CN103589232B - Environment-friendly gold ink or silver ink for gravure aluminium foil wine label - Google Patents
Environment-friendly gold ink or silver ink for gravure aluminium foil wine label Download PDFInfo
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- CN103589232B CN103589232B CN201210287879.3A CN201210287879A CN103589232B CN 103589232 B CN103589232 B CN 103589232B CN 201210287879 A CN201210287879 A CN 201210287879A CN 103589232 B CN103589232 B CN 103589232B
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Abstract
The invention discloses an environment-friendly gold ink or silver ink for a gravure aluminium foil wine label, and relates to an environment-friendly printing ink. The environment-friendly gold ink or silver ink for the gravure aluminium foil wine label comprises the following components by weight: 40-50 parts of polyamide resin, 3-7 parts of phenolic resin, 5-7 parts of rosin modified maleic acid, 3-4 parts of erucic acid amide, 3-7 parts of a wax powder, 0.15-0.25 part of a dustproof agent, 0.3-0.7 part of an anti-scratch agent, 15-20 parts of a gold powder or silver powder and 14-20 parts of a diluent. Compared with the prior art, the environment-friendly gold ink or silver ink for the gravure aluminium foil label protected by the invention solves the problem that an existing gold ink or silver ink cannot completely remove benzophenone residual and has good product performance.
Description
Technical field
The present invention relates to a kind of environment-friendly ink, particularly a kind of gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink.
Background technology
Wine mark ink refers to the aluminium foil ornamental label printing ink on bottle (as beer mouth).Gravure aluminium foil wine printing ink is bright-colored because of it, high-light transparent, printed product has original natural metal-like, brightness and noticeable property are higher than other any base materials, just as the exquisite ornaments on imperial crown, with abdomen mark, carry on the back and mark one integrated mass, jointly create the perfection of brand beer, flourish in Beer grand printing.Beer packed is more and more adopts aluminum foil sealing bottleneck and thin aluminium foil bottleneck label, as Zhujiang River beer, bule ribbon beer, draft beer, Tsingtao beer, San Minquel beer, golden prestige beer etc., all must need the ink being specifically designed to aluminium foil packing printing.In addition, gravure aluminium foil wine printing ink is not only applied in Beer grand, can also be widely used in the printing of candy wrapping and other food product pack.Intaglio aluminum foil Beer grand, also known as cap mark, its advantage shows handling ease, has good printability and stickiness, can not affect print and labeling compared with paper mark because of silk stream.
Traditional wine standard gold ink or silver-colored black solvent are toluene, vinyl acetic monomer, Virahol are mixed in proportion (being commonly called as three-in-one), and main because the surface tension of toluene is low, printability is good; Add on the other hand the modified resin that toluene dissolves in golden ink or silver-colored ink, effectively improve gloss and the transparency of Jin Mo or silver ink, make it bright in luster magnificent, chromatography level is plentiful.
vocabulary of terms
Polyamide resin molecular weight 2000-6000 in polyamide resin-embodiment of the present invention, viscosity is 90-180cp, and softening temperature is 100-130 DEG C, amine value >=5, originates in Japan's three Hes.
Cured powder in cured powder-embodiment of the present invention adopts PE Microcrystalline Wax.
Scratch resistance agent in scratch resistance agent-embodiment of the present invention adopts Dow corning DC-51.
In thinner-embodiment of the present invention, thinner is made up of dehydrated alcohol 6 parts, vinyl acetic monomer 6 parts, Virahol 3.8 parts, and part is weight part.
In the present invention, if no special instructions, various chemical substance is conventional commercial chemical pure level chemical.
Summary of the invention
An object of the present invention is just to provide a kind of gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink, and this gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink be not thoroughly containing benzophenone, and good product performance.
Technical scheme of the present invention is: a kind of gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink, this gravure aluminium foil wine label Environment-friendlygold gold ink or silver-colored ink comprise following composition: polyamide resin 40-50 part, resol 3-7 part, Abietyl modified toxilic acid 5-7 part, erucicamide 3-4 part, cured powder 3-7 part, dust-proofing agent 0.15-0.25 part, scratch resistance agent 0.3-0.7 part, bronze or silver powder 15-20 part and thinner 14-20 part, described number is weight part.
As preferably, described gravure aluminium foil wine label Environment-friendlygold gold ink or silver-colored ink are also containing acrylic resin.
As preferably, described acrylic resin is 1 part.
As preferably, polyamide resin 45 parts, 5 parts, resol, Abietyl modified toxilic acid 6 parts, erucicamide 3.5 parts, 5 parts, cured powder, dust-proofing agent 0.2 part, scratch resistance agent 0.5 part, bronze or 18 parts, silver powder and thinner 16.8 parts.
As preferably, described thinner consists of: dehydrated alcohol 6 parts, vinyl acetic monomer 6 parts and Virahol 3.8 parts, described number is weight part.
As preferably, described cured powder is PE Microcrystalline Wax.
As preferably, described scratch resistance agent is polydimethylsiloxane dispersion.
Two of object of the present invention is to provide a kind of method preparing above-mentioned gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink.
Technical scheme is: a kind of method preparing above-mentioned gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink, comprises the following steps:
1) weigh by formula;
2) dispersed with stirring is carried out after mixing, first low speed dispersion 3-5 minute during dispersion, then high speed dispersion 10-15 minute;
3) grind, Task-size Controlling, at 4um, adopts circulating water cooling during grinding
As preferably, application number in step 3), is adopted to be that the ink horizontal sand mill of CN201120238526.5 grinds.
The present invention compared with prior art tool has the following advantages:
1. thinner adopts dehydrated alcohol, vinyl acetic monomer, Virahol to replace toluene to solve the problem of environmental protection, by polyamide resin and resol two kinds of resins reasonably combined, learn from other's strong points to offset one's weaknesses, performance is taken into account, and solves and cuts bad problem.
2. add polyamide resin and reduce its hardness, increase snappiness, improve attachment fastness.Polyamide system then ink film is soft and sticky, and rate of drying is slow, and water resisting property is better than nitro-cotton system.So by reasonably combined for two kinds of resins, learn from other's strong points to offset one's weaknesses, performance is taken into account.
3. add resol and can increase ink degree.
4. the slippery on surface selects the adjustment of cured powder to reach requirement.
5. use wax powder, particularly PE Microcrystalline Wax, water resisting property and the resistance to blocking of ink can be solved.
6. dust-proofing agent: adding dust-proofing agent can bronze or silver powder rapid dispersion in resin and solvent, improves dissolution rate, reduces the phenomenon that it floats when dissolving.
7. add scratch resistance agent: adopt alcohol ester dispersiveness, the polydimethylsiloxane dispersion of ultra-high molecular weight, increase smoothness and wear resistance.
8. adding acrylic resin makes this environment-friendly ink have more excellent performance, as better photostabilization and outdoor ageing resistance and other premium properties.
9. erucicamide provides excellent wear-resistant, anti-scratch for ink, antiseized and increase slippery surface property, avoids film in high-speed printing process to rub mutually and the ink pellet surface and affect printing effect of wearing and tearing.Eliminate ink film in high-speed printing process easily to come off the phenomenon on roller bearing.
10. Abietyl modified maleic acid resin-Abietyl modified maleic acid resin and polyamide resin, resol complement each other, and improve hardness of paint film, luminance brightness, grinability and fullness ratio.
Embodiment
The preparation of embodiment 1 gold medal ink or silver-colored black A1
Take that weight part is polyamide resin 40 parts respectively, 3 parts, resol, Abietyl modified maleic acid resin 5 parts, erucicamide 3 parts, 3 parts, cured powder, dust-proofing agent 0.15 part, scratch resistance agent 0.3 part, bronze or 15 parts, silver powder, thinner 14 parts of input charging baskets carry out mix and blend dispersion.Stirrer adopts FS series of high speed dispersion machine, first low speed dispersion 3-5 minute, then high speed dispersion 10-15 minute.It is more even that first low speed can make material dispersion obtain at a high speed again.Stirrer will clean very clean, answers attentional manipulation viscosity, fineness, tinting strength, sticking power etc. during stirring.
After mixture stirs, material is ground, after grinding, the granularity of material is 4um, because temperature is higher during grinding, need to adopt recirculated water to lower the temperature, therefore during grinding, employing application number is the ink horizontal sand mill of CN201120238526.5, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life; Ink horizontal sand mill, comprise frame, relief valve, grinding vessel, tensimeter and thermometer, frame is L-shaped, the below of frame arranges base, and the top of frame arranges grinding vessel and relief valve, and frame is fixedly connected with relief valve, in the both sides of grinding vessel, tensimeter and thermometer are set respectively, suitably can be adjusted flow velocity and the draft speed of grinding vessel inner cooling water by the display of tensimeter and thermometer, make Matter Transfer, electric appliance box is set in the side of frame.In described grinding vessel, arrange dispersion impeller, spacer sleeve respectively, arrange pearl in dispersion impeller, by pearl friction of motion, material is ground, and is rotated by axle, tape loop animal material, makes mixing of materials even.At the side setting operation dish of described frame, operation board can show all temps intuitively and operate with prompting, conveniently adjusts parameter, makes material safety, stable operation.What grinding vessel adopted is sandwich structure, dually can lower the temperature, make the ongoing operation of ink horizontal sand mill with recirculated cooling water, and extends practical life.Use this operation of equipment safety, can use continuously, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life.
Get Jin Mo or silver-colored black A1 after grinding, performance is as table one.
The preparation of embodiment 2 gold medal ink or silver-colored black A2
Take that weight part is polyamide resin 45 parts respectively, 5 parts, resol, Abietyl modified maleic acid resin 6 parts, erucicamide 3.5 parts, 5 parts, cured powder, dust-proofing agent 0.2 part, scratch resistance agent 0.5 part, bronze or 18 parts, silver powder, thinner 16.8 parts of input charging baskets carry out mix and blend dispersion.Stirrer adopts FS series of high speed dispersion machine, first low speed dispersion 3-5 minute, then high speed dispersion 10-15 minute.It is more even that first low speed can make material dispersion obtain at a high speed again.Stirrer will clean very clean, answers attentional manipulation viscosity, fineness, tinting strength, sticking power etc. during stirring.
After mixture stirs, material is ground, after grinding, the granularity of material is 4um, because temperature is higher during grinding, need to adopt recirculated water to lower the temperature, therefore during grinding, employing application number is the ink horizontal sand mill of CN201120238526.5, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life; Ink horizontal sand mill, comprise frame, relief valve, grinding vessel, tensimeter and thermometer, frame is L-shaped, the below of frame arranges base, and the top of frame arranges grinding vessel and relief valve, and frame is fixedly connected with relief valve, in the both sides of grinding vessel, tensimeter and thermometer are set respectively, suitably can be adjusted flow velocity and the draft speed of grinding vessel inner cooling water by the display of tensimeter and thermometer, make Matter Transfer, electric appliance box is set in the side of frame.In described grinding vessel, arrange dispersion impeller, spacer sleeve respectively, arrange pearl in dispersion impeller, by pearl friction of motion, material is ground, and is rotated by axle, tape loop animal material, makes mixing of materials even.At the side setting operation dish of described frame, operation board can show all temps intuitively and operate with prompting, conveniently adjusts parameter, makes material safety, stable operation.What grinding vessel adopted is sandwich structure, dually can lower the temperature, make the ongoing operation of ink horizontal sand mill with recirculated cooling water, and extends practical life.Use this operation of equipment safety, can use continuously, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life.
Get Jin Mo or silver-colored black A2 after grinding, performance is as table one.
The preparation of embodiment 3 gold medal ink or silver-colored black A3
Take that weight part is polyamide resin 50 parts respectively, 7 parts, resol, Abietyl modified maleic acid resin 7 parts, erucicamide 4 parts, 7 parts, cured powder, dust-proofing agent 0.25 part, scratch resistance agent 0.7 part, bronze or 20 parts, silver powder, thinner 20 parts of input charging baskets carry out mix and blend dispersion.Stirrer adopts FS series of high speed dispersion machine, first low speed dispersion 3-5 minute, then high speed dispersion 10-15 minute.It is more even that first low speed can make material dispersion obtain at a high speed again.Stirrer will clean very clean, answers attentional manipulation viscosity, fineness, tinting strength, sticking power etc. during stirring.
After mixture stirs, material is ground, after grinding, the granularity of material is 4um, because temperature is higher during grinding, need to adopt recirculated water to lower the temperature, therefore during grinding, employing application number is the ink horizontal sand mill of CN201120238526.5, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life; Ink horizontal sand mill, comprise frame, relief valve, grinding vessel, tensimeter and thermometer, frame is L-shaped, the below of frame arranges base, and the top of frame arranges grinding vessel and relief valve, and frame is fixedly connected with relief valve, in the both sides of grinding vessel, tensimeter and thermometer are set respectively, suitably can be adjusted flow velocity and the draft speed of grinding vessel inner cooling water by the display of tensimeter and thermometer, make Matter Transfer, electric appliance box is set in the side of frame.In described grinding vessel, arrange dispersion impeller, spacer sleeve respectively, arrange pearl in dispersion impeller, by pearl friction of motion, material is ground, and is rotated by axle, tape loop animal material, makes mixing of materials even.At the side setting operation dish of described frame, operation board can show all temps intuitively and operate with prompting, conveniently adjusts parameter, makes material safety, stable operation.What grinding vessel adopted is sandwich structure, dually can lower the temperature, make the ongoing operation of ink horizontal sand mill with recirculated cooling water, and extends practical life.Use this operation of equipment safety, can use continuously, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life.
Get Jin Mo or silver-colored black A3 after grinding, performance is as table one.
The preparation of embodiment 4 gold medal ink or silver-colored black A4
Take that weight part is polyamide resin 45 parts respectively, 5 parts, resol, acrylic resin 1 part, Abietyl modified maleic acid resin 6 parts, erucicamide 3.5 parts, 5 parts, cured powder, dust-proofing agent 0.2 part, scratch resistance agent 0.5 part, bronze or 18 parts, silver powder, thinner 16.8 parts of input charging baskets carry out mix and blend dispersion.Stirrer adopts FS series of high speed dispersion machine, first low speed dispersion 3-5 minute, then high speed dispersion 10-15 minute.It is more even that first low speed can make material dispersion obtain at a high speed again.Stirrer will clean very clean, answers attentional manipulation viscosity, fineness, tinting strength, sticking power etc. during stirring.
After mixture stirs, material is ground, after grinding, the granularity of material is 4um, because temperature is higher during grinding, need to adopt recirculated water to lower the temperature, therefore during grinding, employing application number is the ink horizontal sand mill of CN201120238526.5, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life; Ink horizontal sand mill, comprise frame, relief valve, grinding vessel, tensimeter and thermometer, frame is L-shaped, the below of frame arranges base, and the top of frame arranges grinding vessel and relief valve, and frame is fixedly connected with relief valve, in the both sides of grinding vessel, tensimeter and thermometer are set respectively, suitably can be adjusted flow velocity and the draft speed of grinding vessel inner cooling water by the display of tensimeter and thermometer, make Matter Transfer, electric appliance box is set in the side of frame.In described grinding vessel, arrange dispersion impeller, spacer sleeve respectively, arrange pearl in dispersion impeller, by pearl friction of motion, material is ground, and is rotated by axle, tape loop animal material, makes mixing of materials even.At the side setting operation dish of described frame, operation board can show all temps intuitively and operate with prompting, conveniently adjusts parameter, makes material safety, stable operation.What grinding vessel adopted is sandwich structure, dually can lower the temperature, make the ongoing operation of ink horizontal sand mill with recirculated cooling water, and extends practical life.Use this operation of equipment safety, can use continuously, by the water coolant in grinding vessel, temperature is reduced, prolonged mechanical work-ing life.
Get Jin Mo or silver-colored black A4 after grinding, performance is as table one.
Table one
Upper table one general ink wherein refers to commercially available containing benzophenone intaglio plate gold ink or silver ink.
Claims (1)
1. a gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink, this gravure aluminium foil wine label Environment-friendlygold gold ink or silver-colored ink comprise following composition: polyamide resin 40-50 part, resol 3-7 part, Abietyl modified maleic acid resin 5-7 part, erucicamide 3-4 part, wax powder 3-7 part, dust-proofing agent 0.15-0.25 part, scratch resistance agent 0.3-0.7 part, bronze or silver powder 15-20 part and thinner 14-20 part, and described number is weight part; Also containing acrylic resin, described acrylic resin is 1 part; Described thinner consist of by weight, dehydrated alcohol: vinyl acetic monomer: Virahol=6:6:3.8.
2. gravure aluminium foil wine label Environment-friendlygold gold ink according to claim 1 or silver ink, is characterized in that: polyamide resin 45 parts, 5 parts, resol, Abietyl modified maleic acid resin 6 parts, erucicamide 3.5 parts, 5 parts, wax powder, dust-proofing agent 0.2 part, scratch resistance agent 0.5 part, bronze or 18 parts, silver powder and thinner 16.8 parts.
3., according to the gravure aluminium foil wine label Environment-friendlygold gold ink described in claim 2 or silver ink, it is characterized in that: described wax powder is PE Microcrystalline Wax.
4., according to the gravure aluminium foil wine label Environment-friendlygold gold ink described in claim 3 or silver ink, it is characterized in that: described scratch resistance agent is polydimethylsiloxane dispersion.
5. prepare a method for the arbitrary described gravure aluminium foil wine label Environment-friendlygold gold ink of claim 1-4 or silver ink, comprise the following steps:
1) weigh by formula;
2) dispersed with stirring is carried out after mixing, first low speed dispersion 3-5 minute during dispersion, then high speed dispersion 10-15 minute;
3) grind, Task-size Controlling, at 4 μm, adopts circulating water cooling during grinding.
6., according to the method preparing gravure aluminium foil wine label Environment-friendlygold gold ink or silver ink described in claim 5, it is characterized in that: in step 3), adopt ink horizontal sand mill to grind.
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| CN201210287879.3A CN103589232B (en) | 2012-08-14 | 2012-08-14 | Environment-friendly gold ink or silver ink for gravure aluminium foil wine label |
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| CN201210287879.3A CN103589232B (en) | 2012-08-14 | 2012-08-14 | Environment-friendly gold ink or silver ink for gravure aluminium foil wine label |
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| CN103589232B true CN103589232B (en) | 2015-07-08 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021176086A1 (en) * | 2020-03-06 | 2021-09-10 | Domino Uk Limited | Ink composition for inkjet printing |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112480740A (en) * | 2020-11-27 | 2021-03-12 | 成都普瑞斯特新材料有限公司 | High-performance water-based beer label ink and preparation method thereof |
| CN112694787A (en) * | 2020-12-28 | 2021-04-23 | 黄山新力油墨科技有限公司 | High-scratch-resistance plastic surface printing delustering oil and preparation method thereof |
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|---|---|---|---|---|
| JPS6248775A (en) * | 1985-08-26 | 1987-03-03 | Ishihara Sangyo Kaisha Ltd | Gravure ink composition |
| CN101768388A (en) * | 2008-12-27 | 2010-07-07 | 广东油墨厂有限公司 | Alcohol-soluble environmental intaglio aluminum foil ink and preparation method thereof |
-
2012
- 2012-08-14 CN CN201210287879.3A patent/CN103589232B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6248775A (en) * | 1985-08-26 | 1987-03-03 | Ishihara Sangyo Kaisha Ltd | Gravure ink composition |
| CN101768388A (en) * | 2008-12-27 | 2010-07-07 | 广东油墨厂有限公司 | Alcohol-soluble environmental intaglio aluminum foil ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 浅谈凹版铝箔酒标油墨的原理、特性及发展;中国食品产业网;《http://news.foodqs.cn/spbz02/2008222103116248.htm》;20080222;全文 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021176086A1 (en) * | 2020-03-06 | 2021-09-10 | Domino Uk Limited | Ink composition for inkjet printing |
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Denomination of invention: Environment-friendly gold ink or silver ink for gravure aluminium foil wine label Effective date of registration: 20190327 Granted publication date: 20150708 Pledgee: Agricultural Bank of China Limited by Share Ltd. Chengdu West Branch Pledgor: CHENGDU PRESSTER NEW MATERIALS Co.,Ltd. Registration number: 2019510000034 |
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Date of cancellation: 20230907 Granted publication date: 20150708 Pledgee: Agricultural Bank of China Limited by Share Ltd. Chengdu West Branch Pledgor: CHENGDU PRESSTER NEW MATERIALS Co.,Ltd. Registration number: 2019510000034 |