CN106277843A - 一种微波辐射制备硅烷改性玻璃纤维的方法 - Google Patents

一种微波辐射制备硅烷改性玻璃纤维的方法 Download PDF

Info

Publication number
CN106277843A
CN106277843A CN201610626265.1A CN201610626265A CN106277843A CN 106277843 A CN106277843 A CN 106277843A CN 201610626265 A CN201610626265 A CN 201610626265A CN 106277843 A CN106277843 A CN 106277843A
Authority
CN
China
Prior art keywords
mass parts
glass fibre
unit
microwave
silane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610626265.1A
Other languages
English (en)
Inventor
龚小平
吕海波
刘海顺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Urumqi Yihao Youke New Material Co Ltd
Original Assignee
Urumqi Yihao Youke New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Urumqi Yihao Youke New Material Co Ltd filed Critical Urumqi Yihao Youke New Material Co Ltd
Priority to CN201610626265.1A priority Critical patent/CN106277843A/zh
Publication of CN106277843A publication Critical patent/CN106277843A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/62—Surface treatment of fibres or filaments made from glass, minerals or slags by application of electric or wave energy; by particle radiation or ion implantation
    • C03C25/6206—Electromagnetic waves
    • C03C25/621—Microwaves
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/25—Non-macromolecular compounds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

本发明是一种微波辐射制备硅烷改性玻璃纤维的方法，属非金属材料领域。是以微波辐射法对玻璃纤维改性，提高玻璃纤维与有机、无机，由其是石膏材料黏合或握裹力的方法。

Description

一种微波辐射制备硅烷改性玻璃纤维的方法
本发明属非金属材料领域。是以微波辐射法对玻璃纤维改性，提高玻璃纤维与有机、无机，由其是石膏材料黏合或握裹力的方法。
西电东送战略实施加快了新疆经济发展，同时也带来新疆脱硫石膏的增加，脱硫石膏深层次加工和高档化利用成为经济发展与环境保护的焦点。提高脱硫石膏抗折强度、抗冲击力是这一课题的前提。本发明正是在种背景下完成。
本发明方法是针对脱硫石膏开发，经试验证明对于高分子材料、热固性塑料、热塑型塑料、天然石膏、硅酸盐水泥、高铝水泥及氯氧镁水泥同样适用。
发明内容
本发明是以玻璃纤维为基材，用以下工艺：1配制改性液，2搅拌、3微波辐射、4干燥。4个步骤实现。
步骤1配制改性液：0.2－0.8份硅烷改性剂与0－20份醇与50－100份水混合，其中醇为甲醇、乙醇、或丙醇或异丙醇中的一种或两种以上的混合物，可以使用蒸馏水、去离子水或自来水。
步骤2搅拌：该步骤是在滚筒式混料机中实现。搅拌温度在20℃到60℃，搅拌在时间15－30分钟。以100质量份短切玻璃纤维加入20到50质量份改性液。
步骤3辐射，是使用频率为2.45GHz的S波段微波对上述混合好的物料照射，照射功率是以ｔ为变量的线性函数，照射功率与照射时间Pt＝Ｋ32Ｇ其中ｔ大于0单位为分钟，Ｇ为混合物质量，单位Kg，Ｋ为系数取值0.5到1.5之间，P的单位为KVA。
步骤4干燥是常温或110℃以下环境中得到质量衡重的产物。
实例1：乙醇40g加入Kn172硅烷改性剂1g 搅拌均匀，用220g去离子水稀释。加入1Kg短切玻纤在滚筒式搅拌机中搅拌15分钟。选择2KVA S波段微波炉以起始功率为2KVA，系数K选择常数1计算t＝20分钟，设定微波辐射功率从2KVA到0辐射时间为20分钟。微波照射完成后自然干燥至恒重。
实例2：乙醇20g加入Kn560硅烷改性剂0.8g 搅拌均匀，用80g去离子水稀释。加入400g短切玻纤在滚筒式搅拌机中搅拌15分钟。选用0.75KVA S波段微波炉设定起始功率100% 选择系数0.9通过计算时间t＝19微波结束功率0%线性递减照射时间19分钟。微波照射完成后110℃热风干燥至恒重。
以上实例只是本发明的一个具体方案，并不代表发明全部内容。本发明权利见《权利要求书》。

Claims (5)

1.本发明是以玻璃纤维为基材，通过以下工艺：1配制改性液，2搅拌、3微波辐射、4干燥，4个步骤实现。
2.根据权利要求1，步骤1配制改性液：0.2－0.8质量份硅烷改性剂与0－20质量份醇与50－100质量份水混合，其中醇为甲醇、乙醇、或丙醇或异丙醇中的一种或两种以上的混合物，可以使用蒸馏水、去离子水或自来水。
3.根据权利要求1，步骤2在混料机中实现，搅拌温度在20℃到60℃，搅拌在时间15－30分钟，100质量份短切玻璃纤维加入20到50质量份改性液。
4.步骤3辐射，是使用频率为2.45GHz的S波段微波对上述混合好的物料照射，照射功率是以ｔ为变量的线性函数，照射功率与照射时间Pt＝Ｋ32Ｇ其中ｔ大于0单位为分钟，Ｇ为混合物质量，单位Ｋｇ，Ｋ为系数取值0.5到1.5之间，P的单位为KVA。
5.根据权利要求1，步骤4干燥是常温或110℃环境中得到质量衡重的产物。
CN201610626265.1A 2016-08-03 2016-08-03 一种微波辐射制备硅烷改性玻璃纤维的方法 Pending CN106277843A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610626265.1A CN106277843A (zh) 2016-08-03 2016-08-03 一种微波辐射制备硅烷改性玻璃纤维的方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610626265.1A CN106277843A (zh) 2016-08-03 2016-08-03 一种微波辐射制备硅烷改性玻璃纤维的方法

Publications (1)

Publication Number Publication Date
CN106277843A true CN106277843A (zh) 2017-01-04

Family

ID=57664213

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610626265.1A Pending CN106277843A (zh) 2016-08-03 2016-08-03 一种微波辐射制备硅烷改性玻璃纤维的方法

Country Status (1)

Country Link
CN (1) CN106277843A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107732114A (zh) * 2017-09-27 2018-02-23 芜湖华力五星电源科技有限公司 一种电动汽车用纳米硅胶体铅酸蓄电池隔板
CN111395093A (zh) * 2020-03-20 2020-07-10 河南省高远公路养护技术有限公司 一种抗裂乳化沥青冷再生混合料路面结构及其制备方法
CN112876204A (zh) * 2021-03-22 2021-06-01 乌鲁木齐胜达天利建材科技有限公司 一种改性聚酯纤维增强的硅钙材料及制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1846958A (zh) * 2005-04-13 2006-10-18 上海麦风微波设备有限公司 一种制备轻质墙体板的方法和装置
CN103755302A (zh) * 2013-12-12 2014-04-30 纳诺科技有限公司 一种纤维增强TiO2-SiO2气凝胶复合材料的制备方法
CN104261797A (zh) * 2014-09-02 2015-01-07 南京工业大学 玻璃纤维增强TiO2-SiO2复合气凝胶隔热材料的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1846958A (zh) * 2005-04-13 2006-10-18 上海麦风微波设备有限公司 一种制备轻质墙体板的方法和装置
CN103755302A (zh) * 2013-12-12 2014-04-30 纳诺科技有限公司 一种纤维增强TiO2-SiO2气凝胶复合材料的制备方法
CN104261797A (zh) * 2014-09-02 2015-01-07 南京工业大学 玻璃纤维增强TiO2-SiO2复合气凝胶隔热材料的制备方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107732114A (zh) * 2017-09-27 2018-02-23 芜湖华力五星电源科技有限公司 一种电动汽车用纳米硅胶体铅酸蓄电池隔板
CN111395093A (zh) * 2020-03-20 2020-07-10 河南省高远公路养护技术有限公司 一种抗裂乳化沥青冷再生混合料路面结构及其制备方法
CN112876204A (zh) * 2021-03-22 2021-06-01 乌鲁木齐胜达天利建材科技有限公司 一种改性聚酯纤维增强的硅钙材料及制备方法
CN112876204B (zh) * 2021-03-22 2022-04-12 乌鲁木齐胜达天利建材科技有限公司 一种改性聚酯纤维增强的硅钙材料及制备方法

Similar Documents

Publication Publication Date Title
Chen et al. Influence of silane on hydration characteristics and mechanical properties of cement paste
Escalante-Garcia et al. Effect of temperature on the hydration of the main clinker phases in Portland cements: Part I, neat cements
Wang et al. Influence of polymer on cement hydration in SBR-modified cement pastes
Leung et al. Microwave curing of Portland cement concrete: experimental results and feasibility for practical applications
Kong et al. Hydration and microstructure of cement-based materials under microwave curing
CN106277843A (zh) 一种微波辐射制备硅烷改性玻璃纤维的方法
Makul et al. Microwave-assisted heating of cementitious materials: Relative dielectric properties, mechanical property, and experimental and numerical heat transfer characteristics
Binici et al. Insulation properties of bricks made with cotton and textile ash wastes
Khazma et al. Optimization of flax shive-cementitious composites: Impact of different aggregate treatments using linseed oil
CN109270255A (zh) 一种预测预拌混凝土强度的方法
Jiang et al. Preparation of amphoteric polycarboxylate superplasticizers and their performances in cementitious system
CN105565736B (zh) 一种抗紫外线的功能砂浆的制备方法
Brzozowski et al. The influence of natural and nano-additives on early strength of cement mortars
CN108975836A (zh) 一种电磁波透射复合材料及其制备方法和应用
CN103601455A (zh) 一种速凝时间可控注浆材料及其制备方法
CN106747631A (zh) 一种吸波多孔地聚物及其制备方法和应用
Pan et al. Effects of isothermal microwave curing on steel fibre-reinforced reactive powder concrete: Strength, microstructure and hydration products
Makul Utilization of microwave-accelerated heating and dewatering in low-pressure conditions to accelerated-cure Type-I cement paste for early-age compressive strength development
Makul et al. Use of microwave energy for accelerated curing of concrete: a review.
Fernández-Carrasco et al. Autoclaved cellulose fibre reinforced cement: Effects of silica fume
KR100978289B1 (ko) 바텀애쉬와 폐유리로 제조된 저흡수 경량골재를 사용하여 만든 단열모르타르의 제조방법
Makul et al. Influence of microwave-accelerated curing procedures on the microstructure and strength characteristics of Type I-Portland cement pastes
JP6629615B2 (ja) 繊維混入石膏板の製造方法
KR100440356B1 (ko) 콘크리트의 조기강도를 추정하기 위한 시험체 양생장치 및 이를 이용한 조기강도판정기법
CN104355586A (zh) 防潮石膏板

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170104

WD01 Invention patent application deemed withdrawn after publication