CN106348660B - A kind of marble waste residue material processing method - Google Patents
A kind of marble waste residue material processing method Download PDFInfo
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- CN106348660B CN106348660B CN201610779300.3A CN201610779300A CN106348660B CN 106348660 B CN106348660 B CN 106348660B CN 201610779300 A CN201610779300 A CN 201610779300A CN 106348660 B CN106348660 B CN 106348660B
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- marble
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- modified
- dali
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/026—Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a kind of marble waste residue material processing methods, belong to processing of stone and consolidate gurry technical field of comprehensive utilization.The method of the present invention includes the step of have:(1) sieving and grading;(2) raw material is prepared;(3) plank is made.It is raw material that the present invention, which utilizes the waste slag charge generated in marble process, through being classified post-modification processing, with other Raw material processings at artificial marble sheet material;The artificial marble sheet material that the present invention makes has the characteristics that cost of material is low, is conveniently easy to get, technique is unique, good decorating effect, and compared with natural marble plate, appearance tactile impression has the advantages such as antibacterial, deodorization, sun-proof without marked difference.
Description
Technical field
The invention belongs to processing of stone to consolidate gurry technical field of comprehensive utilization, specifically a kind of marble waste residue material processing side
Method.
Background technology
With the promotion of people's living standard, the improvement of living conditions, interior decoration industry is grown rapidly, decoration material
Dosage is very big, wherein stone material be it is a kind of most generally use, one of most basic building materials are widely used in ground, metope and table top
Mat formation.Common stone material is broadly divided into lithotome and artificial stone currently on the market.Lithotome refers to from natural rock mass
In it is mined and processed at blocky or board-like material general name.Natural stone used in construction and decoration mainly has granite
With two big kinds of marble.
In marble process, saw blade, cutting, grinding process all generate a large amount of solid waste-waste residues.With
It marble industry and continues to develop and grow, pile up like a mountain for generated waste, not only occupies a large amount of soils, and dust is dirty
Dye and its people's lives are affected to the seriously polluted of water source.Restrict the sustainable economic development of this area simultaneously.It controls
It is marble processing area of concentration sustainable economic development that reason, which is polluted, optimized the environment, economizing on resources, is transformed mode of economic growth
Important measures.
Invention content
The technical problem to be solved by the present invention is to be directed to prior art Shortcomings, a kind of marble waste residue material is provided and is added
Work method.
In order to achieve the above object, the present invention uses following technical scheme.
A kind of marble waste residue material processing method, includes the following steps:
(1) sieving and grading
The waste residue powder generated in marble process is spread out, is dried, is sieved for the first time, is divided into grain size more than 5mm's
The Dali stone sand three-level of the marble powder of Dali rock ballast, grain size less than 1mm, grain size 1-5mm, grain size 1- is ground by Dali ballast
The Dali stone sand of 5mm carries out regrading, and gained Dali stone sand merges with the Dali stone sand sieved for the first time, regrading process
The marble powder of middle generation merges with the marble powder sieved for the first time, carries out regrading to combined marble powder, obtains grain
Diameter is more than 0.1mm, the marble middling flour less than 1mm, the marble microlith powder no more than 0.1mm, and marble microlith powder is used
Flour mill is milled to 200-600 mesh, obtains the ultra-fine mountain flour of marble of 200-600 mesh;
(2) raw material is prepared
1. 10-20 parts of the Dali stone sand 300-500 part titanate coupling agents by weight, (1) step handled
It is modified processing, obtains modified Dali stone sand, it is spare;100-300 parts of (1) marble microlith powder that step is handled with
1-10 parts of mixings of 200-300 mesh diatomite are modified processing for 5-10 parts with silane coupling agent, obtain modified marble microlith
Powder, it is spare;Ultra-fine mountain flour 50-200 parts of (1) marble that step is handled and 1-5 parts of mixings of grain size 40-60nm zinc oxide,
It is modified processing for 1-2 parts with silane coupling agent, obtains the ultra-fine mountain flour of modified marble, it is spare;
2. by weight, extracting epoxy resin 45-65 parts, 35-55 parts of organic silicon modified polyurethane resin, triethanolamine 1-
2 parts are placed in blender, stir 10-25min, then take step (2)-modification Dali stone sand 1., modified marble microlith powder, change
Property the ultra-fine mountain flour of marble put into blender, stir 2-5min, add 0.1-0.5 parts of carboxymethyl cellulose, hydrogenated rosin
0.5-1.5 parts, 1-2 parts of polyamide stir 15-25min;
(3) plank is made
The slurry being stirred is poured into framed inner surface to be coated in the mold of releasing agent, 20- is made in high pressure vacuum molding
30mm thickness artificial marble sheet materials are placed into 4-5h in the environment of 100-120 DEG C of constant temperature again after demoulding, be sent into marble and throw automatically
Surface polishing, cutting are carried out in ray machine.
The advantageous effects of the present invention:It is original that the present invention, which utilizes the waste slag charge generated in marble process,
Material, through being classified post-modification processing, with other Raw material processings at artificial marble sheet material;The artificial marble sheet material that the present invention makes
Have the characteristics that cost of material is low, be conveniently easy to get, technique uniqueness, good decorating effect, compared with natural marble plate, appearance matter
Sense has the advantages such as antibacterial, deodorization, sun-proof without marked difference.
Specific implementation mode
With reference to embodiment detailed elaboration further made to technical scheme of the present invention, but the not all present invention in pairs
Range limits.
Embodiment 1
A kind of marble waste residue material processing method, includes the following steps:
(1) sieving and grading
The waste residue powder generated in marble process is spread out, is dried, is sieved for the first time, is divided into grain size more than 5mm's
The Dali stone sand three-level of the marble powder of Dali rock ballast, grain size less than 1mm, grain size 1-5mm, grain size 1- is ground by Dali ballast
The Dali stone sand of 5mm carries out regrading, and gained Dali stone sand merges with the Dali stone sand sieved for the first time, regrading process
The marble powder of middle generation merges with the marble powder sieved for the first time, carries out regrading to combined marble powder, obtains grain
Diameter is more than 0.1mm, the marble middling flour less than 1mm, the marble microlith powder no more than 0.1mm, and marble microlith powder is used
Flour mill is milled to 200 mesh, obtains the ultra-fine mountain flour of marble of 200 mesh;
(2) raw material is prepared
1. by weight, (1) 300 parts of Dali stone sand that step is handled is changed for 10 parts with titanate coupling agent
Property processing, obtain modified Dali stone sand, it is spare;(1) 100 parts of marble microlith powder and 200 mesh diatomite that step is handled
1 part of mixing is modified processing for 5 parts with silane coupling agent, obtains modified marble microlith powder, spare;(1) step is handled
50 parts of the ultra-fine mountain flour of marble arrived and 1 part of mixing of grain size 40nm zinc oxide, are modified processing for 1 part with silane coupling agent, obtain
It is spare to the ultra-fine mountain flour of modified marble;
2. by weight, 45 parts of extracting epoxy resin, 35 parts of organic silicon modified polyurethane resin, 1 part of triethanolamine are placed in
Blender stirs 10min, then take step (2)-modification Dali stone sand 1., modified marble microlith powder, modified marble be super
Microlith powder puts into blender, stirs 2min, adds 0.1 part of carboxymethyl cellulose, 0.5 part of hydrogenated rosin, polyamide 1
Part, stir 15min;
(3) plank is made
The slurry being stirred is poured into framed inner surface to be coated in the mold of releasing agent, 20mm is made in high pressure vacuum molding
Thick artificial marble sheet material is placed into 4h in the environment of 100 DEG C of constant temperature again after demoulding, be sent into marble automatic polishing machine and carry out
Surface polishes, cutting.
Embodiment 2
A kind of marble waste residue material processing method, includes the following steps:
(1) sieving and grading
The waste residue powder generated in marble process is spread out, is dried, is sieved for the first time, is divided into grain size more than 5mm's
The Dali stone sand three-level of the marble powder of Dali rock ballast, grain size less than 1mm, grain size 1-5mm, grain size 1- is ground by Dali ballast
The Dali stone sand of 5mm carries out regrading, and gained Dali stone sand merges with the Dali stone sand sieved for the first time, regrading process
The marble powder of middle generation merges with the marble powder sieved for the first time, carries out regrading to combined marble powder, obtains grain
Diameter is more than 0.1mm, the marble middling flour less than 1mm, the marble microlith powder no more than 0.1mm, and marble microlith powder is used
Flour mill is milled to 600 mesh, obtains the ultra-fine mountain flour of marble of 600 mesh;
(2) raw material is prepared
1. by weight, (1) 500 parts of Dali stone sand that step is handled is changed for 20 parts with titanate coupling agent
Property processing, obtain modified Dali stone sand, it is spare;(1) 300 parts of marble microlith powder and 300 mesh diatomite that step is handled
10 parts of mixings are modified processing for 10 parts with silane coupling agent, obtain modified marble microlith powder, spare;(1) step is handled
200 parts of the obtained ultra-fine mountain flour of marble and 5 parts of mixings of grain size 60nm zinc oxide, processing is modified for 2 parts with silane coupling agent,
The ultra-fine mountain flour of modified marble is obtained, it is spare;
2. by weight, 65 parts of extracting epoxy resin, 55 parts of organic silicon modified polyurethane resin, 2 parts of triethanolamine are placed in
Blender stirs 25min, then take step (2)-modification Dali stone sand 1., modified marble microlith powder, modified marble be super
Microlith powder puts into blender, stirs 5min, adds 0.5 part of carboxymethyl cellulose, 1.5 parts of hydrogenated rosin, polyamide 2
Part, stir 25min;
(3) plank is made
The slurry being stirred is poured into framed inner surface to be coated in the mold of releasing agent, 30mm is made in high pressure vacuum molding
Thick artificial marble sheet material is placed into 5h in the environment of 120 DEG C of constant temperature again after demoulding, be sent into marble automatic polishing machine and carry out
Surface polishes, cutting.
Embodiment 3
A kind of marble waste residue material processing method, includes the following steps:
(1) sieving and grading
The waste residue powder generated in marble process is spread out, is dried, is sieved for the first time, is divided into grain size more than 5mm's
The Dali stone sand three-level of the marble powder of Dali rock ballast, grain size less than 1mm, grain size 1-5mm, grain size 1- is ground by Dali ballast
The Dali stone sand of 5mm carries out regrading, and gained Dali stone sand merges with the Dali stone sand sieved for the first time, regrading process
The marble powder of middle generation merges with the marble powder sieved for the first time, carries out regrading to combined marble powder, obtains grain
Diameter is more than 0.1mm, the marble middling flour less than 1mm, the marble microlith powder no more than 0.1mm, and marble microlith powder is used
Flour mill is milled to 400 mesh, obtains the ultra-fine mountain flour of marble of 400 mesh;
(2) raw material is prepared
1. by weight, (1) 400 parts of Dali stone sand that step is handled is changed for 15 parts with titanate coupling agent
Property processing, obtain modified Dali stone sand, it is spare;(1) 200 parts of marble microlith powder and 250 mesh diatomite that step is handled
5.5 parts of mixings are modified processing for 7.5 parts with silane coupling agent, obtain modified marble microlith powder, spare;(1) step is located
150 parts obtained of the ultra-fine mountain flour of marble and 3 parts of mixings of grain size 50nm zinc oxide are managed, are modified for 1.5 parts with silane coupling agent
Processing obtains the ultra-fine mountain flour of modified marble, spare;
2. by weight, 55 parts of extracting epoxy resin, 45 parts of organic silicon modified polyurethane resin, 1.5 parts of triethanolamine are set
In blender, stir 17.5min, then take step (2)-modification Dali stone sand 1., modified marble microlith powder, modified Dali
The ultra-fine mountain flour of stone puts into blender, stirs 3.5min, adds 0.3 part of carboxymethyl cellulose, 1 part of hydrogenated rosin, polyamide resin
1.5 parts of fat stirs 20min;
(3) plank is made
The slurry being stirred is poured into framed inner surface to be coated in the mold of releasing agent, 25mm is made in high pressure vacuum molding
Thick artificial marble sheet material, is placed into 4.5h in the environment of 110 DEG C of constant temperature again after demoulding, be sent into marble automatic polishing machine into
Row surface polishes, cutting.
Claims (1)
1. a kind of marble waste residue material processing method, which is characterized in that include the following steps:
(1) sieving and grading
The waste residue powder generated in marble process is spread out, is dried, is sieved for the first time, the Dali that grain size is more than 5mm is divided into
The Dali stone sand three-level of the marble powder of rock ballast, grain size less than 1mm, grain size 1-5mm, grain size 1-5mm is ground by Dali ballast
Dali stone sand, carry out regrading, gained Dali stone sand merges with the Dali stone sand sieved for the first time, regrading production in the process
Raw marble powder merges with the marble powder sieved for the first time, carries out regrading to combined marble powder, it is big to obtain grain size
In 0.1mm, the marble middling flour less than 1mm, the marble microlith powder no more than 0.1mm, marble microlith powder is milled
Machine is milled to 200-600 mesh, obtains the ultra-fine mountain flour of marble of 200-600 mesh;
(2) raw material is prepared
1. by weight, (1) stone sand 300-500 parts of Dali that step is handled is carried out for 10-20 parts with titanate coupling agent
Modification obtains modified Dali stone sand, spare;(1) 100-300 parts of marble microlith powder and 200- that step is handled
300 1-10 parts of mesh diatomite mixings are modified processing for 5-10 parts with silane coupling agent, obtain modified marble microlith powder, standby
With;Ultra-fine mountain flour 50-200 parts of (1) marble that step is handled and 1-5 parts of mixings of grain size 40-60nm zinc oxide, use silicon
1-2 parts of alkane coupling agent is modified processing, obtains the ultra-fine mountain flour of modified marble, spare;
2. by weight, extracting epoxy resin 45-65 parts, 35-55 parts of organic silicon modified polyurethane resin, 1-2 parts of triethanolamine
Be placed in blender, stir 10-25min, then take step (2)-it is modification Dali stone sand 1., modified marble microlith powder, modified big
The ultra-fine mountain flour of reason stone puts into blender, stirs 2-5min, adds 0.1-0.5 parts of carboxymethyl cellulose, hydrogenated rosin 0.5-1.5
Part, 1-2 parts of polyamide stir 15-25min;
(3) plank is made
The slurry being stirred is poured into framed inner surface to be coated in the mold of releasing agent, it is thick that 20-30mm is made in high pressure vacuum molding
Artificial marble sheet material is placed into 4-5h in the environment of 100-120 DEG C of constant temperature again after demoulding, be sent into marble automatic polishing machine
Carry out surface polishing, cutting.
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CN201610779300.3A CN106348660B (en) | 2016-08-31 | 2016-08-31 | A kind of marble waste residue material processing method |
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CN106348660B true CN106348660B (en) | 2018-10-26 |
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Families Citing this family (5)
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CN107265916A (en) * | 2017-06-20 | 2017-10-20 | 合肥慧林建材有限公司 | A kind of marble leftover pieces reprocessing technique for road sheet material |
CN108940538A (en) * | 2018-08-21 | 2018-12-07 | 耒阳市百汇粉体有限公司 | A kind of production technology of marble superfine powder |
CN110563444B (en) * | 2019-08-19 | 2022-04-15 | 福建德胜新建材有限公司 | Comprehensive utilization method of Rouyuan red tailings |
CN113278306A (en) * | 2021-05-12 | 2021-08-20 | 广西科学院 | Microwave wet-method modified artificial granite waste residue and recycling process method thereof |
CN115925321B (en) * | 2023-02-17 | 2023-06-02 | 江苏百代节能建材有限公司 | High-strength ecological stone slab and preparation method thereof |
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CN1644552A (en) * | 2004-01-19 | 2005-07-27 | 石汇玉 | Production of artificial stone products |
CN104003652A (en) * | 2014-05-16 | 2014-08-27 | 中科院广州化学有限公司 | Phase-transition insulation artificial stone sheet material containing stone material waste residue, preparation method and application thereof |
CN104556823A (en) * | 2015-01-12 | 2015-04-29 | 卓培琨 | Energy-saving high-performance artificial stone and preparation method thereof |
CN105236836A (en) * | 2015-09-29 | 2016-01-13 | 广西钟山县中源石业有限公司 | Artificial agglomerated stone and preparation method thereof |
CN105271944A (en) * | 2015-11-16 | 2016-01-27 | 武宣县宝信石材有限公司 | Board or artware produced through marble leftover materials |
-
2016
- 2016-08-31 CN CN201610779300.3A patent/CN106348660B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1644552A (en) * | 2004-01-19 | 2005-07-27 | 石汇玉 | Production of artificial stone products |
CN104003652A (en) * | 2014-05-16 | 2014-08-27 | 中科院广州化学有限公司 | Phase-transition insulation artificial stone sheet material containing stone material waste residue, preparation method and application thereof |
CN104556823A (en) * | 2015-01-12 | 2015-04-29 | 卓培琨 | Energy-saving high-performance artificial stone and preparation method thereof |
CN105236836A (en) * | 2015-09-29 | 2016-01-13 | 广西钟山县中源石业有限公司 | Artificial agglomerated stone and preparation method thereof |
CN105271944A (en) * | 2015-11-16 | 2016-01-27 | 武宣县宝信石材有限公司 | Board or artware produced through marble leftover materials |
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