CN106281627A - The metalworking fluid that a kind of anti-extreme pressure is good - Google Patents
The metalworking fluid that a kind of anti-extreme pressure is good Download PDFInfo
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- CN106281627A CN106281627A CN201610651581.4A CN201610651581A CN106281627A CN 106281627 A CN106281627 A CN 106281627A CN 201610651581 A CN201610651581 A CN 201610651581A CN 106281627 A CN106281627 A CN 106281627A
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- extreme pressure
- good
- boric acid
- metalworking fluid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Abstract
The invention discloses the metalworking fluid that a kind of anti-extreme pressure is good, its raw material includes by weight: its raw material includes by weight: 15 25 parts of mineral oil, emulsifying agent 11 17 parts, sodium molybdate 46 parts, phytic acid 13 parts, 2 tolimidazole quinolines 23 parts, organic boric acid ester 8 12 parts, nano boric acid lanthanum 12 parts, nano titanium oxide 15 parts, chlorinated paraffin 13 parts, defoamer 0.2 0.4 parts, preservative 13 parts, antibacterial 12 parts, 50 60 parts of water;Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant.The present invention is cooperated by organic boric acid ester, nano boric acid lanthanum, nano titanium oxide, chlorinated paraffin so that the present invention has good anti-extreme pressure.
Description
Technical field
The present invention relates to cutting fluid technical field, particularly relate to the metalworking fluid that a kind of anti-extreme pressure is good.
Background technology
Cutting fluid is that one is used in metal cutting, the mill course of processing, is used for cooling down and lubricating the work of cutter and workpiece
Industry liquid.Cutting fluid is divided into oil base metalworking fluid and aqueous cutting fluid.Aqueous cutting fluid has three types, point
Wei emulsifying oil type, synthesis liquid type and semi-synthetic liquid type.Wherein, to have emulsion concurrently good simultaneously for semi-synthetic liquid type metalworking fluid
Lubricity and the synthesis good cleaning feature of liquid, there is again suitable extreme pressure property, and be used widely.But at present
The anti-extreme pressure of commercially available semi-synthetic metalworking fluid is the highest, thus limits its application.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes the metalworking fluid that a kind of anti-extreme pressure is good, this
Invention is cooperated by organic boric acid ester, nano boric acid lanthanum, nano titanium oxide, chlorinated paraffin so that the present invention has good
Good anti-extreme pressure.
The good metalworking fluid of a kind of anti-extreme pressure that the present invention proposes, its raw material includes by weight: mineral oil 15-25
Part, emulsifying agent 11-17 part, sodium molybdate 4-6 part, phytic acid 1-3 part, 2-tolimidazole quinoline 2-3 part, organic boric acid ester 8-12
Part, nano boric acid lanthanum 1-2 part, nano titanium oxide 1-5 part, chlorinated paraffin 1-3 part, defoamer 0.2-0.4 part, preservative 1-3
Part, antibacterial 1-2 part, water 50-60 part;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant.
Preferably, fatty acid methyl sodium sulfonate, NPE, the weight ratio of fluorocarbon surfactant are 8-10:
2-4:1-3.
Preferably, defoamer is the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxy second
The mixture of a kind of and emulsified silicone oil composition in alkene polyoxy propanol amidogen ether or polypropylene glycerol aether.
Preferably, preservative is polyaniline aqueous preservative.
Preferably, antibacterial is Methylisothiazolinone.
Preferably, organic boric acid ester, nano boric acid lanthanum, nano titanium oxide, the weight ratio of chlorinated paraffin are 9-11:1.3-
1.7:2-4:1.5-2.5.
Preferably, its raw material includes by weight: mineral oil 18-22 part, emulsifying agent 13-15 part, sodium molybdate 4.5-5.5
Part, phytic acid 1.5-2.5 part, 2-tolimidazole quinoline 2.3-2.7 part, organic boric acid ester 9-11 part, nano boric acid lanthanum 1.3-1.7
Part, nano titanium oxide 2-4 part, chlorinated paraffin 1.5-2.5 part, defoamer 0.25-0.35 part, preservative 1.5-2.5 part, sterilization
Agent 1.3-1.7 part, water 52-58 part.
The present invention selects organic boric acid ester, nano boric acid lanthanum, nano titanium oxide, chlorinated paraffin to cooperate, nanometer boron
Acid lanthanum, nano titanium oxide have the highest surface activity, cooperate when cutting, can adsorb to be formed in metal surface and inhale
Membrane thus reduce friction, wear-resistant, along with the increase of cutting pressure, the nano-particle on adsorbed film can be formed with metal reaction
More firm reaction film, thus be greatly increased wear-resistant, anti-attrition and the anti-extreme pressure of the present invention, and with organic boric acid ester, chlorination
The boundary lubricant film that paraffin is formed cooperates, and increases wear-resistant, anti-attrition and the anti-extreme pressure of the present invention further;Organic boronic
Ester, nano boric acid lanthanum, nano titanium oxide, chlorinated paraffin with proper ratio coordinate, can increase further the present invention wear-resistant,
Anti-extreme pressure;Selected fatty acid methanesulfonic sodium, NPE, fluorocarbon surfactant cooperate as emulsifying
Agent, and cooperate with mineral oil, organic boric acid ester, nano boric acid lanthanum, nano titanium oxide, chlorinated paraffin so that the present invention
The energy moderate viscosity of holding and preferable stability, and the surface tension of the present invention can be reduced, increase the permeability of the present invention,
Thus increase the anti-extreme pressure of the present invention further;Emulsifying agent coordinates the low bubble increasing the present invention with defoamer, thus enters one
Step increases permeability and the anti-extreme pressure of the present invention;Sodium molybdate, phytic acid, 2-tolimidazole quinoline cooperate, and can increase
The rustless property of the present invention;Preservative, antibacterial can increase stability and the sterilization and anticorrosion performance of the present invention;Above-mentioned each material
Cooperate, promote that the present invention has good anti-extreme pressure.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The metalworking fluid that a kind of anti-extreme pressure is good, its raw material includes by weight: 20 parts of mineral oil, emulsifying agent 14 parts,
Sodium molybdate 5 parts, phytic acid 2 parts, 2-tolimidazole quinoline 2.5 parts, organic boric acid ester 10 parts, nano boric acid lanthanum 1.5 parts, nanometer two
Titanium oxide 3 parts, chlorinated paraffin 2 parts, defoamer 0.3 part, preservative 2 parts, antibacterial 1.5 parts, 55 parts of water;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant.
Embodiment 2
The metalworking fluid that a kind of anti-extreme pressure is good, its raw material includes by weight: 15 parts of mineral oil, emulsifying agent 17 parts,
Sodium molybdate 4 parts, phytic acid 3 parts, 2-tolimidazole quinoline 2 parts, organic boric acid ester 12 parts, nano boric acid lanthanum 1 part, nanometer titanium dioxide
Titanium 5 parts, chlorinated paraffin 1 part, defoamer 0.4 part, polyaniline aqueous preservative 1 part, Methylisothiazolinone 2 parts, 50 parts of water;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant,
Fatty acid methyl sodium sulfonate, NPE, the weight ratio of fluorocarbon surfactant are 10:2:3;
Defoamer is the mixture of the fatty acid ester compounded thing of higher alcohols and emulsified silicone oil composition.
Embodiment 3
The metalworking fluid that a kind of anti-extreme pressure is good, its raw material includes by weight: 25 parts of mineral oil, emulsifying agent 11 parts,
Sodium molybdate 6 parts, phytic acid 1 part, 2-tolimidazole quinoline 3 parts, organic boric acid ester 8 parts, nano boric acid lanthanum 2 parts, nanometer titanium dioxide
Titanium 1 part, chlorinated paraffin 3 parts, defoamer 0.2 part, polyaniline aqueous preservative 3 parts, Methylisothiazolinone 1 part, 60 parts of water;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant,
Fatty acid methyl sodium sulfonate, NPE, the weight ratio of fluorocarbon surfactant are 8:4:1;
Defoamer is the mixture of polyoxyethylene polyoxypropylene tetramethylolmethane ether and emulsified silicone oil composition.
Embodiment 4
The metalworking fluid that a kind of anti-extreme pressure is good, its raw material includes by weight: 18 parts of mineral oil, emulsifying agent 15 parts,
Sodium molybdate 4.5 parts, phytic acid 2.5 parts, 2-tolimidazole quinoline 2.3 parts, organic boric acid ester 11 parts, nano boric acid lanthanum 1.3 parts, receive
Rice titanium dioxide 4 parts, chlorinated paraffin 1.5 parts, defoamer 0.35 part, polyaniline aqueous preservative 1.5 parts, Methylisothiazolinone
1.7 parts, 52 parts of water;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant,
Fatty acid methyl sodium sulfonate, NPE, the weight ratio of fluorocarbon surfactant are 9.5:2.5:2.5;
Defoamer is the mixture of polyoxyethylene polyoxy propanol amidogen ether and emulsified silicone oil composition.
Embodiment 5
The metalworking fluid that a kind of anti-extreme pressure is good, its raw material includes by weight: 22 parts of mineral oil, emulsifying agent 13 parts,
Sodium molybdate 5.5 parts, phytic acid 1.5 parts, 2-tolimidazole quinoline 2.7 parts, organic boric acid ester 9 parts, nano boric acid lanthanum 1.7 parts, receive
Rice titanium dioxide 2 parts, chlorinated paraffin 2.5 parts, defoamer 0.25 part, polyaniline aqueous preservative 2.5 parts, Methylisothiazolinone
1.3 parts, 58 parts of water;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant,
Fatty acid methyl sodium sulfonate, NPE, the weight ratio of fluorocarbon surfactant are 8.5:3.5:1.5;
Defoamer is the mixture of polypropylene glycerol aether and emulsified silicone oil composition.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. the metalworking fluid that an anti-extreme pressure is good, it is characterised in that its raw material includes by weight: mineral oil 15-25 part,
Emulsifying agent 11-17 part, sodium molybdate 4-6 part, phytic acid 1-3 part, 2-tolimidazole quinoline 2-3 part, organic boric acid ester 8-12 part, receive
Rice lanthanum borate 1-2 part, nano titanium oxide 1-5 part, chlorinated paraffin 1-3 part, defoamer 0.2-0.4 part, preservative 1-3 part, kill
Microbial inoculum 1-2 part, water 50-60 part;
Wherein, the raw material of emulsifying agent includes: fatty acid methyl sodium sulfonate, NPE, fluorocarbon surfactant.
The metalworking fluid that the most according to claim 1, anti-extreme pressure is good, it is characterised in that fatty acid methyl sodium sulfonate, nonyl
Phenol polyethenoxy ether, the weight ratio of fluorocarbon surfactant are 8-10:2-4:1-3.
The metalworking fluid that anti-extreme pressure the most according to claim 1 or claim 2 is good, it is characterised in that defoamer is high-carbon alcohol ester
Fat acid esters complex, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether or polypropylene glycerol aether
In a kind of with emulsified silicone oil the mixture of composition.
4. according to the metalworking fluid that anti-extreme pressure described in any one of claim 1-3 is good, it is characterised in that preservative is polyphenyl
Amine waterborne preservative.
5. according to the metalworking fluid that anti-extreme pressure described in any one of claim 1-4 is good, it is characterised in that antibacterial is methyl
Isothiazolone.
6. according to the metalworking fluid that anti-extreme pressure described in any one of claim 1-5 is good, it is characterised in that organic boric acid ester,
Nano boric acid lanthanum, nano titanium oxide, the weight ratio of chlorinated paraffin are 9-11:1.3-1.7:2-4:1.5-2.5.
7. according to the metalworking fluid that anti-extreme pressure described in any one of claim 1-6 is good, it is characterised in that its raw material is by weight
Part includes: mineral oil 18-22 part, emulsifying agent 13-15 part, sodium molybdate 4.5-5.5 part, phytic acid 1.5-2.5 part, 2-methyl benzo miaow
Oxazoline 2.3-2.7 part, organic boric acid ester 9-11 part, nano boric acid lanthanum 1.3-1.7 part, nano titanium oxide 2-4 part, chlorinated paraffin
1.5-2.5 part, defoamer 0.25-0.35 part, preservative 1.5-2.5 part, antibacterial 1.3-1.7 part, water 52-58 part.
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