CN106282019A - A kind of preparation method of environment-friendly type soaping agent - Google Patents
A kind of preparation method of environment-friendly type soaping agent Download PDFInfo
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- CN106282019A CN106282019A CN201610721552.0A CN201610721552A CN106282019A CN 106282019 A CN106282019 A CN 106282019A CN 201610721552 A CN201610721552 A CN 201610721552A CN 106282019 A CN106282019 A CN 106282019A
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
Abstract
The invention discloses the preparation method of a kind of environment-friendly type soaping agent, belong to soaping agent preparing technical field.Pond Silt and oily sludge are mixed by the present invention, add the heat-preservation fermentations such as sucrose, mix with sterilized water after fermentation, filter to get filtrate standing, obtain bacterium solution, it is seeded on the solid medium that peptone etc. prepares cultivate, mycelia is collected after cultivation, after fluid medium mycelium inoculation to beef extract etc. prepared is cultivated, obtain zymocyte liquid, with the mixed fermentation such as Semen Maydis grit, fermenting mixture through filtration under diminished pressure, centrifugal, stand and filter to obtain filtering residue, mixing with acetone soln, remove impurity, filtering to get filtrate to be dried prepares environment-friendly type soaping agent.The invention has the beneficial effects as follows: preparation process of the present invention is simple, products obtained therefrom efficiency of soaping is high, and color fastness is good；Remaining without dirt after using, releasing chromatic effect is good.
Description
Technical field
The present invention relates to the preparation method of a kind of environment-friendly type soaping agent, belong to soaping agent preparing technical field.
Background technology
The process of soaping after textile dyeing printing can remove the loose colour of fabric face, improves the fastness of dyed fabric.
Add soaping agent and can improve the effect of eccysis loose colour, and make the most counter being stained with of dyestuff knit by dispersion, suspension, complexing
On thing, thus reach to improve soaping fastness and the purpose of anti-staining.Dyestuff can be washed by conventional soaping agent from fabric face,
Washing effect is obtained by emulsifying, dispersion.Owing to the dyestuff in residual liquid thoroughly can not be destroyed, decomposes, extend with wash time,
In residual liquid, dye strength can increase, and is easily caused that the dyestuff washed is the most counter sticks in fabric face, has both reduced dyed fabric
Color fastness, again can cause process scrub raffinate cost increase；Additionally, the salt resistant character of conventional soaping agent is the most very poor, there is salt
In the presence of ability of soaping drastically decline, even completely lose.Therefore, investigated a kind of efficiently soaping agent.
Efficiently soaping agent is composited by multiple special highly reactive polymer, by the interaction with dyestuff, makes residual
Be stored in the dyestuff of soaping in liquid by high-polymer molecular emulsifying, solubilising, form stable dispersion, it is to avoid dyestuff to fabric two
Secondary counter it is stained with, reaches the purpose of anti-staining.In component, contained sp act high polymer can pass through osmosis, reduces working solution circle
The surface tension in face, penetrates into not and between the dyestuff of fiber set and fiber, weakens the interaction force between them, then add
Upper water soluble polymer to the cladding of dyestuff and and dyestuff between the electrostatic that produces, hydrogen bond, dispersion force etc. interact, can make
Dyestuff and hydrolyzate thereof through eluting form the micelle with dyestuff as kernel, make the loose colour come off on fiber be dispersed in water
In washing liquid, and to washing the certain emulsifying of the dyestuff generation fallen, solubilization, form stable suspension/dispersion, no longer return and be stained with
On fabric.But it is low to there is efficiency of soaping in it, and color fastness is poor, has the problem that dirt remains after using.
Summary of the invention
The technical problem to be solved: low for current soaping agent efficiency of soaping, color fastness is poor, has dirt after using
The drawback of dirt residual, it is provided that Pond Silt and oily sludge are mixed by one, add the heat-preservation fermentations such as sucrose, with nothing after fermentation
Bacterium water mixes, and filter to get filtrate standing, obtains bacterium solution, is seeded on the solid medium that peptone etc. prepares cultivate, receives after cultivation
Collection mycelia, after being cultivated by the fluid medium that mycelium inoculation to beef extract etc. prepares, obtains zymocyte liquid, mixes with Semen Maydis grit etc.
Fermentation, fermenting mixture through filtration under diminished pressure, centrifugal, stand and filter to obtain filtering residue, mix with acetone soln, remove impurity, filter to get filtrate
It is dried the method preparing environment-friendly type soaping agent.Preparation process of the present invention is simple, and products obtained therefrom efficiency of soaping is high, and color fastness is good, makes
Remaining without dirt with rear, releasing chromatic effect is good.
For solving above-mentioned technical problem, the present invention uses the technical scheme as described below to be:
(1) 1:3 in mass ratio, takes Pond Silt and oily sludge mix homogeneously, puts into fermentation vat, then is separately added into pond silt
Shale amount 10～the sucrose of 12%, Pond Silt quality 4～the sodium bicarbonate of 8% and Pond Silt quality 2～the carbamide of 4%,
Stirring, then lay Caulis et Folium Oryzae on mixture surface, laying depth is 8～12cm, and keeping fermentation vat internal temperature is 28～36
DEG C, heat-preservation fermentation 2～4 days；
(2) after above-mentioned fermentation ends, in fermentation vat, add the sterilized water of the quality such as above-mentioned Pond Silt, stir with 160r/min
Mix 30～40min, then filter, collect filtrate, subsequently filtrate is placed at 28～35 DEG C, stand 4～6h, remove lower floor and sink
Form sediment, collect upper liquid, obtain bacterium solution；
(3) count by weight, take 35～40 parts of peptones, 23～26 parts of yeast extracts, 18～20 parts of sucrose, 9～12 parts of fine jades
Fat, 3～5 parts of sodium glutamate and 0.4～1.2 part of dipotassium hydrogen phosphate, stir, and sterilizing, obtains solid medium, by connecing
Plant amount 10～15%, above-mentioned bacterium solution is seeded to solid medium, is placed in constant incubator, design temperature 33～38 DEG C,
With 130rpm shaken cultivation 13～15h, in incubation, every 6～7h, use x-ray bombardment solid medium 6～9s；
(4) after above-mentioned cultivation terminates, use inoculating loop to collect media surface mycelia, count by weight, take 43～46 parts
Sterilized water, 24～26 portions of beef extracts, 21～22 parts of casein peptones, 9～12 parts of glucoses and 3～4 parts of sodium chloride, stirring is all
Even, and sterilizing, obtain fluid medium, by inoculum concentration 13～16%, by the media surface mycelium inoculation of collection to liquid
Culture medium, is 34～38 DEG C in temperature, and rotating speed is to cultivate 18～21h under 160r/min, obtains zymocyte liquid；
(5) count by weight, take on 44～48 parts of Semen Maydis grit, 31～33 parts of sterilized water, 23～26 parts of bean cake and 11～13 parts
Stating zymocyte liquid, put in fermentation tank, design temperature is 33～38 DEG C, with 110r/min stirring fermentation 2～4 days, subsequently to sending out
Fermenting mixture in ferment tank carries out filtration under diminished pressure, collects filtrate, is placed in centrifuge, with 4500～5500r/min from
The heart 10～15min, collects supernatant, and using mass fraction is 20% phosphoric acid solution regulation pH to 3.0, after standing 6～8h, mistake
Filter, collects filtering residue, is placed in acetone soln by filtering residue by solid-liquid mass ratio 1:2, stirs 1～2h with 120r/min, filters, and collects
Filtrate, and being spray-dried, collects dried object, environment-friendly type soaping agent.
The application process of the present invention: the environment-friendly type soaping agent present invention prepared adds to 30～38 DEG C of warm water, adds
Amount is 3～5g/L, mixes to soap liquid, then by solid-liquid mass ratio 1:20, take stained clot-h and etc. the textile calico of quality put into soap
In washing liquid, under the conditions of 96～98 DEG C, soap 20～25min, with cold water flush 2～3 times after soaping, take out and dry.This soap
Lotion WASHING COLOR FASTNESS reaches 4～5 grades, and releasing chromatic effect is good, remains without dirt after using, and efficiency of soaping is high.
The present invention is compared with additive method, and Advantageous Effects is:
(1) preparation process of the present invention is simple, and products obtained therefrom efficiency of soaping is high, and color fastness is good；
(2) remaining without dirt after the present invention uses, releasing chromatic effect is good.
Detailed description of the invention
1:3 the most in mass ratio, takes Pond Silt and oily sludge mix homogeneously, puts into fermentation vat, then be separately added into
Pond Silt quality 10～the sucrose of 12%, Pond Silt quality 4～the sodium bicarbonate of 8% and Pond Silt quality 2～4%
Carbamide, stirs, then lays Caulis et Folium Oryzae on mixture surface, and laying depth is 8～12cm, and keeping fermentation vat internal temperature is 28
～36 DEG C, heat-preservation fermentation 2～4 days；After above-mentioned fermentation ends, in fermentation vat, add the aseptic of the quality such as above-mentioned Pond Silt
Water, stirs 30～40min with 160r/min, then filters, and collects filtrate, filtrate is placed in subsequently at 28～35 DEG C, stands 4
～6h, remove lower sediment, collect upper liquid, obtain bacterium solution；Count the most by weight, take 35～40 parts of peptones, 23～26 parts
Yeast extract, 18～20 portions of sucrose, 9～12 parts of agar, 3～5 parts of sodium glutamate and 0.4～1.2 part of dipotassium hydrogen phosphate, stirring is all
Even, and sterilizing, obtain solid medium, by inoculum concentration 10～15%, above-mentioned bacterium solution is seeded to solid medium, is placed in
In constant incubator, design temperature 33～38 DEG C, with 130rpm shaken cultivation 13～15h, in incubation, every 6～7h, make
With x-ray bombardment solid medium 6～9s；Then, after above-mentioned cultivation terminates, inoculating loop is used to collect media surface mycelia,
Count by weight, take 43～46 parts of sterilized water, 24～26 parts of beef extracts, 21～22 parts of casein peptones, 9～12 parts of glucoses
And 3～4 parts of sodium chloride, stir, and sterilizing, obtain fluid medium, by inoculum concentration 13～16%, the cultivation that will collect
Primary surface mycelium inoculation, to fluid medium, is 34～38 DEG C in temperature, and rotating speed is to cultivate 18～21h under 160r/min, must send out
Yeast-like fungi liquid；Finally count by weight, take 44～48 parts of Semen Maydis grit, 31～33 parts of sterilized water, 23～26 parts of bean cake and 11～13
The above-mentioned zymocyte liquid of part, puts in fermentation tank, and design temperature is 33～38 DEG C, with 110r/min stirring fermentation 2～4 days, subsequently
Fermenting mixture in fermentation tank is carried out filtration under diminished pressure, collects filtrate, be placed in centrifuge, with 4500～5500r/
Min is centrifuged 10～15min, collects supernatant, and using mass fraction is 20% phosphoric acid solution regulation pH to 3.0, stands 6～8h
After, filter, collect filtering residue, by solid-liquid mass ratio 1:2, filtering residue is placed in acetone soln, stir 1～2h with 120r/min, mistake
Filter, collects filtrate, and is spray-dried, and collects dried object, environment-friendly type soaping agent.
Example 1
1:3 the most in mass ratio, takes Pond Silt and oily sludge mix homogeneously, puts into fermentation vat, then be separately added into pond
The sucrose of mud quality 10%, the sodium bicarbonate of Pond Silt quality 4% and the carbamide of Pond Silt quality 2%, stir,
Lay Caulis et Folium Oryzae again on mixture surface, laying depth is 8cm, and keeping fermentation vat internal temperature is 28 DEG C, heat-preservation fermentation 2 days；?
After above-mentioned fermentation ends, in fermentation vat, add the sterilized water of the quality such as above-mentioned Pond Silt, stir 30min with 160r/min,
Filter again, collect filtrate, subsequently filtrate is placed at 28 DEG C, stand 4h, remove lower sediment, collect upper liquid, obtain bacterium
Liquid；Count the most by weight, take 35 parts of peptones, 23 parts of yeast extracts, 18 parts of sucrose, 9 parts of agar, 3 parts of sodium glutamate and 0.4
Part dipotassium hydrogen phosphate, stirs, and sterilizing, obtains solid medium, by inoculum concentration 10%, above-mentioned bacterium solution is seeded to solid
Body culture medium, is placed in constant incubator, design temperature 33 DEG C, with 130rpm shaken cultivation 13h, in incubation, often
6h, uses x-ray bombardment solid medium 6s；Then, after above-mentioned cultivation terminates, inoculating loop is used to collect media surface bacterium
Silk, counts by weight, takes 43 parts of sterilized water, 24 portions of beef extracts, 21 parts of casein peptones, 9 parts of glucoses and 3 parts of sodium chloride,
Stir, and sterilizing, obtain fluid medium, by inoculum concentration 13%, by the media surface mycelium inoculation of collection to liquid
Body culture medium, is 34 DEG C in temperature, and rotating speed is cultivation 18h under 160r/min, obtains zymocyte liquid；Finally count by weight, take
44 parts of Semen Maydis grit, 31 parts of sterilized water, 23 parts of bean cake and 11 parts of above-mentioned zymocyte liquids, put in fermentation tank, and design temperature is 33 DEG C,
With 110r/min stirring fermentation 2 days, subsequently the fermenting mixture in fermentation tank is carried out filtration under diminished pressure, collects filtrate, juxtaposition
In centrifuge, being centrifuged 10min with 4500r/min, collect supernatant, using mass fraction is that 20% phosphoric acid solution regulates pH extremely
3.0, after standing 6h, filter, collect filtering residue, by solid-liquid mass ratio 1:2, filtering residue is placed in acetone soln, stir with 120r/min
1h, filters, and collects filtrate, and is spray-dried, and collects dried object, environment-friendly type soaping agent.
The environment-friendly type soaping agent present invention prepared adds to 30 DEG C of warm water, and addition is 3g/L, mixes to soap liquid,
Again by solid-liquid mass ratio 1:20, take stained clot-h and etc. the textile calico of quality put into and soap in liquid, soap under the conditions of 96 DEG C
20min, uses cold water flush 2 times after soaping, and takes out and dries.This soaping agent WASHING COLOR FASTNESS reaches 4 grades, and releasing chromatic effect is good,
Remaining without dirt after using, efficiency of soaping is high.
Example 2
1:3 the most in mass ratio, takes Pond Silt and oily sludge mix homogeneously, puts into fermentation vat, then be separately added into pond
The sucrose of mud quality 11%, the sodium bicarbonate of Pond Silt quality 6% and the carbamide of Pond Silt quality 3%, stir,
Lay Caulis et Folium Oryzae again on mixture surface, laying depth is 10cm, and keeping fermentation vat internal temperature is 32 DEG C, heat-preservation fermentation 3 days；?
After above-mentioned fermentation ends, in fermentation vat, add the sterilized water of the quality such as above-mentioned Pond Silt, stir 35min with 160r/min,
Filter again, collect filtrate, subsequently filtrate is placed at 31 DEG C, stand 5h, remove lower sediment, collect upper liquid, obtain bacterium
Liquid；Count the most by weight, take 38 parts of peptones, 25 parts of yeast extracts, 19 portions of sucrose, 11 parts of agar, 4 parts of sodium glutamate and
0.8 part of dipotassium hydrogen phosphate, stirs, and sterilizing, obtains solid medium, by inoculum concentration 13%, above-mentioned bacterium solution is inoculated
To solid medium, being placed in constant incubator, design temperature 35 DEG C, with 130rpm shaken cultivation 14h, in incubation
In, every 7h, use x-ray bombardment solid medium 8s；Then, after above-mentioned cultivation terminates, use inoculating loop to collect and cultivate base table
Face mycelia, counts by weight, takes 45 parts of sterilized water, 25 portions of beef extracts, 22 parts of casein peptones, 11 parts of glucoses and 4 parts of chlorine
Change sodium, stir, and sterilizing, obtain fluid medium, by inoculum concentration 15%, the media surface mycelium inoculation that will collect
To fluid medium, being 36 DEG C in temperature, rotating speed is cultivation 20h under 160r/min, obtains zymocyte liquid；The most by weight
Meter, takes 46 parts of Semen Maydis grit, 32 parts of sterilized water, 25 parts of bean cake and 12 parts of above-mentioned zymocyte liquids, puts in fermentation tank, and design temperature is
35 DEG C, with 110r/min stirring fermentation 3 days, subsequently the fermenting mixture in fermentation tank is carried out filtration under diminished pressure, collects filtrate,
Being placed in centrifuge, be centrifuged 13min with 5000r/min, collect supernatant, using mass fraction is 20% phosphoric acid solution regulation
PH to 3.0, after standing 7h, filters, collects filtering residue, be placed in acetone soln by filtering residue by solid-liquid mass ratio 1:2, with 120r/min
Stirring 2h, filters, and collects filtrate, and is spray-dried, and collects dried object, environment-friendly type soaping agent.
The environment-friendly type soaping agent present invention prepared adds to 34 DEG C of warm water, and addition is 4g/L, mixes to soap liquid,
Again by solid-liquid mass ratio 1:20, take stained clot-h and etc. the textile calico of quality put into and soap in liquid, soap under the conditions of 97 DEG C
23min, uses cold water flush 3 times after soaping, and takes out and dries.This soaping agent WASHING COLOR FASTNESS reaches 5 grades, and releasing chromatic effect is good,
Remaining without dirt after using, efficiency of soaping is high.
Example 3
1:3 the most in mass ratio, takes Pond Silt and oily sludge mix homogeneously, puts into fermentation vat, then be separately added into pond
The sucrose of mud quality 12%, the sodium bicarbonate of Pond Silt quality 8% and the carbamide of Pond Silt quality 4%, stir,
Lay Caulis et Folium Oryzae again on mixture surface, laying depth is 12cm, and keeping fermentation vat internal temperature is 36 DEG C, heat-preservation fermentation 4 days；?
After above-mentioned fermentation ends, in fermentation vat, add the sterilized water of the quality such as above-mentioned Pond Silt, stir 40min with 160r/min,
Filter again, collect filtrate, subsequently filtrate is placed at 35 DEG C, stand 6h, remove lower sediment, collect upper liquid, obtain bacterium
Liquid；Count the most by weight, take 40 parts of peptones, 26 parts of yeast extracts, 20 portions of sucrose, 12 parts of agar, 5 parts of sodium glutamate and
1.2 parts of dipotassium hydrogen phosphates, stir, and sterilizing, obtain solid medium, by inoculum concentration 15%, above-mentioned bacterium solution are inoculated
To solid medium, being placed in constant incubator, design temperature 38 DEG C, with 130rpm shaken cultivation 15h, in incubation
In, every 7h, use x-ray bombardment solid medium 9s；Then, after above-mentioned cultivation terminates, use inoculating loop to collect and cultivate base table
Face mycelia, counts by weight, takes 46 parts of sterilized water, 26 portions of beef extracts, 22 parts of casein peptones, 12 parts of glucoses and 4 parts of chlorine
Change sodium, stir, and sterilizing, obtain fluid medium, by inoculum concentration 16%, the media surface mycelium inoculation that will collect
To fluid medium, being 38 DEG C in temperature, rotating speed is cultivation 21h under 160r/min, obtains zymocyte liquid；The most by weight
Meter, takes 48 parts of Semen Maydis grit, 33 parts of sterilized water, 26 parts of bean cake and 13 parts of above-mentioned zymocyte liquids, puts in fermentation tank, and design temperature is
38 DEG C, with 110r/min stirring fermentation 4 days, subsequently the fermenting mixture in fermentation tank is carried out filtration under diminished pressure, collects filtrate,
Being placed in centrifuge, be centrifuged 15min with 5500r/min, collect supernatant, using mass fraction is 20% phosphoric acid solution regulation
PH to 3.0, after standing 8h, filters, collects filtering residue, be placed in acetone soln by filtering residue by solid-liquid mass ratio 1:2, with 120r/min
Stirring 2h, filters, and collects filtrate, and is spray-dried, and collects dried object, environment-friendly type soaping agent.
The environment-friendly type soaping agent present invention prepared adds to 38 DEG C of warm water, and addition is 5g/L, mixes to soap liquid,
Again by solid-liquid mass ratio 1:20, take stained clot-h and etc. the textile calico of quality put into and soap in liquid, soap under the conditions of 98 DEG C
25min, uses cold water flush 3 times after soaping, and takes out and dries.This soaping agent WASHING COLOR FASTNESS reaches 5 grades, and releasing chromatic effect is good,
Remaining without dirt after using, efficiency of soaping is high.
Claims (1)
1. the preparation method of an environment-friendly type soaping agent, it is characterised in that concrete preparation process is:
(1) 1:3 in mass ratio, takes Pond Silt and oily sludge mix homogeneously, puts into fermentation vat, then is separately added into pond silt
Shale amount 10～the sucrose of 12%, Pond Silt quality 4～the sodium bicarbonate of 8% and Pond Silt quality 2～the carbamide of 4%,
Stirring, then lay Caulis et Folium Oryzae on mixture surface, laying depth is 8～12cm, and keeping fermentation vat internal temperature is 28～36
DEG C, heat-preservation fermentation 2～4 days；
(2) after above-mentioned fermentation ends, in fermentation vat, add the sterilized water of the quality such as above-mentioned Pond Silt, stir with 160r/min
Mix 30～40min, then filter, collect filtrate, subsequently filtrate is placed at 28～35 DEG C, stand 4～6h, remove lower floor and sink
Form sediment, collect upper liquid, obtain bacterium solution；
(3) count by weight, take 35～40 parts of peptones, 23～26 parts of yeast extracts, 18～20 parts of sucrose, 9～12 parts of fine jades
Fat, 3～5 parts of sodium glutamate and 0.4～1.2 part of dipotassium hydrogen phosphate, stir, and sterilizing, obtains solid medium, by connecing
Plant amount 10～15%, above-mentioned bacterium solution is seeded to solid medium, is placed in constant incubator, design temperature 33～38 DEG C,
With 130rpm shaken cultivation 13～15h, in incubation, every 6～7h, use x-ray bombardment solid medium 6～9s；
(4) after above-mentioned cultivation terminates, use inoculating loop to collect media surface mycelia, count by weight, take 43～46 parts
Sterilized water, 24～26 portions of beef extracts, 21～22 parts of casein peptones, 9～12 parts of glucoses and 3～4 parts of sodium chloride, stirring is all
Even, and sterilizing, obtain fluid medium, by inoculum concentration 13～16%, by the media surface mycelium inoculation of collection to liquid
Culture medium, is 34～38 DEG C in temperature, and rotating speed is to cultivate 18～21h under 160r/min, obtains zymocyte liquid；
(5) count by weight, take on 44～48 parts of Semen Maydis grit, 31～33 parts of sterilized water, 23～26 parts of bean cake and 11～13 parts
Stating zymocyte liquid, put in fermentation tank, design temperature is 33～38 DEG C, with 110r/min stirring fermentation 2～4 days, subsequently to sending out
Fermenting mixture in ferment tank carries out filtration under diminished pressure, collects filtrate, is placed in centrifuge, with 4500～5500r/min from
The heart 10～15min, collects supernatant, and using mass fraction is 20% phosphoric acid solution regulation pH to 3.0, after standing 6～8h, mistake
Filter, collects filtering residue, is placed in acetone soln by filtering residue by solid-liquid mass ratio 1:2, stirs 1～2h with 120r/min, filters, and collects
Filtrate, and being spray-dried, collects dried object, environment-friendly type soaping agent.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107012017A (en) * | 2017-05-14 | 2017-08-04 | 常州五荣化工有限公司 | A kind of preparation method for reactive dye soaping agent of economizing on water |
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| 赵辉 等: "高效生物表面活性剂产生菌筛选及其性质研究", 《生物技术》 * |
| 陈忠喜 等: "除油生物表面活性剂产生菌的分离及其特异性", 《哈尔滨工业大学学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107012017A (en) * | 2017-05-14 | 2017-08-04 | 常州五荣化工有限公司 | A kind of preparation method for reactive dye soaping agent of economizing on water |
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Application publication date: 20170104 |