CN106380943A - Special slurry for printing wallpapers with crack effect, and production method of slurry - Google Patents
Special slurry for printing wallpapers with crack effect, and production method of slurry Download PDFInfo
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- CN106380943A CN106380943A CN201610794106.2A CN201610794106A CN106380943A CN 106380943 A CN106380943 A CN 106380943A CN 201610794106 A CN201610794106 A CN 201610794106A CN 106380943 A CN106380943 A CN 106380943A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention relates to a slurry for printing wallpapers, and especially relates to a special slurry for printing wallpapers with a crack effect, and a production method of the slurry. The slurry is mainly produced from, by weight, 5-20 parts of dioctyl phthalate, 30-50 parts of polyvinylchloride paste resin, 1-2 parts of a foaming agent, 1-5 parts of environmentally-friendly D80 solvent oil, 12-18 parts of calcium carbonate, 4-6 parts of hollow glass beads, 5-8 parts of lignin, 10-30 parts of a plasticizer, 1-5 parts of a stabilizer, 5-8 parts of a VAE emulsion, 5-10 parts of titanium dioxide, 1-3 parts of a thickener and 1-3 parts of a drying speed regulator. The slurry has high adhesion, realizes the crack effect, is suitable for embedding gold powder, silver powder and pearl essence in a gold sprinkling technology, can wrap the gold powder, the silver powder and the pearl essence to improve the class of the wallpapers, and prolongs the service life of the wallpapers.
Description
Technical field
The present invention relates to a kind of slurry of wallpaper printing, print special particularly to a kind of wallpaper with crack effect
Slurry and preparation method thereof.
Background technology
In recent years, because of material environmental protection, sound-insulation and heat-insulation, lovely luster, good visual effect and short construction period etc. were many for wallpaper
Weight advantage, at home and abroad increasing consumer selection wallpaper, has been the trend trend of current wall surfacing using wallpaper.With
This simultaneously, people also grow with each passing day to the aesthetic of wallpaper, and the space pattern that wallpaper surface presents also increasingly be subject to people
Like.But, because the ink slurry in current wallpaper raw materials for production product has many deficiencies：1) slurry is impermeable
Bright, the pattern in the face of falling down, the three-dimensional its aesthetic appearance assuming effect, limiting wallpaper pattern of limitation wallpaper pattern can be covered；2) adhere to
Power is not enough, poor in the wearability of wallpaper face coat, easy to wear, leads to construction in later period, use to there is flaw impact wallpaper row
The popularization of industry；3) later process that can produce in wallpaper in traditional wallpaper production process increases spills gold process (in wallpaper surface
Sprinkle bronze, argentum powder etc. to be modified), there is bronze phenomenon easy to fall off, have a strong impact on the attractive in appearance of wallpaper, meanwhile, because spilling metal working
The utilization of skill, the bronze of wallpaper surface exposes to the open air completely in wallpaper surface, easily with environment in air, steam and other microorganism send out
Raw reaction leads to metal powder variable color to badly influence the pursuit to wallpaper color and environmental-protecting performance for the consumer, and unfavorable wallpaper industry is good for
Kang Fazhan.Therefore, people's exigence one kind can assume transparent stereo sense, have stronger tack, wearability simultaneously,
Possesses the transparent wallpaper slurry of parcel ability, what that is, a kind of wallpaper printing was special possesses the wallpaper slurry of transparent effect.
Content of the invention
The present invention provides a kind of wallpaper printing special sizing agent with crack effect, and this slurry can make outside wallpaper after using
Surface assumes transparent stereo sense, has stronger tack, wearability simultaneously, possesses parcel ability.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of wallpaper printing special sizing agent with crack effect, this slurry is mainly by the raw material system of following weight portion
Become：
During the printing of traditional wallpaper, the third dimension of wallpaper is mainly utilized in increasing foaming agent in ink slurry to be sent out by high temperature
Bubble makes slurry pile up to be presented on wallpaper surface and realize wallpaper pattern and possess stereoeffect, can cover previous step positioned at accumulation
The printed patterns of material lower section, limit stereovision, the third dimension that wallpaper presents, and limit thinking circle that wallpaper designs research staff
Limit, unfavorable domestic wallpaper industry diverse development；Simultaneously as traditional slurry formula limits, lead to the color being attached on wallpaper
Gloss pigments and covering with paint presence wear no resistance, easily abrasion, water repelling property and anti-scouring poor performance；Traditional technique can be on slurry
Some bronzes, argentum powder, the material of pearl essence class are adhered in face, easy to fall off.The present invention is by making the coating be in using negative pressure high-temperature technology
Existing multiple stereoeffect, and combine the adhesive force of instantaneously low-temperature shaped lifting slurry coating, the firmness of lifting wallpaper itself, carry
High wallpaper scrubbing resistance ability.Using packing technology of the present invention, the material adding is wrapped up wherein, increase its color and luster, will not take off
Fall, assume crystal stereo sense more.
The present invention selects dioctyl phthalate and PVC paste resin as slurry film forming matter, also adds in the present invention simultaneously
Add the filming performance that VAE emulsion component can effectively lift slurry, lifting slurry and the adhesive force of base stock, increase the saturating of slurry
Lightness, can make wallpaper surface form the third dimension of a kind of " pebble ", the material simultaneously adding is also all nontoxic, to sky
Gas is pollution-free.First lithium magnesium silicate or aluminium-magnesium silicate are added in slurry as thickening agent, it has very strong thickening property, thixotroping
Property and rheological characteristic, and high adsorption capacity；Lithium magnesium silicate or aluminium-magnesium silicate have very strong water solublity and water-retaining property, relatively conventional slurry
Material, can improve mobility and the adsorptivity of slurry, lift transferring effect, slurry can be made more uniformly to cohere on wallpaper.This
Hollow glass micropearl and lignin is with the addition of, wherein hollow glass micropearl serves folding in the coating made in the component of invention
Penetrate the effect with reflection light, collectively form natural crack effect on the basis of original third dimension with lignin.One
Divide lignin to wrap up hollow glass micropearl outside wall surface, according to the difference of parcel situation, create the effect that different light changes
Really, it is achieved that natural crackle lines.
Relatively conventional slurry simultaneously, this slurry after high temperature oven is baked, instantaneous temperature reduction, the transparency very well, printing
The effect of a kind of " glittering and translucent " is given people on wallpaper, and because its tack is very strong, using packing technology, can be in slurry
The materials such as middle addition bronze, argentum powder, increase the brightness of wallpaper, will not fall off, and the material one in traditional slurry touches to fall.By
In the high adsorption capacity of slurry, so add slurry material therein can be firmly attached to wherein, will not fall off.Increased simultaneously
The anti-scratch power of slurry, substantially increases the water proofing property of wallpaper and anti-scouring performance.
Compared with traditional method slurry third dimension difference, main advantage of the present invention is：Assume crystal and pile up third dimension；Slurry energy
Assuming transparent effect does not affect the pattern of wallpaper itself, improves appreciation effect；Slurry of the present invention have very strong wearability and
Water proofing property, can extend the life-span of wallpaper；Because the adhesive force of slurry of the present invention is strong, transparent effect can be assumed simultaneously, be suitable for spilling gold
In technique, embedding treatment is carried out to bronze, argentum powder, pearl essence, bronze, argentum powder, pearl essence lifting wallpaper class can be wrapped up, extend
Wallpaper service life.
Preferably, this slurry is mainly made up of following raw material：
Preferably, described foaming agent is azodicarbonamide, described plasticizer is epoxy soybean oil, and described stabilizer is
Potassium zinc composite stabilizer, described thickening agent be lithium magnesium silicate or aluminium-magnesium silicate, described rate of drying regulator be 1,3 butylene glycol,
N-butyl alcohol or propylene glycol.
Preferably, also including 5%～35% bronze or argentum powder in this slurry, counted with slurry gross weight for 100%.
Preferably, the particle diameter of hollow glass micropearl is 50-200 μm, the particle diameter≤0.5mm of lignin.
A kind of wallpaper with crack effect prints the preparation method of special sizing agent, and this preparation method comprises the steps：
Step A：Dioctyl phthalate is added in agitator, is subsequently adding PVC paste resin and stirs；Step B：To send out successively
Infusion, D80 environmentally friendly solvent oil, Calcium Carbonate, plasticizer, stabilizer, VAE emulsion, titanium dioxide are added in agitator, control rotating speed
It is maintained at 2000-2500r/min, stir；Step C：Again by hollow glass micropearl, lignin, thickening agent and rate of drying
Regulator adds in agitator, is uniformly mixing to obtain slurry products.
The invention has the beneficial effects as follows：
1st, it is transparent after being parched due to slurry coating, third dimension is presented on wallpaper, so not affecting wallpaper itself
The stereovision of pattern.
2nd, because slurry coating with the addition of lithium magnesium silicate or aluminium-magnesium silicate, improve the mobility of slurry it is easier to film forming,
So rub resistance power is stronger, the water proofing property on wallpaper surface and anti-scouring performance can be increased substantially.
3rd, slurry coating of the present invention can by traditional spill gold process and become wrap up in gold process, can add in the slurry bronze,
The materials such as argentum powder, pearl essence, increase the stereovision attractive in appearance of wallpaper, product surface gloss brightness, can also protect bronze class simultaneously
Material not by environmental pollution, oxidation it is ensured that persistently beautiful, extend wallpaper service life.
4th, pass through to adjust the negative pressure in wallpaper production technology, the temperature of lifting baking oven is 200～220 DEG C of drying, in conjunction with 3
～5 second moment sub-cooled, makes coating paste moment solidify, assumes crystal stereo sense, and lift the anti-scratch energy of wallpaper surface
Power.
5th, with the addition of hollow glass micropearl and lignin in the component of the present invention, wherein hollow glass micropearl is in the painting made
Serve the effect of refraction and reflection light in layer, collectively form natural splitting on the basis of original third dimension with lignin
Stricture of vagina effect.Hollow glass micropearl outside wall surface is wrapped up by a part of lignin, according to the difference of parcel situation, creates different light
The effect that line changes, it is achieved that natural crackle lines.
Specific embodiment
Below by specific embodiment, technical scheme is described in further detail.It should be appreciated that this
Bright enforcement is not limited to the following examples, and any pro forma flexible and/or change that the present invention is made all will fall
Enter the scope of the present invention.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, the equipment being adopted and raw material etc.
All it is commercially available or commonly used in the art.Method in following embodiments, if no special instructions, is the normal of this area
Rule method.
Dioctyl phthalate producer is Guangzhou Chen Yi Chemical Co., Ltd.；
PVC paste resin producer is Lianyun Harbour Hang Hao plastics company limited；
Foaming agent is azodicarbonamide, and company limited, model AC-410 are spun for Zhangjagang City Chang Yuanhua by producer；
D80 environmentally friendly solvent oil producer is the happy Chemical Co., Ltd. in Nanjing hundred；
Calcium Carbonate producer is Fuyang Nan Xinwanli mineral powder plant；
Plasticizer refers to epoxy soybean oil, and producer is Guangzhou Zhong Ye Chemical Co., Ltd.；
Stabilizer is potassium zinc composite stabilizer, and producer is Jiangsu Jingjiang Bulbus Lilii plastic additive company limited；
VAE emulsion producer is Beijing DongFang petroleum chemical engineering Co., Ltd. Organic Chemical Plant；
Titanium dioxide producer is Hengyang Ao Tai Chemical Co., Ltd., model anatase thpe white powder.
The particle diameter of the hollow glass micropearl adopting in embodiment is 50-200 μm, the particle diameter≤0.5mm of lignin.
Embodiment 1
A kind of wallpaper with crack effect prints the preparation method of special sizing agent, includes following preparation process successively：
Step A：10 parts of dioctyl phthalate is added in agitator, is subsequently adding 40 parts of PVC paste resin stirring
Uniformly；
Step B：Successively will be big to 2 parts of AC-410,3 parts of D80 environmentally friendly solvent oil, 18 parts of Calcium Carbonate, 20 parts of epoxy
Oleum Glycines, 2 parts of potassium zinc composite stabilizer, 8 parts of VAE emulsion, 5 parts of titanium dioxide are added in agitator, and rotating speed is maintained at
More than 2000-2500r/min, stirs；
Step C：Again the n-butyl alcohol of 6 parts of hollow glass micropearl, 8 parts of lignin, 1 part of lithium magnesium silicate and 1 part is added and stir
Mix in bucket, stir；Wherein, lithium magnesium silicate producer is Guangzhou Bo Feng Chemical Industry Science Co., Ltd, and n-butyl alcohol producer is
Guangzhou Ju Hui Chemical Co., Ltd.；
Step D：The temperature of baking oven is adjusted to 200 DEG C, the slurry stirring is coated on the wallpaper of printing good pattern,
Then 3 second moment sub-cooled, is allowed to moment solidification, assumes natural crackle sense.
Embodiment 2
Step A：10 parts of dioctyl phthalate is added in agitator, is subsequently adding 30 parts of PVC paste resin stirring
Uniformly；
Step B：Successively will be big to 1 part of AC-410,1 part of D80 environmentally friendly solvent oil, 15 parts of Calcium Carbonate, 20 parts of epoxy
The titanium dioxide of Oleum Glycines, 1 part of potassium zinc composite stabilizer, 5 parts of VAE emulsion and 8 parts is added in agitator, and rotating speed is maintained at
2000-2500r/min, stirs；
Step C：Again the propylene glycol of 4 parts of hollow glass micropearl, 5 parts of lignin, 2 parts of lithium magnesium silicate and 1 part is added and stir
Mix in bucket, be uniformly mixing to obtain slurry products；Wherein, propylene glycol producer is Guangzhou Ju Hui Chemical Co., Ltd.；
Step D：Finally 28% bronze (being counted for 100% with slurry products gross weight) is added in the middle of slurry, stirring
Uniformly obtain product；
Step E：The temperature of baking oven is adjusted to 200 DEG C, the slurry stirring is coated on the wallpaper of printing good pattern,
Then 5 second moment sub-cooled, is allowed to moment solidification, assumes natural crackle lines, can see bronze simultaneously in crackle
Refraction is shinny.
Embodiment 3
Step A：10 parts of dioctyl phthalate is added in agitator, is subsequently adding 35 parts of PVC paste resin stirring
Uniformly；
Step B：Successively will be big to 1 part of AC-410,3 parts of D80 environmentally friendly solvent oil, 15 parts of Calcium Carbonate, 25 parts of epoxy
Oleum Glycines, 3 parts of potassium zinc composite stabilizer, 6 parts of VAE emulsion, 10 parts of titanium dioxide are added in agitator, and rotating speed is maintained at
2000-2500r/min, stirs；
Step C：Again the propylene glycol of 5 parts of hollow glass micropearl, 6 parts of lignin, 3 parts of aluminium-magnesium silicate and 1 part is added and stir
Mix in bucket, stir, obtain slurry products；Wherein, aluminium-magnesium silicate producer is Guangzhou Bo Feng Chemical Industry Science Co., Ltd；
Step D：Finally 25% argentum powder (being counted for 100% with slurry products gross weight) is added in the middle of slurry, stirring
Uniformly.
Step E：The temperature of baking oven is adjusted to 200 DEG C, the slurry stirring is coated on the wallpaper of printing good pattern,
Then 5 second moment sub-cooled, is allowed to moment solidification, assumes natural crackle lines, can see that argentum powder is wrapped in simultaneously and split
In stricture of vagina lines, do not fallen with the basic wiping of handss.
Embodiment 4
Step A：12 parts of dioctyl phthalate is added in agitator, is subsequently adding 40 parts of PVC paste resin stirring
Uniformly；
Step B：Successively will be big to 1 part of AC-410,4 parts of D80 environmentally friendly solvent oil, 12 parts of Calcium Carbonate, 20 parts of epoxy
The titanium dioxide of Oleum Glycines, 3 parts of potassium zinc composite stabilizer, 8 parts of VAE emulsion and 8 parts is added in agitator, and rotating speed is maintained at
2000-2500r/min, stirs；
Step C：Again the 1,3 butylene glycol of 5 parts of hollow glass micropearl, 5 parts of lignin, 3 parts of aluminium-magnesium silicate and 1 part is added
Enter in agitator, stir；Wherein, 1,3 butylene glycol producer is Guangzhou Ju Hui Chemical Co., Ltd.；
Step D：The temperature of baking oven is adjusted to 200 DEG C, the slurry stirring is coated on the wallpaper of printing good pattern,
Then 8S moment sub-cooled, is allowed to moment solidification, assumes crackle lines.
The wallpaper product that the slurry of the present invention produces is shown in Table 1 with the key technical indexes Contrast on effect of traditional slurry.
Table 1
By table 1 it can clearly be seen that 4 embodiments printed using slurry of the present invention, its wallpaper is either resistance to
Crock fastness or washable property aspect, will be better than the wallpaper of traditional slurry production；This is also the advantage institute of slurry of the present invention
Aesthetics and the life-span of wallpaper can be greatly improved.
Embodiment described above is one kind preferably scheme of the present invention, not the present invention is made any pro forma
Limit, also have other variants and remodeling on the premise of without departing from the technical scheme described in claim.
Claims (6)
1. a kind of wallpaper printing special sizing agent with crack effect is it is characterised in that this slurry is mainly by following weight portion
Raw material is made：
Dioctyl phthalate 5-20 part,
PVC paste resin 30-50 part,
Foaming agent 1-2 part,
D80 environmentally friendly solvent oil 1-5 part,
Calcium Carbonate 12-18 part,
Hollow glass micropearl 4-6 part,
Lignin 5-8 part,
Plasticizer 10-30 part,
Stabilizer 1-5 part,
VAE emulsion 5-8 part,
Titanium dioxide 5-10 part,
Thickening agent 1-3 part,
Rate of drying regulator 1-3 part.
2. wallpaper according to claim 1 printing special sizing agent it is characterised in that：This slurry is mainly by following raw material system
Become：
Dioctyl phthalate 10-12 part,
PVC paste resin 30-40 part,
Foaming agent 1-2 part,
D80 environmentally friendly solvent oil 1-5 part,
Calcium Carbonate 15-18 part,
Hollow glass micropearl 4-6 part,
Lignin 5-8 part,
Plasticizer 20-25 part,
Stabilizer 1-3 part,
VAE emulsion 5-8 part,
Titanium dioxide 8-10 part,
Thickening agent 1-3 part,
1 part of rate of drying regulator.
3. wallpaper according to claim 1 printing special sizing agent it is characterised in that：Described foaming agent is azo two formyl
Amine, described plasticizer is epoxy soybean oil, and described stabilizer is potassium zinc composite stabilizer, and described thickening agent is lithium magnesium silicate or silicon
Sour magnalium, described rate of drying regulator is 1,3 butylene glycol, n-butyl alcohol or propylene glycol.
4. wallpaper according to claim 1 printing special sizing agent it is characterised in that：5% ~ 35% gold is also included in this slurry
Powder or argentum powder, are counted with slurry gross weight for 100%.
5. wallpaper according to claim 1 printing special sizing agent it is characterised in that：The particle diameter of hollow glass micropearl is 50-
200 μm, the particle diameter≤0.5mm of lignin.
6. a kind of wallpaper with crack effect print special sizing agent preparation method it is characterised in that this preparation method include as
Lower step：
Step A：Dioctyl phthalate is added in agitator, is subsequently adding PVC paste resin and stirs；
Step B：Successively foaming agent, D80 environmentally friendly solvent oil, Calcium Carbonate, plasticizer, stabilizer, VAE emulsion, titanium dioxide are added
To in agitator, control rotating speed to be maintained at 2000-2500 r/min, stir；
Step C：Again hollow glass micropearl, lignin, thickening agent and rate of drying regulator are added in agitator, stir
Obtain slurry products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610794106.2A CN106380943A (en) | 2016-08-31 | 2016-08-31 | Special slurry for printing wallpapers with crack effect, and production method of slurry |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610794106.2A CN106380943A (en) | 2016-08-31 | 2016-08-31 | Special slurry for printing wallpapers with crack effect, and production method of slurry |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106380943A true CN106380943A (en) | 2017-02-08 |
Family
ID=57938257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610794106.2A Pending CN106380943A (en) | 2016-08-31 | 2016-08-31 | Special slurry for printing wallpapers with crack effect, and production method of slurry |
Country Status (1)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107739559A (en) * | 2017-10-13 | 2018-02-27 | 广西大自然壁高高新装饰材料有限公司 | A kind of coating sizing-agent of high whiteness and preparation method thereof |
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