CN106317493A - Rubber antiskid and abrasion-resistant shoe sole and preparation method thereof - Google Patents
Rubber antiskid and abrasion-resistant shoe sole and preparation method thereof Download PDFInfo
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- CN106317493A CN106317493A CN201610747515.7A CN201610747515A CN106317493A CN 106317493 A CN106317493 A CN 106317493A CN 201610747515 A CN201610747515 A CN 201610747515A CN 106317493 A CN106317493 A CN 106317493A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention provides a rubber antiskid and abrasion-resistant shoe sole and a preparation method thereof. The rubber antiskid and abrasion-resistant shoe sole is prepared from, by weight, 20-30 parts of butadiene rubber, 40-55 parts of natural rubber, 1-2 parts of sulfur, 4.5-6.5 parts of nano-zinc oxide, 1-3 parts of stearic acid, 0.5-3 parts of vulcanization accelerator DM, 0.5-1.5 parts of nanometer silicon nitride, 40-50 parts of carbon black, 1-3 parts of antiager DNP, 6-10 parts of diethyl phthalate, 7-15 parts of modified benzoxazine resin, 5-15 parts of bicyclopentadiene dioxide epoxy resin, 5-10 parts of B205 ceramic sand, 3-8 parts of high-performance hollow glass beads and 7.5-12.5 parts of aramid fibers. The rubber antiskid and abrasion-resistant shoe sole is prepared through the steps of pre-mixing, mixing, cooling and vulcanizing. The formula and preparation method of shoe sole rubber are improved, the shoe sole rubber with the high anti-skid coefficient and abrasion resistance is obtained, the service life is prolonged, and the use comfort is improved.
Description
Technical field
The present invention relates to rubber materials, be specifically related to a kind of rubber antiskid wear-resisting sole and preparation method thereof.
Background technology
Footwear are that people go on a journey requisite articles for use, and footwear of a great variety is available for various people and selects.Rubber is made
For a kind of elastomeric polymer, raw material is sufficient, cheap, and has the multiple advantages such as good springiness, intensity are high, be especially suitable for for
As the material making sole.People have different requirements to footwear, but wear-resisting and non-skid property is people institute common prescription.
Along with the development in epoch, people are more and more higher to the requirement of footwear, have running shoe, sneakers, football boot etc. to be specifically designed to various motion
Footwear, substantial amounts of friction can be produced with ground when these footwear are worn, therefore can cause the biggest abrasion, thus to material for sole of shoe
Wearability is had higher requirement.Shoes wear no resistance, and affect the physical life of shoes.Equally on the road surface of snow and ice cover and
Rainy day easy ways section, wears the most anti-skidding footwear and is easy to fall down, and some meeting therefore traumatic injurys, particularly old man and child are more easy to fall
Wound.Occurring that the frictional force that the phenomenon skidded is because between road surface and sole drops to the least, the footwear that market is sold are commonly used in footwear
Suppress lines at the end, but after wearing a period of time, lines can be smoothed, still do not have anti-skidding effect.But rubber system simultaneously
To there is also the biggest deficiency, especially rubber sliding-proof excessively poor for the sole become, and at ice face or the smooth earth that has hydrops, wears
The sole being made up of elastomeric material is very easy to slip.
Summary of the invention
Solve the technical problem that: it is an object of the invention to provide a kind of rubber antiskid wear resistant shoe, it solve sole and prevent
Sliding weak effect, a series of shortcomings such as the most wear-resisting, improve the service life of shoes.
Technical scheme: a kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 20-
30 parts, natural rubber 40-55 part, sulfur 1-2 part, nano zine oxide 4.5-6.5 part, stearic acid 1-3 part, vulcanization accelerator
DM0.5-3 part, nano-silicon nitride 0.5-1.5 part, white carbon black 40-50 part, antioxidant D NP1-3 part, diethyl phthalate 6-10
Part, modified benzoxazine resin 7-15 part, bicyclopentadiene dioxide expoxy resin 5-15 part, B205 ceramic sand 5-10 part, height
Performance hollow glass micropearl 3-8 part, aramid fiber 7.5-12.5 part.
It is further preferred that described a kind of rubber antiskid wear-resisting sole, following component it is prepared from by weight: suitable
Buna 22-28 part, natural rubber 45-50 part, sulfur 1.5-1.8 part, nano zine oxide 5-6 part, stearic acid 1.5-2.5 part,
Accelerator DM 1-2.5 part, nano-silicon nitride 0.8-1.2 part, white carbon black 43-58 part, antioxidant D NP1.8-2.2 part, adjacent benzene two
Formic acid diethylester 7-9 part, modified benzoxazine resin 10-13 part, bicyclopentadiene dioxide expoxy resin 8-12 part, B205 pottery
Porcelain sand 8-10 part, high-performance hollow glass micropearl 5-7 part, aramid fiber 9-11 part.
Further, described a kind of rubber antiskid wear-resisting sole, described accelerator DM be diphenyl disulfide also
Thiazole.
Further, described a kind of rubber antiskid wear-resisting sole, described antioxidant D NP is N, N'-bis-(betanaphthyl)
P-phenylenediamine.
The preparation method of above-mentioned rubber antiskid wear-resisting sole comprises the following steps:
(1) pre-mixing: white carbon black is added with butadiene rubber, natural rubber, nano zine oxide, stearic acid and diethyl phthalate
Enter in banbury after masterbatching 5-12 minute, and at room temperature deposit 24-36 hour；
(2) mixing: to divide 1-2.5 refined under conditions of temperature 100-120 DEG C by blend glue stuff input rubber mixing machine in step (1)
Accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide ring is added after clock
Epoxy resins, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 3.5-5 minute；
(3) cooling: by the material preforms after mixing, cool down 24 hours；
(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, and curing temperature is 140-160 DEG C, the time
For 4-7 minute, sulfide stress was that 15-20MPa prepares finished product.
Further, the preparation method of described a kind of rubber antiskid wear-resisting sole, the masterbatching time in described step (1)
For 8-10 minute, at room temperature deposit 30 hours.
Further, the preparation method of described a kind of rubber antiskid wear-resisting sole, in described step (2), temperature is
115 DEG C, the refining time is 1.5 minutes, and the continuation refining time is 4.5 minutes.
Further, the preparation method of described a kind of rubber antiskid wear-resisting sole, curing temperature in described step (4)
For 145-155 DEG C, the time is 5 minutes, and sulfide stress is 18MPa.
Beneficial effect: rubber antiskid wear-resisting sole prepared by the present invention has the highest anti-skid wearable, Akron weares and teares
The life-span of rubber boots, up to 0.32cm3/1.61km, is improve more than 3 times by value；Dry sliding coefficient is 1.35, and wet and slippery coefficient is
0.92, well ensure that the performance comfortable and easy to wear of rubber soles.
Detailed description of the invention
Embodiment 1
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 20 parts, natural rubber 55
Part, 2 parts of sulfur, nano zine oxide 4.5 parts, stearic acid 1 part, accelerator DM 0.5 part, nano-silicon nitride 0.5 part, white carbon black
40 parts, antioxidant D NP3 part, diethyl phthalate 10 parts, modified benzoxazine resin 7 parts, bicyclopentadiene dioxide ring
Epoxy resins 15 parts, B205 ceramic sand 10 parts, high-performance hollow glass micropearl 3 parts, aramid fiber 7.5 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 5 minutes, and at room temperature deposited 36
Hour；(2) mixing: blend glue stuff in step (1) to be put into and adds after rubber mixing machine is refined 1 minute under conditions of temperature 120 DEG C
Enter accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide asphalt mixtures modified by epoxy resin
Fat, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 3.5 minutes；(3) cooling: after mixing
Material preforms, cools down 24 hours；(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, curing temperature
Being 140 DEG C, the time is 4 minutes, and sulfide stress is that 20MPa prepares finished product.
Embodiment 2
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 30 parts, natural rubber 40
Part, 1 part of sulfur, nano zine oxide 6.5 parts, stearic acid 3 parts, accelerator DM 3 parts, nano-silicon nitride 1.5 parts, white carbon black 50
Part, antioxidant D NP1 part, diethyl phthalate 6 parts, modified benzoxazine resin 15 parts, bicyclopentadiene dioxide epoxy
Resin 5 parts, B205 ceramic sand 5 parts, high-performance hollow glass micropearl 8 parts, aramid fiber 12.5 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 12 minutes, and at room temperature deposited
24 hours；(2) mixing: blend glue stuff in step (1) to be put in rubber mixing machine and refines 2.5 minutes under conditions of temperature 100 DEG C
Rear addition accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide epoxy
Resin, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 5 minutes；(3) cooling: after mixing
Material preforms, cools down 24 hours；(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, curing temperature
Being 160 DEG C, the time is 7 minutes, and sulfide stress is that 15MPa prepares finished product.
Embodiment 3
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 22 parts, natural rubber 50
Part, 1.8 parts of sulfur, nano zine oxide 6 parts, stearic acid 1.5 parts, accelerator DM 2.5 parts, nano-silicon nitride 1.2 parts, charcoal
Black 43 parts, antioxidant D NP1.8 part, diethyl phthalate 7 parts, modified benzoxazine resin 13 parts, titanium dioxide dicyclo penta 2
Alkene epoxy resin 8 parts, B205 ceramic sand 10 parts, high-performance hollow glass micropearl 7 parts, aramid fiber 11 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 8 minutes, and at room temperature deposited 30
Hour；(2) mixing: blend glue stuff in step (1) to be put into after rubber mixing machine is refined 1.5 minutes under conditions of temperature 115 DEG C
Add accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide asphalt mixtures modified by epoxy resin
Fat, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 4.5 minutes；(3) cooling: after mixing
Material preforms, cools down 24 hours；(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, curing temperature
Being 155 DEG C, the time is 5 minutes, and sulfide stress is that 18MPa prepares finished product.
Embodiment 4
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 28 parts, natural rubber 45
Part, 1.5 parts of sulfur, nano zine oxide 5 parts, stearic acid 2.5 parts, accelerator DM 1 part, nano-silicon nitride 0.8 part, white carbon black
58 parts, antioxidant D NP2.2 part, diethyl phthalate 9 parts, modified benzoxazine resin 10 parts, bicyclopentadiene dioxide
Epoxy resin 12 parts, B205 ceramic sand 8 parts, high-performance hollow glass micropearl 5 parts, aramid fiber 9 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 10 minutes, and at room temperature deposited
30 hours；(2) mixing: blend glue stuff in step (1) to be put in rubber mixing machine and refines 1.5 minutes under conditions of temperature 115 DEG C
Rear addition accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide epoxy
Resin, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 4.5 minutes；(3) cooling: after mixing
Material preforms, cool down 24 hours；(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, sulfuration temperature
Degree is 145 DEG C, and the time is 5 minutes, and sulfide stress is that 18MPa prepares finished product.
Embodiment 5
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 25 parts, natural rubber 50
Part, 1.6 parts of sulfur, nano zine oxide 5.5 parts, stearic acid 2 parts, accelerator DM 2 parts, nano-silicon nitride 1 part, white carbon black 50
Part, antioxidant D NP 2 parts, diethyl phthalate 8 parts, modified benzoxazine resin 11 parts, bicyclopentadiene dioxide ring
Epoxy resins 10 parts, B205 ceramic sand 9 parts, high-performance hollow glass micropearl 6 parts, aramid fiber 10 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 9 minutes, and at room temperature deposited 30
Hour；(2) mixing: blend glue stuff in step (1) to be put into after rubber mixing machine is refined 1.5 minutes under conditions of temperature 115 DEG C
Add accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide asphalt mixtures modified by epoxy resin
Fat, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 4.5 minutes；(3) cooling: after mixing
Material preforms, cools down 24 hours；(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, curing temperature
Being 150 DEG C, the time is 5 minutes, and sulfide stress is that 18MPa prepares finished product.
Comparative example 1
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 20 parts, natural rubber 55
Part, 2 parts of sulfur, nano zine oxide 4.5 parts, stearic acid 1 part, accelerator DM 0.5 part, nano-silicon nitride 0.5 part, white carbon black
40 parts, antioxidant D NP3 part, diethyl phthalate 10 parts, B205 ceramic sand 10 parts, high-performance hollow glass micropearl 3 parts,
Aramid fiber 7.5 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 5 minutes, and at room temperature deposited 36
Hour；(2) mixing: blend glue stuff in step (1) to be put into and adds after rubber mixing machine is refined 1 minute under conditions of temperature 120 DEG C
Enter accelerator DM, antioxidant D NP, nano-silicon nitride, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue
Continuous refining 3.5 minutes；(3) cooling: by the material preforms after mixing, cool down 24 hours；(4) sulfuration: in the material cooled down
Adding sulfur, send into vulcanizer sulfuration, curing temperature is 140 DEG C, and the time is 4 minutes, and sulfide stress is that 20MPa prepares finished product.
Comparative example 2
A kind of rubber antiskid wear-resisting sole, is prepared from by weight by following component: butadiene rubber 30 parts, natural rubber 40
Part, 1 part of sulfur, nano zine oxide 6.5 parts, stearic acid 3 parts, accelerator DM 3 parts, nano-silicon nitride 1.5 parts, white carbon black 50
Part, antioxidant D NP1 part, diethyl phthalate 6 parts, modified benzoxazine resin 15 parts, bicyclopentadiene dioxide epoxy
Resin 5 parts.
The preparation method of above-mentioned rubber antiskid wear-resisting sole is: (1) is pre-mixing: by white carbon black and butadiene rubber, natural rubber,
Nano zine oxide, stearic acid and diethyl phthalate joined in banbury masterbatching after 12 minutes, and at room temperature deposited
24 hours；(2) mixing: blend glue stuff in step (1) to be put in rubber mixing machine and refines 2.5 minutes under conditions of temperature 100 DEG C
Rear addition accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide epoxy
Resin, continues refining 5 minutes；(3) cooling: by the material preforms after mixing, cool down 24 hours；(4) sulfuration: at the material cooled down
Adding sulfur in material, send into vulcanizer sulfuration, curing temperature is 160 DEG C, and the time is 7 minutes, and sulfide stress is that 15MPa prepares into
Product.
Being tested at smooth surface ceramic tile enterprising whereabouts sliding/friction coefficient by prepared sole, property indices see table 1,
It may be seen that this rubber antiskid wear-resisting sole has the highest anti-skid wearable, Akron attrition value minimum up to
0.32cm3/1.61km, dry sliding coefficient is 1.35, and wet and slippery coefficient is 0.92.
The property indices of table 1 rubber antiskid wear-resisting sole
Claims (8)
1. a rubber antiskid wear-resisting sole, it is characterised in that be prepared from by weight by following component: butadiene rubber 20-
30 parts, natural rubber 40-55 part, sulfur 1-2 part, nano zine oxide 4.5-6.5 part, stearic acid 1-3 part, vulcanization accelerator
DM0.5-3 part, nano-silicon nitride 0.5-1.5 part, white carbon black 40-50 part, antioxidant D NP1-3 part, diethyl phthalate 6-10
Part, modified benzoxazine resin 7-15 part, bicyclopentadiene dioxide expoxy resin 5-15 part, B205 ceramic sand 5-10 part, height
Performance hollow glass micropearl 3-8 part, aramid fiber 7.5-12.5 part.
A kind of rubber antiskid wear-resisting sole the most according to claim 1, it is characterised in that made by weight by following component
For forming: butadiene rubber 22-28 part, natural rubber 45-50 part, sulfur 1.5-1.8 part, nano zine oxide 5-6 part, stearic acid
1.5-2.5 part, accelerator DM 1-2.5 part, nano-silicon nitride 0.8-1.2 part, white carbon black 43-58 part, antioxidant D NP1.8-
2.2 parts, diethyl phthalate 7-9 part, modified benzoxazine resin 10-13 part, bicyclopentadiene dioxide expoxy resin
8-12 part, B205 ceramic sand 8-10 part, high-performance hollow glass micropearl 5-7 part, aramid fiber 9-11 part.
3. according to a kind of rubber antiskid wear-resisting sole described in claim 1 and 2, it is characterised in that: accelerator DM is two
Dibenzothiazyl disulfide.
4. according to a kind of rubber antiskid wear-resisting sole described in claim 1 and 2, it is characterised in that: antioxidant D NP is N, N'-
Two (betanaphthyl) p-phenylenediamine.
5. the preparation method of a rubber antiskid wear-resisting sole, it is characterised in that: comprise the following steps:
(1) pre-mixing: white carbon black is added with butadiene rubber, natural rubber, nano zine oxide, stearic acid and diethyl phthalate
Enter in banbury after masterbatching 5-12 minute, and at room temperature deposit 24-36 hour；
(2) mixing: to divide 1-2.5 refined under conditions of temperature 100-120 DEG C by blend glue stuff input rubber mixing machine in step (1)
Accelerator DM, antioxidant D NP, nano-silicon nitride, modified benzoxazine resin, bicyclopentadiene dioxide ring is added after clock
Epoxy resins, B205 ceramic sand, high-performance hollow glass micropearl, aramid fiber, continue refining 3.5-5 minute；
(3) cooling: by the material preforms after mixing, cool down 24 hours；
(4) sulfuration: add sulfur in the material cooled down, sends into vulcanizer sulfuration, and curing temperature is 140-160 DEG C, the time
For 4-7 minute, sulfide stress was that 15-20MPa prepares finished product.
The preparation method of a kind of rubber antiskid wear-resisting sole the most according to claim 5, it is characterised in that: described step
(1) in, the masterbatching time is 8-10 minute, at room temperature deposits 30 hours.
The preparation method of a kind of rubber antiskid wear-resisting sole the most according to claim 5, it is characterised in that: described step
(2) in, temperature is 115 DEG C, and the refining time is 1.5 minutes, and the continuation refining time is 4.5 minutes.
The preparation method of a kind of rubber antiskid wear-resisting sole the most according to claim 5, it is characterised in that: described step
(4) in, curing temperature is 145-155 DEG C, and the time is 5 minutes, and sulfide stress is 18MPa.
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Cited By (11)
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| CN108752652A (en) * | 2018-05-24 | 2018-11-06 | 际华三五七橡胶制品有限公司 | Caliga rubber outsole is made in a kind of lightweight |
| CN108864498A (en) * | 2018-05-24 | 2018-11-23 | 际华三五七橡胶制品有限公司 | A kind of lightweight dual density operation shoes sole and preparation method thereof |
| CN109181124A (en) * | 2018-10-11 | 2019-01-11 | 安徽世界村新材料有限公司 | A kind of hollow sulfidization molding sole of high elasticity abrasion-proof and preparation method thereof |
| CN110204803A (en) * | 2019-07-04 | 2019-09-06 | 福建省卓睿新材料科技有限公司 | A kind of Specific gravity rubber product and preparation method thereof |
| CN111037829A (en) * | 2019-12-26 | 2020-04-21 | 扬州锦沃科技有限公司 | Ice surface antiskid warm-keeping sole material and preparation method thereof |
| CN111849043A (en) * | 2020-08-15 | 2020-10-30 | 温州市鹿城金米莉金足皮鞋厂 | Wear-resistant sole and production process thereof |
| CN112477325A (en) * | 2020-12-31 | 2021-03-12 | 际华三五一五皮革皮鞋有限公司 | One-step formed light-weight cushioning composite outsole and preparation method thereof |
| CN112724476A (en) * | 2020-12-18 | 2021-04-30 | 温州市宜和鞋材有限公司 | Novel high-performance rubber sole with flame-retardant function and preparation method thereof |
| CN113603947A (en) * | 2021-08-10 | 2021-11-05 | 常州大学 | Ice surface anti-slip rubber composite material and preparation method thereof |
| CN114213723A (en) * | 2021-12-22 | 2022-03-22 | 浙江三益鞋业有限公司 | Wear-resistant high-strength shoe material and preparation method thereof |
| CN114276590A (en) * | 2022-01-19 | 2022-04-05 | 浙江奔达橡塑有限公司 | Wear-resistant sole and production process thereof |
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