CN106316125B - A kind of Environmental-friendceramic ceramic glaze and preparation method thereof - Google Patents
A kind of Environmental-friendceramic ceramic glaze and preparation method thereof Download PDFInfo
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- CN106316125B CN106316125B CN201610704836.9A CN201610704836A CN106316125B CN 106316125 B CN106316125 B CN 106316125B CN 201610704836 A CN201610704836 A CN 201610704836A CN 106316125 B CN106316125 B CN 106316125B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of Environmental-friendceramic ceramic glazes, component including following parts by weight: 120 ~ 150 parts of sepiolite, 100 ~ 150 parts of wollastonite, 100 ~ 120 parts of quartz, 80 ~ 100 parts of wollastonite, 20 ~ 60 parts of cordierite, 10 ~ 30 parts of cerium oxide, 10 ~ 30 parts of zirconium oxide, 10 ~ 20 parts of strontium oxide strontia and 10 ~ 20 parts of cesium oxide.Meanwhile the invention also discloses the preparation methods of above-mentioned Environmental-friendceramic ceramic glaze.The present invention is compared with traditional technology, and the present invention is compared with traditional technology, and formula science, cost of material is low, replaces leady raw materials by the addition of lot of trace heavy metal, reduces the pollution to environment and the harm of human body.
Description
Technical field
The invention belongs to ceramic coating fields, and in particular to a kind of Environmental-friendceramic ceramic glaze and preparation method thereof.
Background technique
The lead oxide that certain content is had in traditional ceramic glaze, with the raising of compatriots' environmental consciousness and to leaded object
The understanding of matter harm, more and more building ceramic enterprises are dedicated to studying leadless environment-friendly ceramic glaze.Generally, leady raw materials can lead to
The replacement of other heavy metal raw materials is crossed, but expensive heavy metal raw material virtually improves production cost again.
Summary of the invention
Goal of the invention: in view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of Environmental-friendceramic ceramic glaze.
Another object of the present invention is to provide the preparation methods of above-mentioned Environmental-friendceramic ceramic glaze.
Technical solution: in order to achieve the above object of the invention, the present invention is specifically achieved like this: a kind of enviroment protective ceramic glaze
Material, the component including following parts by weight: 120 ~ 150 parts of sepiolite, 100 ~ 150 parts of wollastonite, 100 ~ 120 parts of quartz
Stone, 80 ~ 100 parts of wollastonite, 20 ~ 60 parts of cordierite, 10 ~ 30 parts of cerium oxide, 10 ~ 30 parts of zirconium oxide, 10 ~ 20 parts
Strontium oxide strontia and 10 ~ 20 parts of cesium oxide.
Preferably, it is composed of the following parts by weight: 130 parts of sepiolite, 120 parts of wollastonite, 100 parts of stone
Diamond stone, 80 parts of wollastonite, 30 parts of cordierite, 15 parts of cerium oxide, 15 parts of zirconium oxide, 10 parts of strontium oxide strontia and 10 parts
Cesium oxide.
The method for preparing above-mentioned Environmental-friendceramic ceramic glaze, comprising the following steps:
(1) each raw material is measured by formula, carries out grinding and sieving;
(2) by smashed sepiolite, wollastonite, quartz, wollastonite, cordierite addition kiln calcining, control temperature
It 1200 ~ 1300 DEG C, calcines 12 ~ 24 hours;
(3) oily cold, the addition oxidation when temperature is reduced to 700 ~ 800 DEG C is carried out to the resulting calcined mixed material of step (2)
Cerium, zirconium oxide, strontium oxide strontia and cesium oxide continue to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours;
(4) after to step (3), 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 60 ~ 80% is added is sent together
Enter ball mill ball milling 12 ~ 24 hours to obtain the final product.
The utility model has the advantages that the present invention, compared with traditional technology, the present invention is compared with traditional technology, formula science, cost of material
It is low, leady raw materials are replaced by the addition of lot of trace heavy metal, reduce the pollution to environment and the harm of human body.
Specific embodiment
Embodiment 1:
Take 120 parts of parts by weight of sepiolite, 100 parts of wollastonite, 100 parts of quartz, 80 parts of wollastonite, 20 parts
Cordierite, 10 parts of strontium oxide strontia, 10 parts of zirconium oxide, 10 parts of strontium oxide strontia and 10 parts of cesium oxide are smashed it through
Sieve, preferably 50 meshes;By smashed sepiolite, wollastonite, quartz, wollastonite, cordierite addition kiln calcining, control temperature
1200 ~ 1300 DEG C of degree is calcined 12 ~ 24 hours;Resulting calcined mixed material progress oil is cold, when temperature is reduced to 700 ~ 800 DEG C
When cerium oxide, zirconium oxide, strontium oxide strontia and cesium oxide is added, continue to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours;Heating
After, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 60% is added is sent into ball mill ball milling 12 ~ 24 hours i.e. together
?.
Embodiment 2:
Take 150 parts of parts by weight of sepiolite, 150 parts of wollastonite, 120 parts of quartz, 100 parts of wollastonite,
60 parts of cordierite, 30 parts of cerium oxide, 30 parts of zirconium oxide, 20 parts of strontium oxide strontia and 20 parts of cesium oxide, are crushed
After be sieved, preferably 50 meshes;By smashed sepiolite, wollastonite, quartz, wollastonite, cordierite addition kiln calcining, control
It 1200 ~ 1300 DEG C of temperature processed, calcines 12 ~ 24 hours;It is cold that resulting calcined mixed material is subjected to oil, when temperature is reduced to 700 ~
Strontium oxide strontia, zirconium oxide, strontium oxide strontia and cesium oxide are added at 800 DEG C, continues to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 is small
When;After heating, naturally cool to 100 DEG C hereinafter, be added total mass of raw material 80% water be sent into together ball mill ball milling 12 ~
24 hours to obtain the final product.
Embodiment 3:
Take 130 parts of parts by weight of sepiolite, 120 parts of wollastonite, 110 parts of quartz, 90 parts of wollastonite, 40 parts
Cordierite, 20 parts of cerium oxide, 20 parts of zirconium oxide, 15 parts of strontium oxide strontia and 15 parts of cesium oxide are smashed it through
Sieve, preferably 50 meshes;By smashed sepiolite, wollastonite, quartz, wollastonite, cordierite addition kiln calcining, control temperature
1200 ~ 1300 DEG C of degree is calcined 12 ~ 24 hours;Resulting calcined mixed material progress oil is cold, when temperature is reduced to 700 ~ 800 DEG C
When strontium oxide strontia, zirconium oxide, strontium oxide strontia and cesium oxide is added, continue to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours;Heating
After, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 70% is added is sent into ball mill ball milling 12 ~ 24 hours i.e. together
?.
Embodiment 4:
Take 140 parts of parts by weight of sepiolite, 130 parts of wollastonite, 105 parts of quartz, 85 parts of wollastonite, 30 parts
Cordierite, 15 parts of cerium oxide, 15 parts of zirconium oxide, 10 parts of strontium oxide strontia and 10 parts of cesium oxide are smashed it through
Sieve, preferably 50 meshes;By smashed sepiolite, wollastonite, quartz, wollastonite, cordierite addition kiln calcining, control temperature
1200 ~ 1300 DEG C of degree is calcined 12 ~ 24 hours;Resulting calcined mixed material progress oil is cold, when temperature is reduced to 700 ~ 800 DEG C
When strontium oxide strontia, zirconium oxide, strontium oxide strontia and cesium oxide is added, continue to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours;Heating
After, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 75% is added is sent into ball mill ball milling 12 ~ 24 hours i.e. together
?.
Embodiment 5:
Take 140 parts of parts by weight of sepiolite, 135 parts of wollastonite, 115 parts of quartz, 85 parts of wollastonite, 50 parts
Cordierite, 20 parts of cerium oxide, 15 parts of zirconium oxide, 15 parts of strontium oxide strontia and 10 parts of cesium oxide are smashed it through
Sieve, preferably 50 meshes;By smashed sepiolite, wollastonite, quartz, wollastonite, cordierite addition kiln calcining, control temperature
1200 ~ 1300 DEG C of degree is calcined 12 ~ 24 hours;Resulting calcined mixed material progress oil is cold, when temperature is reduced to 700 ~ 800 DEG C
When strontium oxide strontia, zirconium oxide, strontium oxide strontia and cesium oxide is added, continue to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours;Heating
After, 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 80% is added is sent into ball mill ball milling 12 ~ 24 hours i.e. together
?.
Claims (2)
1. a kind of Environmental-friendceramic ceramic glaze, which is characterized in that be composed of the following parts by weight: 130 parts of sepiolite, 200
The wollastonite of part, 100 parts of quartz, 30 parts of cordierite, 15 parts of cerium oxide, 15 parts of zirconium oxide, 10 parts of strontium oxide strontia
With 10 parts of cesium oxide.
2. the method for preparing Environmental-friendceramic ceramic glaze described in claim 1, which comprises the following steps:
(1) each raw material is measured by formula, carries out grinding and sieving;
(2) by smashed sepiolite, wollastonite, quartz, cordierite is added kiln calcining, controls 1200 ~ 1300 DEG C of temperature,
Calcining 12 ~ 24 hours;
(3) cold to step (2) resulting calcined mixed material progress oil, cerium oxide, oxygen are added when temperature is reduced to 700 ~ 800 DEG C
Change zirconium, strontium oxide strontia and cesium oxide, continues to be warming up to 900 ~ 950 DEG C, continuous heating 24 ~ 36 hours;
(4) after to step (3), 100 DEG C are naturally cooled to hereinafter, the water that total mass of raw material 60 ~ 80% is added is sent into ball together
Grinding machine ball milling 12 ~ 24 hours to obtain the final product.
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CN107721170A (en) * | 2017-11-07 | 2018-02-23 | 广西壮族自治区黎塘工业瓷厂 | A kind of ceramic glaze |
CN108585507A (en) * | 2018-07-16 | 2018-09-28 | 界首市伟盛古窑彩陶制作发展有限公司 | A kind of unleaded antibacterial glaze |
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CN101786795B (en) * | 2009-12-31 | 2014-03-12 | 深圳国瓷永丰源股份有限公司 | Enamel glaze and preparation process thereof |
CN104860723A (en) * | 2015-05-18 | 2015-08-26 | 青岛百千川海洋生态科技有限公司 | Improved ceramic glaze |
CN105859138B (en) * | 2016-04-06 | 2018-08-31 | 伟业陶瓷有限公司 | A kind of ceramic glaze and preparation method thereof that the high fire resistance of intensity is good |
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