CN106398364A - Oil painting stick and preparation method thereof - Google Patents
Oil painting stick and preparation method thereof Download PDFInfo
- Publication number
- CN106398364A CN106398364A CN201610854135.3A CN201610854135A CN106398364A CN 106398364 A CN106398364 A CN 106398364A CN 201610854135 A CN201610854135 A CN 201610854135A CN 106398364 A CN106398364 A CN 106398364A
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- Prior art keywords
- lake
- oil painting
- painting stick
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention provides an oil painting stick which comprises, by weight, 100 parts of vegetable wax, 30-125 parts of calcium carbonate and 5-30 parts of colorant. The invention further provides a preparation method of the oil painting stick. The preparation method includes: weighing the vegetable wax in needed weight part, heating to 70-80 DEG C to melt the vegetable wax, adding the colorant after the vegetable wax is fully molten, and stirring well; using a three-roller grinder to grind a mixed material to 5-15um in grain size, heating for melting, adding calcium carbonated in needed weight part, and using a high-speed stirring disperser to disperse for 1h; injecting into a former, and adopting low-temperature condensation and demolding technology at 6-15 DEG C to obtain an oil painting stick core. The vegetable wax which is adopted as a raw material is a pure vegetable ingredient, so that the oil painting stick is natural, organic, degradable, safe, and environment-friendly and conforms to mainstream development tendency of green low-carbon economy.
Description
Technical field
The present invention relates to painting material technical field, more particularly to a kind of artistic oil painting stick and preparation method thereof.
Background technology
Artistic oil painting stick is a kind of oiliness polychrome painting pigment, has that feel is fine and smooth, smooth, spreadability is good, folded color, a colour mixture performance
Excellent, the features such as bright-colored.Coating has certain thickness, and coating is higher in the adhesive force of paper, covering power, has matter
Sense, fully can represent oil paint effect, meet various pictorial skill difficulty demands.Oil painting stick core is usually by wax, oil, pigment etc.
Raw material mixing is made, and wherein wax and oil are and refine from oil, but non-renewable due to oil, in recent years
Come, price constantly rises, and brings huge pressure to the manufacturing of artistic oil painting stick.Meanwhile, if not selecting refined paraffin wax
If, in oil, contained non-hydrocarbon compound and condensed-nuclei aromatics can be brought in oil painting rod product, therewith thus endangering consumer
Health.
Content of the invention
In order to overcome drawbacks described above, the present invention provides a kind of artistic oil painting stick, and this artistic oil painting stick can solve to make currently with paraffin
The price existing for the artistic oil painting stick that raw material prepares is high, the problem of harm consumer health.
The present invention be employed technical scheme comprise that to solve its technical problem：A kind of artistic oil painting stick, in terms of parts by weight, bag
Include：Vegetable wax is 100 parts, Calcium Carbonate is 30～125 parts and coloring agent is 5～30 parts.
Preferably, described vegetable wax is one or more of Semen Gossypii wax, soya wax and Semen Allii Tuberosi wax mixture.
Preferably, described coloring agent is safe pigment type colorant, and described pigment type colorant is food grade pigment type
Coloring agent.
Preferably, described food grade pigment type coloring agent is light green aluminum lake, Brilliant blue aluminum lake and tartrazine aluminum lake, day
Fall yellow lake, carmine lake, erythrosine color lake, the red shallow lake of temptation, amaranth color lake, form sediment blue shallow lake, food titanium dioxide, plant
One or more of white carbon black etc..
Preferably, also bitters are included, described bitters parts by weight are 0.001～0.01 part.
The present invention also provides a kind of preparation method of artistic oil painting stick, and step is as follows：
(1) vegetable wax weighing required deal first is heated to 70～80 DEG C of meltings, adds coloring agent after melting completely
Stir；
(2) again the mixture that (1) obtains is ground through three-roll grinder, mixed material is ground to particle diameter and is 5～15 μm,
Heating adds the desired amount of Calcium Carbonate after melting again, then disperses 1 hour through high-speed stirred dispersion machine；
(3) the scattered material injection molding machine finally obtaining (2), through condensation at low temperature and de- at 6～15 DEG C
Mould, obtains oil painting stick core.
Preferably, the preparation method of described vegetable wax is, Vegetable oil lipoprotein is added in reactor, being evacuated to vacuum is
0.1MPa, to remove the air in raw material and moisture content, then temperature is risen to is passed through hydrogen after 180～200 DEG C, and by supplementing plus
Hydrogen makes pressure maintain 0.2～0.5MPa, and under catalyst action, stirring reaction completed after 1 hour, finally it is cooled to 70～
90 DEG C, obtain final product vegetable wax through filtering, decolouring.
Preferably, described coloring agent be light green aluminum lake, Brilliant blue aluminum lake and tartrazine aluminum lake, sunset yellow lake,
Carmine lake, erythrosine color lake, red shallow lakes of temptation, amaranth color lake, blueness of forming sediment shallow lake, in food titanium dioxide, plant white carbon black etc.
One or more.
Preferably, it is additionally added the desired amount of bitters while adding Calcium Carbonate in step (2).
The invention has the beneficial effects as follows：
1. the material plant wax that the present invention adopts is pure plant component, natural organic degradable, and safety and environmental protection complies with green
Economy, the mainstream development trend of low-carbon economy；
2. the artistic oil painting stick that the present invention makes has a distinctive sweet-smelling of Vegetable oil lipoprotein, and excellent core is painted function admirable, good hand touch, its
Smoothness, folded normal complexion colour mixture all can compare favourably with common artistic oil painting stick, and its temperature tolerance is obviously improved；And plant
Wax is can be biodegradable, if polluteing skin or clothes, is easier to clean than paraffin.
3. more safe and reliable using food grade pigment type coloring agent in the present invention, can be used as child's early education Fructus Alpiniae Oxyphyllae product
Use, add appropriate bitters in the product and can prevent child from biting and swallow.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of not making creative work, all
Belong to the scope of protection of the invention.
The artistic oil painting stick of the present invention, in terms of parts by weight, including：Vegetable wax be 100 parts, Calcium Carbonate be 30～125 parts and
Toner is 5～30 parts.
Wherein, each component in artistic oil painting stick can adopt but be not limited to following component：
1. vegetable wax can be using one of Semen Gossypii wax, soya wax and Semen Allii Tuberosi wax, wherein soya wax because its raw soybeans
The preferred raw materials that the yield of oil is big, price is low and becomes the present invention；
2. Calcium Carbonate can adopt the Calcium Carbonate of common Calcium Carbonate or food stage according to the practical application of product；
3. coloring agent can adopt common grade security pigment commonly used in the art or food grade pigment, for example, food stage face
Material can be light green aluminum lake, Brilliant blue aluminum lake, tartrazine aluminum lake, sunset yellow lake, carmine lake, erythrosine color lake, lure
One or more of puzzled redness shallow lake, amaranth color lake, blueness of forming sediment shallow lake, food titanium dioxide and plant white carbon black etc.；When adopting food
During level pigment type colorant, the present invention can use as child's early education Fructus Alpiniae Oxyphyllae product, swallows in order to avoid child bites, and can produce
Appropriate bitters are added in product.
The present invention use vegetable wax can be prepared with Vegetable oil lipoprotein, preferred Vegetable oil lipoprotein be soybean oil, Oleum Gossypii semen,
Oleum Brassicae campestriss and other vegetable oil and some marine oil.Soybean oil becomes first-selected because its yield high price is low.System with soya wax
As a example standby process：Soybean oil is added in reactor, being evacuated to vacuum is 0.1MPa, to remove the air in raw material and water
Part, then it is passed through hydrogen when temperature is risen to 180～200 DEG C, and make pressure maintain 0.2～0.5MPa by supplementing hydrogenation,
The lower stirring reaction of catalyst (copper, nickel) effect completed after 1 hour, was finally cooled to 70～90 DEG C, obtained final product greatly through filtering, decolouring
Bean wax (other vegetable wax preparation process are identical, and here does not illustrate one by one).The vegetable wax of gained is Vegetable oil lipoprotein in catalyst
In the presence of, hydrogen is added on unsaturated double-bond, is allowed to saturation and improves, general liquid oil is transformed into half and consolidates fat or solid
Fat, is allowed to there is the pre-arcing characterisiticses meeting Special Products requirement, also improves the oxidation stability of oils and fatss simultaneously.
Embodiment 1：Raw material composition and parts by weight are：Raw material composition and parts by weight are：Soya wax is 100 parts, food
Level Calcium Carbonate is 30 parts and titanium white powder pigment is 30 parts.
Preparation method is as follows：
(1) weigh the soya wax of required deal first and be heated to 70 DEG C of meltings, treat to melt addition titanium white powder pigment completely
Stir；
(2) again the mixture that (1) obtains is ground through three-roll grinder, mixed material is ground to particle diameter and is 5～15 μm,
Heating adds the desired amount of food-grade calcium carbonate after melting again, disperses 1 hour through high-speed stirred dispersion machine；
(3) the scattered material injection molding machine finally obtaining (2), through condensation at low temperature and demoulding skill at 6 DEG C
Art, obtains oil painting stick core.
Embodiment 2：Raw material composition and parts by weight are：Raw material composition and parts by weight are：Soya wax is 100 parts, food
Level Calcium Carbonate is 75 parts, light green aluminum lake is 20 parts and 0.001 part of bitters.
Preparation method is as follows：
(1) weigh the soya wax of required deal first and be heated to 75 DEG C of meltings, treat to melt the light green aluminum lake of addition completely
Stir；
(2) again the mixture that (1) obtains is ground through three-roll grinder, mixed material is ground to particle diameter and is 5～15 μm,
Heating adds the desired amount of food-grade calcium carbonate and bitters after melting again, disperses 1 hour through high-speed stirred dispersion machine；
(3) the scattered material injection molding machine finally obtaining (2), through condensation at low temperature and demoulding skill at 10 DEG C
Art, obtains oil painting stick core.
Embodiment 3：Raw material composition and parts by weight are：Raw material composition and parts by weight are：Soya wax is 100 parts, food
Level Calcium Carbonate is 100 parts, Brilliant blue aluminum lake is 10 parts and 0.005 part of bitters.
Preparation method is as follows：
(1) weigh the soya wax of required deal first and be heated to 75 DEG C of meltings, treat to melt addition Brilliant blue aluminum lake completely
Stir；
(2) again the mixture that (1) obtains is ground through three-roll grinder, mixed material is ground to particle diameter and is 5～15 μm,
Heating adds the desired amount of food-grade calcium carbonate and bitters after melting again, disperses 1 hour through high-speed stirred dispersion machine；
(3) the scattered material injection molding machine finally obtaining (2), through condensation at low temperature and demoulding skill at 15 DEG C
Art, obtains oil painting stick core.
Embodiment 4：Raw material composition and parts by weight are：Raw material composition and parts by weight are：Soya wax is 100 parts, food
Level Calcium Carbonate is 125 parts, tartrazine aluminum lake is 5 parts and 0.01 part of bitters.
Preparation method is as follows：
(1) weigh the soya wax of required deal first and be heated to 80 DEG C of meltings, treat to melt addition lemon yellow aluminum color completely
Shallow lake stirs；
(2) again the mixture that (1) obtains is ground through three-roll grinder, mixed material is ground to particle diameter and is 5～15 μm,
Heating adds the desired amount of food-grade calcium carbonate and bitters after melting again, disperses 1 hour through high-speed stirred dispersion machine；
(3) the scattered material injection molding machine finally obtaining (2), through condensation at low temperature and demoulding skill at 15 DEG C
Art, obtains oil painting stick core.
Test result：The artistic oil painting stick core being obtained by above-described embodiment is compared with common paraffin artistic oil painting stick：Drawing function admirable,
Good hand touch, smoothness, folded normal complexion colour mixture all can be compared favourably with common paraffin artistic oil painting stick；Its resistance to elevated temperatures is more excellent,
Test 4 hours at 60 DEG C, the oil pump capacity of artistic oil painting stick of the present invention is considerably less than common paraffin artistic oil painting stick；Test 4 hours at 65 DEG C, this
Invention artistic oil painting stick remains to write at once, and common artistic oil painting stick has softened and can not write at once.
It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise,
Some deformation can also be made and improve, these broadly fall into protection scope of the present invention.Therefore, the protection domain of patent of the present invention
Should be defined by claims.
Claims (10)
1. a kind of artistic oil painting stick is it is characterised in that in terms of parts by weight, including：
Vegetable wax is 100 parts, Calcium Carbonate is 30～125 parts and coloring agent is 5～30 parts.
2. artistic oil painting stick according to claim 1 it is characterised in that：Described vegetable wax is Semen Gossypii wax, soya wax and Semen Allii Tuberosi wax
One or more of mixture.
3. artistic oil painting stick according to claim 1 it is characterised in that：Described coloring agent is safe pigment type colorant.
4. artistic oil painting stick according to claim 3 it is characterised in that：Described pigment type colorant colours for food grade pigment type
Agent.
5. artistic oil painting stick according to claim 4 it is characterised in that：Described food grade pigment type coloring agent is light green aluminum color
Shallow lake, Brilliant blue aluminum lake, tartrazine aluminum lake, sunset yellow lake, carmine lake, erythrosine color lake, the red shallow lake of temptation, amaranth
One or more in color lake, form sediment blue shallow lake, food titanium dioxide and plant white carbon black.
6. artistic oil painting stick according to claim 1 it is characterised in that：Also include bitters, described bitters parts by weight are
0.001～0.01 part.
7. a kind of preparation method of artistic oil painting stick any one of claim 1-6 is it is characterised in that step is as follows：
(1) vegetable wax weighing required deal first is heated to 70～80 DEG C of meltings, adds coloring agent stirring after melting completely
Uniformly；
(2) again the mixture that (1) obtains is ground through three-roll grinder, mixed material is ground to particle diameter and is 5～15 μm, again
Heating adds the desired amount of Calcium Carbonate after melting, and then disperses 1 hour through high-speed stirred dispersion machine；
(3) the scattered material injection molding machine finally obtaining (2), through condensation at low temperature and the demoulding at 6～15 DEG C, obtains
To oil painting stick core.
8. according to claim 7 artistic oil painting stick preparation method it is characterised in that：The preparation method of described vegetable wax is to incite somebody to action
Vegetable oil lipoprotein adds in reactor, and being evacuated to vacuum is 0.1MPa, then temperature is risen to is passed through hydrogen after 180～200 DEG C, and leads to
Crossing supplementary hydrogenation makes pressure maintain 0.2～0.5MPa, and under catalyst action, stirring reaction completed after 1 hour, finally dropped
Temperature, to 70～90 DEG C, obtains final product vegetable wax through filtering, decolouring.
9. artistic oil painting stick according to claim 7 preparation method it is characterised in that：Described coloring agent is light green aluminum color
Shallow lake, Brilliant blue aluminum lake, tartrazine aluminum lake, sunset yellow lake, carmine lake, erythrosine color lake, the red shallow lake of temptation, amaranth
One or more of color lake, blueness of forming sediment shallow lake, food titanium dioxide and plant white carbon black.
10. artistic oil painting stick according to claim 9 preparation method it is characterised in that：Calcium Carbonate is added in step (2)
It is additionally added the desired amount of bitters simultaneously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610854135.3A CN106398364A (en) | 2016-09-27 | 2016-09-27 | Oil painting stick and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610854135.3A CN106398364A (en) | 2016-09-27 | 2016-09-27 | Oil painting stick and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106398364A true CN106398364A (en) | 2017-02-15 |
Family
ID=57998270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610854135.3A Pending CN106398364A (en) | 2016-09-27 | 2016-09-27 | Oil painting stick and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106398364A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108467630A (en) * | 2018-04-14 | 2018-08-31 | 江苏天时新材料科技有限公司 | A kind of artistic oil painting stick synthetic wax and preparation method thereof |
| CN109606008A (en) * | 2018-12-17 | 2019-04-12 | 宁波旷世智源工艺设计有限公司 | A kind of wax crayon oil painting brush |
| CN112812604A (en) * | 2021-01-20 | 2021-05-18 | 上海晨光文具股份有限公司 | Safe and environment-friendly finger print formula and preparation method thereof |
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|---|---|---|---|---|
| JP2003221552A (en) * | 2002-01-31 | 2003-08-08 | Pentel Corp | Color-changeable glossy drawing material |
| CN101993636A (en) * | 2009-08-17 | 2011-03-30 | 真彩文具有限公司 | Crayon and manufacturing method thereof |
| CN102558969A (en) * | 2012-01-06 | 2012-07-11 | 深圳云之彩美术工艺用品有限公司 | Low volatile organic compound (VOC) green crayon |
| CN105176202A (en) * | 2015-10-21 | 2015-12-23 | 上海晨光文具股份有限公司 | Oil painting stick and preparation method thereof |
-
2016
- 2016-09-27 CN CN201610854135.3A patent/CN106398364A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003221552A (en) * | 2002-01-31 | 2003-08-08 | Pentel Corp | Color-changeable glossy drawing material |
| CN101993636A (en) * | 2009-08-17 | 2011-03-30 | 真彩文具有限公司 | Crayon and manufacturing method thereof |
| CN102558969A (en) * | 2012-01-06 | 2012-07-11 | 深圳云之彩美术工艺用品有限公司 | Low volatile organic compound (VOC) green crayon |
| CN105176202A (en) * | 2015-10-21 | 2015-12-23 | 上海晨光文具股份有限公司 | Oil painting stick and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 肖引隽: "《装饰画设计》", 31 August 2010 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108467630A (en) * | 2018-04-14 | 2018-08-31 | 江苏天时新材料科技有限公司 | A kind of artistic oil painting stick synthetic wax and preparation method thereof |
| CN109606008A (en) * | 2018-12-17 | 2019-04-12 | 宁波旷世智源工艺设计有限公司 | A kind of wax crayon oil painting brush |
| CN112812604A (en) * | 2021-01-20 | 2021-05-18 | 上海晨光文具股份有限公司 | Safe and environment-friendly finger print formula and preparation method thereof |
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Application publication date: 20170215 |
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