CN106432785A - Antibacterial medical product and production process thereof - Google Patents

Antibacterial medical product and production process thereof Download PDF

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Publication number
CN106432785A
CN106432785A CN201610891367.6A CN201610891367A CN106432785A CN 106432785 A CN106432785 A CN 106432785A CN 201610891367 A CN201610891367 A CN 201610891367A CN 106432785 A CN106432785 A CN 106432785A
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Prior art keywords
antibacterial
qualified
inspection
medical articles
foaming
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张立波
吉田干浩
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Priority to CN201610891367.6A priority Critical patent/CN106432785A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/365Coating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • C08J2375/06Polyurethanes from polyesters

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Materials For Medical Uses (AREA)

Abstract

The invention discloses an antibacterial medical product. The antibacterial medical product is prepared by foaming polyester polyol, toluene diisocyanate, a foaming agent, water and a powdery mixture and then spraying an antibacterial agent. A production process comprises the following steps: material preparation, foaming, checking, foam breaking and segmentation, pore opening through blasting, slicing, slitting, antibacterial agent spraying and drying, center line forming and heating lamination, checking, inner packing, checking, outer packing, checking and boxing and warehousing. The antibacterial medical product and the production process have the advantages that the antibacterial substance is added after the foaming link and slitting, so that double guarantee is achieved and bacterium and germ breeding can be effectively inhibited; the added antibacterial substance is nontoxic and free from peculiar smell and has excellent weatherability and lasting antibacterial property; the quality of the product is ensured through multiple detection in the production process; and a food flavor can be added as required and gives off pleasant fragrance, thus avoiding harms to human bodies while improving the comfort of the product.

Description

A kind of antimicrobial medical articles for use and its production technology
Technical field
The present invention relates to a kind of antimicrobial medical articles for use and its production technology, belong to antimicrobial medical product technical field.
Background technology
Mask and binder are conventional health care protective articless, at present and binder be mostly stacked using multilamellar cotton cloth and Become, cotton cloth only has the effect stopping antibacterial and dust, does not have antibacterial functions.Although most of masks and binder just use It is through sterilization, but is as the passage of use time, it stops that the effect of antibacterial then substantially reduces, and this is mainly due to biography The mask of system and binder do not have antibiotic layer, and pathomycete gradually grows.Because nose and mouth pressed close to by mask, wound portion pressed close to by binder Position, antibacterial easily works the mischief for human body.Also occur in that a kind of antibacterial mask and binder on the market, be in mask or binder Multilamellar cotton cloth in add certain Antibiotic-odor Resistant Agent to reach antibacterial effect, but because additive helps for a kind of chemistry Agent, presses close to human body using having certain harm, and more unfortunately these Antibiotic-odor Resistant Agents are elapsing through washing and time The effect of antibacterial deodourizing is greatly reduced afterwards.
Content of the invention
The technical problem to be solved in the present invention, is to provide and a kind of can effectively suppress antibacterial, the growing, no of pathogenic bacteria Poison, free from extraneous odour, and there is medical supplies and its production technology of excellent weatherability.
The present invention is realized by following proposal:A kind of antimicrobial medical articles for use, it is by PEPA, toluene diisocynate Spray antibacterial after ester, foaming agent, water and powder mixture foaming to be made, the composition of powder mixture is oxidation Silver, zirconium phosphate, zinc oxide, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloromethane sulfur Base)-sulfonamide, N- benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles - 1,3- (2H)-diketone, sodium polyacrylate.
A kind of production technology of antimicrobial medical articles for use, it comprises the following steps:
Step one:Get the raw materials ready, material is PEPA, toluene di-isocyanate(TDI), foaming agent and water;
Step 2:Foaming, adds powder mixture in the material of step one, the composition of powder mixture is silver oxide, Zirconium phosphate, zinc oxide, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloromethane sulfur Base)-sulfonamide, N- benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles - 1,3- (2H)-diketone, sodium polyacrylate, generate polyurethane sponge foam;
Step 3:Inspection, the polyurethane sponge foam that step 2 is generated is tested, and checks its density, hardness, color, tough Whether property, pore size are qualified;
Step 4:The segmentation of disconnected bubble, carries out segmentation to the polyurethane sponge foam checking qualified in step 3;
Step 5:Explosion perforate, removes its hole to the polyurethane sponge foam after step 4 segmentation by the way of gas blast Barrier film between gap;
Step 6:Section, cuts into slices to the polyurethane sponge foam after step 5 membrane removal, according to the requirement of medical supplies, cuts Become coiled material in uniform thickness;
Step 7:Article points, are divided into the wide coiled material of 250-300mm;
Step 8:Spray antimicrobial agent is dried, and sprays antibacterial to the coiled material after step 7 article points, and antibacterial is that polyhexamethylene is double Guanidine solution, dries to section after spraying antibacterial;
Step 9:Make molding heating pressing centrage;
Step 10:Whether inspection, check the cohesive of finished form, heated pressure section qualified;
Step 11:Carry out inner packing after step 10 is qualified
Step 12:Inspection, whether the sealing of inspection inner packing, sealing shape are qualified;
Step 13:Carry out outer package after step 12 is qualified
Step 14:Inspection, whether the sealing of inspection outer package, sealing shape, outer package pattern are qualified;
Step 15:Case after step 14 is qualified, warehouse-in.
Described antimicrobial medical articles for use are mask or binder.
In described step one, the composition of each material is, in parts by mass, polyester polyols 100-200 part alcohol, toluene diisocyanate Acid esters 100-200 part, foaming agent part and water 700-1000 part.
In described step 2, the composition of the powder mixture of addition is silver oxide 1-2 part, zirconium phosphate 1-2 part, zinc oxide 1-2 part, 1,2- benzisothiazole-3-ketone 1-2 part, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloro methyl mercapto)-sulphur Amide 1-2 part, N- benzimidazolyl-2 radicals-ylcarbamic acid methyl ester 1-2 part, Tebuconazole 1-2 part, 2- [(dichlorofluoromethyl)-sulfur]- 1H- iso-indoles -1,3- (2H)-diketone 1-2 part, sodium polyacrylate 2-3 part.
Being cut into coil thickness in described step 6 is 2-4mm;
In described step 8, in poly hexamethylene biguanide solution, the content of poly hexamethylene biguanide is 0.1%-0.2%.
In described step 8, flavorant is added according to product demand, the addition of flavorant is 2-4 part.
Beneficial effects of the present invention are:Addition antibiotic substance after foaming link and article points, double shield, can be effective Ground suppression antibacterial, the growing of pathogenic bacteria;The antibiotic substance adding is nontoxic, free from extraneous odour, and has excellent weatherability, antibacterial lasting; Through Multiple detection it is ensured that the quality of product of the present invention in production process;Flavorant can be added as needed, distribute pleasant Fragrance, does not result in injury to human body while improving product comfort of the present invention;Carried out explosion perforate before section article points, There are barrier film, the performance of impact polyurethane sponge foam between the hole of polyurethane sponge foam, removed by way of gas blast Film;Carry out the segmentation of disconnected bubble before explosion perforate, because the device space of explosion perforate is limited, polyurethane sponge foam is divided Section, has not only saved cost, also improves efficiency.
Specific embodiment
The present invention is further described below, but the scope of the present invention does not limit to described content.
In order to clear, do not describe whole features of practical embodiments, in the following description, be not described in detail known function And structure because they can make the present invention due to unnecessary details chaotic it should think holding in any practical embodiments It is necessary to make a large amount of implementation details to realize the specific objective of developer in sending out, such as according to relevant system or relevant business Limit, another embodiment is changed into by an embodiment, additionally, it should think that this development is probably complicated and expends Time, but it is only routine work to those skilled in the art.
Embodiment 1:A kind of antimicrobial medical articles for use, its by PEPA, toluene di-isocyanate(TDI), foaming agent, water and Spray antibacterial after powder mixture foaming to be made, the composition of powder mixture is silver oxide, zirconium phosphate, oxidation Zinc, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloro methyl mercapto)-sulfonamide, N- Benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles -1,3- (2H)-diketone, Sodium polyacrylate.
A kind of production technology of antimicrobial medical articles for use, it comprises the following steps:
Step one:Get the raw materials ready, material is 100 parts of alcohol of polyester polyols, 100 parts of toluene di-isocyanate(TDI), foaming agent part in parts by mass With 700 parts of water;
Step 2:Foaming, adds powder mixture, the composition of the powder mixture of addition is oxygen in the material of step one Change 1 part of silver, 1 part of zirconium phosphate, 1 part of zinc oxide, 1 part of 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-benzene Base-(N- fluorine dichloro methyl mercapto) 1 part of-sulfonamide, N- benzimidazolyl-2 radicals -1 part of ylcarbamic acid methyl ester, 1 part of Tebuconazole, 2- [(two Chlorine methyl fluoride)-sulfur] -1H- iso-indoles -1,3- (2H) -1 part of diketone, 2 parts of sodium polyacrylate, generate polyurethane sponge foam;
Step 3:Inspection, the polyurethane sponge foam that step 2 is generated is tested, and checks its density, hardness, color, tough Whether property, pore size are qualified;
Step 4:The segmentation of disconnected bubble, carries out segmentation to the polyurethane sponge foam checking qualified in step 3;
Step 5:Explosion perforate, removes its hole to the polyurethane sponge foam after step 4 segmentation by the way of gas blast Barrier film between gap;
Step 6:Section, cuts into slices to the polyurethane sponge foam after step 5 membrane removal, according to the requirement of medical supplies, cuts Become the coiled material that thickness is 2mm;
Step 7:Article points, are divided into the wide coiled material of 250mm;
Step 8:Spray antimicrobial agent is dried, and sprays antibacterial to the coiled material after step 7 article points, and antibacterial is that polyhexamethylene is double Guanidine solution, in poly hexamethylene biguanide solution, the content of poly hexamethylene biguanide is 0.1%, adds flavorant, flavorant Addition is 2 parts, after spraying antibacterial, section is dried;
Step 9:Make molding heating pressing centrage;
Step 10:Whether inspection, check the cohesive of finished form, heated pressure section qualified;
Step 11:Carry out inner packing after step 10 is qualified
Step 12:Inspection, whether the sealing of inspection inner packing, sealing shape are qualified;
Step 13:Carry out outer package after step 12 is qualified
Step 14:Inspection, whether the sealing of inspection outer package, sealing shape, outer package pattern are qualified;
Step 15:Case after step 14 is qualified, warehouse-in.
This antimicrobial medical articles for use are mask.
Embodiment 2:A kind of antimicrobial medical articles for use, its by PEPA, toluene di-isocyanate(TDI), foaming agent, water and Spray antibacterial after powder mixture foaming to be made, the composition of powder mixture is silver oxide, zirconium phosphate, oxidation Zinc, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloro methyl mercapto)-sulfonamide, N- Benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles -1,3- (2H)-diketone, Sodium polyacrylate.
A kind of production technology of antimicrobial medical articles for use, it comprises the following steps:
Step one:Get the raw materials ready, material is 200 parts of alcohol of polyester polyols, 200 parts of toluene di-isocyanate(TDI), foaming agent part in parts by mass With 1000 parts of water;
Step 2:Foaming, adds powder mixture, the composition of the powder mixture of addition is oxygen in the material of step one Change 2 parts of silver, 2 parts of zirconium phosphate, 2 parts of zinc oxide, 2 parts of 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-benzene Base-(N- fluorine dichloro methyl mercapto) 2 parts of-sulfonamide, N- benzimidazolyl-2 radicals -2 parts of ylcarbamic acid methyl ester, 2 parts of Tebuconazole, 2- [(two Chlorine methyl fluoride)-sulfur] -1H- iso-indoles -1,3- (2H) -2 parts of diketone, 3 parts of sodium polyacrylate, generate polyurethane sponge foam;
Step 3:Inspection, the polyurethane sponge foam that step 2 is generated is tested, and checks its density, hardness, color, tough Whether property, pore size are qualified;
Step 4:The segmentation of disconnected bubble, carries out segmentation to the polyurethane sponge foam checking qualified in step 3;
Step 5:Explosion perforate, removes its hole to the polyurethane sponge foam after step 4 segmentation by the way of gas blast Barrier film between gap;
Step 6:Section, cuts into slices to the polyurethane sponge foam after step 5 membrane removal, according to the requirement of medical supplies, cuts Become the coiled material that thickness is 4mm;
Step 7:Article points, are divided into the wide coiled material of 300mm;
Step 8:Spray antimicrobial agent is dried, and sprays antibacterial to the coiled material after step 7 article points, and antibacterial is that polyhexamethylene is double Guanidine solution, in poly hexamethylene biguanide solution, the content of poly hexamethylene biguanide is 0.2%, adds edible perfume according to product demand Material, the addition of flavorant is 4 parts, after spraying antibacterial, section is dried;
Step 9:Make molding heating pressing centrage;
Step 10:Whether inspection, check the cohesive of finished form, heated pressure section qualified;
Step 11:Carry out inner packing after step 10 is qualified
Step 12:Inspection, whether the sealing of inspection inner packing, sealing shape are qualified;
Step 13:Carry out outer package after step 12 is qualified
Step 14:Inspection, whether the sealing of inspection outer package, sealing shape, outer package pattern are qualified;
Step 15:Case after step 14 is qualified, warehouse-in.
This antimicrobial medical articles for use are binder.
Embodiment 3:A kind of antimicrobial medical articles for use, its by PEPA, toluene di-isocyanate(TDI), foaming agent, water and Spray antibacterial after powder mixture foaming to be made, the composition of powder mixture is silver oxide, zirconium phosphate, oxidation Zinc, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloro methyl mercapto)-sulfonamide, N- Benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles -1,3- (2H)-diketone, Sodium polyacrylate.
A kind of production technology of antimicrobial medical articles for use, it comprises the following steps:
Step one:Get the raw materials ready, material is 150 parts of alcohol of polyester polyols, 150 parts of toluene di-isocyanate(TDI), foaming agent part in parts by mass With 900 parts of water;
Step 2:Foaming, adds powder mixture, the composition of the powder mixture of addition is oxygen in the material of step one Change 1.5 parts of silver, 1.5 parts of zirconium phosphate, 1.5 parts of zinc oxide, 1.5 parts of 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- diformazan Base-N- phenyl-(N- fluorine dichloro methyl mercapto) 1.5 parts of-sulfonamide, N- benzimidazolyl-2 radicals -1.5 parts of ylcarbamic acid methyl ester, penta azoles 1.5 parts of alcohol, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles -1,3- (2H) -1.5 parts of diketone, 2.5 parts of sodium polyacrylate, generate Polyurethane sponge foam;
Step 3:Inspection, the polyurethane sponge foam that step 2 is generated is tested, and checks its density, hardness, color, tough Whether property, pore size are qualified;
Step 4:The segmentation of disconnected bubble, carries out segmentation to the polyurethane sponge foam checking qualified in step 3;
Step 5:Explosion perforate, removes its hole to the polyurethane sponge foam after step 4 segmentation by the way of gas blast Barrier film between gap;
Step 6:Section, cuts into slices to the polyurethane sponge foam after step 5 membrane removal, according to the requirement of medical supplies, cuts Become the coiled material that thickness is 3mm;
Step 7:Article points, are divided into the wide coiled material of 280mm;
Step 8:Spray antimicrobial agent is dried, and sprays antibacterial to the coiled material after step 7 article points, and antibacterial is that polyhexamethylene is double Guanidine solution, in poly hexamethylene biguanide solution, the content of poly hexamethylene biguanide is 0.15%, after spraying antibacterial, section is carried out Dry;
Step 9:Make molding heating pressing centrage;
Step 10:Whether inspection, check the cohesive of finished form, heated pressure section qualified;
Step 11:Carry out inner packing after step 10 is qualified
Step 12:Inspection, whether the sealing of inspection inner packing, sealing shape are qualified;
Step 13:Carry out outer package after step 12 is qualified
Step 14:Inspection, whether the sealing of inspection outer package, sealing shape, outer package pattern are qualified;
Step 15:Case after step 14 is qualified, warehouse-in.
This antimicrobial medical articles for use are mask.
Although technical scheme having been done with more detailed elaboration and having enumerated it will be appreciated that for ability For field technique personnel, above-described embodiment is made with modification or using equivalent replacement scheme, this is to those skilled in the art It is it is clear that these modifications or improvements without departing from theon the basis of the spirit of the present invention for member, belong to the present invention Claimed scope.

Claims (8)

1. a kind of antimicrobial medical articles for use it is characterised in that:Its by PEPA, toluene di-isocyanate(TDI), foaming agent, water and Spray antibacterial after powder mixture foaming to be made, the composition of powder mixture is silver oxide, zirconium phosphate, oxidation Zinc, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloro methyl mercapto)-sulfonamide, N- Benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles -1,3- (2H)-diketone, Sodium polyacrylate.
2. a kind of production technology of antimicrobial medical articles for use is it is characterised in that it comprises the following steps:
Step one:Get the raw materials ready, material is PEPA, toluene di-isocyanate(TDI), foaming agent and water;
Step 2:Foaming, adds powder mixture in the material of step one, the composition of powder mixture is silver oxide, Zirconium phosphate, zinc oxide, 1,2- benzisothiazole-3-ketone, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloromethane sulfur Base)-sulfonamide, N- benzimidazolyl-2 radicals-ylcarbamic acid methyl ester, Tebuconazole, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles - 1,3- (2H)-diketone, sodium polyacrylate, generate polyurethane sponge foam;
Step 3:Inspection, the polyurethane sponge foam that step 2 is generated is tested, and checks its density, hardness, color, tough Whether property, pore size are qualified;
Step 4:The segmentation of disconnected bubble, carries out segmentation to the polyurethane sponge foam checking qualified in step 3;
Step 5:Explosion perforate, removes its hole to the polyurethane sponge foam after step 4 segmentation by the way of gas blast Barrier film between gap;
Step 6:Section, cuts into slices to the polyurethane sponge foam after step 5 membrane removal, according to the requirement of medical supplies, cuts Become coiled material in uniform thickness;
Step 7:Article points, are divided into the wide coiled material of 250-300mm;
Step 8:Spray antimicrobial agent is dried, and sprays antibacterial to the coiled material after step 7 article points, and antibacterial is that polyhexamethylene is double Guanidine solution, dries to section after spraying antibacterial;
Step 9:Make molding heating pressing centrage;
Step 10:Whether inspection, check the cohesive of finished form, heated pressure section qualified;
Step 11:Carry out inner packing after step 10 is qualified
Step 12:Inspection, whether the sealing of inspection inner packing, sealing shape are qualified;
Step 13:Carry out outer package after step 12 is qualified
Step 14:Inspection, whether the sealing of inspection outer package, sealing shape, outer package pattern are qualified;
Step 15:Case after step 14 is qualified, warehouse-in.
3. a kind of antimicrobial medical articles for use according to claims 2 production technology it is characterised in that:Described antimicrobial medical Articles for use are mask or binder.
4. a kind of antimicrobial medical articles for use according to claims 2 production technology it is characterised in that:Described step In, the composition of each material is, in parts by mass, polyester polyols 100-200 part alcohol, toluene di-isocyanate(TDI) 100-200 part, foaming Agent part and water 700-1000 part.
5. a kind of antimicrobial medical articles for use according to claims 2 production technology it is characterised in that:Described step 2 In, the composition of the powder mixture of addition is silver oxide 1-2 part, zirconium phosphate 1-2 part, zinc oxide 1-2 part, 1,2- benzisothia Azoles -3- ketone 1-2 part, dimethylamino/N, N- dimethyl-N-phenyl-(N- fluorine dichloro methyl mercapto)-sulfonamide 1-2 part, N- benzo miaow Azoles -2- ylcarbamic acid methyl ester 1-2 part, Tebuconazole 1-2 part, 2- [(dichlorofluoromethyl)-sulfur] -1H- iso-indoles -1,3- (2H) - Diketone 1-2 part, sodium polyacrylate 2-3 part.
6. a kind of antimicrobial medical articles for use according to claims 2 production technology it is characterised in that:In described step 6 Being cut into coil thickness is 2-4mm.
7. a kind of antimicrobial medical articles for use according to claims 2 production technology it is characterised in that:Described step 8 In, in poly hexamethylene biguanide solution, the content of poly hexamethylene biguanide is 0.1%-0.2%.
8. a kind of antimicrobial medical articles for use according to claims 2 production technology it is characterised in that:In described step 8 Middle flavorant is added according to product demand, the addition of flavorant is 2-4 part.
CN201610891367.6A 2016-10-13 2016-10-13 Antibacterial medical product and production process thereof Pending CN106432785A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publications (1)

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CN106432785A true CN106432785A (en) 2017-02-22

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111493425A (en) * 2020-04-23 2020-08-07 宁波格林美孚新材料科技有限公司 Mask protection buffering strip and mask
US11179663B1 (en) * 2021-02-01 2021-11-23 Aviro Llc Polyurethane-based materials

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CN104059244A (en) * 2013-03-22 2014-09-24 上海高裕家居科技有限公司 Production process of high-crystal molecule slow-rebound polyurethane
CN105455254A (en) * 2016-01-08 2016-04-06 清华大学 Nanofiber mouth mask capable of effectively blocking PM0.3 and rich in nanometer antibacterial ingredients
CN105566936A (en) * 2016-02-29 2016-05-11 张立波 Material with antimicrobial and odor removing effects and processing method thereof
CN105658245A (en) * 2013-08-29 2016-06-08 绿色影响控股公司 A disinfectant composition for textile and related substrates, and method of treating a substrate to provide disinfecting antibacterial, antiviral and antifungal, wash durable, optionally enhanced with multifunctional properties

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101189971A (en) * 2006-11-20 2008-06-04 北京崇高纳米科技有限公司 Inorganic/organic nano composite antibacterial agent and its fabric product application
CN102190882A (en) * 2010-03-10 2011-09-21 华中科技大学 Inorganic nanoparticles-modified polyurethane sponge mask material, and preparation method and application thereof
CN104059244A (en) * 2013-03-22 2014-09-24 上海高裕家居科技有限公司 Production process of high-crystal molecule slow-rebound polyurethane
CN105658245A (en) * 2013-08-29 2016-06-08 绿色影响控股公司 A disinfectant composition for textile and related substrates, and method of treating a substrate to provide disinfecting antibacterial, antiviral and antifungal, wash durable, optionally enhanced with multifunctional properties
CN105455254A (en) * 2016-01-08 2016-04-06 清华大学 Nanofiber mouth mask capable of effectively blocking PM0.3 and rich in nanometer antibacterial ingredients
CN105566936A (en) * 2016-02-29 2016-05-11 张立波 Material with antimicrobial and odor removing effects and processing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111493425A (en) * 2020-04-23 2020-08-07 宁波格林美孚新材料科技有限公司 Mask protection buffering strip and mask
US11179663B1 (en) * 2021-02-01 2021-11-23 Aviro Llc Polyurethane-based materials

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Application publication date: 20170222