CN106351032A - Disperse dyestuff composition for steaming-washing-free printing process for polybutylene terephthalate 1,3-propylene glycol ester fabric - Google Patents
Disperse dyestuff composition for steaming-washing-free printing process for polybutylene terephthalate 1,3-propylene glycol ester fabric Download PDFInfo
- Publication number
- CN106351032A CN106351032A CN201610744260.9A CN201610744260A CN106351032A CN 106351032 A CN106351032 A CN 106351032A CN 201610744260 A CN201610744260 A CN 201610744260A CN 106351032 A CN106351032 A CN 106351032A
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- China
- Prior art keywords
- disperse
- sodium
- disperse dyestuff
- ester fabric
- propylene glycol
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/36—Material containing ester groups using dispersed dyestuffs
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention provides a disperse dyestuff composition for a steaming-washing-free printing process for a polybutylene terephthalate 1,3-propylene glycol ester fabric. The disperse dyestuff composition comprises the following components: 20-30% of high-temperature-resistant disperse dyestuff, 5-10% of biological maleic anhydrides-taurine-acrylamide-sodium allylsulfonate copolymer, 5-15% of carboxymethylated sodium lignin sulfonate, 5-15% of dodecylbenzene sodium sulfonate, 5-15% of sodium polyacrylate and the balance of water. The components of the disperse dyestuff composition are good in high-temperature resistance, so that the disperse dyestuff composition is suitable for high-temperature dyeing.
Description
Technical field
The present invention relates to a kind of poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dyes group
Compound, belongs to fabrics printing and dyeing technical field.
Background technology
With the fast development of scientific and technological progress and social economy, the protection pay attention to day by day to ecological environment.In weaving neck
Domain, biotechnology, digital technology, automatic control technology, waterless staining technique are used for developing high-performance, high added value spinning
Knit product, on the one hand realize green from raw material to the course of processing, low-carbon (LC) and sustainable development, on the other hand realize textile product
Ecology.The fiber with biomass as raw material for the exploitation, particularly biomass synthetic fibers become focus in recent years, from resource
All meet the trend of social development with environment two aspect, on the one hand realize, to petrochemical material substitution of resources, reducing to petroleum resources
Depend on unduly, on the other hand realize chemical industry machining process route is substituted, reduce production process and final garbage to environment
Impact.
Poly terephthalic acid 1,3-PD ester (polytrimethylene terephthalate, ptt) is to continue 50 years
For polyethylene terephthalate (pet) industrialization and real after the polybutylene terephthalate seventies (pbt) industrialization
The polyester material of the become fibre of existing commercial scale exploitation.It overcomes the rigidity of pet fiber and the flexibility of pbt fiber, has concurrently poly-
Ester and the advantage of Fypro, have excellent elastic recovery, bulkiness, chromatophilia, inherent pollution resistance, antistatic behaviour
The features such as with good color fastness.With bio-based ptt composite fibre as raw material, design and develop with different-style feature and function
Property bio-based ptt composite fibre take and household series textile, deep processing is carried out by the dyeing and finishing technique of environmental protection, exploitation is high attached
The great market development potential of value added fabric, applies in biology herein by newly developed in recent years " non-evaporating wash anhydrous printing technology "
In the exploitation of base ptt fabric, Discussion on Technology is carried out to related process main points, be the environmental protection dyeing and finishing processing skill of bio-based ptt fabric
Art provides reference.
Content of the invention
It is an object of the present invention to provide a kind of poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique dispersion
Dye composite.
For reaching above-mentioned purpose, the technical solution used in the present invention is: a kind of poly terephthalic acid 1,3-PD ester face
Material free steam cleaning printing technique disperse dye composition, described disperse dye composition includes the material of following masses percentage ratio:
High temperature resistant disperse dyes 20 ~ 30%;
Maleic anhydride-taurine-Acrylamide Sodium-Allylsulfonate-Copolymer 5 ~ 10%;
Carboxy methylation sodium lignin sulfonate 5 ~ 15%;
Dodecylbenzene sodium sulfonate 5 ~ 15%;
Sodium polyacrylate 5 ~ 15%;
Water surplus.
Preferably technical scheme is: described high temperature resistant disperse dyes are selected from disperse yellow 30#, Red 167 #, disperse blue
291:1, disperse violet 93#, disperse orange 288#, Disperse Blue-79 #.
Because technique scheme is used, the present invention compared with prior art has following advantages and an effect:
The resistance to elevated temperatures of the component of the present invention is good so that disperse dye composition is suitable for high-temperature dyeing.
Specific embodiment
With reference to embodiment, the invention will be further described:
Embodiment one: poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition.
A kind of poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition, described point
Scattered dye composite includes the material of following masses percentage ratio:
High temperature resistant disperse dyes 20%;
Maleic anhydride-taurine-Acrylamide Sodium-Allylsulfonate-Copolymer 8%;
Carboxy methylation sodium lignin sulfonate 10%;
Dodecylbenzene sodium sulfonate 10%;
Sodium polyacrylate 10%;
Water 42%.
Described high temperature resistant disperse dyes are disperse violet 93#.
The preparation method of maleic anhydride-taurine-Acrylamide Sodium-Allylsulfonate-Copolymer may is that in band stirring
It is initially charged 120ml hexamethylene/emulsifying agent span in 1000 ml four-necked bottles of device, Dropping funnel, thermometer and reflux condensing tube
80 and tween 80 each 50 ml, are subsequently adding a certain proportion of maleic anhydride and taurine, are warming up to 80 DEG C, stirring is allowed to
After dissolving, fully reaction 50 min, be respectively dropped into a certain proportion of acrylamide with two Dropping funnels, sodium allylsulfonate and
The mixed liquor of water and a small amount of potassium peroxydisulfate are dissolved in the solution of water, 85 DEG C of controlling reaction temperature, drip off, then react 2h then after 1h
Condensing tube is changed into distilling apparatus, steams hexamethylene-water azeotropic mixture, reclaim.Cooling discharging, then with atent solvent by emulsifying agent
Wash off, obtain copolymer.
Embodiment two: poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition
A kind of poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition, described dispersion dye
Feed composition includes the material of following masses percentage ratio:
High temperature resistant disperse dyes 26%;
Maleic anhydride-taurine-Acrylamide Sodium-Allylsulfonate-Copolymer 10%;
Carboxy methylation sodium lignin sulfonate 7%;
Dodecylbenzene sodium sulfonate 7%;
Sodium polyacrylate 8%;
Water 42%.
Described high temperature resistant disperse dyes are to disperse the black mixing system for disperse blue 291:1, disperse violet 93# and disperse orange 288#
Product.
Embodiment three: poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition
A kind of poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition, described dispersion dye
Feed composition includes the material of following masses percentage ratio:
High temperature resistant disperse dyes 22%;
Maleic anhydride-taurine-Acrylamide Sodium-Allylsulfonate-Copolymer 8%;
Carboxy methylation sodium lignin sulfonate 8%;
Dodecylbenzene sodium sulfonate 5%;
Sodium polyacrylate 5%;
Water 52%.
The mixture that described high temperature resistant disperse dyes Red 167 # and Disperse Blue-79 # is constituted according to the mass ratio of 1:1.
Above-described embodiment only technology design to illustrate the invention and feature, its object is to allow person skilled in the art
Scholar will appreciate that present disclosure and implements according to this, can not be limited the scope of the invention with this.All according to the present invention
Equivalence changes or modification that spirit is made, all should be included within the scope of the present invention.
Claims (2)
1. a kind of poly terephthalic acid 1,3-PD ester fabric free steam cleaning printing technique disperse dye composition, its feature exists
Include the material of following masses percentage ratio in: described disperse dye composition:
High temperature resistant disperse dyes 20 ~ 30%;
Maleic anhydride-taurine-Acrylamide Sodium-Allylsulfonate-Copolymer 5 ~ 10%;
Carboxy methylation sodium lignin sulfonate 5 ~ 15%;
Dodecylbenzene sodium sulfonate 5 ~ 15%;
Sodium polyacrylate 5 ~ 15%;
Water surplus.
2. poly terephthalic acid 1,3- propylene glycol ester fabric free steam cleaning printing technique disperse dyes according to claim 1
Compositionss it is characterised in that: described high temperature resistant disperse dyes be selected from disperse yellow 30#, Red 167 #, disperse blue 291:1, dispersion
Purple 93#, disperse orange 288#, Disperse Blue-79 #.
Priority Applications (1)
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CN201610744260.9A CN106351032A (en) | 2016-08-29 | 2016-08-29 | Disperse dyestuff composition for steaming-washing-free printing process for polybutylene terephthalate 1,3-propylene glycol ester fabric |
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CN201610744260.9A CN106351032A (en) | 2016-08-29 | 2016-08-29 | Disperse dyestuff composition for steaming-washing-free printing process for polybutylene terephthalate 1,3-propylene glycol ester fabric |
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CN106351032A true CN106351032A (en) | 2017-01-25 |
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CN201610744260.9A Pending CN106351032A (en) | 2016-08-29 | 2016-08-29 | Disperse dyestuff composition for steaming-washing-free printing process for polybutylene terephthalate 1,3-propylene glycol ester fabric |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115182176A (en) * | 2022-07-26 | 2022-10-14 | 浙江真爱时尚家居有限公司 | Preparation method of printing and dyeing wash-free Raschel blanket |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101899784A (en) * | 2010-07-27 | 2010-12-01 | 苏州大学 | Steam-cleaning free printing process for disperse dye |
CN102493227A (en) * | 2011-12-14 | 2012-06-13 | 上海市毛麻纺织科学技术研究所 | Steaming-and-washing-free printing paste, and novel steaming-and-washing-free printing process |
-
2016
- 2016-08-29 CN CN201610744260.9A patent/CN106351032A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101899784A (en) * | 2010-07-27 | 2010-12-01 | 苏州大学 | Steam-cleaning free printing process for disperse dye |
CN102493227A (en) * | 2011-12-14 | 2012-06-13 | 上海市毛麻纺织科学技术研究所 | Steaming-and-washing-free printing paste, and novel steaming-and-washing-free printing process |
Non-Patent Citations (2)
Title |
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闫海刚等: "MA-TA-AA-AM-SAS共聚物的反相乳液合成及其性能", 《应用化工 》 * |
闫海刚等: "一种新型阻垢分散剂的反相乳液聚合及性能", 《化工时刊》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115182176A (en) * | 2022-07-26 | 2022-10-14 | 浙江真爱时尚家居有限公司 | Preparation method of printing and dyeing wash-free Raschel blanket |
CN115182176B (en) * | 2022-07-26 | 2024-03-01 | 浙江真爱时尚家居有限公司 | Preparation method of printing and dyeing washing-free raschel blanket |
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