CN106278717A - A kind of oxygen supplement coated fertilizer of salt affected soil improvement - Google Patents

A kind of oxygen supplement coated fertilizer of salt affected soil improvement Download PDF

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Publication number
CN106278717A
CN106278717A CN201610646859.9A CN201610646859A CN106278717A CN 106278717 A CN106278717 A CN 106278717A CN 201610646859 A CN201610646859 A CN 201610646859A CN 106278717 A CN106278717 A CN 106278717A
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China
Prior art keywords
powder
soil
gained
fertilizer
coated fertilizer
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CN201610646859.9A
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Chinese (zh)
Inventor
陆建双
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Anhui Luhu Biotechnology Co Ltd
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Anhui Luhu Biotechnology Co Ltd
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Priority to CN201610646859.9A priority Critical patent/CN106278717A/en
Publication of CN106278717A publication Critical patent/CN106278717A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses the oxygen supplement coated fertilizer of a kind of salt affected soil improvement, be prepared by the raw materials in: Sargassum 10 12, bagasse 43 47, soy sauce residues 24 25, disodiumedetate 23, ferrous sulfate 34, ammonium chloride 56, Pulvis Talci 45, carbamide 68,30% hydrogenperoxide steam generator 10 12, Laxogenin powder 12, butyl acrylate 0.5 0.7, sodium dihydrogen phosphate dry powder 12, nano zine oxide 0.6 0.7, water are appropriate;Fertilizer of the present invention is rich in substantial amounts of bioactie agent and probiotic bacteria, can effectively expand the distribution of soil with organic matter, the problems such as the elimination soil salinity characters that dependence chemical fertilizer causes throughout the year, organic matter are barren, particularly can increase soil agreegate and permeability, improve fertile soil degree, improve the physicochemical structure of salinization soil, be allowed to the normal growth of suitable for crop.

Description

A kind of oxygen supplement coated fertilizer of salt affected soil improvement
Technical field
The present invention relates to technical field of fertilizers, particularly relate to the oxygen supplement coated fertilizer of a kind of salt affected soil improvement.
Background technology
Along with global climate is abnormal, some areas heavy rain, flood frequently occur, because of improper irrigation or draining the most not The factor such as good often results in crop arable land hydrops waterlogging, makes soil be in waterflooding state, and under flooding condition, in soil, gas is forced Discharge, easily cause oxygen in soil not enough.And oxygen is that root system of plant breathing is necessary, long term hypoxia can make plant cell Electron transmission is obstructed, and active oxygen accumulates in a large number, and membrane structure and function are destroyed, and even there will be crop mortality. Under Hypoxia Stress, root system accumulates the noxious substances such as a large amount of ethanol, lactic acid, and root system metabolism disorder, aerobic respiration is suppressed and causes Energy supply lacks, and the impact absorption to nutrient, waterflooding causes the minimizing of root system oxygen supply, also can cause plant leaf blade pore Closing, stomatal conductance reduces, and in turn results in net photosynthetic rate, the reduction of photochemistry quantum efficiency, and in blade, total leaf is green simultaneously Element and Chlorophyll-a Content decline, and cause the minimizing of plant growth and total biomass, affect greatly crop yield.For Case above, common solution is chesson or enriches oxygenating agent, and the former amount of labour is relatively big, latter increases production Cost, is all not carried out preferable economic benefit.
Research shows, under waterflooding anoxia condition, in plant cell, proline content is exponentially increased, and remains thin with this The turgescence of born of the same parents, protective enzyme and membranous system escape injury, and proline can be alleviated to a certain extent as a kind of osmotic adjustment The anoxia injury effect to cell membrane.Laxogenin is structurally similar to Study on Brassinosteroids, and obtains into This is the cheapest compared with brassinosteroid, Laxogenin can induce soluble sugar in plant, soluble protein, Proline long-pending Tired, Premeabilisation of cells regulating power can be strengthened under waterflooding anoxia condition, make cell maintain a constant turgescence, thus maintain The physiological and biochemical activities relevant with turgescence such as cell growth, stomatal opening and photosynthesis are smoothed out.And Laxogenin Polyradical can be removed by improving oxidase system activity, reduce autoxidation rate, and then reduce membrane lipid The integrity of extent of peroxidation, protecting film structure and macromolecular substances structure, and then keep the stability of cell to carry with vigor Its anoxia resistance high.Meet water after being meanwhile blended with hydrogen peroxide by carbamide and can slowly release the feature of oxygen, by upper State in the preparation being applied to fertilizer, soil epiliminion dissolved oxygen amount can be improved, increase the active o content in the soil liquid, think root The oxygen needed for providing is breathed by system, can prevent again the adverse effect to crop under waterflooding anoxia condition, and then improve crop yield, Increase planting benefit.
The application for a patent for invention of Publication No. 104045386A discloses a kind of hyperoxic plant organic fertilizer, this fertilizer Material is made up of the raw material of following parts by weight: bean cake 20-40 part, cottonseed meal 10-20 part, sugar slag 5-10 part, silicon dioxide 4-8 Part, coal humic acid 5-10 part, manioc waste 20-30 part, shale 7-14 part, plant ash 4-8 part, plant mushroom waste soil 20-30 Part, maltose residues 5-10 part, Semen Maydis grit 5-10 part, Ramulus et folium taxi cuspidatae 3-9 part, Os Sus domestica powder 7-12 part, bulls powder 8-14 part.This invention fertilizer Nutrient content is higher, and fertilizer efficiency is very fast, but is not effectively improved the oxygen content of soil plough horizon, also cannot for unfavorable conditions such as waterflooding Improve the repellence of crop, and without the raising of notable surcharge, limit the use of fertilizer.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that the oxygen supplement coat fertilizer of a kind of salt affected soil improvement Material.
The present invention is achieved by the following technical solutions:
The oxygen supplement coated fertilizer of a kind of salt affected soil improvement, is prepared by the raw materials in: Sargassum 10-12, bagasse 43- 47, soy sauce residues 24-25, disodiumedetate 2-3, ferrous sulfate 3-4, ammonium chloride 5-6, Pulvis Talci 4-5, carbamide 6-8, 30% hydrogenperoxide steam generator 10-12, Laxogenin powder 1-2, butyl acrylate 0.5-0.7, sodium dihydrogen phosphate dry powder 1-2, receive Rice zinc oxide 0.6-0.7, water are appropriate.
Specifically comprising the following steps that of the oxygen supplement coated fertilizer preparation method of described salt affected soil improvement
(1) Sargassum, bagasse, soy sauce residues mixing being placed in fermentation vat, controlling water content is fermentation heap maximum water holding capacity 34-38%, in retting fermentation 3-4 week, dries fermentation material after having fermented, is ground into siccative standby;
(2) 25-30 times of mixture is joined with disodiumedetate, ferrous sulfate after being mixed by Laxogenin powder In the water of quality, it is heated to 63-67 DEG C, is incubated and is stirred continuously 35-40 minute, be down to room temperature afterwards, then be added thereto to step Rapid 1 gained siccative, soaks and stirs 4-6 hour, filters after completing, and collects filtrate and filtrate respectively, and filtrate is dried pulverizing Standby for powder;
(3) carbamide is put in 30% hydrogenperoxide steam generator, then is added thereto to sodium dihydrogen phosphate dry powder, be warming up to 30-32 DEG C, Reacting 50-60 minute, period is constantly stirred, and has reacted and has been placed on subzero 3-5 DEG C of crystallization, after drying by gained material with Step 2 gained powder, ammonium chloride, Pulvis Talci mixing granulation, obtain nuclear core fertiliser granulates standby;
(4) step 2 gained filtrate is sufficiently mixed with butyl acrylate, nano zine oxide, stirs, obtain coating nutritional solution, Being placed in fluidized bed coating equipment by step 3 gained nuclear core fertiliser granulates, control inlet temperature and be 53-55 DEG C, leaving air temp is 33-35 DEG C, coating nutritional solution flow velocity is 2-2.5 ml/min, and coating nutritional solution is coated uniformly on nuclear core fertiliser granulates table Face, obtains coated fertilizer of the present invention.
The invention have the advantage that
Oxygen supplement coated fertilizer of the present invention passes through the peplos effect release with slow-release oxygen gas, it is ensured that crop root aerobic respiration Be normally carried out, for the various physiological metabolism of plant provide energy, enhance crop cell activities of antioxidant enzymes simultaneously, and reduce nothing Oxygen breathes the noxious substance the produced injury to plant, can maintain stable cellularity to a certain extent, and then improve leaf Sheet activities of antioxidant enzymes, alleviates the accumulated active oxygen injury to plant under waterflooding anoxia condition, has strengthening crop resistance to overhead flooding injury Positive role.
Fertilizer of the present invention, rich in substantial amounts of bioactie agent and probiotic bacteria, can effectively expand dividing of soil with organic matter Cloth, eliminates the soil salinity characters relying on chemical fertilizer throughout the year and causing, the organic problem such as barren, particularly can increase soil agreegate and Permeability, improves fertile soil degree, improves the physicochemical structure of salinization soil, be allowed to the normal growth of suitable for crop.
Detailed description of the invention
The oxygen supplement coated fertilizer of a kind of salt affected soil improvement, is made up of the raw material of following weight portion (kg): Sargassum 10, Caulis Sacchari sinensis Slag 43, soy sauce residues 24, disodiumedetate 2, ferrous sulfate 3, ammonium chloride 5, Pulvis Talci 4, carbamide 6,30% hydrogen peroxide are molten Liquid 10, Laxogenin powder 1, butyl acrylate 0.5, sodium dihydrogen phosphate dry powder 1, nano zine oxide 0.6, water are appropriate.
Specifically comprising the following steps that of the oxygen supplement coated fertilizer preparation method of described salt affected soil improvement
(1) Sargassum, bagasse, soy sauce residues mixing being placed in fermentation vat, controlling water content is fermentation heap maximum water holding capacity 34%, retting is fermented 3 weeks, is dried by fermentation material, be ground into siccative standby after having fermented;
(2) 25 times of compounding substances are joined with disodiumedetate, ferrous sulfate after being mixed by Laxogenin powder In the water of amount, it is heated to 63 DEG C, is incubated and is stirred continuously 35 minutes, be down to room temperature afterwards, then it is dry to be added thereto to step 1 gained Material, soaks and stirs 4 hours, filters after completing, and collects filtrate and filtrate respectively, and it is standby for powder that filtrate is dried pulverizing;
(3) carbamide is put in 30% hydrogenperoxide steam generator, then be added thereto to sodium dihydrogen phosphate dry powder, be warming up to 30 DEG C, reaction 50 minutes, period was constantly stirred, and has reacted and has been placed on subzero 3 DEG C of crystallizations, by gained material and step 2 gained after drying Powder, ammonium chloride, Pulvis Talci mixing granulation, obtain nuclear core fertiliser granulates standby;
(4) step 2 gained filtrate is sufficiently mixed with butyl acrylate, nano zine oxide, stirs, obtain coating nutritional solution, Being placed in fluidized bed coating equipment by step 3 gained nuclear core fertiliser granulates, controlling inlet temperature is 53 DEG C, and leaving air temp is 33 DEG C, coating nutritional solution flow velocity is 2 ml/min, and coating nutritional solution is coated uniformly on nuclear core fertiliser granulates surface, i.e. get Ben Fa Bright coated fertilizer.
In order to further illustrate the using value of the present invention, inventor have selected two blocks of micro-alkali that many Yushan Districts physical features is identical Property experiment field plantation Semen Tritici aestivi, one of field use fertilizer of the present invention as experimental group, another block use commercially available common fertilizer As a control group, wheat planting period, two groups of field management were identical for material, recorded yield after results, and the equal 501kg of experimental group per mu yield is right According to the group equal 464kg of per mu yield, it is seen that fertilizer of the present invention has preferable using effect.

Claims (2)

1. the oxygen supplement coated fertilizer of a salt affected soil improvement, it is characterised in that be prepared by the raw materials in: Sargassum 10-12, bagasse 43-47, soy sauce residues 24-25, disodiumedetate 2-3, ferrous sulfate 3-4, ammonium chloride 5-6, Talcum Powder 4-5, carbamide 6-8,30% hydrogenperoxide steam generator 10-12, Laxogenin powder 1-2, butyl acrylate 0.5-0.7, di(2-ethylhexyl)phosphate Hydrogen sodium dry powder 1-2, nano zine oxide 0.6-0.7, water are appropriate.
2. the oxygen supplement coated fertilizer improved according to the salt affected soil described in claims 1, it is characterised in that the tool of preparation method Body step is as follows:
(1) Sargassum, bagasse, soy sauce residues mixing being placed in fermentation vat, controlling water content is fermentation heap maximum water holding capacity 34-38%, in retting fermentation 3-4 week, dries fermentation material after having fermented, is ground into siccative standby;
(2) 25-30 times of mixing is joined with disodiumedetate, ferrous sulfate after being mixed by Laxogenin powder In the water of material amount, it is heated to 63-67 DEG C, is incubated and is stirred continuously 35-40 minute, be down to room temperature afterwards, then be added thereto to Step 1 gained siccative, soaks and stirs 4-6 hour, filters after completing, and collects filtrate and filtrate respectively, and by filtrate ovendry power Broken standby for powder;
(3) carbamide is put in 30% hydrogenperoxide steam generator, then is added thereto to sodium dihydrogen phosphate dry powder, be warming up to 30-32 DEG C, Reacting 50-60 minute, period is constantly stirred, and has reacted and has been placed on subzero 3-5 DEG C of crystallization, after drying by gained material with Step 2 gained powder, ammonium chloride, Pulvis Talci mixing granulation, obtain nuclear core fertiliser granulates standby;
(4) step 2 gained filtrate is sufficiently mixed with butyl acrylate, nano zine oxide, stirs, obtain coating nutritional solution, Being placed in fluidized bed coating equipment by step 3 gained nuclear core fertiliser granulates, control inlet temperature and be 53-55 DEG C, leaving air temp is 33-35 DEG C, coating nutritional solution flow velocity is 2-2.5 ml/min, and coating nutritional solution is coated uniformly on nuclear core fertiliser granulates table Face, obtains coated fertilizer of the present invention.
CN201610646859.9A 2016-08-10 2016-08-10 A kind of oxygen supplement coated fertilizer of salt affected soil improvement Pending CN106278717A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1651357A (en) * 2004-02-08 2005-08-10 吴永常 Organic-inorganic adulterated formula fertilizer
CN102007923A (en) * 2010-11-19 2011-04-13 西北农林科技大学 Laxogenin and derivative thereof-containing plant growth regulator and application thereof
CN104692929A (en) * 2015-02-05 2015-06-10 山东棉花研究中心 Special medicinal fertilizer for overwintering pisum sativum and production method thereof
CN105801273A (en) * 2016-04-25 2016-07-27 纪新强 Trace element liquid water soluble color change fertilizer and dilution control method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1651357A (en) * 2004-02-08 2005-08-10 吴永常 Organic-inorganic adulterated formula fertilizer
CN102007923A (en) * 2010-11-19 2011-04-13 西北农林科技大学 Laxogenin and derivative thereof-containing plant growth regulator and application thereof
CN104692929A (en) * 2015-02-05 2015-06-10 山东棉花研究中心 Special medicinal fertilizer for overwintering pisum sativum and production method thereof
CN105801273A (en) * 2016-04-25 2016-07-27 纪新强 Trace element liquid water soluble color change fertilizer and dilution control method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
何红振 等: ""过氧化尿素的合成及其应用研究进展"", 《化学推进剂与高分子材料》 *
王蕾: ""缓释氧肥解除林木幼苗涝害胁迫的研究"", 《中国优秀硕士学位论文全文数据库 农业科技辑》 *

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