CN105887515B - A kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric - Google Patents

A kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric Download PDF

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Publication number
CN105887515B
CN105887515B CN201610428281.XA CN201610428281A CN105887515B CN 105887515 B CN105887515 B CN 105887515B CN 201610428281 A CN201610428281 A CN 201610428281A CN 105887515 B CN105887515 B CN 105887515B
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China
Prior art keywords
polyamide fibre
fibers
printing method
face fabric
cotton blended
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CN201610428281.XA
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Chinese (zh)
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CN105887515A (en
Inventor
郝新敏
鞠景堂
赵鹏程
严欣宁
倪成涛
仇凯
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Liaoning Sunichem Co Ltd
Best Fiber Technology (dandong) Co Ltd
Quartermaster Research Institute of General Logistics Department of CPLA
Original Assignee
Liaoning Sunichem Co Ltd
Best Fiber Technology (dandong) Co Ltd
Quartermaster Research Institute of General Logistics Department of CPLA
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Application filed by Liaoning Sunichem Co Ltd, Best Fiber Technology (dandong) Co Ltd, Quartermaster Research Institute of General Logistics Department of CPLA filed Critical Liaoning Sunichem Co Ltd
Priority to CN201610428281.XA priority Critical patent/CN105887515B/en
Publication of CN105887515A publication Critical patent/CN105887515A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/628Compounds containing nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D06P1/6497Amides of di- or polyamines; Acylated polyamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/008Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8219Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups

Abstract

The invention discloses a kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric.The printing method includes the following steps:Stamp is carried out to 56 fibers of polyamide fibre/cotton blended spinning face fabric using reactive dye;56 fibers of the polyamide fibre/cotton blended spinning face fabric is 56 fiber of polyamide fibre and the blended yarn weaved fabric of cotton fiber.The printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric of the present invention, has the following advantages that:56 fiber of polyamide fibre of the present invention is with cotton blended fabric one-step method stamp by the way of Graft versus host disease, have the advantages that to save the energy, environmental protection, printing method technique of the present invention is simple, and due to the particularity of 56 fiber of polyamide fibre, Graft versus host disease can reach two kinds of fibers and obtain the consistent effect of color.

Description

A kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric
Technical field
The present invention relates to a kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric.
Background technology
Nylon fibre is the first synthetic fibers occurred in the world, and the generally common kind of polyamide fibre has polyamide fibre -6 to gather oneself Lactams, nylon-66 are polymerized for hexamethylene diamine with adipic acid, and polyamide fibre 56 is a kind of new Fypro, with polyamide fibre 66 Different using petroleum, the raw material that it is used is biological raw material, by biological engineering method from each kind of starch and stalk fibre Fermentation prepares pentanediamine in element, due to of large quantities, inexpensive, therefore can replace hexamethylene diamine.Bio-based fiber has green, environment The good characteristics such as friendly, raw material is renewable and biodegradable, help to solve what current global economy social development was faced Serious resource and energy shortage, and the problems such as environmental pollution.
Polyamide fibre 56 has many excellent characteristics, and intensity is close to polyamide fibre 66, and higher than terylene, density is less than terylene;Hygroscopicity Height, antistatic property are good;Pliability is close to wool;Glass transition temperature is less than polyamide fibre 66,56 crystallinity of polyamide fibre be relatively lower than polyamide fibre- 66,56 glass transition temperature of polyamide fibre is 46 DEG C, far below terylene, it is ensured that lower temperature resistance under cold conditions;Softness, wearability are good Deng.
Various fibers, whether natural fiber or all respective merits and demerits of staple fibre and synthetic fibers.Generally Natural fiber such as cotton, wool hygroscopicity is all relatively good, comfortable and easy to wear, and the general wearability of synthetic fibers is good, and strength is high, but moisture absorption Property is poor, and gas permeability is bad.Various fibers, such as fiber of natural fiber, artificial fiber and synthesis carries out different proportion and mixes Spin, it is possible to fully with various fibers the characteristics of, learn from other's strong points to offset one's weaknesses, strengthen the wearability of fabric, 56 fibers of polyamide fibre/cotton is pure mixed The printing method of textile fabric has no the disclosure of correlation technique.
The content of the invention
The object of the present invention is to provide a kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric, stamp side of the invention Method is by the way of Graft versus host disease, it then follows saves the energy, environmental protection and the simple principle of technique.
A kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric provided by the present invention, includes the following steps:
Stamp is carried out to 56 fibers of polyamide fibre/cotton blended spinning face fabric using reactive dye;
56 fibers of the polyamide fibre/cotton blended spinning face fabric is 56 fiber of polyamide fibre and the blended yarn weaved fabric of cotton fiber.
In above-mentioned printing method, the stamp includes the following steps:
(1) printing paste is prepared, the composition of the printing paste of every 100 mass parts is as follows:
5 parts of thickener, 5 parts of urea, 1 part of reserve salt, 2 parts of sodium acid carbonate, and the water of surplus;
The reserve salt be between nitro paratoluenesulfonic acid sodium salt;
(2) reactive dye are added into the printing paste, to 56 fibers of polyamide fibre/cotton blend face after stirring evenly Material carries out stamp, then drying and evaporates successively and realizes stamp process.
In above-mentioned printing method, thickener FS-80E may be selected in the thickener, can be had by Liaoning fixed star fine chemistry industry Limit company provides, and be more carboxyl high molecular polymers, has good level-dyeing property, armful water-based good, does not carry on the back the characteristics of oozing, make the figure of printing Case profile is more fine while has the characteristics that desizing is easy, soft.
In above-mentioned printing method, the selection of the reactive dye is most important, because reactive dye color fixing is in alkalescence Under the conditions of carry out, so selection reactive dyes with double active group, processes such as Type B reactive dye or p-type reactive dye, are conducive to activity Bonding reaction occurs under the conditions of low alkali with cotton fiber and 56 fiber of polyamide fibre for dyestuff, the p-type reactive dye concretely P-6B Red reactive dye.
In above-mentioned printing method, the addition of the reactive dye can be the 0.1%~8% of the printing paste quality, Concretely 4%.
In above-mentioned printing method, the temperature of the drying can be 100 DEG C~110 DEG C, and the time of the drying can be 2 points Clock~4 minute, can specifically dry 3 minutes under conditions of 110 DEG C;
The temperature evaporated can be 102 DEG C~105 DEG C, and the time evaporated can be 8~20 minutes, specifically can be Evaporated under conditions of 105 DEG C 15 minutes.
The printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric of the present invention, has the following advantages that:56 fiber of polyamide fibre of the present invention with Cotton blended fabric one-step method stamp has the advantages that to save the energy, environmental protection, printing method of the present invention by the way of Graft versus host disease Technique is simple, and due to the particularity of 56 fiber of polyamide fibre, Graft versus host disease can reach two kinds of fibers and obtain the consistent effect of color.
Embodiment
Experimental method used in following embodiments is conventional method unless otherwise specified.
The materials, reagents and the like used in the following examples, is commercially available unless otherwise specified.
Thickener FS-80 used in following embodiments is purchased from Liaoning Sunichem Co., Ltd..
The red reactive dye of P-6B used are purchased from Hensel Mann in following embodiments.
Embodiment 1,56 fiber of polyamide fibre and cotton fiber blended fabric reactive dye Graft versus host disease
(1) printing paste is prepared, quality composition is as follows:
Thickener FS-80:5%, urea:5%, reservehao S (a nitro paratoluenesulfonic acid sodium salt):1%, sodium acid carbonate 2% And water:87%.
(2) the red reactive dye of P-6B are added into the printing paste of above-mentioned preparation, wherein, the addition of the red reactive dye of P-6B Measure as the 4% of printing paste quality, then stir evenly and Graft versus host disease is carried out to 56 fiber of polyamide fibre and cotton fiber blended fabric, then Drying (110 DEG C × 3 minutes), evaporate (105 DEG C × 15 minutes) and washing post processing.
The stamp items color fastness index of the present embodiment blended fabric is as shown in table 1.
Every fastness reaches requirement after stamp it can be seen from data in table 1.
1 embodiment polyamide fibre of table, 56 fiber and cotton blended fabric stamp items color fastness index ratio
Name of an article project Embodiment 1
Dry friction color fastness 3.5
Wet friction color fastness 3.5
Color fastness to water 5
Color fastness to chlorine 3.5
Color fastness to sea water 3.5
Alkaline-resisting PERSPIRATION COLOR FASTNESS 3.5
Colour fasteness to sunlight 5.5
Fastness to soaping 3.5
The assay method of each index is as follows in table 1:
1st, soaping fastness is tested by national standard GB/T3921.4-1997.
2nd, dry and wet crock fastness is performed by GB/3920.
3rd, resistance to (alkali) PERSPIRATION COLOR FASTNESS presses ISO105-E04:2008 perform.
4th, chlorine-resistant drift color fastness presses ISO105E03:2010 perform.
5th, color fastness to sea water is performed by AATCC106-2002.
6th, color fastness to water presses JIS (37 ± 2) DEG C × 4h.
7th, colour fasteness to sunlight is performed by ISO105B02-1994.

Claims (3)

1. a kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric, includes the following steps:
Stamp is carried out to 56 fibers of polyamide fibre/cotton blended spinning face fabric using reactive dye;
56 fibers of the polyamide fibre/cotton blended spinning face fabric is 56 fiber of polyamide fibre and the blended yarn weaved fabric of cotton fiber;
The stamp includes the following steps:
(1) printing paste is prepared, the composition of the printing paste of every 100 mass parts is as follows:
5 parts of thickener, 5 parts of urea, 1 part of reserve salt, 2 parts of sodium acid carbonate, and the water of surplus;
The reserve salt be between nitro paratoluenesulfonic acid sodium salt;
The thickener is thickener FS-80E;
(2) reactive dye are added into the printing paste, after stirring evenly to 56 fibers of the polyamide fibre/cotton blended spinning face fabric into Row stamp, then drying and evaporates successively and realizes stamp process;
The reactive dye are Type B reactive dye or p-type reactive dye;
The addition of the reactive dye is the 0.1%~8% of the printing paste quality.
2. printing method according to claim 1, it is characterised in that:The temperature of the drying is 100 DEG C~110 DEG C, institute The time for stating drying is 2 minutes~4 minutes.
3. printing method according to claim 1 or 2, it is characterised in that:The temperature evaporated is 102 DEG C~105 DEG C, The time evaporated is 8~20 minutes.
CN201610428281.XA 2016-06-17 2016-06-17 A kind of printing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric Active CN105887515B (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112011868A (en) * 2019-05-28 2020-12-01 上海凯赛生物技术股份有限公司 Polyamide fiber and cotton blended yarn and preparation method and application thereof
CN111778736A (en) * 2020-01-09 2020-10-16 军事科学院系统工程研究院军需工程技术研究所 Acid low-temperature quick printing method for chinlon 56 fabric or non-woven fabric
CN111826977A (en) * 2020-01-22 2020-10-27 军事科学院系统工程研究院军需工程技术研究所 Acid printing method for chinlon 56 and protein fiber blended fabric
CN111172785A (en) * 2020-02-04 2020-05-19 军事科学院系统工程研究院军需工程技术研究所 Alkaline printing method for nylon 56 and cellulose fiber blended fabric
CN111235911A (en) * 2020-02-07 2020-06-05 军事科学院系统工程研究院军需工程技术研究所 Alkaline rapid printing method for chinlon 56 fiber and fabric

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* Cited by examiner, † Cited by third party
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CN101597868B (en) * 2009-06-05 2011-10-12 浙江嘉欣兴昌印染有限公司 Brocade fabric active and neutral dye combination catalytic fixation printing technique
CN103572580B (en) * 2012-08-07 2016-01-13 中国人民解放军总后勤部军需装备研究所 A kind of polyamide fibre or polyamide fibre/cotton blending PRINTED FABRIC and preparation method thereof
CN102936855A (en) * 2012-11-19 2013-02-20 湖州金塔地纺织厂 Textile printing method

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