CN107973945A - A kind of wear-resisting anti-wet and slippery rubber sole formula and preparation method thereof - Google Patents
A kind of wear-resisting anti-wet and slippery rubber sole formula and preparation method thereof Download PDFInfo
- Publication number
- CN107973945A CN107973945A CN201711372114.9A CN201711372114A CN107973945A CN 107973945 A CN107973945 A CN 107973945A CN 201711372114 A CN201711372114 A CN 201711372114A CN 107973945 A CN107973945 A CN 107973945A
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- Prior art keywords
- wet
- wear
- rubber
- slippery
- sole
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of wear-resisting anti-wet and slippery rubber sole formula and prepares the wear-resisting method for preventing wet and slippery rubber soles by it.The wear-resisting anti-wet and slippery rubber sole formula, is made of the raw material of following each mass parts (phr)：Raw rubber：100；Reinforcing filler:50~70；Activator：8~12.5；Tackifier：1~2；Antioxidant：2.5~3.8；Accelerating agent：2~3；Vulcanizing agent：3.5~4.5.The present invention is adjusted by being formulated, realize that sole prevents wet and slippery and wear-resisting property balance, make two indices performance ratio more prominent, the formula of sole material of the present invention is suitable for wearing when training intensity is big, ground is complicated, ground may contact the more army of water, armed police troops physical training, it is ensured that antiskid effect of the antiskid effect especially on wet-skid road surface in the endurable performance and wearing process of sole.
Description
Technical field
The present invention relates to a kind of elastomeric material and preparation method thereof, particularly a kind of wear-resisting and anti-wet skidding performance exsertile footwear
Bottom rubber compounding and preparation method thereof.
Background technology
Sole wear-resisting property is one of most important quality index of footwear, especially army with footwear, and to require sole to possess prominent
The wear-resisting property gone out.Because soldier's training strength is big, training condition is complicated, if sole wear-resisting property is bad will necessarily to influence military footwear
Wear the service life.And non-skid property is also one of critically important index of footwear.In the dry general anti-skid property of soles of medium side all
It can meet the requirements, but when there is water on ground, the non-skid property of sole declines the soldier for seriously, being especially engaged in violent tactics movement,
Probably because sole, which skids, causes training-related injury.Cause non-combat casualty.But sole prevents that wet skidding performance can be one with wear-resisting property
To paradox, it is difficult to which the two is taken into account.
The content of the invention
An object of the present invention is to provide a kind of wear-resisting anti-wet and slippery rubber soles.
Wear-resisting anti-wet and slippery rubber soles provided by the present invention, are made of the raw material of following each mass parts (phr)：
Raw rubber：100；
Reinforcing filler:50~70；
Activator：8~12.5；
Tackifier：1~2；
Antioxidant：2.5~3.8；
Accelerating agent：2~3；
Vulcanizing agent：3.5~4.5.
The raw rubber is made of natural rubber, butadiene rubber and brombutyl, wherein natural rubber (1# marks glue)：45
~60phr, butadiene rubber (BR9000)：20~30phr, brombutyl (BIIR2222)：10~25phr.
The reinforcing filler is made of precipitated silica and tire glue powder, wherein precipitated silica：40~50phr,
Tire glue powder：10~20phr.
The activator is made of diethylene glycol (DEG) (DEG), polyethylene glycol (PEG) and nano zine oxide (ZnO), wherein DEG：1
~1.5phr, PEG：2~3phr, ZnO：5~8phr.
The tackifier concretely coumarone indene resin.
The antioxidant is by 2,2,4- trimethyl -1,2- dihyaroquinolines (anti-aging agent RD), N- phenyl-N '-cyclohexyl pair
Phenylenediamine (antioxidant 4010) and protection wax composition, wherein anti-aging agent RD：1~1.5phr, antioxidant 4010：1~1.5phr, prevents
Protect wax：0.5~0.8phr.
The accelerating agent is by dibenzothiazyl disulfide (altax) and TBTM tetrabutyl thiuram monosulfide (accelerating agent
TBTS) form, wherein altax：1.5~2phr, accelerating agent TBTS：0.5~1.0phr.
The vulcanizing agent is made of tetra-sulfurized pair (triethoxy propyl group) silane (Si-69) and sulphur, wherein Si-69：1.5
~2phr, sulphur：2~2.5phr.
The wear-resisting method for preventing wet and slippery rubber soles is prepared it is a further object of the present invention to provide a kind of.
It is provided by the present invention to prepare the wear-resisting method for preventing wet and slippery rubber soles, comprise the following steps：
1) compounding rubber：According to raw rubber, tackifier, antioxidant, accelerating agent, activator, reinforcing filler, Si-69 it is suitable
Sequence feeds, mixing, discharge cooling, mill, and control mill mixer roller temperature adds sulphur, Bao Tong, is kneaded below 55 DEG C
Glue；
2) compression molding：Rubber compound after mixing slice is placed in die for shoe-sole and is molded sulfidization molding, to obtain the final product.
In above method step 1), the temperature control of the mixing is below 120 DEG C.
The time of the mixing can be 12~15min.
It is described it is thin it is logical can carry out repeatedly, concretely 3~5 times.
In above method step 2), the condition of the molding sulfidization molding can be：50~60MPa of pressure, temperature 160~
165 DEG C, 5~6min of time.
The present invention also provides a kind of footwear, the sole of the footwear is above-mentioned wear-resisting anti-wet and slippery rubber soles.
The present invention is adjusted by being formulated, and is realized that sole prevents wet and slippery and wear-resisting property balance, is compared two indices performance
It is prominent, it is mainly used for meeting wearing needs during the daily complicated high pressure training of soldier.
The formula of sole material of the present invention is more suitable for training intensity is big, ground is complicated, ground may contact water
Army, armed police troops physical training when wear, it is ensured that the antiskid effect in the endurable performance and wearing process of sole is especially
It is the antiskid effect on wet-skid road surface.
Embodiment
Below by specific embodiment, the present invention will be described, but the present invention is not limited thereto.
Experimental method used in following embodiments is conventional method unless otherwise specified；Institute in following embodiments
Reagent, material etc., are commercially available unless otherwise specified.
Embodiment
Rubber sole is prepared according to following techniques using the formula in table 1.
Technique：1) compounding rubber：It is kneaded using rubber internal mixer and open mill.Charging sequence is：Raw rubber, thickening
Agent, antioxidant, accelerating agent, activator, reinforcing filler, vulcanizing agent (Si-69), control in mixing temperature below 120 DEG C, close
Discharge cools down after refining 12~15min.Control mill mixer roller temperature to add sulphur at this time less than 55 DEG C, it is thin lead to 3~5 times after
Slice is stand-by.
2) compression molding：Rubber compound after mixing slice is placed in die for shoe-sole and is molded sulfidization molding, conditions of vulcanization is：
50~60MPa of pressure, 160~165 DEG C of temperature, 5~6min of time.
1 rubber sole formula of table
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Natural rubber | 50 | 50 | 60 | 55 | 45 | 55 |
| Butadiene rubber | 30 | 25 | 30 | 30 | 30 | 25 |
| Brombutyl | 20 | 25 | 10 | 15 | 25 | 20 |
| White carbon | 40 | 40 | 45 | 45 | 50 | 50 |
| Tire glue powder | 15 | 20 | 15 | 20 | 10 | 15 |
| DEG | 1 | 1 | 1 | 1.5 | 1.5 | 1.5 |
| PEG | 2.5 | 2.5 | 3 | 2.5 | 2 | 2 |
| ZnO | 8 | 6 | 5 | 5 | 6 | 8 |
| Coumarone indene resin | 1 | 1.5 | 1.5 | 2 | 2 | 2 |
| Anti-aging agent RD | 1 | 1 | 1 | 1.5 | 1.5 | 1.5 |
| Antioxidant 4010 | 1.5 | 1.5 | 1.5 | 1 | 1 | 1 |
| Protection wax | 0.5 | 0.8 | 0.7 | 0.6 | 0.7 | 0.7 |
| Altax | 1.5 | 1.5 | 2 | 2 | 1.5 | 1.5 |
| Accelerating agent TBTS | 1 | 1 | 0.5 | 0.5 | 1 | 1 |
| Si-69 | 1.5 | 1.5 | 1.5 | 2 | 2 | 2 |
| Sulphur | 2 | 2 | 2.5 | 2.5 | 2.5 | 2 |
The performance of thus obtained rubber sole semi-finished product such as table 2.
2 rubber sole semi-finished product performance of table
Thus obtained rubber sole end properties such as table 3.
3 rubber sole end properties of table
From embodiment as can be seen that the wear-resisting property in each embodiment of this formula is very prominent：National footwear rubber test piece
General Requirement provides Akron abrasion volume in 1.0cm3It is certified products below, and the Akron abrasion body of this formula rubber test piece
Product is in 0.3cm3Below；It is 200mm to wear away the national universal standard into footwear sole DIN3Hereinafter, and this formula is in 90mm3Below；Footwear
The bottom polishing scratch length country universal standard is below 9mm, and substantially in below 6mm in the present embodiment.In addition prepare into footwear footwear
The non-skid property at bottom is very prominent, and especially wet and slippery performance is notable.The wet and slippery coefficient of general sole is said more than 0.23 in the world
This bright footwear it is standby preferably it is anti-it is wet skidding performance can, and the wet and slippery performance of this formula no matter half sole or heel anti-wet and slippery coefficient it is equal
Be far longer than 0.23, illustrate sole it is anti-it is wet skidding performance can be very prominent.
Claims (10)
1. a kind of wear-resisting anti-wet and slippery rubber soles, are made of the raw material of following each mass parts：
Raw rubber：100phr；
Reinforcing filler:50~70phr；
Activator：8~12.5phr；
Tackifier：1~2phr；
Antioxidant：2.5~3.8phr；
Accelerating agent：2~3phr；
Vulcanizing agent：3.5~4.5phr.
2. wear-resisting anti-wet and slippery rubber soles according to claim 1, it is characterised in that：The raw rubber is by natural rubber, suitable
Buna and brombutyl composition, wherein natural rubber：45~60phr, butadiene rubber：20~30phr, butyl rubber bromide
Glue：10~25phr.
3. wear-resisting anti-wet and slippery rubber soles according to claim 1 or 2, it is characterised in that：The reinforcing filler is by sinking
Shallow lake method white carbon and tire glue powder composition, wherein precipitated silica：40~50phr, tire glue powder：10~20phr.
4. wear-resisting anti-wet and slippery rubber soles according to any one of claim 1-3, it is characterised in that：The activator by
Diethylene glycol (DEG), polyethylene glycol and nano zine oxide composition, wherein diethylene glycol (DEG)：1~1.5phr, polyethylene glycol：2~3phr, nano oxygen
Change zinc：5~8phr；The tackifier are coumarone indene resin.
5. the wear-resisting anti-wet and slippery rubber soles according to any one of claim 1-4, it is characterised in that：The antioxidant by
Anti-aging agent RD, antioxidant 4010 and protection wax composition, wherein anti-aging agent RD：1~1.5phr, antioxidant 4010：1~1.5phr,
Protection wax：0.5~0.8phr.
6. the wear-resisting anti-wet and slippery rubber soles according to any one of claim 1-5, it is characterised in that：The accelerating agent by
Altax and accelerating agent TBTS compositions, wherein altax：1.5~2phr, accelerating agent TBTS：0.5~1.0phr.
7. the wear-resisting anti-wet and slippery rubber soles according to any one of claim 1-6, it is characterised in that：The vulcanizing agent by
Si-69 and sulphur composition, wherein Si-69：1.5~2phr, sulphur：2~2.5phr.
8. a kind of wear-resisting method for preventing wet and slippery rubber soles prepared any one of claim 1-7, comprises the following steps：
1) compounding rubber：Order according to raw rubber, tackifier, antioxidant, accelerating agent, activator, reinforcing filler, Si-69 adds
Material, mixing, discharge cooling, mill, control mill mixer roller temperature add sulphur, Bao Tong, obtains rubber compound below 55 DEG C；
2) compression molding：Rubber compound after mixing slice is placed in die for shoe-sole and is molded sulfidization molding, to obtain the final product.
9. according to the method described in claim 8, it is characterized in that：In step 1), the temperature control of the mixing 120 DEG C with
Under；
The time of the mixing is 12~15min；
It is described it is thin it is logical can carry out repeatedly, concretely 3~5 times；
In above method step 2), the condition of the molding sulfidization molding is：50~60MPa of pressure, 160~165 DEG C of temperature, when
Between 5~6min.
10. a kind of footwear, wear-resisting anti-wet and slippery rubber soles of its sole any one of claim 1-7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711372114.9A CN107973945B (en) | 2017-12-19 | 2017-12-19 | Formula and preparation method of wear-resistant and anti-slippery rubber sole |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711372114.9A CN107973945B (en) | 2017-12-19 | 2017-12-19 | Formula and preparation method of wear-resistant and anti-slippery rubber sole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107973945A true CN107973945A (en) | 2018-05-01 |
| CN107973945B CN107973945B (en) | 2022-04-26 |
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|---|---|---|---|
| CN201711372114.9A Active CN107973945B (en) | 2017-12-19 | 2017-12-19 | Formula and preparation method of wear-resistant and anti-slippery rubber sole |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988344A (en) * | 2019-04-22 | 2019-07-09 | 昆山多威体育用品有限公司 | A kind of goal shoes rubber ground and preparation method thereof |
| CN111196880A (en) * | 2019-12-30 | 2020-05-26 | 际华易北河高分子材料科技(岳阳)有限公司 | Economic and environment-friendly rubber compound for rubber shoe outsole |
| CN113698710A (en) * | 2021-09-30 | 2021-11-26 | 泉州鑫泰鞋材有限公司 | Wear-resistant and antibacterial shoe material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080216361A1 (en) * | 2007-03-05 | 2008-09-11 | Pardo Vitulli | Light weight, non-slip, wear resistant boot |
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
| CN104672514A (en) * | 2013-12-01 | 2015-06-03 | 朱伟萍 | Wear-resisting anti-slip mountaineering sole material and preparation method thereof |
| CN104672515A (en) * | 2013-12-01 | 2015-06-03 | 朱伟萍 | Antiskid wear-resistant sole material and preparation method thereof |
-
2017
- 2017-12-19 CN CN201711372114.9A patent/CN107973945B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080216361A1 (en) * | 2007-03-05 | 2008-09-11 | Pardo Vitulli | Light weight, non-slip, wear resistant boot |
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN104672514A (en) * | 2013-12-01 | 2015-06-03 | 朱伟萍 | Wear-resisting anti-slip mountaineering sole material and preparation method thereof |
| CN104672515A (en) * | 2013-12-01 | 2015-06-03 | 朱伟萍 | Antiskid wear-resistant sole material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988344A (en) * | 2019-04-22 | 2019-07-09 | 昆山多威体育用品有限公司 | A kind of goal shoes rubber ground and preparation method thereof |
| CN111196880A (en) * | 2019-12-30 | 2020-05-26 | 际华易北河高分子材料科技(岳阳)有限公司 | Economic and environment-friendly rubber compound for rubber shoe outsole |
| CN113698710A (en) * | 2021-09-30 | 2021-11-26 | 泉州鑫泰鞋材有限公司 | Wear-resistant and antibacterial shoe material and preparation method thereof |
| CN113698710B (en) * | 2021-09-30 | 2023-08-25 | 泉州鑫泰鞋材有限公司 | Wear-resistant antibacterial shoe material and preparation method thereof |
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| CN107973945B (en) | 2022-04-26 |
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