CN106229414A - A kind of wide spectrum solar cell material - Google Patents
A kind of wide spectrum solar cell material Download PDFInfo
- Publication number
- CN106229414A CN106229414A CN201610837274.5A CN201610837274A CN106229414A CN 106229414 A CN106229414 A CN 106229414A CN 201610837274 A CN201610837274 A CN 201610837274A CN 106229414 A CN106229414 A CN 106229414A
- Authority
- CN
- China
- Prior art keywords
- solar cell
- cell material
- wide spectrum
- stirring
- rotating speed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of wide spectrum solar cell material, including following raw material: 2 bromothiophenes, 2 amino 5 sulfydryls 1, 3, 4 thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst, graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron fibre, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxy-propyltrimethoxy silane, 701 powder, aluminium polychlorid, EP rubbers, decanedioic acid double (2, 2, 6, 6 tetramethyl 4 piperidine esters), dibasic lead stearate, 2 hydroxyl 4 methoxy benzophenones, APP.The solar cell material of the present invention can effectively utilize sunlight to include, and ultraviolet and infrared band, at interior energy, improve photoelectric transformation efficiency, carrier transmission efficiency and carrier mobility.
Description
Technical field
The invention belongs to battery material preparing technical field, be specifically related to a kind of wide spectrum solar cell material.
Background technology
The energy of shortage has had a strong impact on life and the development of restriction society of people.Abundant solar energy is important clear
The clean energy, is the energy that can freely utilize of inexhaustible, nexhaustible, pollution-free, cheap, the mankind.The first oil crisis
Afterwards, various countries competitively carry out cleaning and the applied researcies of regenerative resource, especially solar energy such as solar energy, water energy, wind energy
Applied research is the most extensive.
Solar energy does not has any nonstaining property as a kind of green energy resource to environment, and its source is simple, it may be said that
It is that it is inexhaustible in the existence time limit of the mankind.Solar energy is not only the disposable energy, or cleaning energy
Source, its aboundresources, generally exist, without transporting, also can freely use, the most important thing is environment is not had any pollution.Too
Sun also can have the advantage not available for other generation modes many because of the particularity of solar energy by battery: without geographical restrictions, no
Consume fuel, scale is changeable, motility is big, pollution-free, noiselessness, safe and reliable, the construction period is short, safeguard simply,
There is the probability of large-scale application.So a lot of experts go solar energy to exploitation as the alternative energy, it is desirable to too
Sun can be brought benefit to the mankind.Nowadays the solar energy used have greatly by solar cell conversion get.Because
Solaode has sensing to light, it is possible to the luminous energy being radiated at its surface is converted to electric energy.At present, exerting relevant expert
Under power, solaode is own through having moved towards commercialization and industrialization.
The most crucial part of solaode is the p-n junction being made up of quasiconductor.Solar irradiation on semiconductor p-n junctions,
Forming hole-electron pair, under the effect of p-n junction internal electric field, hole is flowed to n district by p district, and electronics is flowed to p district by n district, connects
Electric current it is formed for after circuit.Owing to quasiconductor has certain bandwidth, solaode can only be by close to quasiconductor bandwidth, energy
Photon for hv is effectively converted into electric energy.Energy cannot be absorbed by battery less than the photon of bandwidth, and energy is more than bandwidth
Photon then only has part energy to be utilized by battery, and the part beyond bandwidth is converted into heat by interactions such as electronics-phonons
Can thus cause energy loss.More than the 99% of solar radiation spectrum is at wavelength 150-4000nm, the sunlight of the most about 50%
For visible ray, remaining is ultraviolet light or infrared light.Due to the semi-conducting material difference used, outside different solaodes
Portion's quantum efficiency is the most different.But for fixing semi-conducting material, the solaode all only sun to specific band
Light effectively utilizes.Even the unijunction silica-based solar cell that spectral response range is wider at present is also only with visible ray
The energy in district, ultraviolet and infrared band are the current sun at interior wide spectral energy the most effectively to utilize sunlight to include
An important problem in energy battery research.
Summary of the invention
The present invention provides a kind of wide spectrum solar cell material, to solve existing solar cell material only to certain wave
The sunlight of section effectively utilizes, and ultraviolet and infrared band are at interior wide spectrum energy cannot effectively to utilize sunlight to include
Amount, causes the problems such as photoelectric transformation efficiency, carrier transmission efficiency and carrier mobility are low.The wide spectrum solar energy of the present invention
Battery material has good electronics bulk property, higher carrier mobility, all has absorption in the range of 150-4000nm
Peak, ultraviolet and infrared band, at interior wide spectral energy, can be effectively improved solaode effectively to utilize sunlight to include
Photoelectric transformation efficiency, have broad application prospects.
For solve above technical problem, the present invention by the following technical solutions:
A kind of wide spectrum solar cell material, in units of weight, including following raw material: 2-bromothiophene 35-50 part, 2-ammonia
Base-5-sulfydryl-1,3,4-thiadiazoles 18-25 parts, trimethylolpropane 4-8 part, epoxy silane class coupling agent 1-2 part, maleic acid
Acid anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-0.2 part, graphite 15-24 part, white carbon black
18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, aluminium sesquioxide 7-9 part, silicon dioxide 4-8 part,
Kaolin 3-6 part, carbon fiber 4-7 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 5-9 part, dibasic lead phosphite 0.6-
1.2 parts, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4 part, 701 powder 0.8-1.6 parts,
Aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, double (2,2,6, the 6-tetramethyl-4-piperidine ester) 3-10 of decanedioic acid
Part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP 2-4 part;
The preparation method of described wide spectrum solar cell material, comprises the following steps:
S1: by 2-bromothiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, horse
Maleic anhydride grafted compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200-300W at microwave power, and temperature is
240-280 DEG C, rotating speed is stirring 2-4h under 400-600r/min, prepares mixture A;
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron
Fiber, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy silicon
Alkane, 701 powder, aluminium polychlorid, EP rubbers mix, and are 250-360W at microwave power, and temperature is 82-90 DEG C, and rotating speed is
Stir 1-2h under 500-700r/min, prepare mixture B;
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, heats up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is 150-240W,
Prepare mixture C;
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepares wide spectrum solar cell material.
Preferably, microwave power described in step S1 is 250-300W, and temperature is 260-280 DEG C, and rotating speed is 500-600r/
2-3h is stirred under min.
It is highly preferred that described microwave power is 300W, temperature is 280 DEG C, and rotating speed is stirring 2h under 600r/min.
Preferably, microwave power described in step S2 is 300-360W, and temperature is 85-90 DEG C, and rotating speed is 600-700r/
1-1.5h is stirred under min.
It is highly preferred that described microwave power is 360W, temperature is 90 DEG C, and rotating speed is stirring 1h under 700r/min.
Preferably, 1.5-2h is stirred under microwave power described in step S3 is 200-240W.
It is highly preferred that described microwave power is stirring 1.5h under 240W.
Preferably, temperature described in step S4 is 250-285 DEG C, and rotating speed is stirring 1-1.2h under 350-400r/min.
It is highly preferred that described temperature is 285 DEG C, rotating speed is stirring 1h under 400r/min.
The method have the advantages that
(1) the wide spectrum solar cell material of the present invention has a good electronics bulk property, higher carrier mobility,
All having absworption peak in the range of 150-4000nm, ultraviolet and infrared band are at interior wide spectrum effectively to utilize sunlight to include
Energy, can be effectively improved the photoelectric transformation efficiency of solaode, have broad application prospects;
(2) present invention prepares wide spectrum solar cell material environmental protection, preparation cost are low.
Detailed description of the invention
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the present invention's
Protection domain, but it is not intended to protection scope of the present invention.
In an embodiment, described wide spectrum solar cell material, in units of weight, including following raw material: 2-bromine thiophene
Fen 35-50 part, 2-amino-5-sulfydryl-1,3,4-thiadiazoles 18-25 parts, trimethylolpropane 4-8 part, epoxy silane class coupling
Agent 1-2 part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-0.2 part, stone
Ink 15-24 part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, aluminium sesquioxide 7-9 part,
Silicon dioxide 4-8 part, Kaolin 3-6 part, carbon fiber 4-7 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 5-9 part, two alkali
Formula lead phosphite 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4 part,
701 powder 0.8-1.6 parts, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, decanedioic acid double (2,2,6,6-tetramethyls-
4-piperidine ester) 3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP 2-4
Part;
The preparation method of described wide spectrum solar cell material, comprises the following steps:
S1: by 2-bromothiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, horse
Maleic anhydride grafted compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200-300W at microwave power, and temperature is
240-280 DEG C, rotating speed is stirring 2-4h under 400-600r/min, prepares mixture A;
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron
Fiber, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy silicon
Alkane, 701 powder, aluminium polychlorid, EP rubbers mix, and are 250-360W at microwave power, and temperature is 82-90 DEG C, and rotating speed is
Stir 1-2h under 500-700r/min, prepare mixture B;
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, heats up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is 150-240W,
Prepare mixture C;
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepares wide spectrum solar cell material.
Embodiment 1
A kind of wide spectrum solar cell material, in units of weight, including following raw material: 2-bromothiophene 42 parts, 2-amino-5-
Sulfydryl-1, the grafting of 3,4-thiadiazoles 24 parts, trimethylolpropane 6 parts, epoxy silane class coupling agent 1.5 parts, maleic anhydride is compatible
Agent 1.5 parts, acrylic type bridging agent 0.9 part, platinum catalyst 0.1 part, 20 parts of graphite, white carbon black 24 parts, carborundum 5 parts, aluminium nitride 8
Part, silicon nitride 9 parts, aluminium sesquioxide 8 parts, silicon dioxide 6 parts, Kaolin 5 parts, 6 parts of carbon fiber, boron fibre 4 parts, hydroxypropyl first
Base cellulose 7 parts, dibasic lead phosphite 0.9 part, esters of acrylic acid regulator 0.7 part, glycidoxypropyl trimethoxy silicon
Double (2,2,6, the 6-tetramethyl-4-piperidines of 3 parts of alkane, 1.2 parts of 701 powder, aluminium polychlorid 1 part, 1.4 parts of EP rubbers, decanedioic acid
Ester) 7 parts, dibasic lead stearate 4 parts, ESCALOL 567 4 parts, APP 3 parts;
The preparation method of described wide spectrum solar cell material, comprises the following steps:
S1: by 2-bromothiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, horse
Maleic anhydride grafted compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 250W at microwave power, and temperature is 260
DEG C, rotating speed is stirring 3h under 500r/min, prepares mixture A;
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron
Fiber, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy silicon
Alkane, 701 powder, aluminium polychlorid, EP rubbers mix, and are 300W at microwave power, and temperature is 85 DEG C, and rotating speed is under 600r/min
Stirring 1.5h, prepares mixture B;
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 100r/min
Rotating speed stirring, controls charging rate is 13g/min, feed terminate after, be warming up to 740 DEG C with the heating rate of 14 DEG C/min,
Mixing speed improves to 750r/min, and stirs 2h under microwave power is 200W, prepares mixture C;
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 250 DEG C in temperature, and rotating speed is to stir under 350r/min
1.2h, is cooled to room temperature, prepares wide spectrum solar cell material.
Embodiment 2
A kind of wide spectrum solar cell material, in units of weight, including following raw material: 2-bromothiophene 35 parts, 2-amino-5-
Sulfydryl-1,3,4-thiadiazoles 18 parts, trimethylolpropane 4 parts, epoxy silane class coupling agent 1 part, maleic anhydride grafting compatilizer 1
Part, acrylic type bridging agent 0.6 part, platinum catalyst 0.1 part, 15 parts of graphite, white carbon black 18 parts, carborundum 3 parts, aluminium nitride 5 parts, nitrogen
SiClx 6 parts, aluminium sesquioxide 7 parts, silicon dioxide 4 parts, Kaolin 3 parts, 4 parts of carbon fiber, boron fibre 3 parts, hydroxypropyl methyl are fine
Dimension element 5 parts, dibasic lead phosphite 0.6 part, esters of acrylic acid regulator 0.5 part, glycidoxy-propyltrimethoxy silane 2
Part, 0.8 part of 701 powder, aluminium polychlorid 0.7 part, 1.2 parts of EP rubbers, decanedioic acid pair (2,2,6,6-tetramethyl-4-piperidine ester)
3 parts, dibasic lead stearate 2 parts, ESCALOL 567 3 parts, APP 2 parts;
The preparation method of described wide spectrum solar cell material, comprises the following steps:
S1: by 2-bromothiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, horse
Maleic anhydride grafted compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200W at microwave power, and temperature is 240
DEG C, rotating speed is stirring 4h under 400r/min, prepares mixture A;
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron
Fiber, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy silicon
Alkane, 701 powder, aluminium polychlorid, EP rubbers mix, and are 250W at microwave power, and temperature is 82 DEG C, and rotating speed is under 500r/min
Stirring 2h, prepares mixture B;
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90r/min
Rotating speed stirring, controls charging rate is 12g/min, feed terminate after, be warming up to 720 DEG C with the heating rate of 12 DEG C/min,
Mixing speed improves to 700r/min, and stirs 2.5h under microwave power is 150W, prepares mixture C;
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216 DEG C in temperature, and rotating speed is to stir under 300r/min
1.5h, is cooled to room temperature, prepares wide spectrum solar cell material.
Embodiment 3
A kind of wide spectrum solar cell material, in units of weight, including following raw material: 2-bromothiophene 50 parts, 2-amino-5-
Sulfydryl-1,3,4-thiadiazoles 25 parts, trimethylolpropane 8 parts, epoxy silane class coupling agent 2 parts, maleic anhydride grafting compatilizer 2
Part, acrylic type bridging agent 1.2 parts, platinum catalyst 0.2 part, 24 parts of graphite, white carbon black 28 parts, carborundum 7 parts, aluminium nitride 10 parts,
Silicon nitride 12 parts, aluminium sesquioxide 9 parts, silicon dioxide 8 parts, Kaolin 6 parts, 7 parts of carbon fiber, boron fibre 5 parts, hydroxypropyl methyl
Cellulose 9 parts, dibasic lead phosphite 1.2 parts, esters of acrylic acid regulator 0.9 part, glycidoxy-propyltrimethoxy silane 4
Part, 1.6 parts of 701 powder, aluminium polychlorid 1.4 parts, 1.6 parts of EP rubbers, decanedioic acid pair (2,2,6,6-tetramethyl-4-piperidine ester)
10 parts, dibasic lead stearate 6 parts, ESCALOL 567 5 parts, APP 4 parts;
The preparation method of described wide spectrum solar cell material, comprises the following steps:
S1: by 2-bromothiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, horse
Maleic anhydride grafted compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 300W at microwave power, and temperature is 280
DEG C, rotating speed is stirring 2h under 600r/min, prepares mixture A;
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron
Fiber, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy silicon
Alkane, 701 powder, aluminium polychlorid, EP rubbers mix, and are 360W at microwave power, and temperature is 90 DEG C, and rotating speed is under 700r/min
Stirring 1h, prepares mixture B;
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 120r/min
Rotating speed stirring, controls charging rate is 14g/min, feed terminate after, be warming up to 750 DEG C with the heating rate of 16 DEG C/min,
Mixing speed improves to 800r/min, and stirs 1.5h under microwave power is 240W, prepares mixture C;
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 285 DEG C in temperature, and rotating speed is stirring 1h under 400r/min,
It is cooled to room temperature, prepares wide spectrum solar cell material.
Wide spectrum solar cell material embodiment 1-3 prepared is applied on organic photovoltaic solaode, examines
Examining its device photoelectric conversion efficiency, carrier transmission efficiency and carrier mobility, result is as shown in the table.
As seen from the above table, the wide spectrum solar cell material of the present invention has good electronics bulk property, higher
Carrier mobility, can be effectively improved the photoelectric transformation efficiency of solaode, have broad application prospects.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led
For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace,
All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (9)
1. one kind wide spectrum solar cell material, it is characterised in that in units of weight, including following raw material: 2-bromothiophene
35-50 part, 2-amino-5-sulfydryl-1,3,4-thiadiazoles 18-25 parts, trimethylolpropane 4-8 part, epoxy silane class coupling agent
1-2 part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-0.2 part, graphite
15-24 part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, aluminium sesquioxide 7-9 part, two
Silicon oxide 4-8 part, Kaolin 3-6 part, carbon fiber 4-7 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 5-9 part, two alkali formulas
Lead phosphite 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4 part, 701
Powder 0.8-1.6 part, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, double (2,2,6, the 6-tetramethyl-4-of decanedioic acid
Piperidine ester) 3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP 2-4 part;
The preparation method of described wide spectrum solar cell material, comprises the following steps:
S1: by 2-bromothiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazoles, trimethylolpropane, epoxy silane class coupling agent, horse
Maleic anhydride grafted compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, be 200-300W at microwave power, and temperature is
240-280 DEG C, rotating speed is stirring 2-4h under 400-600r/min, prepares mixture A;
S2: by graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, Kaolin, carbon fiber, boron
Fiber, hydroxypropyl methyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy silicon
Alkane, 701 powder, aluminium polychlorid, EP rubbers mix, and are 250-360W at microwave power, and temperature is 82-90 DEG C, and rotating speed is
Stir 1-2h under 500-700r/min, prepare mixture B;
S3: the mixture B that step S2 prepares is joined in the mixture A that step S1 prepares, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, heats up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is 150-240W,
Prepare mixture C;
S4: add decanedioic acid double (2,2,6,6-tetramethyl-4-piperidine ester), dibasic in the mixture C that step S3 prepares hard
Fat acid lead, ESCALOL 567, APP, be 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepares wide spectrum solar cell material.
Wide spectrum solar cell material the most according to claim 1, it is characterised in that microwave power described in step S1
For 250-300W, temperature is 260-280 DEG C, and rotating speed is stirring 2-3h under 500-600r/min.
Wide spectrum solar cell material the most according to claim 2, it is characterised in that described microwave power is 300W,
Temperature is 280 DEG C, and rotating speed is stirring 2h under 600r/min.
Wide spectrum solar cell material the most according to claim 1, it is characterised in that microwave power described in step S2
For 300-360W, temperature is 85-90 DEG C, and rotating speed is stirring 1-1.5h under 600-700r/min.
Wide spectrum solar cell material the most according to claim 4, it is characterised in that described microwave power is 360W,
Temperature is 90 DEG C, and rotating speed is stirring 1h under 700r/min.
Wide spectrum solar cell material the most according to claim 1, it is characterised in that microwave power described in step S3
For stirring 1.5-2h under 200-240W.
Wide spectrum solar cell material the most according to claim 6, it is characterised in that described microwave power is under 240W
Stirring 1.5h.
Wide spectrum solar cell material the most according to claim 1, it is characterised in that temperature described in step S4 is
250-285 DEG C, rotating speed is stirring 1-1.2h under 350-400r/min.
Wide spectrum solar cell material the most according to claim 8, it is characterised in that described temperature is 285 DEG C, rotating speed
For stirring 1h under 400r/min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610837274.5A CN106229414A (en) | 2016-09-21 | 2016-09-21 | A kind of wide spectrum solar cell material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610837274.5A CN106229414A (en) | 2016-09-21 | 2016-09-21 | A kind of wide spectrum solar cell material |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106229414A true CN106229414A (en) | 2016-12-14 |
Family
ID=58076587
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610837274.5A Pending CN106229414A (en) | 2016-09-21 | 2016-09-21 | A kind of wide spectrum solar cell material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106229414A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109535487A (en) * | 2018-11-27 | 2019-03-29 | 江苏拓正茂源新能源有限公司 | A kind of high-performance environment-friendly solar cell material and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102675340A (en) * | 2012-05-18 | 2012-09-19 | 中国科学院长春应用化学研究所 | Compound, polymer, polymer semiconductor material and organic thin film transistor |
CN103044661A (en) * | 2011-10-11 | 2013-04-17 | 中国科学院化学研究所 | Arylene imide conjugated polymer and preparation method and application thereof to organic photoelectronic device |
CN103044660A (en) * | 2011-10-11 | 2013-04-17 | 中国科学院化学研究所 | Arylene imide conjugated polymer and preparation method and application thereof to organic photoelectronic device |
CN103044662A (en) * | 2011-10-11 | 2013-04-17 | 中国科学院化学研究所 | Arylene imide conjugated polymer and preparation method and application thereof to organic photoelectronic device |
CN103374116A (en) * | 2012-04-24 | 2013-10-30 | 南开大学 | Photoelectric material preparation method |
CN103554139A (en) * | 2013-11-08 | 2014-02-05 | 武汉大学 | Thiophene condensed 2,1,3-benzoxadiazole derivative and polymer thereof |
-
2016
- 2016-09-21 CN CN201610837274.5A patent/CN106229414A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103044661A (en) * | 2011-10-11 | 2013-04-17 | 中国科学院化学研究所 | Arylene imide conjugated polymer and preparation method and application thereof to organic photoelectronic device |
CN103044660A (en) * | 2011-10-11 | 2013-04-17 | 中国科学院化学研究所 | Arylene imide conjugated polymer and preparation method and application thereof to organic photoelectronic device |
CN103044662A (en) * | 2011-10-11 | 2013-04-17 | 中国科学院化学研究所 | Arylene imide conjugated polymer and preparation method and application thereof to organic photoelectronic device |
CN103374116A (en) * | 2012-04-24 | 2013-10-30 | 南开大学 | Photoelectric material preparation method |
CN102675340A (en) * | 2012-05-18 | 2012-09-19 | 中国科学院长春应用化学研究所 | Compound, polymer, polymer semiconductor material and organic thin film transistor |
CN103554139A (en) * | 2013-11-08 | 2014-02-05 | 武汉大学 | Thiophene condensed 2,1,3-benzoxadiazole derivative and polymer thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109535487A (en) * | 2018-11-27 | 2019-03-29 | 江苏拓正茂源新能源有限公司 | A kind of high-performance environment-friendly solar cell material and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105099358B (en) | A kind of manufacturing method of quantum dot-doped type solar energy fluorescence concentrating generating system | |
CN106450000A (en) | Environmentally friendly high-performance wide spectrum solar energy cell material | |
CN103669645B (en) | Photovoltaic phase change wall system and implementation method thereof | |
CN106299140A (en) | A kind of new molded breadth spectrum solar cell material | |
CN106449843A (en) | High-performance wide-spectrum solar cell material | |
CN106356459A (en) | Novel environment-friendly broad-spectrum solar cell material | |
CN106229414A (en) | A kind of wide spectrum solar cell material | |
CN102386271A (en) | Method of applying up-conversion materials to crystalline silicon cell | |
CN106588029A (en) | Novel solar heat-absorbing ceramic material and preparation method thereof | |
CN201713967U (en) | Multifunctional energy-saving glass curtain wall | |
CN106449999A (en) | Novel environment-friendly wide-spectrum solar cell material | |
CN109192861A (en) | A kind of wide spectrum type solar cell material and preparation method thereof | |
CN104409640A (en) | Broad spectrum solar cell material and preparation method thereof | |
CN201983524U (en) | Independent power generation type multi-energy complementary ground source heat pump system | |
CN104402234B (en) | Crystal silicon solar energy battery front side silver paste glass dust and preparation method thereof | |
CN202328875U (en) | Solar vacuum tube with inner tube capable of accommodating working medium based on flexible solar cell | |
CN203949387U (en) | A kind of device that utilizes microorganism and solar energy heating air | |
CN208046551U (en) | New material electric energy-saving device | |
CN209131255U (en) | A kind of wind light mutual complementing pillar energy-conserving drying system | |
CN104910899A (en) | Rare earth doped ZnO light conversion material with high-efficiency broadband down-conversion luminescence performance and preparation method therefor | |
CN106085434B (en) | For the preparation method of the doped transition metal ionses upconverter of solar cell | |
CN103094394B (en) | A kind of lower conversion crystal silicon solar cell and preparation method thereof | |
CN206683134U (en) | A kind of energy saving and environment friendly heating ventilation air-conditioning system | |
CN106189019A (en) | A kind of degradable environment-friendly type photoelectric material | |
CN111573727A (en) | Black mesoporous carbon loaded ZrO2Nano particles and preparation method and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161214 |