CN106318736B - A kind of infant's laundry soap and preparation method thereof - Google Patents
A kind of infant's laundry soap and preparation method thereof Download PDFInfo
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- CN106318736B CN106318736B CN201610673381.9A CN201610673381A CN106318736B CN 106318736 B CN106318736 B CN 106318736B CN 201610673381 A CN201610673381 A CN 201610673381A CN 106318736 B CN106318736 B CN 106318736B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D15/00—Manufacture of resin soap or soaps derived from naphthenic acids; Compositions
- C11D15/04—Compositions containing resin soap or soap derived from naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of baby's laundry soap and preparation method thereof, which includes: maleic anhydride-styrene copolymers, sodium alginate, solid protein enzyme, melamine resin, fixed oil, palm oil, coconut oil, rosin, sodium hydroxide, Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether and water.Preparation method is that protease microcapsules first are made in protease, neat soap is prepared again, then it is mixed after neat soap being crushed with Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, it is warming up to 40-50 DEG C, glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, water and protease microcapsules are added, dispersion, after standing molding to get.Infant's laundry soap clean effect of the invention is good, can effectively remove all kinds of spots of infantile clothes；Stability of the enzyme in soap body is good.
Description
Technical field
The invention belongs to daily laundry soap technical field, a kind of infant's laundry soap and preparation method thereof is specifically designed.
Background technique
Enzyme is a kind of biocatalyst of high activity, has the characteristics that high catalytic efficiency, specificity are strong.Enzyme preparation application skill
The maturation of art is successfully applied to single enzyme preparation or complex enzyme formulation in detergent, can be in low temperature such as alkali protease
Under the conditions of efficiently decompose the protides spot such as milk stain, spot is removed from fabric under the synergistic effect of surfactant；
Lipase can targetedly disintegrate oil spot, reach removal purpose；Amylase can decompose and remove starch dirt
Stain；Cellulase, and it is not involved in the effect for decomposing spot, but to the fine fibre on cotton fiber surface during fabric washing
Dimension is decomposed, and has indirectly reached the clean effect of detergent from slight part in this way, is made as bright as new after fabric washing.Enzyme preparation
Efficient clean effect makes it be widely used in washing powder, liquid detergent and approve for consumer, applies skill
Art has tended to be mature by years development.
Milk stain can be often left on the clothes of infant, laundry soap on the market is mostly that detergency is put in the first place at present, suddenly
Omited clothing clean rear surface residue irritation and clothing dry after pliability.
Summary of the invention
A kind of baby's laundry soap and preparation method thereof is provided the purpose of the present invention is overcome the deficiencies in the prior art, this is washed
Clothing soap clean effect is good, can effectively remove all kinds of spots of infantile clothes.
A kind of baby's laundry soap, raw material include: 5-9 parts of maleic anhydride-styrene copolymers in parts by weight, sodium alginate
0.3-1.2 parts, 10 parts of solid protein enzyme, 2-6 parts of melamine resin, 4-10 parts of fixed oil, 2-9 parts of palm oil, 3-7 parts of coconut oil,
0.8-3.2 parts of rosin, 2-6 parts of sodium hydroxide, 0.8-2.4 parts of Sodium Polyacrylate, 0.1-0.4 parts of odium stearate, ethylene glycol is double hard
0.2-1 parts of resin acid ester, 0.4-0.9 parts of glycerol, 0.3-0.7 parts of borax, 0.1-0.8 parts of 4- formylphenyl boronic acid, citric acid 0.3-
0.5 part, 0.2-0.7 parts of alkyl polyoxyethylene base ether, 20-30 parts of water.
The preparation method of baby's laundry soap, comprising the following steps:
Step 1, maleic anhydride-styrene copolymers and sodium alginate are added in 1/2 parts by weight water, solid protein is added
Enzyme, stirring are added dropwise 1/2 parts by weight melamine resin, are warming up to 50-60 DEG C of heat preservation 2-3h, are down to room temperature, then 1/2 parts by weight are added dropwise
Melamine resin is warming up to 60-70 DEG C of heat preservation 2-3h, is down to room temperature, adjusts pH to 10.0~12.0, filters, is dry, obtaining albumen
Enzyme microcapsules；
Step 2, fixed oil, palm oil, coconut oil and rosin are mixed, water-bath is dissolved, and hydrogen-oxygen is added dropwise under agitation
Change sodium solution, continue to stir 1-3h, be cooled to 0-5 DEG C, filtering obtains neat soap；
Step 3, it mixes, is warming up to Sodium Polyacrylate, odium stearate, ethylene glycol double stearate after neat soap being crushed
40-50 DEG C, glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 parts by weight water and egg is added
White enzyme microcapsules, dispersion, after standing molding to get.
Further, in step 1 mixing speed be 200-300rpm, time 20-30min.
Further, the rate of addition of melamine resin is 1-3mL/min in step 1.
Further, the concentration of sodium hydroxide solution is 20-30wt% in step 2.
Further, granularity is in 40-60 mesh after neat soap crushes in step 3.
Further, rate of dispersion is 1000-1200rpm, 10-15min in step 3.
Infant's laundry soap clean effect of the invention is good, can effectively remove all kinds of spots of infantile clothes；Enzyme is in soap
Stability in body is good, still can achieve 70% or more in 3 year shelf-life enzyme activity.
Specific embodiment
Embodiment 1
A kind of baby's laundry soap, raw material include: 5 parts of maleic anhydride-styrene copolymers in parts by weight, sodium alginate
0.3 part, 10 parts of solid protein enzyme, 2 parts of melamine resin, 4 parts of fixed oil, 2 parts of palm oil, 3 parts of coconut oil, 0.8 part of rosin, hydrogen-oxygen
2 parts of sodium of change, 0.8 part of Sodium Polyacrylate, 0.1 part of odium stearate, 0.2 part of ethylene glycol double stearate, 0.4 part of glycerol, borax 0.3
Part, 0.1 part of 4- formylphenyl boronic acid, 0.3 part of citric acid, 0.2 part of alkyl polyoxyethylene base ether, 20 parts of water.
The preparation method of baby's laundry soap, comprising the following steps:
Step 1, maleic anhydride-styrene copolymers and sodium alginate are added in 1/2 parts by weight water, solid protein is added
Enzyme, stirring are added dropwise 1/2 parts by weight melamine resin, are warming up to 50 DEG C of heat preservation 3h, are down to room temperature, then 1/2 parts by weight melamine tree is added dropwise
Rouge is warming up to 60 DEG C of heat preservation 3h, is down to room temperature, adjusts pH to 10.0~12.0, filters, is dry, obtaining protease microcapsules；
Step 2, fixed oil, palm oil, coconut oil and rosin are mixed, water-bath is dissolved, and hydrogen-oxygen is added dropwise under agitation
Change sodium solution, continue to stir 1h, be cooled to 0-5 DEG C, filtering obtains neat soap；
Step 3, it is mixed after neat soap being crushed with Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, is warming up to 40
DEG C, it is micro- that glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 parts by weight water and protease is added
Capsule, dispersion, after standing molding to get.
Wherein, in step 1 mixing speed be 200rpm, time 30min, the rate of addition of melamine resin is 1mL/min；
The concentration of sodium hydroxide solution is 20wt% in step 2；Granularity is in 40 mesh, rate of dispersion after neat soap crushes in step 3
1000rpm、15min。
Embodiment 2
A kind of baby's laundry soap, raw material include: 6 parts of maleic anhydride-styrene copolymers in parts by weight, sodium alginate
0.7 part, 10 parts of solid protein enzyme, 5 parts of melamine resin, 8 parts of fixed oil, 3 parts of palm oil, 6 parts of coconut oil, 1.4 parts of rosin, hydrogen-oxygen
3 parts of sodium of change, 1.7 parts of Sodium Polyacrylate, 0.2 part of odium stearate, 0.4 part of ethylene glycol double stearate, 0.5 part of glycerol, borax 0.6
Part, 0.3 part of 4- formylphenyl boronic acid, 0.4 part of citric acid, 0.5 part of alkyl polyoxyethylene base ether, 24 parts of water.
The preparation method of baby's laundry soap, comprising the following steps:
Step 1, maleic anhydride-styrene copolymers and sodium alginate are added in 1/2 parts by weight water, solid protein is added
Enzyme, stirring are added dropwise 1/2 parts by weight melamine resin, are warming up to 55 DEG C of heat preservation 3h, are down to room temperature, then 1/2 parts by weight melamine tree is added dropwise
Rouge is warming up to 65 DEG C of heat preservation 3h, is down to room temperature, adjusts pH to 10.0~12.0, filters, is dry, obtaining protease microcapsules；
Step 2, fixed oil, palm oil, coconut oil and rosin are mixed, water-bath is dissolved, and hydrogen-oxygen is added dropwise under agitation
Change sodium solution, continue to stir 2h, be cooled to 0-5 DEG C, filtering obtains neat soap；
Step 3, it is mixed after neat soap being crushed with Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, is warming up to 40
DEG C, it is micro- that glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 parts by weight water and protease is added
Capsule, dispersion, after standing molding to get.
Wherein, in step 1 mixing speed be 250rpm, time 20min, the rate of addition of melamine resin is 2mL/min；
The concentration of sodium hydroxide solution is 20wt% in step 2；Granularity is in 40 mesh, rate of dispersion after neat soap crushes in step 3
1200rpm、15min。
Embodiment 3
A kind of baby's laundry soap, raw material include: 8 parts of maleic anhydride-styrene copolymers in parts by weight, sodium alginate
0.9 part, 10 parts of solid protein enzyme, 5 parts of melamine resin, 8 parts of fixed oil, 7 parts of palm oil, 5 parts of coconut oil, 2.3 parts of rosin, hydrogen-oxygen
5 parts of sodium of change, 1.7 parts of Sodium Polyacrylate, 0.3 part of odium stearate, 0.7 part of ethylene glycol double stearate, 0.6 part of glycerol, borax 0.5
Part, 0.6 part of 4- formylphenyl boronic acid, 0.4 part of citric acid, 0.6 part of alkyl polyoxyethylene base ether, 27 parts of water.
The preparation method of baby's laundry soap, comprising the following steps:
Step 1, maleic anhydride-styrene copolymers and sodium alginate are added in 1/2 parts by weight water, solid protein is added
Enzyme, stirring are added dropwise 1/2 parts by weight melamine resin, are warming up to 50 DEG C of heat preservation 3h, are down to room temperature, then 1/2 parts by weight melamine tree is added dropwise
Rouge is warming up to 60 DEG C of heat preservation 3h, is down to room temperature, adjusts pH to 10.0~12.0, filters, is dry, obtaining protease microcapsules；
Step 2, fixed oil, palm oil, coconut oil and rosin are mixed, water-bath is dissolved, and hydrogen-oxygen is added dropwise under agitation
Change sodium solution, continue to stir 1h, be cooled to 0-5 DEG C, filtering obtains neat soap；
Step 3, it is mixed after neat soap being crushed with Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, is warming up to 40
DEG C, it is micro- that glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 parts by weight water and protease is added
Capsule, dispersion, after standing molding to get.
Wherein, in step 1 mixing speed be 200rpm, time 30min, the rate of addition of melamine resin is 1mL/min；
The concentration of sodium hydroxide solution is 20wt% in step 2；Granularity is in 40 mesh, rate of dispersion after neat soap crushes in step 3
1000rpm、15min。
Embodiment 4
A kind of baby's laundry soap, raw material include: 9 parts of maleic anhydride-styrene copolymers in parts by weight, sodium alginate
1.2 parts, 10 parts of solid protein enzyme, 6 parts of melamine resin, 10 parts of fixed oil, 9 parts of palm oil, 7 parts of coconut oil, 3.2 parts of rosin, hydrogen
6 parts of sodium oxide molybdena, 2.4 parts of Sodium Polyacrylate, 0.4 part of odium stearate, 1 part of ethylene glycol double stearate, 0.9 part of glycerol, borax 0.7
Part, 0.8 part of 4- formylphenyl boronic acid, 0.5 part of citric acid, 0.7 part of alkyl polyoxyethylene base ether, 30 parts of water.
The preparation method of baby's laundry soap, comprising the following steps:
Step 1, maleic anhydride-styrene copolymers and sodium alginate are added in 1/2 parts by weight water, solid protein is added
Enzyme, stirring are added dropwise 1/2 parts by weight melamine resin, are warming up to 60 DEG C of heat preservation 2h, are down to room temperature, then 1/2 parts by weight melamine tree is added dropwise
Rouge is warming up to 70 DEG C of heat preservation 2h, is down to room temperature, adjusts pH to 10.0~12.0, filters, is dry, obtaining protease microcapsules；
Step 2, fixed oil, palm oil, coconut oil and rosin are mixed, water-bath is dissolved, and hydrogen-oxygen is added dropwise under agitation
Change sodium solution, continue to stir 3h, be cooled to 0-5 DEG C, filtering obtains neat soap；
Step 3, it is mixed after neat soap being crushed with Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, is warming up to 50
DEG C, it is micro- that glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 parts by weight water and protease is added
Capsule, dispersion, after standing molding to get.
Wherein, in step 1 mixing speed be 300rpm, time 20min, the rate of addition of melamine resin is 3mL/min；
The concentration of sodium hydroxide solution is 30wt% in step 2；Granularity is in 60 mesh, rate of dispersion after neat soap crushes in step 3
1200rpm、10min。
Embodiment 5
The present embodiment and the difference of embodiment 3 are: not containing Sodium Polyacrylate.
Embodiment 6
The present embodiment and the difference of embodiment 3 are: not containing citric acid.
Detergency evaluation
Using national standard carbon black soiled cotton JB-01, national standard albumen soiled cotton JB-02, national standard sebum soiled cotton JB-03, laundry soap is tested
Detergency, specific experiment condition and method are referring to QB1224-2012.As a result as follows:
It is dirty to protide dirt, sebum class by upper table result it is found that laundry soap of the invention has good dirt-removing power
Dirt has good emulsifying capacity, and clean effect is good, can effectively remove just urine stain, saliva stain, food greasy dirt of infants' wear etc..
Enzyme activity evaluation
Based on casein (DMC) by Savinase protease hydrolytic at the polypeptide of small fragment, the amino of release
Sour cluster and trinitrobenzene sulfonic acid (TNBS) form coloured compound.Standard curve is being drawn using standard enzyme, and with control
After enzyme march line core is calculated, the size of enzyme activity can be determined by the variation of unit of account time internal absorbance.
The sample made PE packaging film is sealed, 37 DEG C of climatic chambers are placed on.Respectively at 6 months, 1 year, 2
Year, after 3 years sample detection protease conservation rate, it is as a comparison by the enzyme activity of the fresh enzyme preparation of isodose, as a result as follows:
In embodiment 5, since Sodium Polyacrylate not being added, laundry soap detergency and enzyme activity is caused all to be declined, this can
Can be because Sodium Polyacrylate can allow protease microcapsules to be stabilized in the alkaline environment of soap base, to keep enzyme activity,
Improve detergency.
Softness test
Test method: 1. circulation washing: test towel (pure cotton) is put into tumbling-box washing machine, and liquid detergent is added, opens
Washing machine is opened, (expresses 30 minutes) be automatically performed washing process under the same conditions, be carried out continuously 20 times, taking-up is placed in clothes hanger
Upper naturally dry, use to be tested.
2. sensory testing: standard towel and test towel being laid in tester's palm of the hand (totally 10 people), with dynamics appropriate
It rubs on the cheek of both sides or experiences its flexibility simultaneously with hand, contrast standard towel scores to its softness
(10 is most soft, and 1 is most hard).
As seen from the above table, laundry soap of the invention has good submissive effect.In embodiment 6, since lemon not being added
Acid leads to flexibility degradation, this may be to make its docile in fabric surface because citric acid can soften prominent fiber.
Claims (1)
1. a kind of baby's laundry soap, it is characterised in that: raw material includes: 8 parts of maleic anhydride-styrene copolymers in parts by weight,
0.9 part of sodium alginate, 10 parts of solid protein enzyme, 5 parts of melamine resin, 8 parts of fixed oil, 7 parts of palm oil, 5 parts of coconut oil, rosin
2.3 parts, 5 parts of sodium hydroxide, 1.7 parts of Sodium Polyacrylate, 0.3 part of odium stearate, 0.7 part of ethylene glycol double stearate, glycerol 0.6
Part, 0.5 part of borax, 0.6 part of 4- formylphenyl boronic acid, 0.4 part of citric acid, 0.6 part of alkyl polyoxyethylene base ether, 27 parts of water；
The preparation method of baby's laundry soap, comprising the following steps:
Step 1, maleic anhydride-styrene copolymers and sodium alginate are added in 1/2 parts by weight water, solid protein enzyme are added,
Stirring is added dropwise 1/2 parts by weight melamine resin, is warming up to 50 DEG C of heat preservation 3h, is down to room temperature, then 1/2 parts by weight melamine resin is added dropwise,
60 DEG C of heat preservation 3h are warming up to, room temperature is down to, adjust pH to 10.0~12.0, filters, is dry, obtaining protease microcapsules；
Step 2, fixed oil, palm oil, coconut oil and rosin are mixed, water-bath is dissolved, and sodium hydroxide is added dropwise under agitation
Solution continues to stir 1h, is cooled to 0-5 DEG C, and filtering obtains neat soap；
Step 3, it is mixed after neat soap being crushed with Sodium Polyacrylate, odium stearate, ethylene glycol double stearate, is warming up to 40 DEG C,
Glycerol, borax, 4- formylphenyl boronic acid, citric acid, alkyl polyoxyethylene base ether, 1/2 parts by weight water and the micro- glue of protease is added
Capsule, dispersion, after standing molding to get；
Wherein, in step 1 mixing speed be 200rpm, time 30min, the rate of addition of melamine resin is 1mL/min；Step
The concentration of sodium hydroxide solution is 20wt% in 2；Granularity is in 40 mesh after neat soap crushes in step 3, rate of dispersion 1000rpm, when
Between be 15min.
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| CN201610673381.9A CN106318736B (en) | 2016-08-16 | 2016-08-16 | A kind of infant's laundry soap and preparation method thereof |
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| CN106318736B true CN106318736B (en) | 2019-04-12 |
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| CN107129887A (en) * | 2017-05-09 | 2017-09-05 | 跨越生物科技（滁州）有限公司 | A kind of strong low bubble hand clothes washing soap of soil release performance |
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|---|---|---|---|---|
| CN1687345A (en) * | 2005-05-10 | 2005-10-26 | 刘桂堂 | Concentrated solution for washing and preparation method thereof |
| CN103834512A (en) * | 2014-03-11 | 2014-06-04 | 昆明理工大学 | Montan wax washing soap and preparation method thereof |
| WO2014179305A1 (en) * | 2013-04-29 | 2014-11-06 | IINN, Inc. | Soap composition |
| CN104651099A (en) * | 2015-01-22 | 2015-05-27 | 韦爱琴 | Mildew-proof antibacterial special laundry soap for infants |
-
2016
- 2016-08-16 CN CN201610673381.9A patent/CN106318736B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687345A (en) * | 2005-05-10 | 2005-10-26 | 刘桂堂 | Concentrated solution for washing and preparation method thereof |
| WO2014179305A1 (en) * | 2013-04-29 | 2014-11-06 | IINN, Inc. | Soap composition |
| CN103834512A (en) * | 2014-03-11 | 2014-06-04 | 昆明理工大学 | Montan wax washing soap and preparation method thereof |
| CN104651099A (en) * | 2015-01-22 | 2015-05-27 | 韦爱琴 | Mildew-proof antibacterial special laundry soap for infants |
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