CN106349972A - Waterproof bamboo batten woven adhesive and preparation method thereof - Google Patents
Waterproof bamboo batten woven adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106349972A CN106349972A CN201610783633.3A CN201610783633A CN106349972A CN 106349972 A CN106349972 A CN 106349972A CN 201610783633 A CN201610783633 A CN 201610783633A CN 106349972 A CN106349972 A CN 106349972A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive
- waterproof
- bamboo cane
- waterproof bamboo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a waterproof bamboo batten woven adhesive and a preparation method thereof, and relates to the technical field of adhesives. The waterproof bamboo batten woven adhesive is prepared from the following raw material components in parts by weight: 100 to 120 parts of corn starch, 10 to 20 parts of coking coal oil, 10 to 20 parts of metallic soap, 10 to 20 parts of alkanolamide, 6 to 10 parts of a curing agent, 30 to 50 parts of a filler, 5 to 9 parts of a modifier and 90 to 110 parts of water. The preparation method comprises the following steps: (1) adding the corn starch, the coking coal oil, the metallic soup, the alkanolamide and the water into a stirrer in sequence for full stirring and glue mixing; (2) adding; the filler, and then stirring until no air masses exist in the raw materials in the stirrer; (3) adding the curing agent, stirring for 5 to 10 minutes, and then stewing for 15 minutes; (4) finally adding the modifier for stirring. The waterproof bamboo batten woven adhesive can be high in thermosetting property, high in viscosity, high in intensity, high in staying power, not liable to go bad and good in waterproofing effect, and a plywood is long in service life and not liable to crack.
Description
Technical field:
The present invention relates to glue technical field, specifically a kind of waterproof bamboo cane braiding adhesive and preparation method thereof.
Background technology:
Typically can carry out some special process to bamboo cane before bamboo cane baskets craft, generally comprise softening, strengthen
Toughness, peeling etc. are processed, and the adhesive that the adhesive of existing bamboo cane splicing is general is fairly simple, and adhesive caking property is relatively
Difference, the process of setting time is longer, and viscosity is not enough, and especially when temperature is higher, viscosity substantially reduces, and is unfavorable for the molding of plywood,
Intensity after molding is not enough, and the effect of adhesive waterproof is poor, and the product produced easily ftractures after rainwater, leads to service life
Low.
Content of the invention:
The technical problem to be solved is to provide a kind of thermosetting good, and viscosity is high, and intensity is high, good water-proof effect
Waterproof bamboo cane braiding adhesive and preparation method thereof.
The technical problem solving is adopted following technical scheme:
A kind of waterproof bamboo cane braiding adhesive it is characterised in that: include following raw material component:
Described firming agent includes by weight, 6~10 parts of potassium peroxydisulfate, 5~7 parts of vinyl acetate and hexamethylenetetramine
1~2 part.
Described filler includes by weight, 5~8 parts of bamboo powder, 2~4 parts of conch meal and heavy dibutyl phthalate 2
~4 parts.
Described modifying agent includes by weight, 5~10 parts of tannic extract, 3~8 parts of gelatin and 1~2 part of Quercetin.
A kind of waterproof bamboo cane weave adhesive preparation method it is characterised in that: comprise the following steps,
1) corn starch, bentonite, metallic soap, disodium hydrogen phosphate and water are added sequentially in blender fully be stirred
Mix impregnation;
2) add filler stirring, to there is no air mass in blender raw material;
3) add and stir 5~10 minutes under firming agent vacuum condition, then stand 15 minutes again;Solidification effect is good.
4) finally add modifying agent to be stirred.
Described filler is to be initially charged heavy dibutyl phthalate during adding, and adds bamboo powder, finally
Add conch meal.
No more than 40 DEG C of the temperature of operation in described step.
In instant component raw material, production department's adhesive has good waterproof effect, and the adhesive produced has very high
Gumminess, when hot-forming gumminess reduce very little, the firming agent in the present invention is so that adhesive has more preferable heat
Gu effect, the speed of thermosetting is fast;And the intensity of the filler of the present invention is high, during preparation and later stage hot-forming mistake
More degeneration will not be produced in journey, with the lasting efficacy of intensity, and modifying agent in the present invention, can be also added, can be further
Increase its viscosity, adhesive can be protected to be not easy oxidized simultaneously.
The invention has the beneficial effects as follows: it is good that the present invention can have thermosetting, and viscosity is high, and intensity is high, and endurance is good, does not allow
Perishable, good water-proof effect, long service life is it is not easy to ftracture.
Specific embodiment:
In order that technological means, creation characteristic, reached purpose and effect that the present invention realizes are easy to understand, tie below
Close instantiation, the present invention is expanded on further.
Embodiment one
A kind of waterproof bamboo cane weaves adhesive, including following raw material component:
Described firming agent includes by weight, 6 parts of potassium peroxydisulfate, 5 parts of vinyl acetate and 1 part of hexamethylenetetramine.
Firming agent includes by weight, 6 parts of potassium peroxydisulfate, 2 parts of oxalic acid, 2 parts of methyl salicylate and hexamethylenetetramine 1
Part.
Filler includes by weight, 5 parts of bamboo powder, 2 parts of conch meal and 2 parts of heavy dibutyl phthalate.
Modifying agent includes by weight, 5 parts of tannic extract, 3 parts of gelatin and 1 part of Quercetin.
A kind of waterproof bamboo cane weaves the preparation method of adhesive, comprises the following steps,
1) corn starch, bentonite, metallic soap, disodium hydrogen phosphate and water are added sequentially in blender fully be stirred
Mix impregnation;
2) add filler stirring, to there is no air mass in blender raw material;
3) add and stir 5~10 minutes under firming agent vacuum condition, then stand 15 minutes again;
4) finally add modifying agent to be stirred.
Filler is to be initially charged heavy dibutyl phthalate during adding, and adds bamboo powder, is eventually adding shellfish
Shell powder.Do not allow perishable.
No more than 40 DEG C of the temperature of operation in step.
Embodiment two
A kind of waterproof bamboo cane weaves adhesive, including following raw material component:
Firming agent includes by weight, 8 parts of potassium peroxydisulfate, 6 parts of vinyl acetate and 1.5 parts of hexamethylenetetramine.
Filler includes by weight, 7 parts of bamboo powder, 3 parts of conch meal and 3 parts of heavy dibutyl phthalate.
Modifying agent includes by weight, 8 parts of tannic extract, 6 parts of gelatin and 1.5 parts of Quercetin.
A kind of waterproof bamboo cane weaves the preparation method of adhesive, comprises the following steps,
1) corn starch, bentonite, metallic soap, disodium hydrogen phosphate and water are added sequentially in blender fully be stirred
Mix impregnation;
2) add filler stirring, to there is no air mass in blender raw material;
3) add and stir 5~10 minutes under firming agent vacuum condition, then stand 15 minutes again;
4) finally add modifying agent to be stirred.
Filler is to be initially charged heavy dibutyl phthalate during adding, and adds bamboo powder, is eventually adding shellfish
Shell powder.Do not allow perishable.
No more than 40 DEG C of the temperature of operation in step.
Embodiment three
A kind of waterproof bamboo cane weaves adhesive, including following raw material component:
Firming agent includes by weight, 10 parts of potassium peroxydisulfate, 7 parts of vinyl acetate and 2 parts of hexamethylenetetramine.
Filler includes by weight, 8 parts of bamboo powder, 4 parts of conch meal and 4 parts of heavy dibutyl phthalate.
Modifying agent includes by weight, 10 parts of tannic extract, 8 parts of gelatin and 2 parts of Quercetin.
A kind of waterproof bamboo cane weaves the preparation method of adhesive, comprises the following steps,
1) corn starch, bentonite, metallic soap, disodium hydrogen phosphate and water are added sequentially in blender fully be stirred
Mix impregnation;
2) add filler stirring, to there is no air mass in blender raw material;
3) add and stir 5~10 minutes under firming agent vacuum condition, then stand 15 minutes again;
4) finally add modifying agent to be stirred.
Filler is to be initially charged heavy dibutyl phthalate during adding, and adds bamboo powder, is eventually adding shellfish
Shell powder.Do not allow perishable.
No more than 40 DEG C of the temperature of operation in step.
Ultimate principle and principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry
, it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description is originally for personnel
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and its
Equivalent thereof.
Claims (7)
1. a kind of waterproof bamboo cane braiding adhesive it is characterised in that: include following raw material component:
2. a kind of waterproof bamboo cane braiding adhesive according to claim 1 it is characterised in that: described firming agent is by weight
Part includes, 6~10 parts of potassium peroxydisulfate, 5~7 parts of vinyl acetate and 1~2 part of hexamethylenetetramine.
3. a kind of waterproof bamboo cane braiding adhesive according to claim 1 it is characterised in that: described filler is by weight
Including 5~8 parts of bamboo powder, 2~4 parts of conch meal and 2~4 parts of heavy dibutyl phthalate.
4. a kind of waterproof bamboo cane braiding adhesive according to claim 1 it is characterised in that: described modifying agent is by weight
Part includes, 5~10 parts of tannic extract, 3~8 parts of gelatin and 1~2 part of Quercetin.
5. a kind of waterproof bamboo cane according to claim 1,2,3 or 4 weave adhesive preparation method it is characterised in that:
Comprise the following steps,
1) corn starch, bentonite, metallic soap, disodium hydrogen phosphate and water are added sequentially in blender carry out being sufficiently stirred for adjusting
Glue;
2) add filler stirring, to there is no air mass in blender raw material;
3) add and stir 5~10 minutes under firming agent vacuum condition, then stand 15 minutes again;
4) finally add modifying agent to be stirred.
6. a kind of waterproof bamboo cane according to claim 5 weave adhesive preparation method it is characterised in that: described fills out
Material is to be initially charged heavy dibutyl phthalate during adding, and adds bamboo powder, is eventually adding conch meal.
7. a kind of waterproof bamboo cane according to claim 5 weave adhesive preparation method it is characterised in that: described step
Suddenly no more than 40 DEG C of the temperature of middle operation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610783633.3A CN106349972A (en) | 2016-08-30 | 2016-08-30 | Waterproof bamboo batten woven adhesive and preparation method thereof |
Applications Claiming Priority (1)
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CN201610783633.3A CN106349972A (en) | 2016-08-30 | 2016-08-30 | Waterproof bamboo batten woven adhesive and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN106349972A true CN106349972A (en) | 2017-01-25 |
Family
ID=57857624
Family Applications (1)
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CN201610783633.3A Pending CN106349972A (en) | 2016-08-30 | 2016-08-30 | Waterproof bamboo batten woven adhesive and preparation method thereof |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102850957A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Preparation method for wood adhesive with starch as raw material |
CN105295793A (en) * | 2015-10-29 | 2016-02-03 | 宁贻伟 | Long-acting epoxy glue adhesive |
-
2016
- 2016-08-30 CN CN201610783633.3A patent/CN106349972A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102850957A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Preparation method for wood adhesive with starch as raw material |
CN105295793A (en) * | 2015-10-29 | 2016-02-03 | 宁贻伟 | Long-acting epoxy glue adhesive |
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Application publication date: 20170125 |
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