CN106318736A - Washing soap for infants and preparation method thereof - Google Patents
Washing soap for infants and preparation method thereof Download PDFInfo
- Publication number
- CN106318736A CN106318736A CN201610673381.9A CN201610673381A CN106318736A CN 106318736 A CN106318736 A CN 106318736A CN 201610673381 A CN201610673381 A CN 201610673381A CN 106318736 A CN106318736 A CN 106318736A
- Authority
- CN
- China
- Prior art keywords
- soap
- preparation
- sodium
- protease
- baby
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D15/00—Manufacture of resin soap or soaps derived from naphthenic acids; Compositions
- C11D15/04—Compositions containing resin soap or soap derived from naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a washing soap for infants and a preparation method thereof. The washing soap for infants is prepared from a maleic anhydride-styrene copolymer, sodium alginate, solid protease, melamine resin, hardened oil, palm oil, coconut oil, rosin, sodium hydroxide, sodium polyacrylate, sodium stearate, ethylene glycol distearate, glycerol, borax, 4-formylphenylboronic acid, citric acid, alkyl polyoxyethylene ether and water. The preparation method includes the steps that firstly, protease is prepared into protease microcapsules; then, soap granules are prepared; then, the soap granules are smashed and mixed with sodium polyacrylate, sodium stearate and ethylene glycol distearate, the temperature is raised to 40-50 DEG C, glycerol, borax, 4-formylphenylboronic acid, citric acid, alkyl polyoxyethylene ether, water and the protease microcapsules are added, dispersing is carried out, forming is carried out after standing, and the washing soap for infants is obtained. The washing soap for infants is good in stain removing effect and can effectively remove various stains on infant clothes, and protease has high stability in the soap.
Description
Technical field
The invention belongs to daily laundry soap technical field, specific design one infant laundry soap and preparation method thereof.
Background technology
Enzyme is a kind of highly active biocatalyzer, has the advantages that catalytic efficiency is high, specificity is strong.Enzyme preparation application skill
The maturation of art, makes single enzyme preparation or compound enzymic preparation be successfully applied in detergent, such as alkaline protease, it is possible at low temperature
Under the conditions of efficient decompose the protide spots such as milk stain, under the synergism of surfactant, spot is removed from fabric；
Lipase, can disintegrate oil spot targetedly, reaches to remove purpose；Amylase, can decompose and remove starch based dirty
Stain；Cellulase, and it is not involved in decomposing the effect of spot, but fine fibre to cotton fiber surface during fabric washing
Dimension is decomposed, and has the most indirectly reached the clean effect of detergent from slight part, as bright as new after making fabric washing.Enzyme preparation
Efficient clean effect makes it be widely used in detergent, liquid detergent and is consumer's accreditation, and it applies skill
Art has tended to ripe through years development.
Often can leave over milk stain on the clothes of infant, mostly laundry soap the most on the market is to put detergency in the first place, neglects
Omited medicated clothing clean the zest of rear surface residue and medicated clothing dry after pliability.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art to provide a kind of baby's laundry soap and preparation method thereof, this is washed
Clothing soap clean effect is good, can effectively remove all kinds of spots of infantile clothes.
A kind of baby's laundry soap, raw material includes in parts by weight: maleic anhydride-styrene copolymers 5-9 part, sodium alginate
0.3-1.2 part, solid protein enzyme 10 parts, melamine resin 2-6 part, fixed oil 4-10 part, Petiolus Trachycarpi oil 2-9 part, Oleum Cocois 3-7 part,
Colophonium 0.8-3.2 part, sodium hydroxide 2-6 part, sodium polyacrylate 0.8-2.4 part, sodium stearate 0.1-0.4 part, ethylene glycol bis is hard
Fat acid ester 0.2-1 part, glycerol 0.4-0.9 part, Borax 0.3-0.7 part, 4-formylphenyl boronic acid 0.1-0.8 part, citric acid 0.3-
0.5 part, alkyl polyoxyethylene base ether 0.2-0.7 part, water 20-30 part.
The preparation method of described baby's laundry soap, comprises the following steps:
Step 1, adds maleic anhydride-styrene copolymers and sodium alginate in 1/2 weight parts water, adds solid protein enzyme,
Stirring, drips 1/2 weight portion melamine resin, is warming up to 50-60 DEG C of insulation 2-3h, is down to room temperature, then drips 1/2 weight portion melamine
Resin, is warming up to 60-70 DEG C of insulation 2-3h, is down to room temperature, regulates pH to 10.0～12.0, sucking filtration, is dried, and obtains protease micro-
Capsule；
Step 2, mixes fixed oil, Petiolus Trachycarpi oil, Oleum Cocois and Colophonium, and water-bath is dissolved, and drips sodium hydroxide under agitation
Solution, continues stirring 1-3h, is cooled to 0-5 DEG C, filter, obtain neat soap；
Step 3, mixes with sodium polyacrylate, sodium stearate, Ethylene Glycol Distearate after being pulverized by neat soap, is warming up to 40-50
DEG C, add glycerol, Borax, 4-formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 weight parts water and protease micro-
Capsule, dispersion, stand aftershaping, to obtain final product.
Further, in step 1 mixing speed be 200-300rpm, the time be 20-30min.
Further, in step 1, the rate of addition of melamine resin is 1-3mL/min.
Further, in step 2, the concentration of sodium hydroxide solution is 20-30wt%.
Further, after in step 3, neat soap is pulverized, granularity is at 40-60 mesh.
Further, in step 3, rate of dispersion is 1000-1200rpm, 10-15min.
The infant laundry soap clean effect of the present invention is good, can effectively remove all kinds of spots of infantile clothes；Enzyme is at soap
Good stability in body, lives at 3 year shelf-life enzyme and still can reach more than 70%.
Detailed description of the invention
Embodiment 1
A kind of baby's laundry soap, raw material includes in parts by weight: maleic anhydride-styrene copolymers 5 parts, sodium alginate 0.3 part,
Solid protein enzyme 10 parts, melamine resin 2 parts, fixed oil 4 parts, Petiolus Trachycarpi oil 2 parts, Oleum Cocois 3 parts, Colophonium 0.8 part, sodium hydroxide 2
Part, sodium polyacrylate 0.8 part, sodium stearate 0.1 part, Ethylene Glycol Distearate 0.2 part, glycerol 0.4 part, Borax 0.3 part, 4-
Formylphenyl boronic acid 0.1 part, citric acid 0.3 part, 0.2 part of alkyl polyoxyethylene base ether, 20 parts of water.
The preparation method of described baby's laundry soap, comprises the following steps:
Step 1, adds maleic anhydride-styrene copolymers and sodium alginate in 1/2 weight parts water, adds solid protein enzyme,
Stirring, drips 1/2 weight portion melamine resin, is warming up to 50 DEG C of insulation 3h, is down to room temperature, then drips 1/2 weight portion melamine resin,
It is warming up to 60 DEG C of insulation 3h, is down to room temperature, regulate pH to 10.0～12.0, sucking filtration, be dried, obtain protease microcapsule；
Step 2, mixes fixed oil, Petiolus Trachycarpi oil, Oleum Cocois and Colophonium, and water-bath is dissolved, and drips sodium hydroxide under agitation
Solution, continues stirring 1h, is cooled to 0-5 DEG C, filter, obtain neat soap；
Step 3, mixes with sodium polyacrylate, sodium stearate, Ethylene Glycol Distearate after being pulverized by neat soap, is warming up to 40 DEG C,
Add glycerol, Borax, 4-formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 weight parts water and the micro-glue of protease
Capsule, dispersion, stand aftershaping, to obtain final product.
Wherein, in step 1 mixing speed be 200rpm, the time be 30min, the rate of addition of melamine resin is 1mL/min；
In step 2, the concentration of sodium hydroxide solution is 20wt%；After in step 3, neat soap is pulverized, granularity at 40 mesh, rate of dispersion is
1000rpm、15min。
Embodiment 2
A kind of baby's laundry soap, raw material includes in parts by weight: maleic anhydride-styrene copolymers 6 parts, sodium alginate 0.7 part,
Solid protein enzyme 10 parts, melamine resin 5 parts, fixed oil 8 parts, Petiolus Trachycarpi oil 3 parts, Oleum Cocois 6 parts, Colophonium 1.4 parts, sodium hydroxide 3
Part, sodium polyacrylate 1.7 parts, sodium stearate 0.2 part, Ethylene Glycol Distearate 0.4 part, glycerol 0.5 part, Borax 0.6 part, 4-
Formylphenyl boronic acid 0.3 part, citric acid 0.4 part, 0.5 part of alkyl polyoxyethylene base ether, 24 parts of water.
The preparation method of described baby's laundry soap, comprises the following steps:
Step 1, adds maleic anhydride-styrene copolymers and sodium alginate in 1/2 weight parts water, adds solid protein enzyme,
Stirring, drips 1/2 weight portion melamine resin, is warming up to 55 DEG C of insulation 3h, is down to room temperature, then drips 1/2 weight portion melamine resin,
It is warming up to 65 DEG C of insulation 3h, is down to room temperature, regulate pH to 10.0～12.0, sucking filtration, be dried, obtain protease microcapsule；
Step 2, mixes fixed oil, Petiolus Trachycarpi oil, Oleum Cocois and Colophonium, and water-bath is dissolved, and drips sodium hydroxide under agitation
Solution, continues stirring 2h, is cooled to 0-5 DEG C, filter, obtain neat soap；
Step 3, mixes with sodium polyacrylate, sodium stearate, Ethylene Glycol Distearate after being pulverized by neat soap, is warming up to 40 DEG C,
Add glycerol, Borax, 4-formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 weight parts water and the micro-glue of protease
Capsule, dispersion, stand aftershaping, to obtain final product.
Wherein, in step 1 mixing speed be 250rpm, the time be 20min, the rate of addition of melamine resin is 2mL/min；
In step 2, the concentration of sodium hydroxide solution is 20wt%；After in step 3, neat soap is pulverized, granularity at 40 mesh, rate of dispersion is
1200rpm、15min。
Embodiment 3
A kind of baby's laundry soap, raw material includes in parts by weight: maleic anhydride-styrene copolymers 8 parts, sodium alginate 0.9 part,
Solid protein enzyme 10 parts, melamine resin 5 parts, fixed oil 8 parts, Petiolus Trachycarpi oil 7 parts, Oleum Cocois 5 parts, Colophonium 2.3 parts, sodium hydroxide 5
Part, sodium polyacrylate 1.7 parts, sodium stearate 0.3 part, Ethylene Glycol Distearate 0.7 part, glycerol 0.6 part, Borax 0.5 part, 4-
Formylphenyl boronic acid 0.6 part, citric acid 0.4 part, 0.6 part of alkyl polyoxyethylene base ether, 27 parts of water.
The preparation method of described baby's laundry soap, comprises the following steps:
Step 1, adds maleic anhydride-styrene copolymers and sodium alginate in 1/2 weight parts water, adds solid protein enzyme,
Stirring, drips 1/2 weight portion melamine resin, is warming up to 50 DEG C of insulation 3h, is down to room temperature, then drips 1/2 weight portion melamine resin,
It is warming up to 60 DEG C of insulation 3h, is down to room temperature, regulate pH to 10.0～12.0, sucking filtration, be dried, obtain protease microcapsule；
Step 2, mixes fixed oil, Petiolus Trachycarpi oil, Oleum Cocois and Colophonium, and water-bath is dissolved, and drips sodium hydroxide under agitation
Solution, continues stirring 1h, is cooled to 0-5 DEG C, filter, obtain neat soap；
Step 3, mixes with sodium polyacrylate, sodium stearate, Ethylene Glycol Distearate after being pulverized by neat soap, is warming up to 40 DEG C,
Add glycerol, Borax, 4-formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 weight parts water and the micro-glue of protease
Capsule, dispersion, stand aftershaping, to obtain final product.
Wherein, in step 1 mixing speed be 200rpm, the time be 30min, the rate of addition of melamine resin is 1mL/min；
In step 2, the concentration of sodium hydroxide solution is 20wt%；After in step 3, neat soap is pulverized, granularity at 40 mesh, rate of dispersion is
1000rpm、15min。
Embodiment 4
A kind of baby's laundry soap, raw material includes in parts by weight: maleic anhydride-styrene copolymers 9 parts, sodium alginate 1.2 parts,
Solid protein enzyme 10 parts, melamine resin 6 parts, fixed oil 10 parts, Petiolus Trachycarpi oil 9 parts, Oleum Cocois 7 parts, Colophonium 3.2 parts, sodium hydroxide 6
Part, sodium polyacrylate 2.4 parts, sodium stearate 0.4 part, Ethylene Glycol Distearate 1 part, glycerol 0.9 part, Borax 0.7 part, 4-first
Acyl phenylboric acid 0.8 part, citric acid 0.5 part, 0.7 part of alkyl polyoxyethylene base ether, 30 parts of water.
The preparation method of described baby's laundry soap, comprises the following steps:
Step 1, adds maleic anhydride-styrene copolymers and sodium alginate in 1/2 weight parts water, adds solid protein enzyme,
Stirring, drips 1/2 weight portion melamine resin, is warming up to 60 DEG C of insulation 2h, is down to room temperature, then drips 1/2 weight portion melamine resin,
It is warming up to 70 DEG C of insulation 2h, is down to room temperature, regulate pH to 10.0～12.0, sucking filtration, be dried, obtain protease microcapsule；
Step 2, mixes fixed oil, Petiolus Trachycarpi oil, Oleum Cocois and Colophonium, and water-bath is dissolved, and drips sodium hydroxide under agitation
Solution, continues stirring 3h, is cooled to 0-5 DEG C, filter, obtain neat soap；
Step 3, mixes with sodium polyacrylate, sodium stearate, Ethylene Glycol Distearate after being pulverized by neat soap, is warming up to 50 DEG C,
Add glycerol, Borax, 4-formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 weight parts water and the micro-glue of protease
Capsule, dispersion, stand aftershaping, to obtain final product.
Wherein, in step 1 mixing speed be 300rpm, the time be 20min, the rate of addition of melamine resin is 3mL/min；
In step 2, the concentration of sodium hydroxide solution is 30wt%；After in step 3, neat soap is pulverized, granularity at 60 mesh, rate of dispersion is
1200rpm、10min。
Embodiment 5
The present embodiment is with the difference of embodiment 3: do not contain sodium polyacrylate.
Embodiment 6
The present embodiment is with the difference of embodiment 3: do not contain citric acid.
Detergency evaluation
Use GB white carbon black soiled cotton JB-01, GB albumen soiled cotton JB-02, GB sebum soiled cotton JB-03, going of test laundry soap
Dirty power, specific experiment condition and method are with reference to QB1224-2012.Result is as follows:
From upper table result, the laundry soap of the present invention has good dirt-removing power, to protide dirt, sebum class dirt tool
Having good emulsifying capacity, clean effect is good, can effectively remove the just urine stain of infants' wear, saliva stain, food greasy dirt etc..
Enzyme activity is evaluated
Become the polypeptide of small fragment, the aminoacid bunch of release by Savinase protease hydrolysis based on casein (DMC)
Coloured complex is formed with trinitro-benzene-sulfonic acid (TNBS).Using standard enzyme to draw standard curve, and entering with comparison enzyme
After row curve is adjusted, the size of enzyme activity can be judged by the change of unit of account time internal absorbance.
The sample PE packaging film made is sealed, is placed on 37 DEG C of climatic chambers.Respectively at 6 months, 1 year, 2
Year, the conservation rate of sampling detection protease after 3 years, the enzyme of the fresh enzyme preparation of isodose is lived as a comparison, result is as follows:
In embodiment 5, owing to not adding sodium polyacrylate, causing laundry soap detergency and enzyme to be lived and declined, this is probably
Because sodium polyacrylate can allow protease microcapsule stable existence in the alkaline environment of soap base, thus keep enzyme to live, improve
Detergency.
Softness is tested
Method of testing: 1. circulate washing: putting in tumbling-box washing machine by test towel (textile), add liquid detergent, unlatching is washed
Clothing machine, (expresses 30 minutes) under the same conditions and is automatically performed washing process, is carried out continuously 20 times, takes out and is placed on clothes hanger certainly
So dry, use to be tested.
2. sensory testing: standard towel and test towel are laid in tester's palm of the hand (totally 10 people), by suitable dynamics
Both sides cheek rubs or experiences its flexibility, contrast standard towel with hands simultaneously, its softness is marked
(10 is the softest, and 1 is the hardest).
As seen from the above table, the laundry soap of the present invention has good submissive effect.In embodiment 6, owing to not adding Fructus Citri Limoniae
Acid, causes compliance degradation, and this is possibly due to citric acid can soften prominent fiber so that it is docile is at fabric face.
Claims (7)
1. baby's laundry soap, it is characterised in that: raw material includes in parts by weight: maleic anhydride-styrene copolymers 5-9
Part, sodium alginate 0.3-1.2 part, solid protein enzyme 10 parts, melamine resin 2-6 part, fixed oil 4-10 part, Petiolus Trachycarpi oil 2-9 part, coconut palm
Seed oil 3-7 part, Colophonium 0.8-3.2 part, sodium hydroxide 2-6 part, sodium polyacrylate 0.8-2.4 part, sodium stearate 0.1-0.4 part,
Ethylene Glycol Distearate 0.2-1 part, glycerol 0.4-0.9 part, Borax 0.3-0.7 part, 4-formylphenyl boronic acid 0.1-0.8 part,
Citric acid 0.3-0.5 part, alkyl polyoxyethylene base ether 0.2-0.7 part, water 20-30 part.
2. the preparation method of the baby's laundry soap described in claim 1, it is characterised in that: comprise the following steps:
Step 1, adds maleic anhydride-styrene copolymers and sodium alginate in 1/2 weight parts water, adds solid protein enzyme,
Stirring, drips 1/2 weight portion melamine resin, is warming up to 50-60 DEG C of insulation 2-3h, is down to room temperature, then drips 1/2 weight portion melamine
Resin, is warming up to 60-70 DEG C of insulation 2-3h, is down to room temperature, regulates pH to 10.0～12.0, sucking filtration, is dried, and obtains protease micro-
Capsule；
Step 2, mixes fixed oil, Petiolus Trachycarpi oil, Oleum Cocois and Colophonium, and water-bath is dissolved, and drips sodium hydroxide under agitation
Solution, continues stirring 1-3h, is cooled to 0-5 DEG C, filter, obtain neat soap；
Step 3, mixes with sodium polyacrylate, sodium stearate, Ethylene Glycol Distearate after being pulverized by neat soap, is warming up to 40-50
DEG C, add glycerol, Borax, 4-formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 weight parts water and protease micro-
Capsule, dispersion, stand aftershaping, to obtain final product.
The preparation method of baby's laundry soap the most according to claim 2, it is characterised in that: in step 1, mixing speed is
200-300rpm, time are 20-30min.
The preparation method of baby's laundry soap the most according to claim 2, it is characterised in that: in step 1, melamine resin drips
Acceleration is 1-3mL/min.
The preparation method of baby's laundry soap the most according to claim 2, it is characterised in that: sodium hydroxide solution in step 2
Concentration be 20-30wt%.
The preparation method of baby's laundry soap the most according to claim 2, it is characterised in that: grain after neat soap is pulverized in step 3
Degree is at 40-60 mesh.
The preparation method of baby's laundry soap the most according to claim 2, it is characterised in that: in step 3, rate of dispersion is
1000-1200rpm、10-15min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610673381.9A CN106318736B (en) | 2016-08-16 | 2016-08-16 | A kind of infant's laundry soap and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610673381.9A CN106318736B (en) | 2016-08-16 | 2016-08-16 | A kind of infant's laundry soap and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106318736A true CN106318736A (en) | 2017-01-11 |
| CN106318736B CN106318736B (en) | 2019-04-12 |
Family
ID=57740561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610673381.9A Active CN106318736B (en) | 2016-08-16 | 2016-08-16 | A kind of infant's laundry soap and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106318736B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129887A (en) * | 2017-05-09 | 2017-09-05 | 跨越生物科技（滁州）有限公司 | A kind of strong low bubble hand clothes washing soap of soil release performance |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687345A (en) * | 2005-05-10 | 2005-10-26 | 刘桂堂 | Concentrated solution for washing and preparation method thereof |
| CN103834512A (en) * | 2014-03-11 | 2014-06-04 | 昆明理工大学 | Montan wax washing soap and preparation method thereof |
| WO2014179305A1 (en) * | 2013-04-29 | 2014-11-06 | IINN, Inc. | Soap composition |
| CN104651099A (en) * | 2015-01-22 | 2015-05-27 | 韦爱琴 | Mildew-proof antibacterial special laundry soap for infants |
-
2016
- 2016-08-16 CN CN201610673381.9A patent/CN106318736B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687345A (en) * | 2005-05-10 | 2005-10-26 | 刘桂堂 | Concentrated solution for washing and preparation method thereof |
| WO2014179305A1 (en) * | 2013-04-29 | 2014-11-06 | IINN, Inc. | Soap composition |
| CN103834512A (en) * | 2014-03-11 | 2014-06-04 | 昆明理工大学 | Montan wax washing soap and preparation method thereof |
| CN104651099A (en) * | 2015-01-22 | 2015-05-27 | 韦爱琴 | Mildew-proof antibacterial special laundry soap for infants |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129887A (en) * | 2017-05-09 | 2017-09-05 | 跨越生物科技（滁州）有限公司 | A kind of strong low bubble hand clothes washing soap of soil release performance |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106318736B (en) | 2019-04-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102888194B (en) | High-durability floor wax | |
| CN108893212B (en) | Washing gel bead and preparation method thereof | |
| CN103242973A (en) | Three-effect liquid laundry detergent composition and preparation method thereof | |
| CN103710167B (en) | Liquid laundry detergent for infants and preparation method thereof | |
| CN105296252A (en) | Laundry tablet | |
| CN106635499A (en) | Down clothing cleaning agent and preparation method thereof | |
| CN110408483A (en) | Solid-state powder ball shaped detergent and its preparation method and application | |
| CN106281744A (en) | A kind of infantile clothes concentrated cleaning and preparation method thereof | |
| CN110184133A (en) | A kind of liquid detergent that can allow clothing long-acting bacteriostatic | |
| CN103937629B (en) | The special laundry soap of infant | |
| CN112592774A (en) | Washing gel bead for wool fabric washing and preparation method thereof | |
| CN106318736A (en) | Washing soap for infants and preparation method thereof | |
| CN103614900A (en) | Washing method of colored stains on fabric | |
| CN103266022A (en) | Washing and deodorizing agent for washing feather | |
| CN107083689A (en) | A kind of method for removing duck's down peculiar smell | |
| CN108410593B (en) | Multi-effect laundry detergent and preparation method thereof | |
| CN114395450B (en) | Environment-friendly solid washing tablet and preparation method thereof | |
| CN105112174A (en) | Bactericidal mould-proof laundry detergent | |
| US20040010856A1 (en) | Method for customizing an aged appearance in denim garments | |
| CN104450240B (en) | A kind of diatomite liquid detergent and preparation method thereof | |
| US20170159235A1 (en) | Method and kit for accelerated aging of denim garments | |
| CN108192778B (en) | Non-toxic and non-irritant washing gel bead and preparation method thereof | |
| CN112877148A (en) | Bacteriostatic laundry detergent containing natural plant components | |
| CN104087458A (en) | Low foaming washing liquid used for underwear and preparation method thereof | |
| CN115340909B (en) | Multifunctional ecological cleaning particles and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190314 Address after: 317700 Zhongcun 69, Yuanyuan Street, Jiaojiang District, Taizhou City, Zhejiang Province Applicant after: Wang Yuan Address before: 610000 Xinhua Xinhua 4 group, Chengdu high tech Zone, Sichuan Applicant before: Xue Changlian |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |