CN106278125A - The regeneration aggregate light-weight wall material of a kind of modified ecological fiber reinforcement and preparation method - Google Patents

The regeneration aggregate light-weight wall material of a kind of modified ecological fiber reinforcement and preparation method Download PDF

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Publication number
CN106278125A
CN106278125A CN201610666981.2A CN201610666981A CN106278125A CN 106278125 A CN106278125 A CN 106278125A CN 201610666981 A CN201610666981 A CN 201610666981A CN 106278125 A CN106278125 A CN 106278125A
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China
Prior art keywords
wall material
ecological fiber
light
strengthened
modified
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Pending
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CN201610666981.2A
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Chinese (zh)
Inventor
钱元弟
柯能好
雷团结
王孝平
王慧
李亚辉
黄维军
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Maanshan MCC 17 Engineering Science and Technology Co Ltd
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Maanshan MCC 17 Engineering Science and Technology Co Ltd
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Priority to CN201610666981.2A priority Critical patent/CN106278125A/en
Publication of CN106278125A publication Critical patent/CN106278125A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses regeneration aggregate light-weight wall material and preparation method that a kind of modified ecological fiber is strengthened, composition and the mass percent thereof of the regeneration aggregate light-weight wall material that this modification ecological fiber is strengthened are as follows: Sorel cement: 15 ~ 36;Blast-furnace cinder micro-powder: 5 ~ 15;Haydite: 10 ~ 25;Regeneration lightweight aggregate: 12 ~ 40;Pottery sand: 8 ~ 20;Modified ecological fiber: 0.1 ~ 0.6;Foaming agent: 0.1 ~ 2;Thickening agent: 0.2 ~ 1.0;Water: 10 ~ 30, Sorel cement needed for dispensing, blast-furnace cinder micro-powder, modified ecological fiber, thickening agent are put together and be stirred, stirring incorporation time is 8 ~ 15 minutes, then it is sequentially added into wherein according still further to the water needed for dispensing, foaming agent, continue stirring 10 ~ 15 minutes, obtain pulpous state compound.The present invention utilizes ecological fiber to have good opposing stretcher strain ability, and proportion is relatively light, makes foam concrete flexible, and China has abundant ecological vegetable resource, can save the living environment of ample resources, the beneficially mankind.

Description

The regeneration aggregate light-weight wall material of a kind of modified ecological fiber reinforcement and preparation method
Technical field
The invention belongs to building material technical field, be specifically related to the regeneration aggregate lightweight that a kind of modified ecological fiber is strengthened Walling and preparation method.
Background technology
12 in the works, and energy-saving and cost-reducing is one and vital task.Building trade energy consumption has accounted for whole society's total energy The 40%-50% of consumption.The Eleventh Five-Year Plan period, China cities and towns are by newly-built 40-50 hundred million square metres building.Strict implement is saved by new building Energy mandatory standard, the energy conservation standard of four municipality directly under the Central Government's execution 65%, the energy conservation standard of 65% is performed to 12 nationwides. And light wall material meets this development trend undoubtedly, it can provide the effects such as excellent insulation, sound insulation, antidetonation, fire prevention, joint About energy consumption.But durability of product, aging resistance and intensity on market are the most not fully up to expectations, it is therefore desirable to improve further and change Enter.
Summary of the invention
The present invention is directed to the technical problem that existing lightweight aggregate concrete exists, it is provided that a kind of modified ecological fiber is strengthened again Raw aggregate light-weight wall material and preparation method, technique is simple, high to utilization rate of solid waste, high-strength light, is incubated durable, sound insulation Fire prevention, cracking resistance and fracture resistance are excellent, the least to energy resource consumption, environmentally safe.
In order to solve above-mentioned technical problem, the invention provides following technical scheme:
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber of the present invention is strengthened, the regeneration aggregate that this modification ecological fiber is strengthened Composition and the mass percent thereof of light-weight wall material are as follows: Sorel cement: 15 ~ 36;Blast-furnace cinder micro-powder: 5 ~ 15;Haydite: 10 ~ 25;Regeneration lightweight aggregate: 12 ~ 40;Pottery sand: 8 ~ 20;Modified ecological fiber: 0.1 ~ 0.6;Foaming agent: 0.1 ~ 2;Thickening agent: 0.2 ~ 1.0;Water: 10 ~ 30.
As a preferred technical solution of the present invention, described Sorel cement mainly calcines the light of gained containing giobertite Burn powder or the ashes of low temperature calcination dolomite gained and magnesium chloride hexahydrate water-soluble magnesium salt.
As a preferred technical solution of the present invention, described haydite is coal gangue haydite or haydites of book structure, piles up unit weight Being 400 ~ 900kg/m3, its particle diameter is 4 ~ 11mm.
As a preferred technical solution of the present invention, described regeneration lightweight aggregate is by reclaiming discarded light wall material Crushing, screen and sort and obtain, unit weight scope 100 ~ 1000kg/m3, particle diameter is 0.5-15mm.
As a preferred technical solution of the present invention, described pottery sand is Coal gangue pottery sand or shale pottery, piles up unit weight Being 250 ~ 800kg/m3, its particle diameter is 0.5mm ~ 4mm.
As a preferred technical solution of the present invention, described foaming agent is dodecylbenzene sodium sulfonate and gelatin.
As a preferred technical solution of the present invention, described thickening agent is the hydroxymethyl, methyl cellulose of powder, viscous Degree is 15000Pa.S ~ 200000 Pa.S.
As a preferred technical solution of the present invention, described modified ecological fiber is by by rice straw, wheat straw Stalk, corn straw, bark, trunk are made after processing containing the ecological vegetable pulverizing of high microsteping, modification, drying etc., length Being 0.2 ~ 4mm, density is 100 ~ 500 kg/m3, and modification mode is to be soaked in nano oxidized by the ecological fiber crushed 0.5h ~ 2h in the modification liquid that aluminum, lime water, propylene glycol, acrylic emulsion, tartaric acid and water are made by a certain percentage.
Present invention also offers the preparation method of the regeneration aggregate light-weight wall material that a kind of modified ecological fiber is strengthened, this is concrete Step is as follows:
A, the Sorel cement by needed for dispensing, blast-furnace cinder micro-powder, modified ecological fiber, thickening agent are put together and are stirred Mixing, stirring incorporation time is 8 ~ 15 minutes, is then sequentially added into wherein according still further to the water needed for dispensing, foaming agent, continues stirring 10 ~ 15 minutes, obtain pulpous state compound;
B, the pulpous state compound obtained to step a add the haydite of surfacedry saturated condition, regeneration lightweight aggregate and pottery sand, and stirring 20 ~ 35 minutes, it is directly injected in light-weight wall material mould finally by grouting pump, i.e. obtains the regeneration aggregate that modified ecological fiber is strengthened Light-weight wall material.
The present invention is reached to provide the benefit that:
(1) present invention comprise substantial amounts of light-weight aggregate, and be evenly distributed, there is the sound insulation of excellence, heat-insulating flame-retardant performance, and with master The body structure same life-span.
(2) utilizing ecological fiber to have good opposing stretcher strain ability, proportion is relatively light, makes foam concrete flexible, And China has abundant ecological vegetable resource, can save the living environment of ample resources, the beneficially mankind;
(3) coarse-fine aggregate is light-weight aggregate, greatly reduces concrete density, ensures comprcssive strength simultaneously.
(4) haydite, the porous of pottery sand and the globality good with Behavior of Hardened Cement Paste in the present invention so that it is there is good resisting Freeze performance.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the invention will be further described, but protection scope of the present invention is not limited only to down State the content of embodiment.
Embodiment 1
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber of the present invention is strengthened, weighs raw material according to following parts by weight:
Sorel cement 30, blast-furnace cinder micro-powder 5, haydite 20, regeneration lightweight aggregate 16, pottery sand 12, modified ecological fiber 0.2, send out Infusion 1.5, thickening agent 0.3, water 20.
A, the Sorel cement by needed for dispensing, blast-furnace cinder micro-powder, modified ecological fiber, thickening agent are put together and are carried out Stirring, stirring incorporation time is 8 ~ 15 minutes, is then sequentially added into wherein according still further to the water needed for dispensing, foaming agent, continues to stir Mix 10 ~ 15 minutes, obtain pulpous state compound;
B, the pulpous state compound obtained to step a add the haydite of surfacedry saturated condition, regeneration lightweight aggregate and pottery sand, and stirring 20 ~ 35 minutes, it is directly injected in light-weight wall material mould finally by grouting pump, i.e. obtains the regeneration aggregate that modified ecological fiber is strengthened Light-weight wall material, its unit weight is 950kg/m2, and 28 days comprcssive strength is 10.5MPa, heat conductivity 0.14w/(m k).
Embodiment 2:
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber of the present invention is strengthened, weighs raw material according to following parts by weight:
Portland cement 27, blast-furnace cinder micro-powder 7, haydite 23, regeneration lightweight aggregate 12, pottery sand 13, modified ecological fiber 0.1, send out Infusion 1.8, thickening agent 0.1, water 16.
A, the portland cement by needed for dispensing, flyash, graining blast-furnace cinder micro-powder, thickening agent are put together and are stirred Mix, stirring incorporation time be 3 ~ 6 minutes, then according still further to the water needed for dispensing, foaming agent, be sequentially added into wherein, continue stirring 10 ~ 15 minutes, obtain pulpous state compound;
B, the pulpous state compound obtained to step a add haydite and the pottery sand of surfacedry saturated condition, stir 20 ~ 35 minutes, obtain Complete light self-insulating concrete, its unit weight is 850kg/m2, and 28 days comprcssive strength is 9.3MPa, heat conductivity 0.11w/(m k).
Embodiment 3:
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber of the present invention is strengthened, weighs raw material according to following parts by weight:
Portland cement 25, blast-furnace cinder micro-powder 12, haydite 12, regeneration lightweight aggregate 24, pottery sand 10, ecological fiber 0.4, foaming agent 1.1, thickening agent 0.5, water 15.
A, the portland cement by needed for dispensing, flyash, graining blast-furnace cinder micro-powder, thickening agent are put together and are stirred Mix, stirring incorporation time be 3 ~ 6 minutes, then according still further to the water needed for dispensing, foaming agent, be sequentially added into wherein, continue stirring 10 ~ 15 minutes, obtain pulpous state compound;
B, the pulpous state compound obtained to step a add haydite and the pottery sand of surfacedry saturated condition, stir 20 ~ 35 minutes, obtain Complete light self-insulating concrete, its unit weight is 1050kg/m2, and 28 days comprcssive strength is 12.2MPa, heat conductivity 0.21w/(m K).
Finally it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention, Although being described in detail the present invention with reference to previous embodiment, for a person skilled in the art, it still may be used So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent. All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the present invention's Within protection domain.

Claims (9)

1. the regeneration aggregate light-weight wall material that a modified ecological fiber is strengthened, it is characterised in that this modification ecological fiber is strengthened Composition and the mass percent thereof of regeneration aggregate light-weight wall material are as follows: Sorel cement: 15 ~ 36;Blast-furnace cinder micro-powder: 5 ~ 15; Haydite: 10 ~ 25;Regeneration lightweight aggregate: 12 ~ 40;Pottery sand: 8 ~ 20;Modified ecological fiber: 0.1 ~ 0.6;Foaming agent: 0.1 ~ 2;Thickening Agent: 0.2 ~ 1.0;Water: 10 ~ 30.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute State the Sorel cement light burnt powder mainly containing giobertite calcining gained or the ashes of low temperature calcination dolomite gained and six water chlorine Change magnesium water-soluble magnesium salt.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute Stating haydite is coal gangue haydite or haydites of book structure, and accumulation unit weight is 400 ~ 900kg/m3, and its particle diameter is 4 ~ 11mm.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute Stating regeneration lightweight aggregate is to be crushed, screen and sort by the discarded light wall material of recovery and obtained, unit weight scope 100 ~ 1000kg/ M3, particle diameter is 0.5-15mm.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute Stating pottery sand is Coal gangue pottery sand or shale pottery, and accumulation unit weight is 250 ~ 800kg/m3, and its particle diameter is 0.5mm ~ 4mm.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute Stating foaming agent is dodecylbenzene sodium sulfonate and gelatin.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute Stating the hydroxymethyl, methyl cellulose that thickening agent is powder, viscosity is 15000Pa.S ~ 200000 Pa.S.
The regeneration aggregate light-weight wall material that a kind of modified ecological fiber the most according to claim 1 is strengthened, it is characterised in that institute Stating modified ecological fiber is by by rice straw, wheat stalk, corn straw, bark, the trunk ecological vegetable containing high microsteping Making after the processing such as pulverizing, modification, drying, a length of 0.2 ~ 4mm, density is 100 ~ 500 kg/m3, modification side Formula be the ecological fiber crushed is soaked in nano aluminium oxide, lime water, propylene glycol, acrylic emulsion, tartaric acid and water by 0.5h ~ 2h in the modification liquid that certain proportion is made.
9. the preparation method of the regeneration aggregate light-weight wall material of a modified ecological fiber reinforcement, it is characterised in that these concrete steps As follows:
A, the Sorel cement by needed for dispensing, blast-furnace cinder micro-powder, modified ecological fiber, thickening agent are put together and are stirred Mixing, stirring incorporation time is 8 ~ 15 minutes, is then sequentially added into wherein according still further to the water needed for dispensing, foaming agent, continues stirring 10 ~ 15 minutes, obtain pulpous state compound;
B, the pulpous state compound obtained to step a add the haydite of surfacedry saturated condition, regeneration lightweight aggregate and pottery sand, and stirring 20 ~ 35 minutes, it is directly injected in light-weight wall material mould finally by grouting pump, i.e. obtains the regeneration aggregate that modified ecological fiber is strengthened Light-weight wall material.
CN201610666981.2A 2016-08-15 2016-08-15 The regeneration aggregate light-weight wall material of a kind of modified ecological fiber reinforcement and preparation method Pending CN106278125A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107573009A (en) * 2017-09-28 2018-01-12 马鞍山十七冶工程科技有限责任公司 A kind of ecological permeable sex vesicle foam concrete and preparation method thereof
US9938199B1 (en) * 2017-02-02 2018-04-10 Saudi Arabian Oil Company Lightweight foam concrete
CN109437692A (en) * 2018-12-10 2019-03-08 武汉轻工大学 Noise abatement insulating wall material and preparation method thereof and noise abatement insulation blocks and preparation method thereof
WO2020062010A1 (en) * 2018-09-25 2020-04-02 马鞍山十七冶工程科技有限责任公司 Preparation method and use of phosphogypsum-based spray-type fireproof mortar reinforced with straw fiber
CN111747691A (en) * 2020-06-24 2020-10-09 东南大学 High-crack-resistance foam concrete and preparation method thereof

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CN104446641A (en) * 2014-12-03 2015-03-25 中国科学院青海盐湖研究所 Magnesium oxychloride cement foam block and preparation method thereof
CN105060816A (en) * 2015-08-07 2015-11-18 马鞍山十七冶工程科技有限责任公司 Cement base permeating crystallizing waterproof paint formed by reinforcing straw fibers
CN105350707A (en) * 2015-09-28 2016-02-24 成都理工大学 Mineral fiber reinforced green energy-saving environmentally-friendly novel wall and preparation method

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CN101121599A (en) * 2007-07-04 2008-02-13 李全 Environmental protection light multipurpose building material and preparation method thereof
CN102367208A (en) * 2010-06-25 2012-03-07 香港科技大学 Fiber-reinforced inorganic slurry composite material and preparation method thereof
CN102850034A (en) * 2012-09-29 2013-01-02 江苏尼高科技有限公司 Chlorine magnesium cement compound foaming insulation board and preparation method thereof
CN103102136A (en) * 2013-01-06 2013-05-15 江苏建华新型墙材有限公司 Method for preparing light insulating wallboard by light concrete waste
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CN104446641A (en) * 2014-12-03 2015-03-25 中国科学院青海盐湖研究所 Magnesium oxychloride cement foam block and preparation method thereof
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9938199B1 (en) * 2017-02-02 2018-04-10 Saudi Arabian Oil Company Lightweight foam concrete
CN107573009A (en) * 2017-09-28 2018-01-12 马鞍山十七冶工程科技有限责任公司 A kind of ecological permeable sex vesicle foam concrete and preparation method thereof
WO2020062010A1 (en) * 2018-09-25 2020-04-02 马鞍山十七冶工程科技有限责任公司 Preparation method and use of phosphogypsum-based spray-type fireproof mortar reinforced with straw fiber
CN109437692A (en) * 2018-12-10 2019-03-08 武汉轻工大学 Noise abatement insulating wall material and preparation method thereof and noise abatement insulation blocks and preparation method thereof
CN111747691A (en) * 2020-06-24 2020-10-09 东南大学 High-crack-resistance foam concrete and preparation method thereof
CN111747691B (en) * 2020-06-24 2022-03-29 东南大学 High-crack-resistance foam concrete and preparation method thereof

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