CN104611117A - Compression-resistant cutting fluid - Google Patents

Abstract

The invention discloses a compression-resistant cutting fluid which is prepared from the following raw materials in parts by weight: 3-4 parts of chlorinated paraffin, 0.3-0.5 part of lithium hydroxide, 0.8-1 parts of hexahydrophthalic anhydride, 0.7-1 part of triethanolamine oleic soap, 1-2 parts of hosho oil, 0.5-1 part of zinc naphthenate, 0.8-2 parts of sodium diacetate, 1-2 parts of calcium ricinoleate, 0.6-1 part of 6-tert-butyl-o-cresol, 1-2 parts of bitertanol, 0.4-1 part of allylthiourea, 2-3 parts of oleic acid, 0.4-1 part of dicyclohexylamine carbonate, 5-7 parts of mineral oil, 70-80 parts of deionized water and 6-7 parts of rare earth functional assistants. According to the compression-resistant cutting fluid disclosed by the invention, the rare earth functional assistants are added; alkenyl succinate, wool fat and polyethylene glycol 4000 are blended and modified first to play a stable rustproof role; the added nano silicon dioxide has certain lubricity so as to reduce the cutting force, friction and power consumption; lanthanum sulfate not only has certain corrosion resistance, but also can be used for improving the rust-proof release effect. The assistants provided by the invention have good hydrophilic and oleophylic characteristics and high emulsion dispersion performance and can be used for effectively improving the corrosion resistance, lubrication, rust prevention and stability of a finished product cutting fluid.

Description

A kind of resistance to compression cutting fluid

Technical field

The present invention relates generally to cutting fluid field, particularly relates to a kind of resistance to compression cutting fluid.

Background technology

Cutting fluid is that one is used in metal cutting, the mill course of processing, be used for the industrial type fluid of Cooling and Lubricator cutter and workpiece, cutting fluid is formed through the cooperation of science compound by multiple super strong functional auxiliary agent, possesses good cooling performance, lubricity, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature simultaneously.Overcome the easily difficult dilution in smelly, winter in summer of traditional soap base emulsion, rust-proof effect difference defect, lathe paint is also had no adverse effects, be applicable to ferrous metal cutting and mill processing, belong to leading current abrasive product.Cutting fluid indices is all better than saponified oil, it has good cooling, cleaning, the feature such as antirust, and possess nontoxic, tasteless, non-corrosive to human body, to equipment not burn into features such as environment do not pollute, tradition cutting fluid also exists different shortcomings, some poor stabilities, in storage with precipitation can be produced in using or layering, analyse wet goods phenomenon, to bacterium and mould resistivity poor, easy mildew and cause smelly, rotten, therefore needs constantly to improve cutting fluid quality.

Summary of the invention

The object of the invention is just to provide a kind of resistance to compression cutting fluid.

The present invention is achieved by the following technical solutions:

A kind of resistance to compression cutting fluid, it is made up of the raw material of following weight parts:

Clorafin 3-4, lithium hydroxide 0.3-0.5, hexahydro phthalic anhydride 0.8-1, trihydroxy ethylamine oleate soap 0.7-1, fragrant camphor oil 1-2, zinc naphthenate 0.5-1, sodium Diacetate 0.8-2, calcium ricinoleate 1-2,6-butyl o-cresol 0.6-1, Bitertanol 1-2, thiosinamine 0.4-1, oleic acid 2-3, carbonic acid dicyclohexyl amine 0.4-1, mineral oil 5-7, deionized water 70-80, rare earth functional agent 6-7;

Described rare earth functional agent is made up of the raw material of following weight parts:

Lanthanum sulfat 3-4, octoxinol 1-2, sodium alkyl benzene sulfonate 2-3, Vinylstyrene 0.1-0.2, alkenyl succinic acid ester 4-5, TriMethylolPropane(TMP) 0.5-0.7, lanolin 2-3, nano silicon 1-2, deionized water 150-200, Macrogol 4000 10-14;

Macrogol 4000, lanolin are mixed to join in reactor, heat fused, adjustment temperature of reaction kettle is 110-120 DEG C, adds alkenyl succinic acid ester, stirring reaction 30-40 minute, discharging is cooled to room temperature, add the 60-70% of Vinylstyrene, above-mentioned deionized water weight, at 80-90 DEG C, insulation leaves standstill 40-50 minute, drips octoxinol, be stirred to normal temperature after dropwising, obtain Macrogol 4000 emulsion;

Nano silicon is mixed with lanthanum sulfat, joins in residue deionized water, magnetic agitation 20-30 minute, add Macrogol 4000 emulsion, raised temperature is 70-80 DEG C, adds each raw material of residue, 300-350 rev/min of dispersed with stirring 10-15 minute, obtains described rare earth functional agent.

2, a preparation method for resistance to compression cutting fluid as claimed in claim 1, is characterized in that comprising the following steps:

(1) by clorafin, oleic acid mixing, insulated and stirred 10-20 minute at 60-65 DEG C, adds calcium ricinoleate, is stirred to normal temperature, obtains Preblend;

(2) by mineral oil, Bitertanol, the mixing of fragrant camphor oil, join after stirring in above-mentioned deionized water, add trihydroxy ethylamine oleate soap, 100-160 rev/min of dispersed with stirring 20-30 minute, add above-mentioned Preblend, insulated and stirred 10-20 minute at 60-65 DEG C;

(3) add each raw material of residue, 600-1000 rev/min of dispersed with stirring 30-40 minute, obtains described cutting fluid.

Advantage of the present invention is:

The rare earth functional agent that the present invention adds: first by alkenyl succinic acid ester, lanolin and Macrogol 4000 blending and modifying, stable antirust effect can be played, the nano silicon added can play certain oilness, reduce cutting force, friction and watt consumption, lanthanum sulfat not only has certain preservative property, antirust slow release effect can also be improved, auxiliary agent of the present invention has good lypohydrophilic character and high emulsion dispersion property, effectively can improve anticorrosion, lubrication, the antirust and stability of finished product cutting fluid;

Cutting fluid of the present invention has fabulous anti-pressure ability, and antirust ability is good, and cost is low, long storage periods also without precipitation, without layering, result of use is good, and stability is strong.

Embodiment

Embodiment 1:

A kind of resistance to compression cutting fluid, is characterized in that what it was made up of the raw material of following weight parts:

Clorafin 4, lithium hydroxide 0.5, hexahydro phthalic anhydride 0.8, trihydroxy ethylamine oleate soap 0.7, fragrant camphor oil 1-2, zinc naphthenate 0.5, sodium Diacetate 0.8, calcium ricinoleate 1,6-butyl o-cresol 0.6, Bitertanol 1, thiosinamine 0.4, oleic acid 2, carbonic acid dicyclohexyl amine 0.4, mineral oil 5, deionized water 80, rare earth functional agent 7;

Described rare earth functional agent is made up of the raw material of following weight parts:

Lanthanum sulfat 3, octoxinol 2, sodium alkyl benzene sulfonate 2, Vinylstyrene 0.2, alkenyl succinic acid ester 4, TriMethylolPropane(TMP) 0.7, lanolin 3, nano silicon 1-2, deionized water 200, Macrogol 4000 14;

Macrogol 4000, lanolin are mixed to join in reactor, heat fused, regulate temperature of reaction kettle to be 120 DEG C, add alkenyl succinic acid ester, stirring reaction 40 minutes, discharging is cooled to room temperature, add Vinylstyrene, above-mentioned deionized water weight 70%, at 90 DEG C insulation leave standstill 40 minutes, drip octoxinol, be stirred to normal temperature after dropwising, obtain Macrogol 4000 emulsion;

Mixed with lanthanum sulfat by nano silicon, join in residue deionized water, magnetic agitation 30 minutes, adds Macrogol 4000 emulsion, and raised temperature is 80 DEG C, and add each raw material of residue, 350 revs/min of dispersed with stirring 15 minutes, obtain described rare earth functional agent.

A preparation method for resistance to compression cutting fluid, is characterized in that comprising the following steps:

(1) by clorafin, oleic acid mixing, at 65 DEG C, insulated and stirred 20 minutes, adds calcium ricinoleate, is stirred to normal temperature, obtain Preblend;

(2) by mineral oil, Bitertanol, the mixing of fragrant camphor oil, join after stirring in above-mentioned deionized water, add trihydroxy ethylamine oleate soap, 160 revs/min of dispersed with stirring 20 minutes, add above-mentioned Preblend, insulated and stirred 20 minutes at 60-65 DEG C;

(3) add each raw material of residue, 1000 revs/min of dispersed with stirring 40 minutes, obtain described cutting fluid.

Performance test:

Claims (2)

1. a resistance to compression cutting fluid, is characterized in that what it was made up of the raw material of following weight parts:

Clorafin 3-4, lithium hydroxide 0.3-0.5, hexahydro phthalic anhydride 0.8-1, trihydroxy ethylamine oleate soap 0.7-1, fragrant camphor oil 1-2, zinc naphthenate 0.5-1, sodium Diacetate 0.8-2, calcium ricinoleate 1-2,6-butyl o-cresol 0.6-1, Bitertanol 1-2, thiosinamine 0.4-1, oleic acid 2-3, carbonic acid dicyclohexyl amine 0.4-1, mineral oil 5-7, deionized water 70-80, rare earth functional agent 6-7;

Described rare earth functional agent is made up of the raw material of following weight parts:

Lanthanum sulfat 3-4, octoxinol 1-2, sodium alkyl benzene sulfonate 2-3, Vinylstyrene 0.1-0.2, alkenyl succinic acid ester 4-5, TriMethylolPropane(TMP) 0.5-0.7, lanolin 2-3, nano silicon 1-2, deionized water 150-200, Macrogol 4000 10-14;

Macrogol 4000, lanolin are mixed to join in reactor, heat fused, adjustment temperature of reaction kettle is 110-120 DEG C, adds alkenyl succinic acid ester, stirring reaction 30-40 minute, discharging is cooled to room temperature, add the 60-70% of Vinylstyrene, above-mentioned deionized water weight, at 80-90 DEG C, insulation leaves standstill 40-50 minute, drips octoxinol, be stirred to normal temperature after dropwising, obtain Macrogol 4000 emulsion;

Nano silicon is mixed with lanthanum sulfat, joins in residue deionized water, magnetic agitation 20-30 minute, add Macrogol 4000 emulsion, raised temperature is 70-80 DEG C, adds each raw material of residue, 300-350 rev/min of dispersed with stirring 10-15 minute, obtains described rare earth functional agent.

2. a preparation method for resistance to compression cutting fluid as claimed in claim 1, is characterized in that comprising the following steps:

(1) by clorafin, oleic acid mixing, insulated and stirred 10-20 minute at 60-65 DEG C, adds calcium ricinoleate, is stirred to normal temperature, obtains Preblend;

(2) by mineral oil, Bitertanol, the mixing of fragrant camphor oil, join after stirring in above-mentioned deionized water, add trihydroxy ethylamine oleate soap, 100-160 rev/min of dispersed with stirring 20-30 minute, add above-mentioned Preblend, insulated and stirred 10-20 minute at 60-65 DEG C;

(3) add each raw material of residue, 600-1000 rev/min of dispersed with stirring 30-40 minute, obtains described cutting fluid.