CN106336052B - 一种吸附处理含锰废水的方法 - Google Patents
一种吸附处理含锰废水的方法 Download PDFInfo
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- CN106336052B CN106336052B CN201610729688.6A CN201610729688A CN106336052B CN 106336052 B CN106336052 B CN 106336052B CN 201610729688 A CN201610729688 A CN 201610729688A CN 106336052 B CN106336052 B CN 106336052B
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- waste water
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- 239000002351 wastewater Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 44
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 30
- 239000011572 manganese Substances 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 33
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 24
- 238000005345 coagulation Methods 0.000 claims abstract description 6
- 230000015271 coagulation Effects 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000010903 husk Substances 0.000 claims description 15
- 239000006228 supernatant Substances 0.000 claims description 15
- 239000003575 carbonaceous material Substances 0.000 claims description 12
- 239000011812 mixed powder Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 11
- 229910021532 Calcite Inorganic materials 0.000 claims description 10
- 108010010803 Gelatin Proteins 0.000 claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims description 10
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 239000008273 gelatin Substances 0.000 claims description 10
- 229920000159 gelatin Polymers 0.000 claims description 10
- 235000019322 gelatine Nutrition 0.000 claims description 10
- 235000011852 gelatine desserts Nutrition 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000010457 zeolite Substances 0.000 claims description 10
- 239000000440 bentonite Substances 0.000 claims description 9
- 229910000278 bentonite Inorganic materials 0.000 claims description 9
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 9
- 239000002023 wood Substances 0.000 claims description 9
- 239000006004 Quartz sand Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 6
- 241000487918 Acacia argyrodendron Species 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 235000011222 chang cao shi Nutrition 0.000 claims description 5
- 239000003610 charcoal Substances 0.000 claims description 5
- 239000002283 diesel fuel Substances 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 238000004065 wastewater treatment Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 238000005189 flocculation Methods 0.000 claims 1
- 230000016615 flocculation Effects 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 238000012545 processing Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- 238000003672 processing method Methods 0.000 abstract description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical class 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- BZDIAFGKSAYYFC-UHFFFAOYSA-N manganese;hydrate Chemical compound O.[Mn] BZDIAFGKSAYYFC-UHFFFAOYSA-N 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
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- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/206—Manganese or manganese compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610729688.6A CN106336052B (zh) | 2016-08-25 | 2016-08-25 | 一种吸附处理含锰废水的方法 |
Applications Claiming Priority (1)
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CN201610729688.6A CN106336052B (zh) | 2016-08-25 | 2016-08-25 | 一种吸附处理含锰废水的方法 |
Publications (2)
Publication Number | Publication Date |
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CN106336052A CN106336052A (zh) | 2017-01-18 |
CN106336052B true CN106336052B (zh) | 2019-05-24 |
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CN201610729688.6A Active CN106336052B (zh) | 2016-08-25 | 2016-08-25 | 一种吸附处理含锰废水的方法 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1087878A (zh) * | 1992-12-10 | 1994-06-15 | 王宝贞 | 高效除放射性和重金属的净水方法 |
CN101250000A (zh) * | 2007-12-18 | 2008-08-27 | 同济大学 | 一种去除水中铁锰的深度处理方法 |
CN104229957A (zh) * | 2013-06-24 | 2014-12-24 | 张家领 | 一种以天然矿物质为主成分的复合型絮凝剂 |
CN105236637A (zh) * | 2015-10-10 | 2016-01-13 | 贵州万山兴隆锰业有限公司 | 一种锰矿废水的综合处理方法 |
CN105706704A (zh) * | 2016-03-02 | 2016-06-29 | 贵州闲草堂医药科技有限公司 | 一种碳化材料作天麻栽培填充物栽培天麻方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61118184A (ja) * | 1984-11-12 | 1986-06-05 | Unitika Ltd | 浄水処理方法 |
-
2016
- 2016-08-25 CN CN201610729688.6A patent/CN106336052B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1087878A (zh) * | 1992-12-10 | 1994-06-15 | 王宝贞 | 高效除放射性和重金属的净水方法 |
CN101250000A (zh) * | 2007-12-18 | 2008-08-27 | 同济大学 | 一种去除水中铁锰的深度处理方法 |
CN104229957A (zh) * | 2013-06-24 | 2014-12-24 | 张家领 | 一种以天然矿物质为主成分的复合型絮凝剂 |
CN105236637A (zh) * | 2015-10-10 | 2016-01-13 | 贵州万山兴隆锰业有限公司 | 一种锰矿废水的综合处理方法 |
CN105706704A (zh) * | 2016-03-02 | 2016-06-29 | 贵州闲草堂医药科技有限公司 | 一种碳化材料作天麻栽培填充物栽培天麻方法 |
Non-Patent Citations (1)
Title |
---|
活性炭对锰吸附作用研究;张克荣等;《中国卫生检验杂志》;19940531;第4卷(第5期);第273页摘要、前言、第1-2节、第274页第3节、第275页第3节 |
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CN106336052A (zh) | 2017-01-18 |
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Effective date of registration: 20200709 Address after: 3 / F, building 2, economic development zone, Wanshan District, Tongren City, Guizhou Province Patentee after: Tongren Guizhou Hecheng Manganese Industry Co.,Ltd. Address before: Xi Xiang prosperous village Wanshan District 554200 in Guizhou province Tongren City Patentee before: GUIZHOU WANSHAN XINGLONG MANGANESE INDUSTRY Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: 554299 floor 3, building 2, economic development zone, Wanshan District, Tongren City, Guizhou Province Patentee after: Guizhou Tongren Hecheng Manganese Alloy Co.,Ltd. Address before: 554299 floor 3, building 2, economic development zone, Wanshan District, Tongren City, Guizhou Province Patentee before: Tongren Guizhou Hecheng Manganese Industry Co.,Ltd. |