbers mix, and are 250-360W at microwave power, and temperature is 82-90 DEG C, and rotating speed is 500-
Stir 1-2h under 700r/min, prepare mixture B；
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, heats up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is 150-240W,
Prepare mixture C；
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepares new molded breadth spectrum solar cell material.
Embodiment 1
A kind of new molded breadth spectrum solar cell material, in units of weight, including following raw material: β-chloromethyl thiophene 42 parts,
2-amino-5-sulfydryl-1,3,4-thiadiazoles 24 parts, trimethylolpropane 6 parts, epoxy silane class coupling agent 1.5 parts, maleic anhydride
Grafting compatilizer 1.5 parts, acrylic type bridging agent 0.9 part, platinum catalyst 0.1 part, 20 parts of graphite, white carbon black 24 parts, carborundum 5
Part, aluminium nitride 8 parts, silicon nitride 9 parts, aluminium sesquioxide 8 parts, silicon dioxide 6 parts, bentonite 5 parts, 6 parts of carbon fiber, glass fibre
4 parts, methylcellulose 7 parts, dibasic lead phosphite 0.9 part, esters of acrylic acid regulator 0.7 part, epoxypropoxy front three
Double (2,2,6, the 6-tetramethyl-4-of TMOS 3 parts, 1.2 parts of 701 powder, aluminium polychlorid 1 part, 1.4 parts of EP rubbers, decanedioic acid
Piperidine ester) 7 parts, dibasic lead stearate 4 parts, ESCALOL 567 4 parts, APP 3 parts；
The preparation method of described new molded breadth spectrum solar cell material, comprises the following steps:
S1: by β-chloromethyl thiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling
Agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 250W at microwave power, and temperature is
260 DEG C, rotating speed is stirring 3h under 500r/min, prepares mixture A；
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass
Glass fiber, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane,
701 powder, aluminium polychlorid, EP rubbers mix, and are 300W at microwave power, and temperature is 85 DEG C, and rotating speed is to stir under 600r/min
Mix 1.5h, prepare mixture B；
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 100r/min
Rotating speed stirring, controls charging rate is 13g/min, feed terminate after, be warming up to 740 DEG C with the heating rate of 14 DEG C/min,
Mixing speed improves to 750r/min, and stirs 2h under microwave power is 200W, prepares mixture C；
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 250 DEG C in temperature, and rotating speed is to stir under 350r/min
1.2h, is cooled to room temperature, prepares new molded breadth spectrum solar cell material.
Embodiment 2
A kind of new molded breadth spectrum solar cell material, in units of weight, including following raw material: β-chloromethyl thiophene 36 parts,
2-amino-5-sulfydryl-1,3,4-thiadiazoles 19 parts, trimethylolpropane 4 parts, epoxy silane class coupling agent 1 part, maleic anhydride connect
Branch compatilizer 1 part, acrylic type bridging agent 0.6 part, platinum catalyst 0.1 part, 15 parts of graphite, white carbon black 18 parts, carborundum 3 parts, nitrogen
Change 5 parts of aluminum, silicon nitride 6 parts, aluminium sesquioxide 7 parts, silicon dioxide 4 parts, bentonite 3 parts, 4 parts of carbon fiber, glass fibre 3 parts,
Methylcellulose 5 parts, dibasic lead phosphite 0.6 part, esters of acrylic acid regulator 0.5 part, glycidoxypropyl trimethoxy
Double (2,2,6, the 6-tetramethyl-4-piperazines of 2 parts of silane, 0.8 part of 701 powder, aluminium polychlorid 0.7 part, 1.2 parts of EP rubbers, decanedioic acid
Pyridine ester) 3 parts, dibasic lead stearate 2 parts, ESCALOL 567 3 parts, APP 2 parts；
The preparation method of described new molded breadth spectrum solar cell material, comprises the following steps:
S1: by β-chloromethyl thiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling
Agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200W at microwave power, and temperature is
240 DEG C, rotating speed is stirring 4h under 400r/min, prepares mixture A；
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass
Glass fiber, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane,
701 powder, aluminium polychlorid, EP rubbers mix, and are 250W at microwave power, and temperature is 82 DEG C, and rotating speed is to stir under 500r/min
Mix 2h, prepare mixture B；
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90r/min
Rotating speed stirring, controls charging rate is 12g/min, feed terminate after, be warming up to 720 DEG C with the heating rate of 12 DEG C/min,
Mixing speed improves to 700r/min, and stirs 2.5h under microwave power is 150W, prepares mixture C；
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216 DEG C in temperature, and rotating speed is to stir under 300r/min
1.5h, is cooled to room temperature, prepares new molded breadth spectrum solar cell material.
Embodiment 3
A kind of new molded breadth spectrum solar cell material, in units of weight, including following raw material: β-chloromethyl thiophene 50 parts,
2-amino-5-sulfydryl-1,3,4-thiadiazoles 25 parts, trimethylolpropane 8 parts, epoxy silane class coupling agent 2 parts, maleic anhydride connect
Branch compatilizer 2 parts, acrylic type bridging agent 1.2 parts, platinum catalyst 0.2 part, 24 parts of graphite, white carbon black 28 parts, carborundum 7 parts, nitrogen
Change 10 parts of aluminum, silicon nitride 12 parts, aluminium sesquioxide 9 parts, silicon dioxide 8 parts, bentonite 6 parts, 7 parts of carbon fiber, glass fibre 5
Part, methylcellulose 9 parts, dibasic lead phosphite 1.2 parts, esters of acrylic acid regulator 0.9 part, epoxypropoxy trimethoxy
Double (2,2,6, the 6-tetramethyl-4-of base silane 4 parts, 1.6 parts of 701 powder, aluminium polychlorid 1.4 parts, 1.6 parts of EP rubbers, decanedioic acid
Piperidine ester) 10 parts, dibasic lead stearate 6 parts, ESCALOL 567 5 parts, APP 4 parts；
The preparation method of described new molded breadth spectrum solar cell material, comprises the following steps:
S1: by β-chloromethyl thiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling
Agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 300W at microwave power, and temperature is
280 DEG C, rotating speed is stirring 2h under 600r/min, prepares mixture A；
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass
Glass fiber, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane,
701 powder, aluminium polychlorid, EP rubbers mix, and are 360W at microwave power, and temperature is 90 DEG C, and rotating speed is to stir under 700r/min
Mix 1h, prepare mixture B；
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 120r/min
Rotating speed stirring, controls charging rate is 14g/min, feed terminate after, be warming up to 750 DEG C with the heating rate of 16 DEG C/min,
Mixing speed improves to 800r/min, and stirs 1.5h under microwave power is 240W, prepares mixture C；
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 285 DEG C in temperature, and rotating speed is stirring 1h under 400r/min,
It is cooled to room temperature, prepares new molded breadth spectrum solar cell material.
New molded breadth spectrum solar cell material embodiment 1-3 prepared is applied to organic photovoltaic solaode
On, investigate its device photoelectric conversion efficiency, carrier transmission efficiency and carrier mobility, result is as shown in the table.
As seen from the above table, the new molded breadth spectrum solar cell material of the present invention has good electronics bulk property, relatively
High carrier mobility, can be effectively improved the photoelectric transformation efficiency of solaode, have broad application prospects.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led
For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace,
All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (9)
1. a new molded breadth spectrum solar cell material, it is characterised in that in units of weight, including following raw material: β-chlorine
Methylthiophene 36-50 part, 2-amino-5-sulfydryl-1,3,4-thiadiazoles 19-25 parts, trimethylolpropane 4-8 part, epoxy silane
Class coupling agent 1-2 part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-0.2
Part, graphite 15-24 part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, aluminium sesquioxide 7-
9 parts, silicon dioxide 4-8 part, bentonite 3-6 part, carbon fiber 4-7 part, glass fibre 3-5 part, methylcellulose 5-9 part, two alkali
Formula lead phosphite 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4 part,
701 powder 0.8-1.6 parts, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, decanedioic acid double (2,2,6,6-tetramethyls-
4-piperidine ester) 3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP 2-4
Part；
The preparation method of described new molded breadth spectrum solar cell material, comprises the following steps:
S1: by β-chloromethyl thiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling
Agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200-300W at microwave power, temperature
Degree is for 240-280 DEG C, and rotating speed is stirring 2-4h under 400-600r/min, prepares mixture A；
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, bentonite, carbon fiber, glass
Glass fiber, methylcellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane,
701 powder, aluminium polychlorid, EP rubbers mix, and are 250-360W at microwave power, and temperature is 82-90 DEG C, and rotating speed is 500-
Stir 1-2h under 700r/min, prepare mixture B；
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, heats up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is 150-240W,
Prepare mixture C；
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepares new molded breadth spectrum solar cell material.
New molded breadth spectrum solar cell material the most according to claim 1, it is characterised in that microwave described in step S1
Power is 250-300W, and temperature is 260-280 DEG C, and rotating speed is stirring 2-3h under 500-600r/min.
New molded breadth spectrum solar cell material the most according to claim 2, it is characterised in that described microwave power is
300W, temperature is 280 DEG C, and rotating speed is stirring 2h under 600r/min.
New molded breadth spectrum solar cell material the most according to claim 1, it is characterised in that microwave described in step S2
Power is 300-360W, and temperature is 85-90 DEG C, and rotating speed is stirring 1-1.5h under 600-700r/min.
New molded breadth spectrum solar cell material the most according to claim 4, it is characterised in that described microwave power is
360W, temperature is 90 DEG C, and rotating speed is stirring 1h under 700r/min.
New molded breadth spectrum solar cell material the most according to claim 1, it is characterised in that microwave described in step S3
Power is stirring 1.5-2h under 200-240W.
New molded breadth spectrum solar cell material the most according to claim 6, it is characterised in that described microwave power is
1.5h is stirred under 240W.
New molded breadth spectrum solar cell material the most according to claim 1, it is characterised in that temperature described in step S4
For 250-285 DEG C, rotating speed is stirring 1-1.2h under 350-400r/min.
New molded breadth spectrum solar cell material the most according to claim 8, it is characterised in that described temperature is 285 DEG C,
Rotating speed is stirring 1h under 400r/min.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535487A (en) * | 2018-11-27 | 2019-03-29 | 江苏拓正茂源新能源有限公司 | A kind of high-performance environment-friendly solar cell material and preparation method thereof |
| CN113214316A (en) * | 2021-05-18 | 2021-08-06 | 杭州师范大学 | Phosphorous acid tri (tri-substituted siloxy methyl phenyl) ester, preparation method, coordination platinum catalyst and single-component addition type silicone rubber |
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| CN101084250A (en) * | 2004-12-21 | 2007-12-05 | 三井化学株式会社 | Modified phenolic resin, epoxy resin composition containing the same, and prepreg containing the composition |
| CN101163678A (en) * | 2005-04-08 | 2008-04-16 | 第一三共株式会社 | Pyridylmethylsulfone derivative |
| CN105218565A (en) * | 2008-10-17 | 2016-01-06 | 泽农医药公司 | Spiral shell oxindole compounds and the purposes as therapeutical agent thereof |
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| CN101084250A (en) * | 2004-12-21 | 2007-12-05 | 三井化学株式会社 | Modified phenolic resin, epoxy resin composition containing the same, and prepreg containing the composition |
| CN101163678A (en) * | 2005-04-08 | 2008-04-16 | 第一三共株式会社 | Pyridylmethylsulfone derivative |
| CN105218565A (en) * | 2008-10-17 | 2016-01-06 | 泽农医药公司 | Spiral shell oxindole compounds and the purposes as therapeutical agent thereof |
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| CN109535487A (en) * | 2018-11-27 | 2019-03-29 | 江苏拓正茂源新能源有限公司 | A kind of high-performance environment-friendly solar cell material and preparation method thereof |
| CN113214316A (en) * | 2021-05-18 | 2021-08-06 | 杭州师范大学 | Phosphorous acid tri (tri-substituted siloxy methyl phenyl) ester, preparation method, coordination platinum catalyst and single-component addition type silicone rubber |
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