CN104774350A - High-slip-resistance anti-wear rubber sheet and preparation method thereof - Google Patents
High-slip-resistance anti-wear rubber sheet and preparation method thereof Download PDFInfo
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- CN104774350A CN104774350A CN201510191091.6A CN201510191091A CN104774350A CN 104774350 A CN104774350 A CN 104774350A CN 201510191091 A CN201510191091 A CN 201510191091A CN 104774350 A CN104774350 A CN 104774350A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Abstract
The invention discloses a high-slip-resistance anti-wear rubber sheet, comprising the following components in parts by weight: 40-60 parts of natural rubber, 40-60 parts of butadiene rubber, 3-7 parts of zinc oxide, 1-3 parts of stearic acid,1-3 parts of accelerant, 1-3 parts of an anti-aging agent, 3-7 parts of an anti-wear agent, 3-7 parts of white carbon black and 8-12 parts of fibers. Fibers with certain weight are added to the formula and the advantages of the fibers and the advantages of rubber are combined through the process flow in the invention; a product made from the prepared rubber sheet has dry slip resistance of 98-100% and wet slip resistance of 90-92% and the anti-wear performance of the product can be improved greatly.
Description
Technical field
The present invention and a kind of field of rubber materials, especially a kind of high slip preventing abrasive rubber material.
Background technology
The effect of on-slip is reached in order to adapt to (to compare the ground if any water or ice face) on wet and slippery ground, there is the sole that a lot of Antiskid rubber materials is made in the market, but the Antiskid rubber of existing market is done on-slip and is greater than 60%, wet on-slip is greater than 50%, although reach certain anti-slip effect, but still exist not enough greatly.
Summary of the invention
Goal of the invention: the object of the invention is for the deficiencies in the prior art, provides a kind of dry non-skid property to reach 98 ~ 100%, and wet non-skid property is the high slip preventing abrasive rubber sheet material of 90 ~ 92%;
Another object of the present invention is to provide a kind of method preparing this rubber sheet.
Technical scheme: high slip preventing abrasive rubber sheet material of the present invention, comprises following component:
Further preferably, described high slip preventing abrasive rubber sheet material, comprises following component in the present invention:
The preparation method of high slip preventing abrasive rubber sheet material of the present invention, comprises the steps:
(1) the mark glue prepared by weight and cis-1,4-polybutadiene rubber are prepared by weight send into and thin-pass is carried out in mill plasticate, make plasticity number be greater than 0.42;
(2) the mark glue of having plasticated, cis-1,4-polybutadiene rubber are dropped in Banbury mixer and carry out conjunction refining after 1 ~ 3 minute, add promotor, zinc oxide, stearic acid, anti-aging agent, anti-wear agent and white carbon black and carry out mixing;
(3) by the sizing material boiling hot bag cylinder on a mill until after mixing, then the fiber weighed up by weight is added, after thin-pass mixes, slice, slice thickness 5 ~ 10mm;
(4) by stamping machine, the film gone out is punched to 12cm × 26cm, fits into blob of viscose;
(5) blob of viscose posted is placed on pressing sizing on vulcanizing press;
(6) splitting machine is used blob of viscose to be cutd open into the film that thickness is 2.5mm;
(7) film cutd open is put into sulfuration cylinder sulfuration 1 hour.
Preferably, in step (7), sulfuration cylinder temperature is 130 ~ 140 DEG C, and pressure is 3 ~ 5MPa.
Beneficial effect: the fiber adding certain part by weight in formula of the present invention, and by the technical process in the present invention by the advantage of fiber and rubber advantages, the dry non-skid property of product that the film of output is made reaches 98 ~ 100%, wet non-skid property is 90 ~ 92%, and the wear resisting property of product is also greatly improved.
Embodiment
Below technical solution of the present invention is described in detail, but protection scope of the present invention is not limited to described embodiment.
Embodiment 1: a kind of high slip preventing abrasive rubber sheet material, comprises following component:
The preparation method of described high slip preventing abrasive rubber sheet material, comprises the steps:
(1) the mark glue prepared by weight and cis-1,4-polybutadiene rubber are prepared by weight send into and thin-pass is carried out in mill plasticate, make plasticity number be greater than 0.42;
(2) the mark glue of having plasticated, cis-1,4-polybutadiene rubber are dropped in Banbury mixer and carry out conjunction refining after 1 minute, add promotor, zinc oxide, stearic acid, anti-aging agent, anti-wear agent and white carbon black and carry out mixing;
(3) by the sizing material boiling hot bag cylinder on a mill until after mixing, then the fiber weighed up by weight is added, after thin-pass mixes, slice, slice thickness 5mm;
(4) by stamping machine, the film gone out is punched to 12cm × 26cm, fits into blob of viscose;
(5) blob of viscose posted is placed on pressing sizing on vulcanizing press;
(6) splitting machine is used blob of viscose to be cutd open into the film that thickness is 2.5mm;
(7) film cutd open is put into sulfuration cylinder sulfuration 1 hour, sulfuration cylinder temperature is 130 DEG C, and pressure is 3MPa.
Embodiment 2: a kind of high slip preventing abrasive rubber sheet material, comprises following component:
The preparation method of described high slip preventing abrasive rubber sheet material, comprises the steps:
(1) the mark glue prepared by weight and cis-1,4-polybutadiene rubber are prepared by weight send into and thin-pass is carried out in mill plasticate, make plasticity number be greater than 0.42;
(2) the mark glue of having plasticated, cis-1,4-polybutadiene rubber are dropped in Banbury mixer and carry out conjunction refining after 3 minutes, add promotor, zinc oxide, stearic acid, anti-aging agent, anti-wear agent and white carbon black and carry out mixing;
(3) by the sizing material boiling hot bag cylinder on a mill until after mixing, then the fiber weighed up by weight is added, after thin-pass mixes, slice, slice thickness 10mm;
(4) by stamping machine, the film gone out is punched to 12cm × 26cm, fits into blob of viscose;
(5) blob of viscose posted is placed on pressing sizing on vulcanizing press;
(6) splitting machine is used blob of viscose to be cutd open into the film that thickness is 2.5mm;
(7) film cutd open is put into sulfuration cylinder sulfuration 1 hour, sulfuration cylinder temperature is 140 DEG C, and pressure is 5MPa.
Embodiment 3: a kind of high slip preventing abrasive rubber sheet material, comprises following component:
The preparation method of described high slip preventing abrasive rubber sheet material, comprises the steps:
(1) the mark glue prepared by weight and cis-1,4-polybutadiene rubber are prepared by weight send into and thin-pass is carried out in mill plasticate, make plasticity number be greater than 0.42;
(2) the mark glue of having plasticated, cis-1,4-polybutadiene rubber are dropped in Banbury mixer and carry out conjunction refining after 2 minutes, add promotor, zinc oxide, stearic acid, anti-aging agent, anti-wear agent and white carbon black and carry out mixing;
(3) by the sizing material boiling hot bag cylinder on a mill until after mixing, then the fiber weighed up by weight is added, after thin-pass mixes, slice, slice thickness 8mm;
(4) by stamping machine, the film gone out is punched to 12cm × 26cm, fits into blob of viscose;
(5) blob of viscose posted is placed on pressing sizing on vulcanizing press;
(6) splitting machine is used blob of viscose to be cutd open into the film that thickness is 2.5mm;
(7) film cutd open is put into sulfuration cylinder sulfuration 1 hour, sulfuration cylinder temperature is 135 DEG C, and pressure is 4MPa.
High slip preventing abrasive rubber sheet material of the present invention and existing elastomeric material performance comparison result are in table 1.
Table 1 is embodiment 1-3 and existing elastomeric material product performance detected result.
| Product | Powerful (MPa) | Hardness | Elongation (%) | Dry on-slip (%) | Wet on-slip (%) |
| Contrast material | 12.6 | 58 | 390 | 65 | 55 |
| Embodiment 1 | 13.1 | 63 | 395 | 98 | 90 |
| Embodiment 2 | 12.9 | 63 | 398 | 99 | 91 |
| Embodiment 3 | 13.2 | 65 | 400 | 100 | 92 |
As mentioned above, although represented with reference to specific preferred embodiment and described the present invention, it shall not be construed as the restriction to the present invention self.Under the spirit and scope of the present invention prerequisite not departing from claims definition, various change can be made in the form and details to it.
Claims (4)
1. a high slip preventing abrasive rubber sheet material, is characterized in that comprising following component:
Each component is with parts by weight.
2. high slip preventing abrasive rubber sheet material according to claim 1, comprises following component:
3. a preparation method for high slip preventing abrasive rubber sheet material according to claim 1, is characterized in that comprising the steps:
(1) the mark glue prepared by weight and cis-1,4-polybutadiene rubber are prepared by weight send into and thin-pass is carried out in mill plasticate, make plasticity number be greater than 0.42;
(2) the mark glue of having plasticated, cis-1,4-polybutadiene rubber are dropped in Banbury mixer and carry out conjunction refining after 1 ~ 3 minute, add promotor, zinc oxide, stearic acid, anti-aging agent, anti-wear agent and white carbon black and carry out mixing;
(3) by the sizing material boiling hot bag cylinder on a mill until after mixing, then the fiber weighed up by weight is added, after thin-pass mixes, slice, slice thickness 5 ~ 10mm;
(4) by stamping machine, the film gone out is punched to 12cm × 26cm, fits into blob of viscose;
(5) blob of viscose posted is placed on pressing sizing on vulcanizing press;
(6) splitting machine is used blob of viscose to be cutd open into the film that thickness is 2.5mm;
(7) film cutd open is put into sulfuration cylinder sulfuration 1 hour.
4. the preparation method of high slip preventing abrasive rubber sheet material according to claim 3, is characterized in that, in step (7), sulfuration cylinder temperature is 130 ~ 140 DEG C, and pressure is 3 ~ 5MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510191091.6A CN104774350A (en) | 2015-04-21 | 2015-04-21 | High-slip-resistance anti-wear rubber sheet and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510191091.6A CN104774350A (en) | 2015-04-21 | 2015-04-21 | High-slip-resistance anti-wear rubber sheet and preparation method thereof |
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| CN104774350A true CN104774350A (en) | 2015-07-15 |
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| CN201510191091.6A Pending CN104774350A (en) | 2015-04-21 | 2015-04-21 | High-slip-resistance anti-wear rubber sheet and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317493A (en) * | 2016-08-29 | 2017-01-11 | 樊之雄 | Rubber antiskid and abrasion-resistant shoe sole and preparation method thereof |
Citations (6)
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|---|---|---|---|---|
| WO2014032172A1 (en) * | 2012-08-31 | 2014-03-06 | Soucy Techno Inc. | Rubber compositions and uses thereof |
| CN103980572A (en) * | 2014-05-29 | 2014-08-13 | 南京东亚橡塑制品有限公司 | Non-skid rubber sole material and preparation method thereof |
| CN104311905A (en) * | 2014-11-07 | 2015-01-28 | 无锡宝通带业股份有限公司 | Wear resistant conveying belt primer with low rolling resistance and preparation method thereof |
| CN104341620A (en) * | 2014-10-13 | 2015-02-11 | 安徽奥丰汽车配件有限公司 | Automobile control swing arm rubber bushing composition |
| CN104356447A (en) * | 2014-11-25 | 2015-02-18 | 侨健新能源科技（苏州）有限公司 | Environment-friendly modified natural rubber material applied to cable insulation layer |
| CN104479178A (en) * | 2014-12-09 | 2015-04-01 | 太仓市苏月科技发展有限公司 | Novel composite material hovercraft apron rubber material and method of manufacturing hovercraft apron by rubber material |
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2015
- 2015-04-21 CN CN201510191091.6A patent/CN104774350A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014032172A1 (en) * | 2012-08-31 | 2014-03-06 | Soucy Techno Inc. | Rubber compositions and uses thereof |
| CN103980572A (en) * | 2014-05-29 | 2014-08-13 | 南京东亚橡塑制品有限公司 | Non-skid rubber sole material and preparation method thereof |
| CN104341620A (en) * | 2014-10-13 | 2015-02-11 | 安徽奥丰汽车配件有限公司 | Automobile control swing arm rubber bushing composition |
| CN104311905A (en) * | 2014-11-07 | 2015-01-28 | 无锡宝通带业股份有限公司 | Wear resistant conveying belt primer with low rolling resistance and preparation method thereof |
| CN104356447A (en) * | 2014-11-25 | 2015-02-18 | 侨健新能源科技（苏州）有限公司 | Environment-friendly modified natural rubber material applied to cable insulation layer |
| CN104479178A (en) * | 2014-12-09 | 2015-04-01 | 太仓市苏月科技发展有限公司 | Novel composite material hovercraft apron rubber material and method of manufacturing hovercraft apron by rubber material |
Non-Patent Citations (1)
| Title |
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| 梁纪宇，赵国栋，罗显发: "高止滑耐磨橡胶鞋底材料的", 《中国皮革》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317493A (en) * | 2016-08-29 | 2017-01-11 | 樊之雄 | Rubber antiskid and abrasion-resistant shoe sole and preparation method thereof |
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Application publication date: 20150715 |