CN106316125A

CN106316125A - Environment-friendly ceramic glaze material and preparation method thereof

Info

Publication number: CN106316125A
Application number: CN201610704836.9A
Authority: CN
Inventors: 方薛斐; 方卫明; 张丽
Original assignee: Yixing Fang Weiming Institute Of Pottery Art
Current assignee: Wuxi Taihu University
Priority date: 2016-08-23
Filing date: 2016-08-23
Publication date: 2017-01-11
Anticipated expiration: 2036-08-23
Also published as: CN106316125B

Abstract

The invention discloses an environment-friendly ceramic glaze material. The environment-friendly ceramic glaze material contains the following components in parts by weight: 120-150 parts of sepiolite, 100-150 parts of wollastonite, 100-120 parts of quartz stone, 80-100 parts of aedelforsite, 20-60 parts of cordierite, 10-30 parts of cerium oxide, 10-30 parts of zirconium oxide, 10-20 parts of strontium oxide and 10-20 parts of cesium oxide. The invention simultaneously discloses a preparation method of the environment-friendly ceramic glaze material. Compared with the traditional techniques, the environment-friendly ceramic glaze material has the advantages that the formula is scientific, and the raw material cost is low; and multiple trace heavy metals are added so as to replace a lead raw material, so that the environmental pollution and the harm to the human body are reduced.

Description

A kind of Environmental-friendceramic ceramic glaze and preparation method thereof

Technical field

The invention belongs to ceramic coating field, be specifically related to a kind of Environmental-friendceramic ceramic glaze and preparation method thereof.

Background technology

With the lead oxide of certain content in traditional ceramic glaze, along with the raising of compatriots' environmental consciousness and to leaded thing The understanding of matter harm, increasing building ceramic enterprises is devoted to study leadless environment-friendly ceramic glaze.Usually, leady raw materials can lead to Cross other heavy metal raw materials to replace, but the heavy metal raw material of costliness improves production cost the most virtually.

Summary of the invention

Goal of the invention: present invention aims to the deficiencies in the prior art, it is provided that a kind of Environmental-friendceramic ceramic glaze.

Another object of the present invention is to provide the preparation method of above-mentioned Environmental-friendceramic ceramic glaze.

Technical scheme: in order to reach foregoing invention purpose, the present invention is specifically achieved like this: a kind of enviroment protective ceramic glaze Material, including the component of following parts by weight: the meerschaum of 120 ~ 150 parts, the wollastonite of 100 ~ 150 parts, the quartz of 100 ~ 120 parts Stone, the wollastonite of 80 ~ 100 parts, the cordierite of 20 ~ 60 parts, the cerium oxide of 10 ~ 30 parts, the zirconium oxide of 10 ~ 30 parts, 10 ~ 20 parts Strontium oxide and the Cs2O of 10 ~ 20 parts.

Preferably, it is made up of the component of following parts by weight: the meerschaum of 130 parts, the wollastonite of 120 parts, the stone of 100 parts Diamond stone, the wollastonite of 80 parts, the cordierite of 30 parts, the cerium oxide of 15 parts, the zirconium oxide of 15 parts, the strontium oxide of 10 parts and 10 parts Cs2O.

The method preparing above-mentioned Environmental-friendceramic ceramic glaze, comprises the following steps:

(1) measure each raw material by formula, carry out grinding and sieving；

(2) meerschaum after pulverizing, wollastonite, quartz, wollastonite, cordierite adds kiln calcining, control temperature 1200 ~ 1300 DEG C, calcine 12 ~ 24 hours；

(3) the calcined mixed material to step (2) gained carries out oily cold, adds cerium oxide, oxygen when temperature is reduced to 700 ~ 800 DEG C Change zirconium, strontium oxide and Cs2O, continue to be warmed up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours；

(4) after step (3) terminates, naturally cooling to less than 100 DEG C, the water adding raw material gross mass 60 ~ 80% sends into ball together Grinding machine ball milling 12 ~ 24 hours and get final product.

Beneficial effect: the present invention compared with conventional art, the present invention compared with conventional art, scientific formulation, cost of material Low, replace leady raw materials by the addition of lot of trace heavy metal, decrease the harm of the pollution to environment and human body.

Detailed description of the invention

Embodiment 1:

Take the meerschaum of parts by weight 120 parts, the wollastonite of 100 parts, the quartz of 100 parts, the wollastonite of 80 parts, the violet of 20 parts Cordierite, the strontium oxide of 10 parts, the zirconium oxide of 10 parts, the strontium oxide of 10 parts and the Cs2O of 10 parts, carry out grinding and sieving, excellent Select 50 mesh sieves；Meerschaum after pulverizing, wollastonite, quartz, wollastonite, cordierite adds kiln calcining, controls temperature 1200 ~ 1300 DEG C, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out oil cold, when temperature is reduced to 700 ~ 800 DEG C Add cerium oxide, zirconium oxide, strontium oxide and Cs2O, continue to be warmed up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours；Add accumulation of heat Shu Hou, naturally cools to less than 100 DEG C, and the water of addition raw material gross mass 60% is sent into ball mill ball milling together and 12 ~ 24 hours is ?.

Embodiment 2:

Take the meerschaum of parts by weight 150 parts, the wollastonite of 150 parts, the quartz of 120 parts, the wollastonite of 100 parts, 60 The cordierite of part, the cerium oxide of 30 parts, the zirconium oxide of 30 parts, the strontium oxide of 20 parts and the Cs2O of 20 parts, after pulverizing Sieve, preferably 50 mesh sieves；Meerschaum after pulverizing, wollastonite, quartz, wollastonite, cordierite adds kiln calcining, controls Temperature 1200 ~ 1300 DEG C, calcines 12 ~ 24 hours；The calcined mixed material of gained is carried out oil cold, when temperature is reduced to 700 ~ 800 DEG C time add strontium oxide, zirconium oxide, strontium oxide and Cs2O, continue to be warmed up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours；Add After accumulation of heat bundle, naturally cooling to less than 100 DEG C, the water adding raw material gross mass 80% sends into ball mill ball milling 12 ~ 24 hours together Obtain.

Embodiment 3:

Take the meerschaum of parts by weight 130 parts, the wollastonite of 120 parts, the quartz of 110 parts, the wollastonite of 90 parts, the violet of 40 parts Cordierite, the cerium oxide of 20 parts, the zirconium oxide of 20 parts, the strontium oxide of 15 parts and the Cs2O of 15 parts, carry out grinding and sieving, excellent Select 50 mesh sieves；Meerschaum after pulverizing, wollastonite, quartz, wollastonite, cordierite adds kiln calcining, controls temperature 1200 ~ 1300 DEG C, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out oil cold, when temperature is reduced to 700 ~ 800 DEG C Add strontium oxide, zirconium oxide, strontium oxide and Cs2O, continue to be warmed up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours；Add accumulation of heat Shu Hou, naturally cools to less than 100 DEG C, and the water of addition raw material gross mass 70% is sent into ball mill ball milling together and 12 ~ 24 hours is ?.

Embodiment 4:

Take the meerschaum of parts by weight 140 parts, the wollastonite of 130 parts, the quartz of 105 parts, the wollastonite of 85 parts, the violet of 30 parts Cordierite, the cerium oxide of 15 parts, the zirconium oxide of 15 parts, the strontium oxide of 10 parts and the Cs2O of 10 parts, carry out grinding and sieving, excellent Select 50 mesh sieves；Meerschaum after pulverizing, wollastonite, quartz, wollastonite, cordierite adds kiln calcining, controls temperature 1200 ~ 1300 DEG C, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out oil cold, when temperature is reduced to 700 ~ 800 DEG C Add strontium oxide, zirconium oxide, strontium oxide and Cs2O, continue to be warmed up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours；Add accumulation of heat Shu Hou, naturally cools to less than 100 DEG C, and the water of addition raw material gross mass 75% is sent into ball mill ball milling together and 12 ~ 24 hours is ?.

Embodiment 5:

Take the meerschaum of parts by weight 140 parts, the wollastonite of 135 parts, the quartz of 115 parts, the wollastonite of 85 parts, the violet of 50 parts Cordierite, the cerium oxide of 20 parts, the zirconium oxide of 15 parts, the strontium oxide of 15 parts and the Cs2O of 10 parts, carry out grinding and sieving, excellent Select 50 mesh sieves；Meerschaum after pulverizing, wollastonite, quartz, wollastonite, cordierite adds kiln calcining, controls temperature 1200 ~ 1300 DEG C, calcine 12 ~ 24 hours；The calcined mixed material of gained is carried out oil cold, when temperature is reduced to 700 ~ 800 DEG C Add strontium oxide, zirconium oxide, strontium oxide and Cs2O, continue to be warmed up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours；Add accumulation of heat Shu Hou, naturally cools to less than 100 DEG C, and the water of addition raw material gross mass 80% is sent into ball mill ball milling together and 12 ~ 24 hours is ?.

Claims

1. an Environmental-friendceramic ceramic glaze, it is characterised in that include the component of following parts by weight: the meerschaum of 120 ~ 150 parts, The wollastonite of 100 ~ 150 parts, the quartz of 100 ~ 120 parts, the wollastonite of 80 ~ 100 parts, the cordierite of 20 ~ 60 parts, 10 ~ 30 parts Cerium oxide, the zirconium oxide of 10 ~ 30 parts, the strontium oxide of 10 ~ 20 parts and the Cs2O of 10 ~ 20 parts.

Environmental-friendceramic ceramic glaze the most according to claim 1, it is characterised in that be made up of the component of following parts by weight: 130 The meerschaum of part, the wollastonite of 120 parts, the quartz of 100 parts, the wollastonite of 80 parts, the cordierite of 30 parts, the oxidation of 15 parts Cerium, the zirconium oxide of 15 parts, the strontium oxide of 10 parts and the Cs2O of 10 parts.

3. the method for preparation Environmental-friendceramic ceramic glaze described in claim 1 or 2, it is characterised in that comprise the following steps:

(1) measure each raw material by formula, carry out grinding and sieving；