CN106348660A - Machining method of waste residues of marbles - Google Patents
Machining method of waste residues of marbles Download PDFInfo
- Publication number
- CN106348660A CN106348660A CN201610779300.3A CN201610779300A CN106348660A CN 106348660 A CN106348660 A CN 106348660A CN 201610779300 A CN201610779300 A CN 201610779300A CN 106348660 A CN106348660 A CN 106348660A
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- Prior art keywords
- marble
- powder
- modified
- dali
- particle diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/026—Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a machining method of waste residues of marbles, and belongs to the technical field of comprehensive utilization of solid wastes in stone machining. The method comprises the following steps: firstly, sieving and grading; secondly, preparation of raw material; thirdly, production of panels from the raw materials. According to the method, solid residues produced during machining of marbles are taken as raw materials, the solid residues are graded and then are subjected to modification treatment, and machined with other raw materials, so as to be prepared into the marble panels; the marble panels prepared through the method have the characteristics of low cost, high convenience and easiness in obtaining, unique technology and good decorative effect, and compared with the natural panels, the marble panels have the advantages of antibacterial property, deodorization and sun protection.
Description
Technical field
The invention belongs to the solid gurry technical field of comprehensive utilization of processing of stone, specifically a kind of marble waste residue material processing side
Method.
Background technology
With the lifting of people's living standard, the improvement of living conditions, interior decoration industry fast development, fit up building materials
Greatly, wherein stone material is that one kind commonly uses most to consumption, and one of most basic building materials are widely used in ground, metope and table top
Mat formation.Stone material common in the market is broadly divided into lithotome and artificial stone.Lithotome refers to from natural rock mass
In mined, and processed become block or board-like material general name.The lithotome of architectural decoration mainly has granite
Plant greatly with marble two.
In the marble course of processing, saw blade, cutting, abrasive disc process all produce a large amount of solid waste-waste residues.With
Marble industry constantly to develop, pile up like a mountain for produced garbage, not only occupy a large amount of soils, and dust is dirty
Dye and its seriously polluted the life affecting people to water source.Govern the sustainable economic development of this area simultaneously.Control
Reason pollutes, optimizes the environment, economizing on resources is that marble is processed area of concentration sustainable economic development, transformed mode of economic growth
Important measures.
Content of the invention
The technical problem to be solved is for prior art Shortcomings, provides a kind of marble waste residue material to add
Work method.
In order to achieve the above object, the present invention employs the following technical solutions.
A kind of marble waste residue material processing method, comprises the following steps:
(1) sieving and grading
The waste residue powder producing in the marble course of processing is spread out, dries, sieve first, be divided into particle diameter to be more than 5mm's
Dali rock ballast, particle diameter are less than the marble powder of 1mm, the Dali stone sand three-level of particle diameter 1-5mm, and Dali ballast is ground into particle diameter 1-
The Dali stone sand of 5mm, carries out regrading, and gained Dali stone sand is merged with the Dali stone sand sieving first, regrading process
The marble powder of middle generation is merged with the marble powder sieving first, carries out regrading to the marble powder merging, obtains grain
Footpath is more than 0.1mm, the marble middling flour less than 1mm, no more than the marble microlith powder of 0.1mm, and marble microlith powder is used
Flour mill is milled to 200-600 mesh, obtains the ultra-fine stone powder of marble of 200-600 mesh；
(2) preparation of raw material
1. by weight, (1) step is processed the Dali stone sand 300-500 part obtaining with titanate coupling agent 10-20 part
It is modified processing, obtain modified Dali stone sand, standby；(1) step is processed the marble microlith powder 100-300 part obtaining with
200-300 mesh kieselguhr 1-10 part mixes, and is modified processing with silane coupler 5-10 part, obtains modified marble microlith
Powder, standby；(1) step is processed the marble obtaining ultra-fine stone powder 50-200 part to mix with particle diameter 40-60nm zinc oxide 1-5 part,
It is modified processing with silane coupler 1-2 part, obtain the ultra-fine stone powder of modified marble, standby；
2. by weight, extracting epoxy resin 45-65 part, organic silicon modified polyurethane resin 35-55 part, triethanolamine 1-
2 parts are placed in blender, stir 10-25min, then take step (2)-modified Dali stone sand 1., modification marble microlith powder, change
Property the ultra-fine stone powder of marble put into blender, stir 2-5min, add carboxymethyl cellulose 0.1-0.5 part, hydrogenated rosin
0.5-1.5 part, polyamide 1-2 part, stir 15-25min；
(3) make sheet material
The slurry being stirred is poured into framed inner surface and scribbles in the mould of releasing agent, high pressure vacuum molding, prepared 20-
30mm thickness artificial marble sheet material, is placed into 4-5h in the environment of 100-120 DEG C of constant temperature again after the demoulding, send into marble and automatically throw
Carry out surface polishing, cutting in ray machine.
The Advantageous Effects of the present invention: it is former that the present invention utilizes the garbage slag charge producing in the marble course of processing
Material, processes through classification post-modification, becomes artificial marble sheet material with other Raw material processings；The artificial marble sheet material that the present invention makes
Have the characteristics that cost of material is low, be conveniently easy to get, technique is unique, good decorating effect, compared with natural marble plate, outward appearance matter
Sense no marked difference, has antibacterial, deodorization, the advantage such as sun-proof.
Specific embodiment
With reference to embodiment further technical scheme is made with detailed elaboration, but the not all paired present invention
Scope limits.
Embodiment 1
A kind of marble waste residue material processing method, comprises the following steps:
(1) sieving and grading
The waste residue powder producing in the marble course of processing is spread out, dries, sieve first, be divided into particle diameter to be more than 5mm's
Dali rock ballast, particle diameter are less than the marble powder of 1mm, the Dali stone sand three-level of particle diameter 1-5mm, and Dali ballast is ground into particle diameter 1-
The Dali stone sand of 5mm, carries out regrading, and gained Dali stone sand is merged with the Dali stone sand sieving first, regrading process
The marble powder of middle generation is merged with the marble powder sieving first, carries out regrading to the marble powder merging, obtains grain
Footpath is more than 0.1mm, the marble middling flour less than 1mm, no more than the marble microlith powder of 0.1mm, and marble microlith powder is used
Flour mill is milled to 200 mesh, obtains the ultra-fine stone powder of marble of 200 mesh；
(2) preparation of raw material
1. by weight, (1) step is processed 300 parts of the Dali stone sand obtaining to be changed for 10 parts with titanate coupling agent
Property process, obtain modified Dali stone sand, standby；(1) step is processed 100 parts of the marble microlith powder obtaining and 200 mesh kieselguhr
1 part of mixing, with silane coupler, 5 parts are modified processing, and obtain modified marble microlith powder, standby；(1) step is processed
1 part with particle diameter 40nm zinc oxide of 50 parts of the ultra-fine stone powder of marble arriving mixes, and with silane coupler, 1 part is modified processing, and obtains
To the modified ultra-fine stone powder of marble, standby；
2. by weight, 45 parts of extracting epoxy resin, 35 parts of organic silicon modified polyurethane resin, 1 part of triethanolamine are placed in
Blender, stirs 10min, then take step (2)-modified Dali stone sand 1., modified marble microlith powder, modified marble be super
Microlith powder puts into blender, stirs 2min, adds 0.1 part of carboxymethyl cellulose, 0.5 part of hydrogenated rosin, polyamide 1
Part, stir 15min；
(3) make sheet material
The slurry being stirred is poured into framed inner surface and scribbles in the mould of releasing agent, high pressure vacuum molding, prepared 20mm
Thick artificial marble sheet material, is placed into 4h in the environment of 100 DEG C of constant temperature again after the demoulding, send in marble automatic polishing machine and carry out
Surface polishes, cutting.
Embodiment 2
A kind of marble waste residue material processing method, comprises the following steps:
(1) sieving and grading
The waste residue powder producing in the marble course of processing is spread out, dries, sieve first, be divided into particle diameter to be more than 5mm's
Dali rock ballast, particle diameter are less than the marble powder of 1mm, the Dali stone sand three-level of particle diameter 1-5mm, and Dali ballast is ground into particle diameter 1-
The Dali stone sand of 5mm, carries out regrading, and gained Dali stone sand is merged with the Dali stone sand sieving first, regrading process
The marble powder of middle generation is merged with the marble powder sieving first, carries out regrading to the marble powder merging, obtains grain
Footpath is more than 0.1mm, the marble middling flour less than 1mm, no more than the marble microlith powder of 0.1mm, and marble microlith powder is used
Flour mill is milled to 600 mesh, obtains the ultra-fine stone powder of marble of 600 mesh；
(2) preparation of raw material
1. by weight, (1) step is processed 500 parts of the Dali stone sand obtaining to be changed for 20 parts with titanate coupling agent
Property process, obtain modified Dali stone sand, standby；(1) step is processed 300 parts of the marble microlith powder obtaining and 300 mesh kieselguhr
10 parts of mixings, with silane coupler, 10 parts are modified processing, and obtain modified marble microlith powder, standby；(1) step is processed
5 parts with particle diameter 60nm zinc oxide of 200 parts of the ultra-fine stone powder of marble obtaining mixes, and with silane coupler, 2 parts are modified processing,
Obtain the ultra-fine stone powder of modified marble, standby；
2. by weight, 65 parts of extracting epoxy resin, 55 parts of organic silicon modified polyurethane resin, 2 parts of triethanolamine are placed in
Blender, stirs 25min, then take step (2)-modified Dali stone sand 1., modified marble microlith powder, modified marble be super
Microlith powder puts into blender, stirs 5min, adds 0.5 part of carboxymethyl cellulose, 1.5 parts of hydrogenated rosin, polyamide 2
Part, stir 25min；
(3) make sheet material
The slurry being stirred is poured into framed inner surface and scribbles in the mould of releasing agent, high pressure vacuum molding, prepared 30mm
Thick artificial marble sheet material, is placed into 5h in the environment of 120 DEG C of constant temperature again after the demoulding, send in marble automatic polishing machine and carry out
Surface polishes, cutting.
Embodiment 3
A kind of marble waste residue material processing method, comprises the following steps:
(1) sieving and grading
The waste residue powder producing in the marble course of processing is spread out, dries, sieve first, be divided into particle diameter to be more than 5mm's
Dali rock ballast, particle diameter are less than the marble powder of 1mm, the Dali stone sand three-level of particle diameter 1-5mm, and Dali ballast is ground into particle diameter 1-
The Dali stone sand of 5mm, carries out regrading, and gained Dali stone sand is merged with the Dali stone sand sieving first, regrading process
The marble powder of middle generation is merged with the marble powder sieving first, carries out regrading to the marble powder merging, obtains grain
Footpath is more than 0.1mm, the marble middling flour less than 1mm, no more than the marble microlith powder of 0.1mm, and marble microlith powder is used
Flour mill is milled to 400 mesh, obtains the ultra-fine stone powder of marble of 400 mesh；
(2) preparation of raw material
1. by weight, (1) step is processed 400 parts of the Dali stone sand obtaining to be changed for 15 parts with titanate coupling agent
Property process, obtain modified Dali stone sand, standby；(1) step is processed 200 parts of the marble microlith powder obtaining and 250 mesh kieselguhr
5.5 parts of mixings, with silane coupler, 7.5 parts are modified processing, and obtain modified marble microlith powder, standby；(1) step is located
Manage 150 parts of the ultra-fine stone powder of marble obtaining to mix for 3 parts with particle diameter 50nm zinc oxide, with silane coupler, 1.5 parts are modified
Process, obtain the ultra-fine stone powder of modified marble, standby；
2. by weight, 55 parts of extracting epoxy resin, 45 parts of organic silicon modified polyurethane resin, 1.5 parts of triethanolamine are put
In blender, stir 17.5min, then take step (2)-modified Dali stone sand 1., modified marble microlith powder, modification Dali
The ultra-fine stone powder of stone puts into blender, stirs 3.5min, adds 0.3 part of carboxymethyl cellulose, 1 part of hydrogenated rosin, polyamide resin
1.5 parts of fat, stirs 20min；
(3) make sheet material
The slurry being stirred is poured into framed inner surface and scribbles in the mould of releasing agent, high pressure vacuum molding, prepared 25mm
Thick artificial marble sheet material, is placed into 4.5h in the environment of 110 DEG C of constant temperature again after the demoulding, send in marble automatic polishing machine
Row surface polishes, cutting.
Claims (1)
1. a kind of marble waste residue material processing method is it is characterised in that comprise the following steps:
(1) sieving and grading
The waste residue powder producing in the marble course of processing is spread out, dries, sieve first, be divided into the Dali that particle diameter is more than 5mm
Rock ballast, particle diameter are less than the marble powder of 1mm, the Dali stone sand three-level of particle diameter 1-5mm, and Dali ballast is ground into particle diameter 1-5mm
Dali stone sand, carry out regrading, gained Dali stone sand is merged with the Dali stone sand sieving first, during regrading produce
Raw marble powder is merged with the marble powder sieving first, carries out regrading to the marble powder merging, obtains particle diameter big
In 0.1mm, the marble middling flour less than 1mm, no more than the marble microlith powder of 0.1mm, by marble microlith powder pulverizing
Machine is milled to 200-600 mesh, obtains the ultra-fine stone powder of marble of 200-600 mesh；
(2) preparation of raw material
1. by weight, (1) step is processed the Dali stone sand 300-500 part obtaining to be carried out with titanate coupling agent 10-20 part
Modification, obtains modified Dali stone sand, standby；(1) step is processed the marble microlith powder 100-300 part obtaining and 200-
300 mesh kieselguhr 1-10 parts mix, and are modified processing with silane coupler 5-10 part, obtain modified marble microlith powder, standby
With；(1) step is processed the marble obtaining ultra-fine stone powder 50-200 part to mix with particle diameter 40-60nm zinc oxide 1-5 part, use silicon
Alkane coupling agent 1-2 part is modified processing, and obtains the ultra-fine stone powder of modified marble, standby；
2. by weight, extracting epoxy resin 45-65 part, organic silicon modified polyurethane resin 35-55 part, triethanolamine 1-2 part
Be placed in blender, stir 10-25min, then take step (2)-modified Dali stone sand 1., modified marble microlith powder, modified greatly
The ultra-fine stone powder of Gypsum Fibrosum puts into blender, stirs 2-5min, adds carboxymethyl cellulose 0.1-0.5 part, hydrogenated rosin 0.5-1.5
Part, polyamide 1-2 part, stir 15-25min；
(3) make sheet material
The slurry being stirred is poured into framed inner surface and scribbles in the mould of releasing agent, high pressure vacuum molding, prepared 20-30mm is thick
Artificial marble sheet material, is placed into 4-5h in the environment of 100-120 DEG C of constant temperature again after the demoulding, send in marble automatic polishing machine
Carry out surface polishing, cutting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610779300.3A CN106348660B (en) | 2016-08-31 | 2016-08-31 | A kind of marble waste residue material processing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610779300.3A CN106348660B (en) | 2016-08-31 | 2016-08-31 | A kind of marble waste residue material processing method |
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| CN106348660A true CN106348660A (en) | 2017-01-25 |
| CN106348660B CN106348660B (en) | 2018-10-26 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107265916A (en) * | 2017-06-20 | 2017-10-20 | 合肥慧林建材有限公司 | A kind of marble leftover pieces reprocessing technique for road sheet material |
| CN108940538A (en) * | 2018-08-21 | 2018-12-07 | 耒阳市百汇粉体有限公司 | A kind of production technology of marble superfine powder |
| CN110563444A (en) * | 2019-08-19 | 2019-12-13 | 福建德胜新建材有限公司 | comprehensive utilization method of Rouyuan red tailings |
| CN113278306A (en) * | 2021-05-12 | 2021-08-20 | 广西科学院 | Microwave wet-method modified artificial granite waste residue and recycling process method thereof |
| CN115925321A (en) * | 2023-02-17 | 2023-04-07 | 江苏百代节能建材有限公司 | High-strength ecological stone slab and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107265916A (en) * | 2017-06-20 | 2017-10-20 | 合肥慧林建材有限公司 | A kind of marble leftover pieces reprocessing technique for road sheet material |
| CN108940538A (en) * | 2018-08-21 | 2018-12-07 | 耒阳市百汇粉体有限公司 | A kind of production technology of marble superfine powder |
| CN110563444A (en) * | 2019-08-19 | 2019-12-13 | 福建德胜新建材有限公司 | comprehensive utilization method of Rouyuan red tailings |
| CN110563444B (en) * | 2019-08-19 | 2022-04-15 | 福建德胜新建材有限公司 | Comprehensive utilization method of Rouyuan red tailings |
| CN113278306A (en) * | 2021-05-12 | 2021-08-20 | 广西科学院 | Microwave wet-method modified artificial granite waste residue and recycling process method thereof |
| CN115925321A (en) * | 2023-02-17 | 2023-04-07 | 江苏百代节能建材有限公司 | High-strength ecological stone slab and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106348660B (en) | 2018-10-26 |
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