CN106305732A - Flutenzine-containing insecticidal acaricidal composition - Google Patents
Flutenzine-containing insecticidal acaricidal composition Download PDFInfo
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Abstract
The present invention belongs to the field of pesticides, and relates to a flutenzine-containing insecticidal acaricidal composition. The flutenzine-containing insecticidal acaricidal composition comprises two active components of components A and B, the weight ratio of A to B is 1:99 to 99:1; the active component A is selected from flufenzine, and the active component B is selected from the group consisting of B1, pyriminostrobin, fluazuron, flucycloxuron, flufenoxuron, bifenthrin, beta-cypermethrin, chlorfenapyr or cypermethrin. The flutenzine-containing insecticidal acaricidal composition has obvious synergic effect, resistance delay and other advantages, and can be used to control various pests and mites.
Description
Technical field
The invention belongs to field of pesticides, relate toA kind of insecticide acaricide composition containing flufenzine。
Background technology
Insecticide has significantly effect in terms of preventing and treating agriculture and forestry injurious insect or urban health insect.
Flufenzine is a kind of acaricide to phytophagous demodicid mite efficiently, to predatory mite safety, it is higher to ovum and children's demodicid mite activity, and the longevity of residure is longer, and the use age is flexible, the kinds such as Tetranychidae, Eriophyidae, Tarsonemidae, Tenuipalpidae are done harm to demodicid mite and are respectively provided with extraordinary biological activity, its structure be asLower instituteShow.
Containing the insecticide of single-activity component, Pest control uses continuously, easily make insect develop immunity to drugs.It is compounded into blending ingredients by a certain percentage by the insecticide of two kinds of active components, often can improve preventive effect, reduce the consumption of effective ingredient, cost-effective, the generation of pest resistance to insecticide can be delayed simultaneously.
Although prior art disclosing flufenzine can produce additional advantage and effect with part Mixture Use of Insecticides, but containing flufenzine and second azoles demodicid mite nitrile, SYP-10898, SYP-11277, fluazuron, flucycloxuron, Cascade, Biphenthrin, effective cypermethrin, capillary, cypermethrin the technical scheme of binary pesticide composition not disclosed.
Summary of the invention
Present invention aim at exploitationA kind of insecticide acaricide composition containing flufenzine, to meet the demand that insecticide effect is day by day improved by agricultural and urban health field pest control aspect and kind is constantly updated.
For achieving the above object, the technical solution used in the present invention is:
A kind of insecticide acaricide composition containing flufenzine: compositions is component A and two kinds of active components of component B, and the ratio of weight and number of two kinds of active components is 1:99～99:1, preferably 1:20～20:1；Active component A is selected from flufenzine, and active component B is selected from B1, pyriminostrobin, fluazuron (fluazuron), flucycloxuron (flucycloxuron), Cascade (flufenoxuron), Biphenthrin (bifenthrin), effective cypermethrin (beta-cypermethrin), capillary (chlorfenapyr) or cypermethrin (cypermethrin) selected from active component B；
B1 structural formula is such asLower instituteShow,
Preferably, in compositions, active component A is selected from flufenzine, and active component B is selected from B1；The ratio of weight and number of two kinds of active components is 7:1～1:3.
Or, in compositions, active component A is selected from flufenzine, and active component B is selected from selected from pyriminostrobin；The ratio of weight and number of two kinds of active components is 1:3～3:1.
The compositions of the present invention can provide in finished product preparation form.Therefore, present invention additionally comprises the insecticide acaricide composition of a kind of dosage form.With compositions as active component, make cream, suspending agent, water-dispersible granules, aqueous emulsion, soluble concentrate, wettable powder, water dispersible oil suspending agent etc. as required.In preparation, the cumulative amount of the active component of compositions is between 0.5%～95%, and preferably cumulative amount is between 1%-85%.In the compositions of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and potentiation degree.The optimum range of active component content is different according to the preparation type of compositions.
The preparation of the compositions finished product preparation of the present invention can be prepared by common processing method, one or more surfactants such as emulsifying agent, dispersant, wetting agent, binding agent, stabilizer and defoamer etc. will be added after active substance mixes with liquid-carrier (solvent) or solid carrier.Generally containing at least one carrier and at least one surfactant in compositions.In all cases, it should be ensured that present composition active component is uniformly distributed.
Cream usually contains the active component of 10～50%, 2～20% emulsifying agent, 0～other additive such as stabilizer, the penetrating agent etc. of 20%, and solvent (if desired possibly together with cosolvent).
Suspending agent generally needs sand milling, to obtain stable non-deposited flowable product.Suspending agent usually contains 5～75% active component, 5～15% dispersant, 4～10% antifreezing agent, 0～other additive such as defoamer, preservative, stabilizer, penetrating agent and the thickening agent of 10%, and liquid-carrier surplus.
Water-dispersible granules is usually made 10～100 international standard sieve meshes (1.676～0.152mm) granule, can be prepared by extruding, dipping or Spray granulation method.Generally water-dispersible granules contains 0.5～the active component of 75% and 5～surfactant such as stabilizer, wetting dispersing agent, disintegrating agent and the binding agent of 20%, and inert carrier surplus.
Wettable powder usually contains the active component of 10～85%, in addition to solid inert carrier, usually contains the dispersant of 3～10%, it is also possible to containing 0～the stabilizer of 10% and (or) other additive, such as penetrating agent or sticker.
Aqueous emulsion is that former medicine, organic solvent, surfactant mixing are formed oil phase；Water, antifreezing agent are mixed, becomes transparent and homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, slowly aqueous phase is added oil phase, usual effective ingredient 1～60%, surfactant 5～20%, antifreezing agent 2～10%, water surplus simultaneously.
Microemulsion is former medicine, organic solvent, surfactant, water to be mixed, and becomes transparent and homogeneous aqueous phase.Generally effective ingredient 1～50%, surfactant 10～40%, antifreezing agent 2～10%, water surplus.
Soluble liquid is active component, organic solvent, surfactant to be mixed, and becomes transparent and homogeneous liquid.Generally effective ingredient 1～50%, surfactant 6～20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added sand milling in sand mill, until particle diameter is qualified, usual effective ingredient 2～60%, surfactant 6～20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion (compositions obtained such as cream, wettable powder or the concentrate of the dilute with water present invention) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick paste-like consistency.
The preparation of the compositions finished product preparation of the present invention can use (liquid or solid) carrier well known to those skilled in the art and various auxiliary agent.Such as include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbitol, methanol, ethanol, butanol, dimethylformamide, dimethyl sulfoxide, N-methyl-pyrrolidon, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, methyl oleate, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often suitable for.
Suitable solid carrier includes clay that is natural or that synthesize and silicate, it is adaptable to the solid carrier of powder includes the mineral (such as microdispersed silicic acid or aluminium oxide) ground of the White Carbon black naturally occurred, rock dust, Chalk, quartz, white carbon, clay, montmorillonite, silicon dioxide, kieselguhr, Pumex, Gypsum Fibrosum, Talcum, bentonite, Kaolin, attapulgite, precipitated calcium carbonate, potter's clay and synthesis.The particulate vector being suitable for includes the synthesis granule that crush and classification natural rock such as calcite, marble, Pumex, meerschaum and dolomite and the powder by Organic substance and inorganic matter are made.
Suitable co-solvents is one or more in methanol, phenol, isoamyl alcohol, dimethyl sulfoxide, ethyl acetate, butanone, dimethylformamide, dimethyl sulfoxide, N-methyl-pyrrolidon, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc..
Suitable emulsifying agent can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin polyoxyethylene ether, oleic acid different thionic acid calcium, triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid triethanolamine salt, agriculture breast AEO-3, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#, agriculture breast 2201#, agriculture breast NP-7, agriculture breast NP-10, agriculture breast NP-15, agriculture breast OP-10 etc..
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer, naphtholsulfonic acid formaldehyde condensation products sodium salt, naphthalenesulfonic acid-formaldehyde condensate, cresol sulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, N-methyl-oleoyl-sodium taurocholate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy based phosphates, detergent LS, pull open powder etc..
Suitable wetting agent can be sodium sulfate, Morwet EFW, isopropyl naphthalene sulfonate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, sodium laurylsulfate, methanonaphthalene sodium sulfonate, dodecylbenzene sodium sulfonate, calcium dodecyl benzene sulfonate, sodium lauryl sulphate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc..
Suitable thickening agent can be synthesis (such as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or natural water-soluble polymer (as xanthan gum,Gelatin, Radix Acaciae senegalis, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, Polyethylene Glycol, phenolic resin, Lac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), add in preparation with powder, granule or latex form.
Suitable defoamer is bubble enemy, silicone, C8～10 fatty alcohol, phosphoric acid ester, C10～20 saturated fat acids (such as capric acid) and amide etc..
Suitable binding agent can be polyvinyl alcohol, polyvinyl acetate, xanthan gum,Gelatin, soluble starch, carboxymethyl cellulose and sodium alginate etc..
Aerosol can be made during for preventing and treating city insect, need to add wherein propellant, it is also possible to make bait formulation compositions, in addition to containing active component, be suitable to the foodstuff of insect's food-taking, optional attractant and optional wetting agent possibly together with one or more.
This combination can be used for preventing and treating the insect of Acarina, and the citing of specific kind of nonexhaustive includes but not limited to grain spider mite, penthaleus major duges, Cotton Gossypii Tetranychus cinnabarinus, vegetable tetranychid, tetranychus viennensis, panonychus citri, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, wart demodicid mite, flour mite, privet mite, Bryobia praetiosa, Citrus tumor demodicid mite；
This combination can be used for preventing and treating the insect of Orthoptera, the citing of specific kind of nonexhaustive include but not limited to Locusta migratoria manilensis (Meyen), reading room management, Ban Tui locust section, Chinese rice grasshopper, Patanga japonica (l.Bol.), single thorn Gryllotalpa, Oriental burmeister, Gryllotalpa unispina, African mole cricket,TaiwanGryllotalpa；
This combination can be used for preventing and treating the insect of Thysanoptera, and the citing of specific kind of nonexhaustive includes but not limited to rice thrips, onion thrips, greenhouse thrips, haplothrips aculeatus, Testa Tritici thrips, end Taeniothrips spp, onion thrips, flower thrips, golden thistle horse, Sugarcane Thrips, yellow thrips；
This combination can be used for preventing and treating the insect of Homoptera, the citing of specific kind of nonexhaustive includes but not limited to Trialeurodes vaporariorum Westwood, rice green leafhopper, Erythroneura subrufa, green leaf hopper, chlorita biguttula, Folium ulmi pumilae Cicadae, smaller green leaf hopper, Indian cotton leafhopper, speckle clothing plant hopper, brown paddy plant hopper, white backed planthopper, small brown rice planthopper, pear sucker, diaphorina citri, Aleurocanthus spiniferus, Caulis Sacchari sinensis flat angle plant hopper, cotten aphid, green bugs, grain aphid, soybean aphid, Aphis medicaginis, Fructus Persicae aphid, kaoliang aphid, radish aphid, sugar cane cottony aphid, eriosoma lanigerum, icerya purchasi, Pseudaulacaspis pentagona, unaspis shield kuwana, san jose scale, wax insect, ceroplastes rubens, Didesmococcus koreanus Borchs, cotton pearl a red-spotted lizard, Caulis Sacchari sinensis mealybug, long white a red-spotted lizard, white peach scale, Fructus Pruni ball heavily fortified point a red-spotted lizard, Ceroplastes japonicus Green, Fructus Kaki floss a red-spotted lizard, bran sheet a red-spotted lizard, chaff scale, brown round a red-spotted lizard, heap wax mealybug；
This combination can be used for preventing and treating the insect of Semiptera, and the citing of specific kind of nonexhaustive includes but not limited to pear lace bug, Fructus Musae lace bug, thin corner piece stinkbug, Orius minutus, slender rice bug, big Leptocorisa spp, paddy fly, niphe elongata, scotinophora lurida, Nezara viridula smaragdula Fabricius., green plant bug, alfalfa plant bug, black striped plant bug, wheat root fleahopper, adelphocoris taeniophorus, tarnished plant bug, Tessaratoma Papillosa Drury；
This combination can be used for preventing and treating lepidopterous insect, the citing of specific kind of nonexhaustive includes but not limited to rain moth, casemaking clothes moth, cnidocampa flavescens walker, brown Limacodidae, thosea siensis, gelechiid, pink bollworm, oriental tobacco budworm, brachmia triannuella, diamondback moth, eating-core bean worm, small heart-eating peach worm, Fructus Cannabis Grapholita spp, oriental fruit months, pear fruit borer, carpocapsa pononella, Fructus Mali pumilae Spilonota lechriaspis, applied perfume, apple tabaniformis, macula lutea leaf roller, apple ermine moth, brown belt length leaf roller, Adoxophyes cyrtosema, the brown leaf roller of stain, the little hairstreak of Fructus Litchi, striped rice borer, bean-pod borer, Pyrausta nubilalis (Hubern)., yellow rice borer,TaiwannullRice borer、Oeobia undalis、Rice leaf roller、Chilotraea infuscatellus、Duckweed ash snout moth's larva、Duckweed snout moth's larva、Bar snout moth's larva、Lap leaf open country snout moth's larva、Sweet Potato snout moth's larva、Some paddy snout moth's larvas、Dichocrocis punctiferalis、Sunflower moth、Yellow snout moth's larva、Chilo infuscatellus、White snout moth's larva、Leucorrhea snout moth's larva、Loxostege sticticalis、Armyworm、Prodenia litura、Three-spotted plusia、Hole wing noctuid、Herba chenopodii noctuid、Corchorus olitorius L. noctuid、Cocytodes caerulea、Fruit piercing moth、Chlumetia transversa Walker、Lopper worm、Beet armyworm、Elegant noctuid、Loquat yellow caterpillar、Pyrameis indica、A Boehmeria Huang a kind of butterfly harmful to crop plants、Rice green caterpillar、Anomis flava、Pink rice borer、Bollworm、Cotton leafroller、Semen sojae atricolor leaf roll snout moth's larva、Peach pyralid moth、Ancient cooking vessel point diamond、Earias fabia、Earias insulana、Black cutworm、Big cutworm、Yellow cutworm、White edge cutworm、Alert stricture of vagina cutworm、Steal acute tonsillitis、Gypsymoth、Palaearctic sweet potato、Greenish brown hawk moth、Straight burr rice hesperiidae、Pelopidas mathias、Papilio xuthus、Common Mormon、Cabbage butterfly、Biobelt butterfly at night、Rice Leaf butterfly at night、Amyloid plaque snout moth、Euproctis pseudoconspersa、Looper、Tea bagworm、Big psychid、Tea bagworm、Parametrites theae、Tea branch sickle moth、Bombyx mandarina Moore、Euproctis similis、Tent caterpillar、Atrijuglans hetaohei、Persimmon fruit moth、Phyllocnistis citrella stainton、Erionota thorax (Linne).；
nullThis combination can be used for preventing and treating the insect of coleoptera，The citing of specific kind of nonexhaustive includes but not limited to bean brassica rapa、Venus ground beetle、Wrinkle sheath ground beetle、Wheat head ground beetle、Pleonomus canaliculatus、Agriotes subrittatus Motschulsky、Wide back of the body wireworm、Brown stricture of vagina wireworm、Khapra beetle、Attagenus piceus、The little buprestid beetle of Citrus、Flat headed apple borer、Gold edge buprestid beetle、Agrilus auriventris、Citrus slip skinworm、Potato bug、Potato ladybug、Herba chenopodii ladybug、Tenebrio molitor、Dark mealworm、Red flour beetle、Confused flour beetle、Grain peat、Saw-toothed grain beetle、Cryptolestes pusillus、Black wrinkle gill Gold Testudinis、Clouding gill Gold Testudinis、Anomala exoleta、Aerugo different beetle、H. parallela、Holotrichia oblita、Mulberry borer、Longicorn beetle、Nadezhdiella cantori、Pink neck Anoplophorae seu Aprionae、Red neck Anoplophorae seu Aprionae、Caulis Sacchari sinensis prionid、Paralglenes fortunei、Hemo longicorn beetle、Brown longicorn beetle、The green Anoplophorae seu Aprionae of light shield、Big daikon leaf beetle、Daicon leaf beetle、Rice root is chrysomelid、Foxtail millet fish-scale is chrysomelid、Folium Cannabis first、Pernicious chrysomelid、Fructus Citri tangerinae leaf mining first、Fructus Ponciri Trifoliatae (Fructus Ponciri Trifoliatae Immaturus) leaf mining first、Aulacophora femoralis、Phyllotreta striolata、Radix Betae flea beetle、Paddy flea beetle、Callosobruchus chinensis、Pea weevil、Broad bean weevil、Sitophilus zea-mais、Rice weevil、Root nodule weevil、Tea beautiful stricture of vagina weevil、Camellia oleosa seed weevil、Radix Betae weevil、Rape stem weevil、Pear curculio、Fructus Pruni tiger、Fructus Persicae tiger、Black floss scarab beetle、Mesh intends ground first、Mongolia intends ground first、Lissorhoptrus oryzophilus Kuschel、Oulema oryzae、Semen Maydis dicladispa armigera、The little green nail of Rhizoma Dioscoreae esculentae、Prominent back of the body glycosides Testudinis、Light back of the body glycosides Testudinis、Yellow leaf worm、Banana root weevil、The double black vaginal discharge curculionid of Fructus Musae；
This combination can be used for preventing and treating dipterous insect, the citing of specific kind of nonexhaustive include but not limited to wheat midge, contarinia tritici, pachydiplosis oryzae, rice midge, ricestem-fly, hydrellia griseola, rice ephydrid, citrus fruit fly, dacus dorsalis, bactrocera tsuneonis, melon trypetid, wheat leaf ash dive fly, Americal rice leaf miner, Soybean stem borer, frit fly, kind fly, onion fly, Radix Raphani fly, sorghum shoot fly, millet stem fly,Herba Astragali Melilotoidis (Herba Astragali Sinici)Liriomyza, duckweed midge, kmangold fly, Radix Betae root maggot, Radix Raphani fly.
During for preventing and treating agricultural pests, fruit tree such as Fructus Mali pumilae, pears, mandarin orange, Fructus Persicae, Fructus Crataegi, Fructus Pruni, Fructus Pruni salicinae, Fructus Jujubae, Semen Juglandis, Fructus Kaki, Arillus Longan, Fructus Musae, Folium Eriobotryae, Fructus Mangifera Indicae, Fructus Litchi etc. can be applied to, cereal such as Semen Tritici aestivi, Oryza sativa L., Semen Maydis, Sorghum vulgare Pers., millet etc., Cotton Gossypii, oil crop such as Semen sojae atricolor, Semen arachidis hypogaeae, Helianthi, Semen Ricini, Semen Sesami etc., sugar crop such as Radix Betae, Caulis Sacchari sinensis etc., crudefiber crop such as Corchorus olitorius L., Boehmeria etc., green manure crop such as Herba Medicaginis, duckweed,Herba Astragali Melilotoidis (Herba Astragali Sinici)Deng, vegetable such as Caulis et Folium Brassicae capitatae, Brassica oleracea L. var. botrytis L., Chinese cabbage, Fructus Cucumidis sativi, Rhizoma Solani tuber osi, Brassica campestris L, Fructus Solani melongenae, Kidney bean, Semen Viciae fabae, Semen phaseoli radiati, Citrullus vulgaris, Rhizoma Dioscoreae esculentae, Fructus Lycopersici esculenti, Fructus Capsici, Herba Alii fistulosi, Folium Allii tuberosi, Bulbus Allii, Rhizoma Zingiberis Recens and flowers, tea, Nicotiana tabacum L., mulberry etc..
During for preventing and treating city insect, family, public place, office space, factory, gardens, golf course can be applied to, and the trees of termite damage, dykes and dams etc. occur.
Present invention additionally comprises a kind of method controlling insect pest, the present composition can be imposed on the medium of the insect needing to control or its growth with effective dose.The more suitable effective dose being generally selected is per hectare 10 grams～500 grams, or is calculated as 5 mg/kg～1000 mg/kg by concentration；Preferably effective dose is per hectare 15 grams～100 grams, or is calculated as 10 mg/kg～500 mg/kg by concentration.
Showing through indoor biological determination of activity, the compositions of the present invention has potentiation.Such as, flufenzine and second azoles demodicid mite nitrile show obvious potentiation in the range of 7:1～1:3 to Tetranychus cinnabarinus.Flufenzine and SYP-11277, SYP-10898 show obvious potentiation in the range of 1:3～3:1 to Tetranychus cinnabarinus.
Present invention have the advantage that
1. the compositions of the present invention shows obvious potentiation in certain ratio range, improves this compound prevention effect to insect.
2. the present composition reduces the using dosage of compound in the application, thus reduces use cost, reduces environmental pollution.
3. in the present composition, the mechanism of action of each effective ingredient is different, and the problem that there is not cross resistance can delay the generation of pest resistance to insecticide, and improve the prevention effect of antagonism population with its pest control.
Detailed description of the invention
Specific examples below is used for further describing the present invention, but the present invention is only limitted to absolutely not these examples.In embodiment, each component percentages or proportioning are by weight.Active component in each formula calculates with effective content, and in compositions, each material all can prepare in a conventional manner simultaneously.
The preparation of embodiment 1,20% second azoles demodicid mite nitrile flufenzine cream
By recipe requirements, be separately added into 5 parts of second azoles demodicid mite nitriles, 15 parts of flufenzine, 7 parts of agriculture breast 0201B, 3 parts of agriculture breast NP-15,2 parts of agriculture breast 1601#, 6 parts of N-methyl-pyrrolidon, dimethylbenzene complement to 100%, mix homogeneously, use hot bath heating for dissolving if desired, i.e. obtain 20% second azoles demodicid mite nitrile flufenzine cream cream.
One in B component described by second azoles demodicid mite nitrile alternative costs description can also be formed 20% new flufenzine B component cream.
The preparation of embodiment 2,40% second azoles demodicid mite nitrile flufenzine wettable powder
By recipe requirements, 10 parts of second azoles demodicid mite nitriles, 30 parts of flufenzine, 2 parts of sodium lauryl sulphates, 3 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 6 parts of calcium lignosulfonates, 5 parts of White Carbon blacks, precipitated calcium carbonates etc. are complemented to 100%, it is sufficiently mixed, after ultra-fine pulverizer disintegrating, i.e. obtain 40% second azoles demodicid mite nitrile flufenzine wettable powder.
One in B component described by second azoles demodicid mite nitrile alternative costs description can also be formed 40% new flufenzine B component wettable powder.
Embodiment 3, the preparation of 40%SYP-10898 flufenzine wettable powder
By recipe requirements, by 20 parts of SYP-10898,20 parts of flufenzine, 2 parts of sodium lauryl sulphates, 5 parts of cresol sulfonic acid formaldehyde condensation products sodium salts, 4 parts pull open powder, 2 parts of detergent LS, 5 parts of White Carbon blacks, precipitated calcium carbonates supply 100%, it is sufficiently mixed, after ultra-fine pulverizer disintegrating, i.e. obtain 40%SYP-10898 flufenzine wettable powder wettable powder.
One in B component described by SYP-10898 alternative costs description can also be formed 40% new flufenzine B component wettable powder.
The preparation of embodiment 4,20% pyriminostrobin flufenzine aqueous emulsion
By recipe requirements, by 10 parts of pyriminostrobin, 10 parts of flufenzine, 8 parts of polyoxyethylene (n20) phenethyl phenol ether through reaction oleate, 15 parts of agriculture breast 2201#, 4 parts of agriculture breast 1601#, 10 parts of Ketohexamethylene, 8 parts of dimethyl sulfoxide mixing, it is stirred to dissolve uniformly oil phase, under high velocity agitation, excess water (complementing to 100%) is joined oil phase, 20% pyriminostrobin flufenzine aqueous emulsion of favorable dispersibility can be formed.
One in B component described by pyriminostrobin alternative costs description can also be formed 20% new flufenzine B component aqueous emulsion.
The preparation of embodiment 5,40% second azoles demodicid mite nitrile flufenzine aqueous emulsion
By recipe requirements, by 25 parts of second azoles demodicid mite nitriles, 15 parts of flufenzine, 2201,6 parts of calcium dodecyl benzene sulfonates of 8 parts of agriculture breasts, 5 parts of Nongru-700 #, 5 parts of N-methyl-pyrrolidon, 8 parts of tributyl phosphates are added together, it is stirred to dissolve uniformly oil phase, under high velocity agitation, the water (complementing to 100%) of surplus is joined oil phase, 40% second azoles demodicid mite nitrile flufenzine aqueous emulsion of favorable dispersibility can be formed.
One in B component described by second azoles demodicid mite nitrile alternative costs description can also be formed the preparation of 40% new flufenzine B component aqueous emulsion.
Embodiment 6,60% second azoles demodicid mite nitrile flufenzine water-dispersible granules
By recipe requirements; 30 parts of second azoles demodicid mite nitriles, 30 parts of flufenzine, 5 parts of methanonaphthalene sodium sulfonates, 5 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 1 part of Morwet EFW, 10 parts of soluble starches, attapulgites are supplied 100%; it is added together; carry out co-grinding; again after the kneading that adds water, it is equipped with in the comminutor of certain specification screen cloth carrying out pelletize.Drying, screening (by screen cloth scope), i.e. can get 60% second azoles demodicid mite nitrile flufenzine water-dispersible granules the most again.
One in B component described by second azoles demodicid mite nitrile alternative costs description can also be formed 60% new flufenzine B component water-dispersible granules.
Embodiment 7,40% second azoles demodicid mite nitrile flufenzine water-dispersible granules
By recipe requirements; 5 parts of second azoles demodicid mite nitriles, 35 parts of flufenzine, 12 parts of methyl naphthalene sulfonate formaldehyde condensates, 5 parts of N-methyl-oleoyl-sodium taurocholates, 1.5 parts of polyvinylpyrrolidones, 8 parts of soluble starches, bentonite etc. are complemented to 100%; it is added together; carry out co-grinding; again after the kneading that adds water, it is equipped with in the comminutor of certain specification screen cloth carrying out pelletize.Drying, screening (by screen cloth scope), i.e. can get 40% second azoles demodicid mite nitrile flufenzine water-dispersible granules the most again.
One in B component described by second azoles demodicid mite nitrile alternative costs description can also be formed 40% new flufenzine B component water-dispersible granules.
Embodiment 8,20% Biphenthrin flufenzine suspending agent
By recipe requirements, by 5 parts of Biphenthrins, 15 parts of flufenzine, 2 parts of agriculture breast 1601#, 2 parts of agriculture breast T-20,4 parts of agriculture breast 0201B, 2 parts of methyl naphthalene sulfonate formaldehyde condensates, 0.2 part of xanthan gum, 0.8 part of white carbon, 5 parts of ethylene glycol, complement to 100% with water, it is added sequentially in blending tank mixing, first pass through high shear to carry out coarse pulverization, homogenize, then it is pumped in sand mill and carries out fine grinding, granularity with particles distribution instrument detection sand milling material, after particle diameter reaches standard-required, filter, i.e. can get 20% Biphenthrin flufenzine suspending agent.
One in B component described by Biphenthrin alternative costs description can also be formed 20% new flufenzine B component suspending agent.
Example 9,50% pyriminostrobin flufenzine suspending agent
By recipe requirements, by 25 parts of pyriminostrobin, 25 parts of flufenzine, 2 parts of naphthalenesulfonic acid-formaldehyde condensates, 1 part of Morwet EFW, 2 parts of agriculture breast T-20,4 parts of agriculture breast 0203B, 0.1 part of xanthan gum, 0.3 part of white carbon, 5 parts of ethylene glycol, complement to 100% with water, it is added sequentially in blending tank mixing, first pass through high shear to carry out coarse pulverization, homogenize, then it is pumped in sand mill and carries out fine grinding, granularity with particles distribution instrument detection sand milling material, after particle diameter reaches standard-required, filter, i.e. can get 50% pyriminostrobin flufenzine suspending agent.
One in B component described by pyriminostrobin alternative costs description can also be formed 50% new flufenzine B component suspending agent.
Embodiment 10,20%SYP-capillary flufenzine microemulsion
By recipe requirements, by 16 parts of capillaries, 4 parts of flufenzine, 10 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid triethanolamine salt, 6 parts of agriculture breast OP-10,8 parts of agriculture breast 2201#, 2 parts of Nongru-700 #, 6 parts of N-methyl-pyrrolidon, 3 parts of triethyl phosphates are added together, make to be dissolved into homogeneous oil phase, surplus water complements to 100%, under high velocity agitation, aqueous phase joined oil phase or oil phase is joined aqueous phase, forming 20% capillary flufenzine microemulsion of favorable dispersibility.
One in B component described by capillary alternative costs description can also be formed 20% new flufenzine B component microemulsion.
Embodiment 11,20% flucycloxuron flufenzine soluble concentrate
By recipe requirements, by 4 parts of flucycloxurons, 16 parts of flufenzine, 12 parts of agriculture breast 2201#, 3 parts of agriculture breast 1601#, 4 parts of agriculture breast 0201B, 10 parts of dimethylformamides, 6 parts of methanol, 20 parts of dimethyl sulfoxide, the molten fibers of methyl complement to 100% mix homogeneously, use hot bath heating for dissolving if desired, 20%SYP-flucycloxuron flufenzine soluble concentrate can be prepared.
One in B component described by flucycloxuron alternative costs description can also be formed 20% new flufenzine B component soluble concentrate.
Embodiment 12,20% second azoles demodicid mite nitrile flufenzine water dispersible oil suspending agent
By recipe requirements, by 15 parts of second azoles demodicid mite nitriles, 5 parts of flufenzine, 5 parts of agriculture breast 0201B, 3 parts of agriculture breast S-80,4 parts of agriculture breast 500#, 3 parts of agriculture breast 1601#, 10 parts of methyl oleates, 3 parts of white carbons, 1 part of agriculture breast T-20, methylated soya oil complements to 100% and is added sequentially in blending tank mixing, first pass through high shear to carry out coarse pulverization, homogenize, then it is pumped in sand mill and carries out fine grinding, granularity with particles distribution instrument detection sand milling material, after particle diameter reaches standard-required, filter, i.e. can get 20% second azoles demodicid mite nitrile flufenzine water dispersible oil suspending agent.
One in B component described by second azoles demodicid mite nitrile alternative costs description can also be formed 20% new flufenzine B component water dispersible oil suspending agent.
Indoor biological determination of activity
The embodiment 13 compositions containing the flufenzine synergism determination to Tetranychus cinnabarinus
For examination object: Tetranychus cinnabarinus (Tetranychus cinnabarinus Boisduval), become demodicid mite, the sensitive strain of indoor feeding.
Test condition: temperature: 24～26 DEG C, humidity: RH 60%, illumination: L:D=14:10
Test method: use pot-spraying method.The sizing potted plant Kidney bean Seedling (2 true leaves) of hot-house culture, stays a piece of true leaf, is connected into demodicid mite 40-60 head thereon.Use Airbrush nebulization medicinal liquid to process examination material, naturally dry in the shade.First process blank, then according to EXPERIMENTAL DESIGN dosage repeats aforesaid operations from low to high, often process 4 times and repeat.Examination worm after processing is placed in observation ward, routine observation examination worm response situation, and 72h " Invest, Then Investigate " is dead, borer population of living, and calculates mortality rate.
Evaluating and use Bliss method, the method is one of classical way evaluating mixture effect.Bliss proposes according to itIndependentSynergy concept is thought, theoretical mortality rate P during Mixture Use of Insecticides can calculate with following formula:
P=Pm+Pn(1-Pm)
PmIt it is the mortality rate (%) of the first active component target when concentration is m；PnIt it is the second active component concentration mortality rate (%) of target when being n.
If the actual of target is more than theoretical mortality rate P after mixing with finite concentration for two kinds of active components, then two kinds of active components of judgement are used in mixed way under setting concentration and have potentiation, otherwise are then antagonism.
Result is shown inTable 1、Table 2WithTable 3。
Table 1Flufenzine is used in mixed way the synergism determination that Tetranychus cinnabarinus becomes demodicid mite with second azoles demodicid mite nitrile
Table 2Flufenzine is used in mixed way the synergism determination that Tetranychus cinnabarinus becomes demodicid mite with SYP-10898
Table 3Flufenzine is used in mixed way the synergism determination that Tetranychus cinnabarinus becomes demodicid mite with pyriminostrobin
Claims (9)
1. the insecticide acaricide composition containing flufenzine, it is characterised in that: compositions is component A
With two kinds of active components of component B, the ratio of weight and number of two kinds of active components is 1:99～99:1；
Active component A is selected from flufenzine, and active component B is selected from B1, phonetic demodicid mite selected from active component B
Amine, fluazuron, flucycloxuron, Cascade, Biphenthrin, effective cypermethrin, capillary or chlorine cyanogen
Chrysanthemum ester；
B1 structural formula is as shown below,
2. according to the compositions described in claim 1, it is characterised in that: the weight of two kinds of active components
Portion rate is 1:20～20:1.
3. according to the compositions described in claim 2, it is characterised in that: active component A in compositions
Selected from flufenzine, active component B is selected from B1；The ratio of weight and number of two kinds of active components is 7:1～1:3.
4. according to the compositions described in claim 2, it is characterised in that: active component A in compositions
Selected from flufenzine, active component B is selected from selected from pyriminostrobin；The ratio of weight and number of two kinds of active components is
1:3～3:1.
5. according to the compositions described in claim 1, it is characterised in that: compositions can be configured to breast
Oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or
Water dispersible oil suspending agent.
6. according to described in claim 5, it is characterised in that: the cumulative amount of active component in compositions
Between 0.5%-95%.
7. according to the compositions described in claim 5, it is characterised in that: active component in compositions
Cumulative amount is between 1%-85%.
8. one kind controls agriculture and forestry injurious insect evil demodicid mite according to the binary insecticide acaricide composition described in claim 1
Or the purposes of urban health insect evil demodicid mite.
9. one kind controls worm, the method for demodicid mite evil, it is characterised in that: by the combination described in claim 1
Thing imposes on effective dose on the medium needing insect evil demodicid mite or its growth controlled.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108684681A (en) * | 2017-03-31 | 2018-10-23 | 沈阳中化农药化工研发有限公司 | A kind of mite-killing preparation and its application |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1105025A (en) * | 1993-07-21 | 1995-07-12 | 奇诺英药物化学工厂有限公司 | Novel acaricidally active tetrazine derivatives |
| WO1997019040A2 (en) * | 1995-11-21 | 1997-05-29 | Chinoin Gyógyszer és Vegyészeti Termékek Gyára Rt. | Pesticide compounds, compositions and process for the preparation thereof |
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN102630691A (en) * | 2012-03-31 | 2012-08-15 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing cyflumetofen |
| CN102986700A (en) * | 2012-12-18 | 2013-03-27 | 海利尔药业集团股份有限公司 | Insecticide composition containing flutenzine and bistrifluron |
| CN103300020A (en) * | 2012-03-12 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Pesticidal composition |
| CN103907623A (en) * | 2012-12-31 | 2014-07-09 | 陕西汤普森生物科技有限公司 | Efficient acaricidal composition containing pyriminostrobin |
| CN104663670A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Synergistic miticidal composition |
-
2015
- 2015-06-18 CN CN201510342374.6A patent/CN106305732B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1105025A (en) * | 1993-07-21 | 1995-07-12 | 奇诺英药物化学工厂有限公司 | Novel acaricidally active tetrazine derivatives |
| WO1997019040A2 (en) * | 1995-11-21 | 1997-05-29 | Chinoin Gyógyszer és Vegyészeti Termékek Gyára Rt. | Pesticide compounds, compositions and process for the preparation thereof |
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN103300020A (en) * | 2012-03-12 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Pesticidal composition |
| CN102630691A (en) * | 2012-03-31 | 2012-08-15 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing cyflumetofen |
| CN102986700A (en) * | 2012-12-18 | 2013-03-27 | 海利尔药业集团股份有限公司 | Insecticide composition containing flutenzine and bistrifluron |
| CN103907623A (en) * | 2012-12-31 | 2014-07-09 | 陕西汤普森生物科技有限公司 | Efficient acaricidal composition containing pyriminostrobin |
| CN104663670A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Synergistic miticidal composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108684681A (en) * | 2017-03-31 | 2018-10-23 | 沈阳中化农药化工研发有限公司 | A kind of mite-killing preparation and its application |
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