CN106280841B - 一种热转印离型剂 - Google Patents
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Abstract
本发明公开了一种热转印离型剂，以重量份计，包括以下组分：水性苯乙烯马来酸酐树脂，氟碳表面活性剂，醇化纳米蒙脱土颗粒，增韧剂，甲醇，去离子水。该离型剂为冷热撕型离型剂，既可以在高温下剥离也可以在常温下进行剥离，而且该离型剂剥离完全，稳定性好，制备方法简单。
Description
技术领域
本发明涉及离型材料技术领域，特别是涉及一种热转印离型剂。
背景技术
近年来，热转印印刷技术受到了国内外的广泛关注。热转印印刷不拘泥于产品的形状，操作简单，生产规模较小，并且印刷产品精美细腻，具有良好的市场前景。其中，离型剂是热转印技术的核心内容，是油墨能否全部有效附着在承印物表面的决定性因素。因此，热转印离型剂的相关研究具有重要的实用意义。离型剂是一种以蜡和硅树脂为主体的低黏度透明液体，在常温下可以保持固体状态并具有黏性，而在一定温度下会发生融化流动的油性物质。离型剂起到缓冲PET薄膜和印刷层附着力的作用，并且具有良好的耐磨性，可以保护彩色油墨，延长油墨使用期的作用。
目前，在热转印中使用的离型剂多数为热撕型离型剂，剥离温度大约在150℃左右。另外一种冷撕型离型剂，在常温下就可以剥离，并且剥离效果和热撕型离型剂差距不大。研究一种冷热撕型离型剂，制备的离型膜用于制备冷热撕型热转印膜，其离型表面既可以印刷又可以将印刷的油墨层从表面完整地剥离，从而实现热转移印刷。同时，该类离型膜还可以在成批热转印结束后再进行剥离，从而提高生产效率。
中国专利CN201110359214.4公开了一种热转印离型剂及其制备和使用方法，该热转印离型剂的配方中包括固化剂以及按一定重量百分比组成的聚酯树脂、硅油、消泡剂、流平剂和稀释剂。制备方法为将稀释剂和聚酯树脂搅拌混匀；将消泡剂、硅油和流平剂搅拌混匀；再将组分按比例调配混合均匀得到热转印离型剂。在使用方法中涂布离型层达到不少于6微米的厚度，转移过去的离型层可以充当保护层。经测试硬度可以达到2-3H，从而达到烤漆的效果，省去喷油工序。
发明内容
本发明的目的是提供一种热转印离型剂，该离型剂为冷热撕型离型剂，既可以在高温下剥离也可以在常温下进行剥离，而且该离型剂剥离完全，稳定性好，制备方法简单。
为实现上述目的，本发明采用以下技术方案：
一种热转印离型剂其特征在于，以重量份计，包括以下组分：
水性苯乙烯马来酸酐树脂50-80份，氟碳表面活性剂12-19份，醇化纳米蒙脱土颗粒11-20份，增韧剂2-5份，甲醇8-15份，去离子水20-50份。
一种热转印离型剂其特征在于，以重量份计，包括以下组分：
水性苯乙烯马来酸酐树脂50-80份，氟碳表面活性剂12-19份，醇化纳米蒙脱土颗粒11-20份，增韧剂2-5份，甲醇8-15份，去离子水20-50份，聚醚改性硅油10-18份，乳化剂2-5份，
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油。
作为上述技术方案的优选，其中所述氟碳表面活性剂为3-三聚环氧六氟丙烷酰胺基丙基甜菜碱或N-乙基全氟辛基磺酰基甘氨酸中的一种。
作为上述技术方案的优选，其中所述增韧剂为氯化聚乙烯、聚醋酸乙烯或聚乙烯醇中的一种或多种混合物。
作为上述技术方案的优选，其中所述醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可。
作为上述技术方案的优选，其中所述聚醚改性硅油中环氧乙烷与环氧丙烷的摩尔比为1:2-3。
作为上述技术方案的优选，其中所述乳化剂为十二烷基苯磺酸钠、十八醇聚氧乙烯醚磺酸盐或季戊四醇脂肪酸酯中的一种或多种混合物。
本发明具有以下有益效果，该热转印离型剂采用水性苯乙烯马来酸酐树脂为主要的离型物质，与氟碳表面活性剂配合使用，使得离型剂的表面张力很小，即在较低温度下也可以完全剥离。同时采用醇化的纳米蒙脱土颗粒为填料，纳米蒙脱土颗粒在醇化后可以更加均匀的分布在离型剂中，同时也加强了该离型剂的剥离效果。总而言之，该离型剂可以在常温或者高温下均可以有效剥离，剥离效果好，稳定性高，十分适合工业化生产使用。
具体实施方式
为了更好的理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例1
水性苯乙烯马来酸酐树脂50份，3-三聚环氧六氟丙烷酰胺基丙基甜菜碱17份，醇化纳米蒙脱土颗粒12份，氯化聚乙烯3份，甲醇9份，去离子水30份。
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油；醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可。
实施例2
水性苯乙烯马来酸酐树脂55份，N-乙基全氟辛基磺酰基甘氨酸19份，醇化纳米蒙脱土颗粒15份，聚醋酸乙烯5份，甲醇12份，去离子水30份。
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油；醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可。
实施例3
水性苯乙烯马来酸酐树脂60份，3-三聚环氧六氟丙烷酰胺基丙基甜菜碱15份，醇化纳米蒙脱土颗粒18份，聚乙烯醇4份，甲醇10份，去离子水30份，聚醚改性硅油10份，十二烷基苯磺酸钠2份，
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油；醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可；聚醚改性硅油中环氧乙烷与环氧丙烷的摩尔比为1:2-3。实施例4
水性苯乙烯马来酸酐树脂75份，N-乙基全氟辛基磺酰基甘氨酸12份，醇化纳米蒙脱土颗粒20份，氯化聚乙烯2份，甲醇15份，去离子水30份，聚醚改性硅油18份，季戊四醇脂肪酸酯4份，
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油；醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可；聚醚改性硅油中环氧乙烷与环氧丙烷的摩尔比为1:2-3。实施例5
水性苯乙烯马来酸酐树脂80份，N-乙基全氟辛基磺酰基甘氨酸14份，醇化纳米蒙脱土颗粒16份，聚醋酸乙烯3份，甲醇8份，去离子水30份，聚醚改性硅油15份，十八醇聚氧乙烯醚磺酸盐3份，
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油；醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可；聚醚改性硅油中环氧乙烷与环氧丙烷的摩尔比为1:2-3。
Claims (5)
1.一种热转印离型剂，其特征在于，以重量份计，包括以下组分：
水性苯乙烯马来酸酐树脂50-80份，氟碳表面活性剂12-19份，醇化纳米蒙脱土颗粒11-20份，增韧剂2-5份，甲醇8-15份，去离子水20-50份；
其中所述氟碳表面活性剂为3-三聚环氧六氟丙烷酰胺基丙基甜菜碱或N-乙基全氟辛基磺酰基甘氨酸中的一种；
其中所述醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可。
2.一种热转印离型剂，其特征在于，以重量份计，包括以下组分：
水性苯乙烯马来酸酐树脂50-80份，氟碳表面活性剂12-19份，醇化纳米蒙脱土颗粒11-20份，增韧剂2-5份，甲醇8-15份，去离子水20-50份，聚醚改性硅油10-18份，乳化剂2-5份，
其中聚醚改性硅油是由环氧乙烷和环氧丙烷混合改性的聚醚改性硅油；
其中所述氟碳表面活性剂为3-三聚环氧六氟丙烷酰胺基丙基甜菜碱或N-乙基全氟辛基磺酰基甘氨酸中的一种；
其中所述醇化纳米蒙脱土颗粒的醇化方法为现将纳米蒙脱土颗粒浸泡在硫酸中，浸泡3h后，过滤，将滤出物质浸泡在乙醇中4h后，过滤，烘干即可。
3.根据权利要求1或2所述的热转印离型剂，其特征在于：其中所述增韧剂为氯化聚乙烯、聚醋酸乙烯或聚乙烯醇中的一种或多种混合物。
4.根据权利要求2所述的热转印离型剂，其特征在于：其中所述聚醚改性硅油中环氧乙烷与环氧丙烷的摩尔比为1:2-3。
5.根据权利要求4所述的热转印离型剂，其特征在于：其中所述乳化剂为十二烷基苯磺酸钠、十八醇聚氧乙烯醚磺酸盐或季戊四醇脂肪酸酯中的一种或多种混合物。
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