CN106380930A - Plastic gravure table printing gold ink containing aluminum-silver paste and preparation method thereof - Google Patents

Plastic gravure table printing gold ink containing aluminum-silver paste and preparation method thereof Download PDF

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Publication number
CN106380930A
CN106380930A CN201610830720.XA CN201610830720A CN106380930A CN 106380930 A CN106380930 A CN 106380930A CN 201610830720 A CN201610830720 A CN 201610830720A CN 106380930 A CN106380930 A CN 106380930A
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CN
China
Prior art keywords
aluminum paste
yinjinmo
biao
containing aluminum
parts
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Pending
Application number
CN201610830720.XA
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Chinese (zh)
Inventor
王学林
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Luohe Yinghua Packaging Material Co Ltd
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Luohe Yinghua Packaging Material Co Ltd
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Priority to CN201610830720.XA priority Critical patent/CN106380930A/en
Publication of CN106380930A publication Critical patent/CN106380930A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

The invention discloses plastic gravure table printing gold ink containing aluminum-silver paste, and the plastic gravure table printing gold ink consists of the following raw materials in parts by weight: 35-50 parts of n-propyl acetate, 15-20 parts of isopropanol, 20-30 parts of polyamide resin, 5-8 parts of transparent yellow, 1-2 parts of micro powder wax and 5-10 parts of aluminum-sliver paste. Compared with the prior art, the aluminum-silver paste disclosed by the invention replaces copper gold powder to produce plastic gravure table printing gold ink, and the core technologies are that: firstly, toxic and harmful solvents such as methylbenzene and dimethylbenzene are not contained, and the main solvent is n-propyl acetate, so that food safety is facilitated; and secondly, transparent yellow and aluminum-sliver paste are added for replacing copper gold powder for being beneficial for reducing cost of printing ink and improving quality of the printing ink. According to the formula of the plastic gravure table printing gold ink containing the aluminum-sliver paste, the gravure surface printing ink which is superior to the industrial standards can be produced. According to related detected data, various performance indexes are as follows: fineness being 5-10 mum, viscosity being 25-40s, initial dryness being 20-50mm, adhesion firmness greater than or equal to 90%, and no benzene residues.

Description

A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste and preparation method thereof
Technical field
The invention belongs to technical field of ink is and in particular to a kind of plastic rotogravure Biao Yinjinmo containing silver paste and its preparation Method.
Background technology
Conventional plastic intaglio plate Biao Yinjinmo with toluene, dimethylbenzene as main solvent, solvent supplemented by isopropanol, Cu-Zn alloy powder be metal Pigment, the advantage of this ink is that evaporation rate is fast, printing adaptability is good, attachment fastness is excellent, because of the addition of polyamide, prints Product glossiness is good, and abrasion-resistant is smooth to the touch, and is deeply favored by color printing industry；Shortcoming is that solvent residual amount is big, particularly benzene content Exceeded, Cu-Zn alloy powder consumption leads to greatly price higher, and dust easily pollutes environment, and impact worker is healthy, and the easy oxygen of Cu-Zn alloy powder Change and lose metallic luster and brightness, ink finished product is long placed in rear Cu-Zn alloy powder and easily precipitates, cause ink particle big, easily go out knife line.
Content of the invention
For solving the above problems, the present invention provides a kind of plastic rotogravure Biao Yinjinmo containing aluminum paste and its preparation side Method.
The purpose of the present invention is realized in the following manner：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 35-50 Part, isopropanol 15-20 part, polyamide 20-30 part, transparent yellow 5-8 part, micro mist wax 1-2 part, aluminum paste 5-10 part.
It is made up of the raw material of following parts by weight：N-propyl acetate 40-50 part, isopropanol 18-20 part, polyamide 25-30 part, transparent yellow 6-8 part, micro mist wax 1-2 part, aluminum paste 7-10 part.
Described polyamide contains intermingle with amide resin for alcohol ester.
Described transparent yellow is the partially reddish tint transparent yellow of HR02 type 83.
Described micro mist wax is polyethylene micropowder wax.
Described aluminum paste contains aluminum paste admittedly for non-buoyancy 70%.
As the preparation method of any of the above-described described plastic rotogravure Biao Yinjinmo containing aluminum paste, each raw material is added and divides Dispersed with stirring 10-30 minute in scattered machine is so as to mix homogeneously forms pre-dispersed mill base, more pre-dispersed mill base is pumped in grinder It is ground, is ground to fineness of materials within 10 microns, filter, encapsulation.
With respect to prior art, a kind of aluminum paste disclosed in this invention replaces Cu-Zn alloy powder to produce plastic rotogravure table bronze printing Ink, its core technology：1. do not contain poisonous, hazardous solvent toluene, dimethylbenzene etc., primary solvent based on n-propyl acetate, favorably In food safety；2. add transparent yellow and aluminum paste to replace Cu-Zn alloy powder to advantageously reduce ink cost and improve ink quality.Press According to the plastic rotogravure table bronze printing ink formulations containing aluminum paste, the plastic rotogravure table printing ink better than industry standard can be produced.Root According to relevant detection data, its property indices is：Fineness：5-10µm；Viscosity：25-40s；Just dryness：20-50mm；Attachment jail Degree：≥90%；Benzene class remains：No.
In a word, the plastic rotogravure Biao Yinjinmo quality that Cu-Zn alloy powder produces is replaced to be better than selling in the market using aluminum paste Tradition gold ink, there is wide market development potential.
Specific embodiment
Raw materials used be technical pure, raw materials used source is：
Alcohol ester contains intermingle with amide resin：Qingdao Ju Bang new material company limited；
The partially reddish tint transparent yellow of HR02 type 83：Shenzhen goes in in a big way Chemical Co., Ltd.；
Polyethylene micropowder wax：Nanjing sky poem micronization wax company limited；
Non- buoyancy 70% contains aluminum paste admittedly：Love card special effect pigments (Zhuhai) company limited.
Embodiment 1：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 35-50 Part, isopropanol 15-20 part, polyamide 20-30 part, transparent yellow 5-8 part, micro mist wax 1-2 part, aluminum paste 5-10 part.
It is made up of the raw material of following parts by weight：N-propyl acetate 40-50 part, isopropanol 18-20 part, polyamide 25-30 part, transparent yellow 6-8 part, micro mist wax 1-2 part, aluminum paste 7-10 part.
N-propyl acetate is environmentally friendly solvent, nontoxic, harmless, has effectively prevented the use of toluene.
Polyamide contains intermingle with amide resin for alcohol ester.
Transparent yellow is the partially reddish tint transparent yellow of HR02 type 83.
Micro mist wax is polyethylene micropowder wax.
Aluminum paste contains aluminum paste admittedly for non-buoyancy 70%.
Preparation method, by each raw material add dispersion machine in dispersed with stirring 10-30 minute so as to mix homogeneously formed pre-dispersed Mill base, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, mistake Filter, encapsulation.
Embodiment 2：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 35g, Isopropanol 15g, alcohol ester contains intermingle with amide resin 20g, the partially reddish tint transparent yellow 5g of HR02 type 83, polyethylene micropowder wax 1g, non-buoyancy 70% contains aluminum paste 5g admittedly.
Preparation method, by dispersed with stirring 10 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 3：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 36g, Isopropanol 15.5g, alcohol ester contains intermingle with amide resin 21g, HR02 type 83 partially reddish tint transparent yellow 5.3g, polyethylene micropowder wax 1.1g, Non- buoyancy 70% contains aluminum paste 5.5g admittedly.
Preparation method, by dispersed with stirring 12 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 4：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 38kg, Isopropanol 16kg, alcohol ester contains intermingle with amide resin 22kg, the partially reddish tint transparent yellow 5.6kg of HR02 type 83, polyethylene micropowder wax 1.2kg, non-buoyancy 70% contains aluminum paste 6kg admittedly.
Preparation method, by dispersed with stirring 14 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 5：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 40g, Isopropanol 16.5g, alcohol ester contains intermingle with amide resin 23g, HR02 type 83 partially reddish tint transparent yellow 6g, polyethylene micropowder wax 1.3g, non- Buoyancy 70% contains aluminum paste 6.5g admittedly.
Preparation method, by dispersed with stirring 16 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 6：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 42kg, Isopropanol 17kg, alcohol ester contains intermingle with amide resin 24kg, the partially reddish tint transparent yellow 6.3kg of HR02 type 83, polyethylene micropowder wax 1.4kg, non-buoyancy 70% contains aluminum paste 7kg admittedly.
Preparation method, by dispersed with stirring 18 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 7：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 44g, Isopropanol 17.5g, alcohol ester contains intermingle with amide resin 25g, HR02 type 83 partially reddish tint transparent yellow 6.6g, polyethylene micropowder wax 1.5g, Non- buoyancy 70% contains aluminum paste 7.5g admittedly.
Preparation method, by dispersed with stirring 20 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 8：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 45g, Isopropanol 18g, alcohol ester contains intermingle with amide resin 26g, HR02 type 83 partially reddish tint transparent yellow 7g, polyethylene micropowder wax 1.6g, non-floating Property 70% contains aluminum paste 8g admittedly.
Preparation method, by dispersed with stirring 22 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 9：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 46g, Isopropanol 18.5g, alcohol ester contains intermingle with amide resin 27g, HR02 type 83 partially reddish tint transparent yellow 7.3g, polyethylene micropowder wax 1.7g, Non- buoyancy 70% contains aluminum paste 8.5g admittedly.
Preparation method, by dispersed with stirring 24 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 10：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 48g, Isopropanol 19g, alcohol ester contains intermingle with amide resin 28g, HR02 type 83 partially reddish tint transparent yellow 7.5g, polyethylene micropowder wax 1.8g, non- Buoyancy 70% contains aluminum paste 9g admittedly.
Preparation method, by dispersed with stirring 26 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 11：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 49g, Isopropanol 19.5g, alcohol ester contains intermingle with amide resin 29g, HR02 type 83 partially reddish tint transparent yellow 7.8g, polyethylene micropowder wax 1.9g, Non- buoyancy 70% contains aluminum paste 9.5g admittedly.
Preparation method, by dispersed with stirring 28 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 12：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 50g, Isopropanol 20g, alcohol ester contains intermingle with amide resin 30g, the partially reddish tint transparent yellow 8g of HR02 type 83, polyethylene micropowder wax 2g, non-buoyancy 70% contains aluminum paste 10g admittedly.
Preparation method, by dispersed with stirring 30 minutes in each raw material addition dispersion machine so as to mix homogeneously forms pre-dispersed color Slurry, more pre-dispersed mill base is pumped in grinder be ground, through being repeatedly ground to fineness of materials within 10 microns, filter, Encapsulation.
Embodiment 13：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 40g, Isopropanol 18g, polyamide 25g, transparent yellow 6g, micro mist wax 1g, aluminum paste 7g.
Other are with embodiment 2.
Embodiment 14：
A kind of plastic rotogravure Biao Yinjinmo containing aluminum paste, is made up of the raw material of following parts by weight：N-propyl acetate 50g, Isopropanol 20g, polyamide 30g, transparent yellow 8g, micro mist wax 2g, aluminum paste 10g.
Other are with embodiment 2.
The quality index of the ink of above-described embodiment preparation is as follows：
Above-described be only the preferred embodiment of the present invention it is noted that for a person skilled in the art, not Under the premise of departing from general idea of the present invention, some changes and improvements can also be made, these also should be considered as the protection of the present invention Scope.

Claims (7)

1. a kind of plastic rotogravure Biao Yinjinmo containing aluminum paste it is characterised in that：It is made up of the raw material of following parts by weight：Second Sour n-propyl 35-50 part, isopropanol 15-20 part, polyamide 20-30 part, transparent yellow 5-8 part, micro mist wax 1-2 part, aluminum silver Slurry 5-10 part.
2. the plastic rotogravure Biao Yinjinmo containing aluminum paste according to claim 1 it is characterised in that：By following weight portion The raw material composition of number：N-propyl acetate 40-50 part, isopropanol 18-20 part, polyamide 25-30 part, transparent yellow 6-8 part is micro- Powder wax 1-2 part, aluminum paste 7-10 part.
3. the plastic rotogravure Biao Yinjinmo containing aluminum paste according to claim 1 and 2 it is characterised in that：Described polyamides Polyimide resin contains intermingle with amide resin for alcohol ester.
4. the plastic rotogravure Biao Yinjinmo containing aluminum paste according to claim 1 and 2 it is characterised in that：Described transparent Yellow is the partially reddish tint transparent yellow of HR02 type 83.
5. the plastic rotogravure Biao Yinjinmo containing aluminum paste according to claim 1 and 2 it is characterised in that：Described micropowder Wax is polyethylene micropowder wax.
6. the plastic rotogravure Biao Yinjinmo containing aluminum paste according to claim 1 and 2 it is characterised in that：Described aluminum silver Starch and admittedly contain aluminum paste for non-buoyancy 70%.
7. as any of the above-described described plastic rotogravure Biao Yinjinmo containing aluminum paste preparation method it is characterised in that：Will be each Raw material adds in dispersion machine dispersed with stirring 10-30 minute so as to mix homogeneously forms pre-dispersed mill base, then by pre-dispersed color paste pump Enter in grinder and be ground, be ground to fineness of materials within 10 microns, filter, encapsulation.
CN201610830720.XA 2016-09-19 2016-09-19 Plastic gravure table printing gold ink containing aluminum-silver paste and preparation method thereof Pending CN106380930A (en)

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CN201610830720.XA CN106380930A (en) 2016-09-19 2016-09-19 Plastic gravure table printing gold ink containing aluminum-silver paste and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610830720.XA CN106380930A (en) 2016-09-19 2016-09-19 Plastic gravure table printing gold ink containing aluminum-silver paste and preparation method thereof

Publications (1)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104356749A (en) * 2014-11-19 2015-02-18 广东峰彩油墨有限公司 Gravure lipophilic golden ink and preparation method thereof
CN105860646A (en) * 2016-06-01 2016-08-17 漯河樱花包装材料有限公司 Alcohol-soluble plastic gravure table printing ink

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104356749A (en) * 2014-11-19 2015-02-18 广东峰彩油墨有限公司 Gravure lipophilic golden ink and preparation method thereof
CN105860646A (en) * 2016-06-01 2016-08-17 漯河樱花包装材料有限公司 Alcohol-soluble plastic gravure table printing ink

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Application publication date: 20170208

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