CN104693585A - Non-slip and wear-resisting sole and preparing method thereof - Google Patents
Non-slip and wear-resisting sole and preparing method thereof Download PDFInfo
- Publication number
- CN104693585A CN104693585A CN201510077022.2A CN201510077022A CN104693585A CN 104693585 A CN104693585 A CN 104693585A CN 201510077022 A CN201510077022 A CN 201510077022A CN 104693585 A CN104693585 A CN 104693585A
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- Prior art keywords
- parts
- rubber
- sole
- wear
- agent
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Classifications
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a non-slip and wear-resisting sole and a preparing method thereof. The sole is prepared by the following steps: uniformly mixing an ethylene vinyl acetate copolymer (EVA), polyolefin elastomer (POE), crude rubber, carbon black, liquid rubber, thermoplastic elastomer, a tackifier, triethylene diamine, paraffin, glass fiber particles, chlorinated polyethylene, hemp xyloid stem superfine powder, an activated charcoal (AC) foaming agent, a cross-linking agent 4,4(bis(imidazol-1-ylmethylene))biphenyl (BIBP), nano-zinc oxide, zinc stearate, stearic acid, a wear-resisting agent AG209 and an inorganic filler; heating the mixed materials to 150-190 DEG C for 20min; then, adding azodicarbonamide at 200 DEG C for 30min, cooling and shaping in a mould. The sole prepared by the invention is significant in non-slip effect, obviously high in wear-resisting performance, long in service life and good in market prospect; and the preparation process is simple and easy to implement, and is applicable to mass production.
Description
Technical field
The present invention relates to a kind of rubber soles, particularly relate to rubber soles of a kind of anti-skid wearable and preparation method thereof, belong to sole preparing technical field.
Background technology
Shoes are requisite daily necessitiess in people's daily life.Rule of thumb known, in shoes, the place of the most easily breakage has been exactly sole, and therefore the quality of sole directly determines the life-span length of a pair of shoes.
Present material for sole of shoe generally adopts rubber.But also there is very large deficiency in the sole that rubber is made, especially rubber sliding-proof poor-performing.In the information age of today, more and more the accident of slipping appears on newspapers and periodicals, and the accident of slipping has a strong impact on the brand image of footwear, and increasing human consumer and production firm focus onto to be increased on shoe soles slip stopping and wear resisting property.In many cases, the reason slided into does not have enough frictional force between sole and interface, road surface, and the most effective terms of settlement is the interaction force increasing material for sole of shoe and medium, thus increase frictional force, shows the non-skid property promoting sole.On the other hand, increase the wear resisting property of sole exactly, to extend its work-ing life.
Therefore, the upper sole in present market all cannot meet human consumer to inherently safe and the requirement in shoes work-ing life.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention is, provides the sole of a kind of anti-skid wearable, long service life and the preparation method of this material for sole of shoe thereof.
For solving prior art problem, technical scheme provided by the invention is:
A kind of anti-skid wearable sole, this sole is made up of obtained following raw material:
EVA, POE, rubber, carbon black, fluid rubber, thermoplastic elastomer, tackifier, triethylene diamine, paraffin, glass fiber granules, chlorinatedpolyethylene, hemp stalk core ultrafine powder, Cellmic C 121, AC whipping agent, crosslinking agent B IBP, nano zine oxide, Zinic stearas, stearic acid, anti-wear agent AG209, mineral filler.
Further, the weight part of each raw material is as follows:
EVA 55 parts, POE 20-25 part, rubber 3-20 part, carbon black 2-7 part, fluid rubber 6-14 part, thermoplastic elastomer 6-14 part, tackifier 5 parts, triethylene diamine 10 parts, 3.8 parts, paraffin, glass fiber granules 20 parts, chlorinatedpolyethylene 4 parts, hemp stalk core ultrafine powder 5 parts, Cellmic C 121 4 parts, AC whipping agent 6 parts, crosslinking agent B IBP 9 parts, nano zine oxide 6 parts, Zinic stearas 3 parts, stearic acid 5 parts, anti-wear agent AG209 10 parts, mineral filler 2 parts.
Preferably, described fluid rubber is liquid isobutylene-isoprene copolymer.
Preferred, also comprise sulphur 5-8 part in described raw material.
Present invention also offers a kind of preparation method of anti-skid wearable sole, this preparation method comprises the steps:
EVA, POE, rubber, carbon black, fluid rubber, thermoplastic elastomer, tackifier, triethylene diamine, paraffin, glass fiber granules, chlorinatedpolyethylene, hemp stalk core ultrafine powder, AC whipping agent, crosslinking agent B IBP, nano zine oxide, Zinic stearas, stearic acid, anti-wear agent AG209, mineral filler is evenly mixing, above-mentioned mixing material is heated to 150-190 DEG C, 20min, then Cellmic C 121 is added, 30min is added at 200 DEG C, cooling, shaping in a mold.
By adopting preceding solution, the invention has the beneficial effects as follows:
The sole that the present invention obtains, skidproof effect is given prominence to, and wear resisting property significantly improves, long service life, has good market outlook, and preparation technology is simple, easily realizes, and is applicable to mass production.
Embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
Embodiment 1:
In the present embodiment, sole is made up of by weight following component:
EVA 55 parts, POE 20 parts, rubber 5 parts, carbon black 8 parts, fluid rubber 7 parts, thermoplastic elastomer 6.2 parts, tackifier 5 parts, triethylene diamine 10 parts, 3.8 parts, paraffin, glass fiber granules 20 parts, chlorinatedpolyethylene 4 parts, hemp stalk core ultrafine powder 5 parts, Cellmic C 121 4 parts, AC whipping agent 6 parts, crosslinking agent B IBP 9 parts, nano zine oxide 6 parts, Zinic stearas 3 parts, stearic acid 5 parts, anti-wear agent AG209 10 parts, mineral filler 2 parts.
By evenly mixing for the mixing raw material of said ratio, above-mentioned mixing material be heated to 150-190 DEG C, 20min, then add Cellmic C 121, at 200 DEG C, add 30min, cooling, shaping in a mold.
In sum, the sole that the present invention obtains, skidproof effect is given prominence to, and wear resisting property significantly improves, long service life, has good market outlook, and preparation technology is simple, easily realizes, and is applicable to mass production.
It should be noted that and understand, when not departing from the spirit and scope of the present invention required by accompanying claim, various amendment and improvement can be made to the present invention of foregoing detailed description.Therefore, the scope of claimed technical scheme is not by the restriction of given any specific exemplary teachings.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of ancillary component, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (5)
1. an anti-skid wearable sole, is characterized in that, this sole is made up of obtained following raw material:
EVA, POE, rubber, carbon black, fluid rubber, thermoplastic elastomer, tackifier, triethylene diamine, paraffin, glass fiber granules, chlorinatedpolyethylene, hemp stalk core ultrafine powder, Cellmic C 121, AC whipping agent, crosslinking agent B IBP, nano zine oxide, Zinic stearas, stearic acid, anti-wear agent AG209, mineral filler.
2. a kind of anti-skid wearable sole according to claim 1, it is characterized in that, the weight part of each raw material is as follows:
EVA 55 parts, POE 20-25 part, rubber 3-20 part, carbon black 2-7 part, fluid rubber 6-14 part, thermoplastic elastomer 6-14 part, tackifier 5 parts, triethylene diamine 10 parts, 3.8 parts, paraffin, glass fiber granules 20 parts, chlorinatedpolyethylene 4 parts, hemp stalk core ultrafine powder 5 parts, Cellmic C 121 4 parts, AC whipping agent 6 parts, crosslinking agent B IBP 9 parts, nano zine oxide 6 parts, Zinic stearas 3 parts, stearic acid 5 parts, anti-wear agent AG209 10 parts, mineral filler 2 parts.
3. a kind of anti-skid wearable sole according to claim 1 and 2, is characterized in that, described fluid rubber is liquid isobutylene-isoprene copolymer.
4. a kind of anti-skid wearable sole according to claim 1, is characterized in that, also comprises sulphur 5-8 part in described raw material.
5. the preparation method of a kind of anti-skid wearable sole according to claim 1 or 2 or 4, it is characterized in that, this preparation method comprises the steps:
EVA, POE, rubber, carbon black, fluid rubber, thermoplastic elastomer, tackifier, triethylene diamine, paraffin, glass fiber granules, chlorinatedpolyethylene, hemp stalk core ultrafine powder, AC whipping agent, crosslinking agent B IBP, nano zine oxide, Zinic stearas, stearic acid, anti-wear agent AG209, mineral filler is evenly mixing, above-mentioned mixing material is heated to 150-190 DEG C, 20min, then Cellmic C 121 is added, 30min is added at 200 DEG C, cooling, shaping in a mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510077022.2A CN104693585A (en) | 2015-02-13 | 2015-02-13 | Non-slip and wear-resisting sole and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510077022.2A CN104693585A (en) | 2015-02-13 | 2015-02-13 | Non-slip and wear-resisting sole and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104693585A true CN104693585A (en) | 2015-06-10 |
Family
ID=53341161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510077022.2A Pending CN104693585A (en) | 2015-02-13 | 2015-02-13 | Non-slip and wear-resisting sole and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104693585A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462049A (en) * | 2015-12-23 | 2016-04-06 | 上海大学 | Hemp stem core powder modified EVA (ethylene vinyl acetate copolymer) composite foam material and preparation method thereof |
| CN106723647A (en) * | 2016-11-29 | 2017-05-31 | 江西省东鹏鞋业有限公司 | A kind of on-slip shoes and preparation method thereof |
| CN110452448A (en) * | 2019-07-25 | 2019-11-15 | 福建省莆田市双源鞋业有限公司 | A kind of ultralight high-elastic sole of CMEVA and its processing method |
| CN110511473A (en) * | 2019-07-25 | 2019-11-29 | 福建省莆田市双源鞋业有限公司 | A kind of super light sole and its processing method |
| CN111037829A (en) * | 2019-12-26 | 2020-04-21 | 扬州锦沃科技有限公司 | Ice surface antiskid warm-keeping sole material and preparation method thereof |
-
2015
- 2015-02-13 CN CN201510077022.2A patent/CN104693585A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462049A (en) * | 2015-12-23 | 2016-04-06 | 上海大学 | Hemp stem core powder modified EVA (ethylene vinyl acetate copolymer) composite foam material and preparation method thereof |
| CN106723647A (en) * | 2016-11-29 | 2017-05-31 | 江西省东鹏鞋业有限公司 | A kind of on-slip shoes and preparation method thereof |
| CN110452448A (en) * | 2019-07-25 | 2019-11-15 | 福建省莆田市双源鞋业有限公司 | A kind of ultralight high-elastic sole of CMEVA and its processing method |
| CN110511473A (en) * | 2019-07-25 | 2019-11-29 | 福建省莆田市双源鞋业有限公司 | A kind of super light sole and its processing method |
| CN111037829A (en) * | 2019-12-26 | 2020-04-21 | 扬州锦沃科技有限公司 | Ice surface antiskid warm-keeping sole material and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150610 |
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| WD01 | Invention patent application deemed withdrawn after publication |