CN106318208A - Anti-moth paint mortar and preparing method thereof - Google Patents

Anti-moth paint mortar and preparing method thereof Download PDF

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Publication number
CN106318208A
CN106318208A CN201610712760.4A CN201610712760A CN106318208A CN 106318208 A CN106318208 A CN 106318208A CN 201610712760 A CN201610712760 A CN 201610712760A CN 106318208 A CN106318208 A CN 106318208A
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China
Prior art keywords
parts
moth
powder
paint
eating
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CN201610712760.4A
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Chinese (zh)
Inventor
白艳萍
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Harbin Qiyi Zhixing Technology Development Co Ltd
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Harbin Qiyi Zhixing Technology Development Co Ltd
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Priority to CN201610712760.4A priority Critical patent/CN106318208A/en
Publication of CN106318208A publication Critical patent/CN106318208A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D193/00Coating compositions based on natural resins; Coating compositions based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to an anti-moth paint mortar and preparing method thereof. The raw material of anti-moth paint mortar comprises refined raw lacquer, quartz powder, quicklime powder, wood powder, stalactite powder, insect repellent, adhesive. The materials is prepared from, by weight, 30-40 parts of refined raw lacquer, 25-35 parts of quartz powder, 20-25 parts of quicklime powder, 15-22 parts of wood powder, 5-12 parts of stalactite powder, 10-15 parts of insect repellent and 8-12 parts of adhesive. The preparing steps are as follows: (1) preparing the mixed powder; (2) preparing the insect repellent; (3) mixing. The anti-moth paint mortar adopts fungal enzyme for refining processing of raw lacquer, and can effectively adjust the rheology of the raw lacquer. The produced paint mortar has strong adhesion and high hardness, with corrosion-resistant, wear-resistant, and anti-moth function. It is easy to be smeared on the wood embryo to improve the hardness and strength of wood embryo and to fill the holes as well as the gaps on the board. The anti-moth agent is made by the extraction of active ingredients from Chinese medicine, and enhances the pest control effect on the board.

Description

A kind of Anti-moth-eating paint mortar and preparation method thereof
Technical field
The present invention relates to lacquer painting and make field, particularly relate to a kind of Anti-moth-eating paint mortar and preparation method thereof.
Background technology
In lacquer painting manufacturing process, lacquer painting tire plate is one of basic material making lacquer painting, and lacquer painting tire plate is commonly called as painting plate, Being the tire bone of lacquer painting, most paint plate is many with plank as tire, it is also possible to metallic plate, fibre board substitute, and tire plate need through Stick one piece of cloth or paper on top of another cloth, scrape the paint operation such as ash, japanning process after just can use.Scraping paint ash is highly important step, because paint ash is possible not only to Hide the eye on lacquerware carcass surface, crack, scratch etc., play the effect of filling-in defect, additionally it is possible to play enhancing paint film attachment The effect of power, reaches laborsaving, the purpose of material-saving, and paints grieshoch and also help the processing and forming works such as follow-up polishing and scraping Sequence, is better protected from wood deformation.Some wood embryo wooden soft, in order to improve wood embryo long-term mar proof, it is necessary to smear Paint ash.
At present, existing paint ash is many adjusts dark grey to form with lacquer, it is also possible to adjust Gypsum Fibrosum powder with Fructus anacardii paint, synthetic lacquer.This Generally there is the deficiency that cohesive is general in class paint ash, and composition is single, preparation section simple, and the finished product paint ash prepared is attached Put forth effort relatively low, it is impossible to fill up eye, the gap smoothing on plank well, and this kind of paint ash scarcely possesses Anti-moth-eating merit Can, and wood boards are due to material reason, easily occur that the situation of damaging by worms, existing paint ash cannot meet the making of high-quality lacquer painting Demand.
Summary of the invention
It is an object of the invention to provide a kind of Anti-moth-eating paint mortar and preparation method thereof, have that viscosity is big, smear conveniently, The advantage of Anti-moth-eating.
The purpose of the present invention is achieved through the following technical solutions:
A kind of Anti-moth-eating paint mortar, the raw material of described Anti-moth-eating paint mortar is refined Resina Toxicodendri verniciflui, silica flour, calcium lime powder, wood dust, Stalactitum powder, insect-proof agent, binding agent, described raw materials by weight portion, refined Resina Toxicodendri verniciflui 30-40 part, silica flour 25-35 part, calculogenesis Ashes 20-25 part, wood dust 15-22 part, Stalactitum powder 5-12 part, insect-proof agent 10-15 part, binding agent 8-12 part.
Described a kind of Anti-moth-eating paint mortar, raw material presses optimum weight number, refined 35 parts of Resina Toxicodendri verniciflui, silica flour 28 parts, calculogenesis Ashes 22 parts, wood dust 15 parts, 8 parts of Stalactitum powder, insect-proof agent 12 parts, binding agent 8 parts.
Described a kind of Anti-moth-eating paint mortar, is made up by following parts by weight of raw material in described insect-proof agent, Herba Cymbopogonis Citrari 10-15 Part, Folium Artemisiae Argyi 8-12 part, Flos Caryophylli 5-8 part.
Described a kind of Anti-moth-eating paint mortar, in described insect-proof agent, raw material presses optimum weight number, Herba Cymbopogonis Citrari 15 parts, Folium Artemisiae Argyi 10 Part, Flos Caryophylli 7 parts.
Described binding agent is the one in polyvinyl acetate resin adhesive, osseocolla, casein.
Described refined Resina Toxicodendri verniciflui is to be added the fungal enzyme of 3-5%, the diluent of 10-15% by Resina Toxicodendri verniciflui, through enzyme reaction, grinding, dilute Obtain after releasing.
The preparation process of described refined Resina Toxicodendri verniciflui is as follows:
Step one: after taking Resina Toxicodendri verniciflui filtering and impurity removing, is placed in container, is gradually heating to 20-30 DEG C, is stirred continuously while intensification, Stirring simultaneously, adds fungal enzyme, and is passed through oxygen, and under the conditions of 20-30 DEG C, constant temperature stirring reaction 5-8h, obtains Resina Toxicodendri verniciflui emulsion;
Step 2: take Resina Toxicodendri verniciflui emulsion, continues stirring under the conditions of 20-30 DEG C, and stirring is simultaneously introduced diluent, after stirring, After grinding 1.5-2h in being placed in grinder, obtain refined Resina Toxicodendri verniciflui.
Described Resina Toxicodendri verniciflui is selected and is originated in the Guizhou natural raw lacquer of Guizhou Bijie or the hair dam natural raw lacquer of enshi.
Described diluent is the one in retinal, oleum lini, Oleum Terebinthinae.
Described a kind of Anti-moth-eating paint mortar, its preparation section is as follows:
(1) mixed powder is prepared:
A, prepare silica flour: by weight, take after quartz cleans, be placed in crusher for crushing to 600-800 mesh, sieve and obtain Silica flour;
B, prepare wood dust: by weight, choose dry wood flour and be placed in pulverizer, be crushed to 500-700 mesh, sieve To wood dust;
C, prepare Stalactitum powder: by weight, take Stalactitum, after rinsing 5-10min with clear water, naturally dry, be placed in pulverizing It is crushed to 1000-1200 mesh in machine, sieves and obtain Stalactitum powder;
D, prepare mixed powder: by weight, take silica flour, wood dust, Stalactitum powder, added the calculogenesis of 400-500 mesh sieve Ashes, is placed in mixer, after middling speed mixing 20-30min, obtains mixed powder;
(2) insect-proof agent is prepared:
A, by weight, takes Herba Cymbopogonis Citrari, Folium Artemisiae Argyi, Flos Caryophylli, after cleaning with clear water, dries top layer moisture, is respectively placed in distillation, Inject water vapour, in 90-100 DEG C, distill 3-4h under conditions of the rice steamer pressure on top surface of 1kg/ square centimeter, obtain Herba Cymbopogonis Citrari distillation Liquid, Folium Artemisiae Argyi distillate, Flos Caryophylli distillate;
B, taking Herba Cymbopogonis Citrari distillate, Folium Artemisiae Argyi distillate, Flos Caryophylli distillate, condensation, to 30-35 DEG C, is placed in ultrasonic extractor, Under the conditions of 25-35 DEG C, use 300-500W ultrasonic Treatment 15-25min, obtain Herba Cymbopogonis Citrari extracting solution, Folium Artemisiae Argyi extractive liquid, Flos Caryophylli extracting solution;
C, take Herba Cymbopogonis Citrari extracting solution, after Folium Artemisiae Argyi extractive liquid, Flos Caryophylli extracting solution at the uniform velocity mix 15-20min in being placed in mixer, obtain Insect-proof agent;
(3) mixing:
By weight, taking mixed powder, be placed in blender, stirring simultaneously, adds insect-proof agent, is stirring evenly and then adding into refined raw Paint, binding agent, after stirring 1-2h, get product.
Beneficial effects of the present invention: a kind of Anti-moth-eating paint mortar of the present invention, uses fungal enzyme that Resina Toxicodendri verniciflui carries out refined place Reason, can effectively regulate Resina Toxicodendri verniciflui rheological characteristic, and the paint mortar produced, and adhesive force is strong, and hardness is high, and also has corrosion resistant Erosion, wear-resisting, the function of Anti-moth-eating, be applied on wood embryo, smeared conveniently, and can be effectively improved the hardness of wood embryo and strong Degree, fills up eye, the gap smoothing on plank well, and the effective ingredient extracted in Chinese medicine makes insect-proof agent, improves plank Vermins-proof effect.
Select calcium lime powder and wood dust, can effectively fill up the eye on plank, gap, the selection of calcium lime powder, can carry The aridity of high plank, and there is certain insect protected function;The selection of wood dust, improves the utilization rate of wood dust, for wood flour Exploitation provide new approach, and the use cost of calcium lime powder and wood dust is low, and raw material sources are extensive.
Selecting silica flour, Stalactitum powder, can be effectively improved the hardness of plank, wherein, the hardness of quartz is high, structure is tight Close, and it is widely distributed, be easy to exploitation, is easily worked, and use cost is low.
Select insect-proof agent, improve the insect protected of plank;Insect-proof agent selection Herba Cymbopogonis Citrari, Folium Artemisiae Argyi, Flos Caryophylli are as raw material, through steaming Evaporate, ultrasonic extraction is made, and makes paint mortar possess the function of pest control and anticorrosion erosion, improves the anticorrosion of plank, Anti-moth-eating.
Using binding agent to be in harmonious proportion paint ash with refined Resina Toxicodendri verniciflui, Resina Toxicodendri verniciflui has elasticity, and mar proof is higher, and hardness Height, adhesive force are strong, are that other synthetic lacquers cannot be substituted, use binding agent can be effectively improved silica flour, calcium lime powder, wood flour Powder, Stalactitum powder and the bonding effect of plank.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of Anti-moth-eating paint mortar, the raw material of described Anti-moth-eating paint mortar is refined Resina Toxicodendri verniciflui, silica flour, calcium lime powder, wood dust, Stalactitum powder, insect-proof agent, binding agent, described raw materials by weight portion, refined Resina Toxicodendri verniciflui 30-40 part, silica flour 25-35 part, calculogenesis Ashes 20-25 part, wood dust 15-22 part, Stalactitum powder 5-12 part, insect-proof agent 10-15 part, binding agent 8-12 part.
Embodiment 2
Described a kind of Anti-moth-eating paint mortar, raw material presses optimum weight number, refined 35 parts of Resina Toxicodendri verniciflui, silica flour 28 parts, calcium lime powder 22 parts, wood dust 15 parts, 8 parts of Stalactitum powder, insect-proof agent 12 parts, binding agent 8 parts.
Embodiment 3
Described a kind of Anti-moth-eating paint mortar, is made up by following parts by weight of raw material in described insect-proof agent, Herba Cymbopogonis Citrari 10-15 part, Folium Artemisiae Argyi 8-12 part, Flos Caryophylli 5-8 part.
Embodiment 4
Described a kind of Anti-moth-eating paint mortar, in described insect-proof agent, optimum weight number pressed by raw material, Herba Cymbopogonis Citrari 15 parts, Folium Artemisiae Argyi 10 parts, Flos Caryophylli 7 parts.
Embodiment 5
Described binding agent is the one in polyvinyl acetate resin adhesive, osseocolla, casein.
Embodiment 6
Described refined Resina Toxicodendri verniciflui is to be added the fungal enzyme of 3-5%, the diluent of 10-15% by Resina Toxicodendri verniciflui, after enzyme reaction, grinding, dilute Obtain.
Embodiment 7
The preparation process of described refined Resina Toxicodendri verniciflui is as follows:
Step one: after taking Resina Toxicodendri verniciflui filtering and impurity removing, is placed in container, is gradually heating to 20-30 DEG C, is stirred continuously while intensification, Stirring simultaneously, adds fungal enzyme, and is passed through oxygen, and under the conditions of 20-30 DEG C, constant temperature stirring reaction 5-8h, obtains Resina Toxicodendri verniciflui emulsion;
Step 2: take Resina Toxicodendri verniciflui emulsion, continues stirring under the conditions of 20-30 DEG C, and stirring is simultaneously introduced diluent, after stirring, After grinding 1.5-2h in being placed in grinder, obtain refined Resina Toxicodendri verniciflui.
Embodiment 8
Described Resina Toxicodendri verniciflui is selected and is originated in the Guizhou natural raw lacquer of Guizhou Bijie or the hair dam natural raw lacquer of enshi.
Embodiment 9
Described diluent is the one in retinal, oleum lini, Oleum Terebinthinae.
Embodiment 10
Described a kind of Anti-moth-eating paint mortar, its preparation section is as follows:
(1) mixed powder is prepared:
A, prepare silica flour: by weight, take after quartz cleans, be placed in crusher for crushing to 600-800 mesh, sieve and obtain Silica flour;
B, prepare wood dust: by weight, choose dry wood flour and be placed in pulverizer, be crushed to 500-700 mesh, sieve To wood dust;
C, prepare Stalactitum powder: by weight, take Stalactitum, after rinsing 5-10min with clear water, naturally dry, be placed in pulverizing It is crushed to 1000-1200 mesh in machine, sieves and obtain Stalactitum powder;
D, prepare mixed powder: by weight, take silica flour, wood dust, Stalactitum powder, added the calculogenesis of 400-500 mesh sieve Ashes, is placed in mixer, after middling speed mixing 20-30min, obtains mixed powder;
(2) insect-proof agent is prepared:
A, by weight, takes Herba Cymbopogonis Citrari, Folium Artemisiae Argyi, Flos Caryophylli, after cleaning with clear water, dries top layer moisture, is respectively placed in distillation, Inject water vapour, in 90-100 DEG C, distill 3-4h under conditions of the rice steamer pressure on top surface of 1kg/ square centimeter, obtain Herba Cymbopogonis Citrari distillation Liquid, Folium Artemisiae Argyi distillate, Flos Caryophylli distillate;
B, taking Herba Cymbopogonis Citrari distillate, Folium Artemisiae Argyi distillate, Flos Caryophylli distillate, condensation, to 30-35 DEG C, is placed in ultrasonic extractor, Under the conditions of 25-35 DEG C, use 300-500W ultrasonic Treatment 15-25min, obtain Herba Cymbopogonis Citrari extracting solution, Folium Artemisiae Argyi extractive liquid, Flos Caryophylli extracting solution;
C, take Herba Cymbopogonis Citrari extracting solution, after Folium Artemisiae Argyi extractive liquid, Flos Caryophylli extracting solution at the uniform velocity mix 15-20min in being placed in mixer, obtain Insect-proof agent;
(3) mixing:
By weight, taking mixed powder, be placed in blender, stirring simultaneously, adds insect-proof agent, is stirring evenly and then adding into refined raw Paint, binding agent, after stirring 1-2h, get product.

Claims (10)

1. an Anti-moth-eating paint mortar, it is characterised in that: the raw material of described Anti-moth-eating paint mortar is refined Resina Toxicodendri verniciflui, silica flour, life Pulverized limestone, wood dust, Stalactitum powder, insect-proof agent, binding agent, described raw materials by weight portion, refined Resina Toxicodendri verniciflui 30-40 part, quartz Powder 25-35 part, calcium lime powder 20-25 part, wood dust 15-22 part, Stalactitum powder 5-12 part, insect-proof agent 10-15 part, binding agent 8- 12 parts.
A kind of Anti-moth-eating paint mortar, it is characterised in that: raw material presses optimum weight number, refined raw Paint 35 parts, silica flour 28 parts, calcium lime powder 22 parts, wood dust 15 parts, 8 parts of Stalactitum powder, insect-proof agent 12 parts, binding agent 8 parts.
3. according to Anti-moth-eating paint mortar a kind of described in claim 1-2 any one, it is characterised in that: by former in described insect-proof agent Material is made by following parts by weight, Herba Cymbopogonis Citrari 10-15 part, Folium Artemisiae Argyi 8-12 part, Flos Caryophylli 5-8 part.
A kind of Anti-moth-eating paint mortar, it is characterised in that: in described insect-proof agent, optimum weight pressed by raw material Number, Herba Cymbopogonis Citrari 15 parts, Folium Artemisiae Argyi 10 parts, Flos Caryophylli 7 parts.
5. according to Anti-moth-eating paint mortar a kind of described in claim 1-2 any one, it is characterised in that: described binding agent is poly-vinegar One in vinyl acetate resin glue, osseocolla, casein.
6. according to Anti-moth-eating paint mortar a kind of described in claim 1-2 any one, it is characterised in that: described refined Resina Toxicodendri verniciflui be by Resina Toxicodendri verniciflui add the fungal enzyme of 3-5%, the diluent of 10-15%, through enzyme reaction, grind, dilute after obtain.
A kind of Anti-moth-eating paint mortar, it is characterised in that: the preparation process of described refined Resina Toxicodendri verniciflui is such as Under:
Step one: after taking Resina Toxicodendri verniciflui filtering and impurity removing, is placed in container, is gradually heating to 20-30 DEG C, is stirred continuously while intensification, Stirring simultaneously, adds fungal enzyme, and is passed through oxygen, and under the conditions of 20-30 DEG C, constant temperature stirring reaction 5-8h, obtains Resina Toxicodendri verniciflui emulsion;
Step 2: take Resina Toxicodendri verniciflui emulsion, continues stirring under the conditions of 20-30 DEG C, and stirring is simultaneously introduced diluent, after stirring, After grinding 1.5-2h in being placed in grinder, obtain refined Resina Toxicodendri verniciflui.
8. according to Anti-moth-eating paint mortar a kind of described in claim 6-7 any one, it is characterised in that: described Resina Toxicodendri verniciflui is selected and is originated in The Guizhou natural raw lacquer of Guizhou Bijie or the hair dam natural raw lacquer of enshi.
9. according to Anti-moth-eating paint mortar a kind of described in claim 6-7 any one, it is characterised in that: described diluent is Colophonium One in oil, oleum lini, Oleum Terebinthinae.
10. according to Anti-moth-eating paint mortar a kind of described in claim 1-9 any one, it is characterised in that: its preparation section is as follows:
(1) mixed powder is prepared:
A, prepare silica flour: by weight, take after quartz cleans, be placed in crusher for crushing to 600-800 mesh, sieve and obtain Silica flour;
B, prepare wood dust: by weight, choose dry wood flour and be placed in pulverizer, be crushed to 500-700 mesh, sieve To wood dust;
C, prepare Stalactitum powder: by weight, take Stalactitum, after rinsing 5-10min with clear water, naturally dry, be placed in pulverizing It is crushed to 1000-1200 mesh in machine, sieves and obtain Stalactitum powder;
D, prepare mixed powder: by weight, take silica flour, wood dust, Stalactitum powder, added the calculogenesis of 400-500 mesh sieve Ashes, is placed in mixer, after middling speed mixing 20-30min, obtains mixed powder;
(2) insect-proof agent is prepared:
A, by weight, takes Herba Cymbopogonis Citrari, Folium Artemisiae Argyi, Flos Caryophylli, after cleaning with clear water, dries top layer moisture, is respectively placed in distillation, Inject water vapour, in 90-100 DEG C, distill 3-4h under conditions of the rice steamer pressure on top surface of 1kg/ square centimeter, obtain Herba Cymbopogonis Citrari distillation Liquid, Folium Artemisiae Argyi distillate, Flos Caryophylli distillate;
B, taking Herba Cymbopogonis Citrari distillate, Folium Artemisiae Argyi distillate, Flos Caryophylli distillate, condensation, to 30-35 DEG C, is placed in ultrasonic extractor, Under the conditions of 25-35 DEG C, use 300-500W ultrasonic Treatment 15-25min, obtain Herba Cymbopogonis Citrari extracting solution, Folium Artemisiae Argyi extractive liquid, Flos Caryophylli extracting solution;
C, take Herba Cymbopogonis Citrari extracting solution, after Folium Artemisiae Argyi extractive liquid, Flos Caryophylli extracting solution at the uniform velocity mix 15-20min in being placed in mixer, obtain Insect-proof agent;
(3) mixing:
By weight, taking mixed powder, be placed in blender, stirring simultaneously, adds insect-proof agent, is stirring evenly and then adding into refined raw Paint, binding agent, after stirring 1-2h, get product.
CN201610712760.4A 2016-08-24 2016-08-24 Anti-moth paint mortar and preparing method thereof Pending CN106318208A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107746603A (en) * 2017-07-26 2018-03-02 深圳市天橙宝投资发展有限公司 A kind of fungicidal paint
CN109098474A (en) * 2017-05-10 2018-12-28 刘义辉 A kind of cabin of protecting a forest of forest conservation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109098474A (en) * 2017-05-10 2018-12-28 刘义辉 A kind of cabin of protecting a forest of forest conservation
CN109098474B (en) * 2017-05-10 2020-12-04 阜阳市伟叶家具有限公司 Forest protection cabin for forest resource protection
CN107746603A (en) * 2017-07-26 2018-03-02 深圳市天橙宝投资发展有限公司 A kind of fungicidal paint

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Application publication date: 20170111