CN106244291A - 一种抗磨防锈金属切削液 - Google Patents

一种抗磨防锈金属切削液 Download PDF

Info

Publication number
CN106244291A
CN106244291A CN201610549119.3A CN201610549119A CN106244291A CN 106244291 A CN106244291 A CN 106244291A CN 201610549119 A CN201610549119 A CN 201610549119A CN 106244291 A CN106244291 A CN 106244291A
Authority
CN
China
Prior art keywords
parts
rust
wear
cutting fluid
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610549119.3A
Other languages
English (en)
Inventor
林伟
江海涛
江海波
江浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Runda Metal Antirust Auxiliary Co Ltd
Original Assignee
Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Runda Metal Antirust Auxiliary Co Ltd filed Critical Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority to CN201610549119.3A priority Critical patent/CN106244291A/zh
Publication of CN106244291A publication Critical patent/CN106244291A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/18—Compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/16—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/081—Inorganic acids or salts thereof containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/064—Thiourea type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油20‑30份、石油磺酸钠5‑15份、烷基酚聚氧乙烯醚2‑8份、烷基醇酰胺3‑5份、二烷基二硫代氨基甲酸钼1‑5份、二烷基亚磷酸酯2‑6份、二壬基聚氧乙烯醚磷酸锌3‑5份、三乙醇胺硼酸酯1‑4份、油酸2‑5份、二烷基二硫代磷酸1‑3份、硫化物硫脲2‑5份、N‑酰基氨基酸三乙醇胺1‑6份、水溶性抗磨纳米颗粒3‑5份、异噻唑啉酮1‑4份、磷酸三丁酯2‑6份、防锈添加剂1‑4份、水6‑12份。本发明的金属切削液具有优异的抗磨防锈性能。

Description

一种抗磨防锈金属切削液
技术领域
本发明涉及一种切削液，尤其涉及一种抗磨防锈金属切削液。
背景技术
金属切削液是金属加工过程所需要的一种重要的辅助材料，它主要起到防锈、润滑、清洗及冷却的效果。目前国内外切削液主要分为油基切削液与水基两个大的种类，而且有油基型向水基切削液过渡的趋势，油基切削液即通常所说的切削油，其润滑性能良好，但冷却效果较差，在高速和重切削条件下会产生烟雾，并会严重污染环境，而且产品使用过程中易着火，造成使用不安全。正是由于以上缺点，因此，油基切削液已不能满足先进金属加工技术的使用要求。而水基切削液具有一系列优点，如冷却效果好，防火性好，对环境的污染问题易于解决等。因此，近年来发展很快，水基切削液包括乳化液、合成切削液和微乳状切削液(也称半合成切削液)。合成切削液的液体形态与半合成切削液近似，稀释性呈透明状，加工过程中便于观察加工情况，使用寿命比乳化液长4～6倍；可对机床滑动部件起到良好的润滑防锈作用。
现有技术中的切削液的合成主要是一些润滑剂、表面活性剂、防锈剂、偶合剂、有机硅型消泡剂等组成，润滑剂主要是应用机油、聚乙二醇、脂肪酸皂等，而防锈剂主要是应用油酸三乙醇胺皂、硼酸盐、亚硝酸盐、铬酸盐等。表面活性剂主要应用NP系列、TX系列、聚醚系列等。
现有技术中的切削液的抗磨、防腐和防锈性能无法满足实际生产过程中的需求，因此亟需开发一种抗磨防锈金属切削液来解决现有技术中的问题。
发明内容
为解决背景技术中存在的技术问题，本发明提出一种抗磨防锈金属切削液，具有优异的抗磨防锈性能。
本发明提出的一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油20-30份、石油磺酸钠5-15份、烷基酚聚氧乙烯醚2-8份、烷基醇酰胺3-5份、二烷基二硫代氨基甲酸钼1-5份、二烷基亚磷酸酯2-6份、二壬基聚氧乙烯醚磷酸锌3-5份、三乙醇胺硼酸酯1-4份、油酸2-5份、二烷基二硫代磷酸1-3份、硫化物硫脲2-5份、N-酰基氨基酸三乙醇胺1-6份、水溶性抗磨纳米颗粒3-5份、异噻唑啉酮1-4份、磷酸三丁酯2-6份、防锈添加剂1-4份、水6-12份。
优选地，水溶性抗磨纳米颗粒按如下工艺进行制备：将La(NO3)3溶液和NaF溶液混合均匀，于50-60℃水浴磁力搅拌0.5-1.5h，冷却至室温，然后加入氨水，接着加入FeCl2溶液和FeCl3溶液混合均匀，搅拌20-40min，然后加入柠檬酸，搅拌0.5-1.5h，洗涤2-4次，干燥得到水溶性抗磨纳米颗粒。
优选地，水溶性抗磨纳米颗粒的制备工艺中，La(NO3)3溶液、NaF溶液、氨水、FeCl2溶液、FeCl3溶液和柠檬酸的质量比为2-5：3-6：1-4：3-5：1-3：2-4。
优选地，防锈添加剂按如下工艺进行制备：将马来海松酸酐、二乙醇胺和氢氧化钾混合均匀，在氮气保护下，升温至150-170℃，保温1-3h，冷却至室温得到防锈添加剂。
优选地，防锈添加剂的制备工艺中，马来海松酸酐、二乙醇胺和氢氧化钾的重量比为1-3：2-5：3-6。
优选地，其原料按重量份包括：蓖麻油22-28份、石油磺酸钠8-12份、烷基酚聚氧乙烯醚3-7份、烷基醇酰胺3.5-4.5份、二烷基二硫代氨基甲酸钼2-4份、二烷基亚磷酸酯3-5份、二壬基聚氧乙烯醚磷酸锌3.5-4.5份、三乙醇胺硼酸酯2-3份、油酸3-4份、二烷基二硫代磷酸1.5-2.5份、硫化物硫脲3-4份、N-酰基氨基酸三乙醇胺2-5份、水溶性抗磨纳米颗粒3.5-4.5份、异噻唑啉酮2-3份、磷酸三丁酯3-5份、防锈添加剂2-3份、水8-10份。
优选地，其原料按重量份包括：蓖麻油25份、石油磺酸钠10份、烷基酚聚氧乙烯醚5份、烷基醇酰胺4份、二烷基二硫代氨基甲酸钼3份、二烷基亚磷酸酯4份、二壬基聚氧乙烯醚磷酸锌4份、三乙醇胺硼酸酯2.5份、油酸3.5份、二烷基二硫代磷酸2份、硫化物硫脲3.5份、N-酰基氨基酸三乙醇胺3.5份、水溶性抗磨纳米颗粒4份、异噻唑啉酮2.5份、磷酸三丁酯4份、防锈添加剂2.5份、水9份。
本发明的一种抗磨防锈金属切削液，其原料包括蓖麻油、石油磺酸钠、烷基酚聚氧乙烯醚、烷基醇酰胺、二烷基二硫代氨基甲酸钼、二烷基亚磷酸酯、二壬基聚氧乙烯醚磷酸锌、三乙醇胺硼酸酯、油酸、二烷基二硫代磷酸、硫化物硫脲、N-酰基氨基酸三乙醇胺、水溶性抗磨纳米颗粒、异噻唑啉酮、磷酸三丁酯、防锈添加剂和水。其中以蓖麻油为油相主料，辅助添加石油磺酸钠、烷基酚聚氧乙烯醚、烷基醇酰胺、二烷基二硫代氨基甲酸钼、二烷基亚磷酸酯、二壬基聚氧乙烯醚磷酸锌、三乙醇胺硼酸酯、油酸、二烷基二硫代磷酸、硫化物硫脲、N-酰基氨基酸三乙醇胺、水溶性抗磨纳米颗粒、异噻唑啉酮、磷酸三丁酯、防锈添加剂和水作为助剂，赋予本发明金属切削液优异的润滑、防锈和防腐抗菌性能。其中水溶性抗磨纳米颗粒以La(NO3)3溶液、NaF溶液、氨水、FeCl2溶液、FeCl3溶液和柠檬酸为原料，以硝酸镧和氟化钠为原料、柠檬酸为修饰剂，利用原位表面修饰法制备了水溶性抗磨纳米颗粒，赋予了本发明金属切削液优异的减摩抗磨性能。防锈添加剂以马来海松酸酐、二乙醇胺和氢氧化钾为原料，制备得到的防锈添加剂含有多个羟基和酰胺基亲水的极性基团，对金属有较大的亲合能力，很容易吸附在金属表面上，改变了双电层的结构，使金属表面的能量状态趋于稳定，增加腐蚀反应的活化能，减缓腐蚀速度；而其非极性基团在金属表面定向排布形成一层疏水性保护层，阻碍与腐蚀反应有关的电荷或物质的转移，也使腐蚀速度减小，从而起到防锈的作用。本发明的金属切削液具有优异的抗磨防锈性能。
具体实施方式
下面结合具体实施例对本发明做出详细说明，应当了解，实施例只用于说明本发明，而不是用于对本发明进行限定，任何在本发明基础上所做的修改、等同替换等均在本发明的保护范围内。
具体实施方式中，蓖麻油的重量份可以为20份、21份、22份、23份、24份、25份、26份、27份、28份、29份、30份；石油磺酸钠的重量份可以为5份、6份、7份、8份、9份、10份、11份、12份、13份、14份、15份；烷基酚聚氧乙烯醚的重量份可以为2份、3份、4份、5份、6份、7份、8份；烷基醇酰胺的重量份可以为3份、3.5份、4份、4.5份、5份；二烷基二硫代氨基甲酸钼的重量份可以为1份、2份、3份、4份、5份；二烷基亚磷酸酯的重量份可以为2份、3份、4份、5份、6份；二壬基聚氧乙烯醚磷酸锌的重量份可以为3份、3.5份、4份、4.5份、5份；三乙醇胺硼酸酯的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份；油酸的重量份可以为2份、2.5份、3份、3.5份、4份、4.5份、5份；二烷基二硫代磷酸的重量份可以为1份、1.5份、2份、2.5份、3份；硫化物硫脲的重量份可以为2份、2.5份、3份、3.5份、4份、4.5份、5份；N-酰基氨基酸三乙醇胺的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份、4.5份、5份、5.5份、6份；水溶性抗磨纳米颗粒的重量份可以为3份、3.5份、4份、4.5份、5份；异噻唑啉酮的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份；磷酸三丁酯的重量份可以为2份、3份、4份、5份、6份；防锈添加剂的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份；水的重量份可以为6份、7份、8份、9份、10份、11份、12份。
实施例1
本发明提出的一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油25份、石油磺酸钠10份、烷基酚聚氧乙烯醚5份、烷基醇酰胺4份、二烷基二硫代氨基甲酸钼3份、二烷基亚磷酸酯4份、二壬基聚氧乙烯醚磷酸锌4份、三乙醇胺硼酸酯2.5份、油酸3.5份、二烷基二硫代磷酸2份、硫化物硫脲3.5份、N-酰基氨基酸三乙醇胺3.5份、水溶性抗磨纳米颗粒4份、异噻唑啉酮2.5份、磷酸三丁酯4份、防锈添加剂2.5份、水9份。
水溶性抗磨纳米颗粒按如下工艺进行制备：按重量份将3.5份La(NO3)3溶液和4.5份NaF溶液混合均匀，于55℃水浴磁力搅拌1.0h，冷却至室温，然后加入2.5份氨水，接着加入4份FeCl2溶液和2份FeCl3溶液混合均匀，搅拌30min，然后加入3份柠檬酸，搅拌1h，洗涤3次，干燥得到水溶性抗磨纳米颗粒。
防锈添加剂按如下工艺进行制备：按重量份将2份马来海松酸酐、3.5份二乙醇胺和4.5份氢氧化钾混合均匀，在氮气保护下，升温至160℃，保温2h，冷却至室温得到防锈添加剂。
实施例2
本发明提出的一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油20份、石油磺酸钠15份、烷基酚聚氧乙烯醚2份、烷基醇酰胺5份、二烷基二硫代氨基甲酸钼1份、二烷基亚磷酸酯6份、二壬基聚氧乙烯醚磷酸锌3份、三乙醇胺硼酸酯4份、油酸2份、二烷基二硫代磷酸3份、硫化物硫脲2份、N-酰基氨基酸三乙醇胺6份、水溶性抗磨纳米颗粒3份、异噻唑啉酮4份、磷酸三丁酯2份、防锈添加剂4份、水6份。
水溶性抗磨纳米颗粒按如下工艺进行制备：按重量份将2份La(NO3)3溶液和6份NaF溶液混合均匀，于50℃水浴磁力搅拌1.5h，冷却至室温，然后加入1份氨水，接着加入5份FeCl2溶液和1份FeCl3溶液混合均匀，搅拌40min，然后加入2份柠檬酸，搅拌1.5h，洗涤2次，干燥得到水溶性抗磨纳米颗粒。
防锈添加剂按如下工艺进行制备：按重量份将1份马来海松酸酐、5份二乙醇胺和3份氢氧化钾混合均匀，在氮气保护下，升温至170℃，保温1h，冷却至室温得到防锈添加剂。
实施例3
本发明提出的一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油30份、石油磺酸钠5份、烷基酚聚氧乙烯醚8份、烷基醇酰胺3份、二烷基二硫代氨基甲酸钼5份、二烷基亚磷酸酯2份、二壬基聚氧乙烯醚磷酸锌5份、三乙醇胺硼酸酯1份、油酸5份、二烷基二硫代磷酸1份、硫化物硫脲5份、N-酰基氨基酸三乙醇胺1份、水溶性抗磨纳米颗粒5份、异噻唑啉酮1份、磷酸三丁酯6份、防锈添加剂1份、水12份。
水溶性抗磨纳米颗粒按如下工艺进行制备：按重量份将5份La(NO3)3溶液和3份NaF溶液混合均匀，于60℃水浴磁力搅拌0.5h，冷却至室温，然后加入4份氨水，接着加入3份FeCl2溶液和3份FeCl3溶液混合均匀，搅拌20min，然后加入4份柠檬酸，搅拌0.5h，洗涤4次，干燥得到水溶性抗磨纳米颗粒。
防锈添加剂按如下工艺进行制备：按重量份将3份马来海松酸酐、2份二乙醇胺和6份氢氧化钾混合均匀，在氮气保护下，升温至150℃，保温3h，冷却至室温得到防锈添加剂。
实施例4
本发明提出的一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油22份、石油磺酸钠12份、烷基酚聚氧乙烯醚3份、烷基醇酰胺4.5份、二烷基二硫代氨基甲酸钼2份、二烷基亚磷酸酯5份、二壬基聚氧乙烯醚磷酸锌3.5份、三乙醇胺硼酸酯3份、油酸3份、二烷基二硫代磷酸2.5份、硫化物硫脲3份、N-酰基氨基酸三乙醇胺5份、水溶性抗磨纳米颗粒3.5份、异噻唑啉酮3份、磷酸三丁酯3份、防锈添加剂3份、水8份。
水溶性抗磨纳米颗粒按如下工艺进行制备：按重量份将3份La(NO3)3溶液和5份NaF溶液混合均匀，于52℃水浴磁力搅拌1.2h，冷却至室温，然后加入2份氨水，接着加入4.5份FeCl2溶液和1.5份FeCl3溶液混合均匀，搅拌35min，然后加入2.5份柠檬酸，搅拌1.2h，洗涤2次，干燥得到水溶性抗磨纳米颗粒。
防锈添加剂按如下工艺进行制备：按重量份将1.5份马来海松酸酐、4份二乙醇胺和4份氢氧化钾混合均匀，在氮气保护下，升温至165℃，保温1.5h，冷却至室温得到防锈添加剂。
实施例5
本发明提出的一种抗磨防锈金属切削液，其原料按重量份包括：蓖麻油28份、石油磺酸钠8份、烷基酚聚氧乙烯醚7份、烷基醇酰胺3.5份、二烷基二硫代氨基甲酸钼4份、二烷基亚磷酸酯3份、二壬基聚氧乙烯醚磷酸锌4.5份、三乙醇胺硼酸酯2份、油酸4份、二烷基二硫代磷酸1.5份、硫化物硫脲4份、N-酰基氨基酸三乙醇胺2份、水溶性抗磨纳米颗粒4.5份、异噻唑啉酮2份、磷酸三丁酯5份、防锈添加剂2份、水10份。
水溶性抗磨纳米颗粒按如下工艺进行制备：按重量份将4份La(NO3)3溶液和4份NaF溶液混合均匀，于58℃水浴磁力搅拌0.8h，冷却至室温，然后加入3份氨水，接着加入3.5份FeCl2溶液和2.5份FeCl3溶液混合均匀，搅拌25min，然后加入3.5份柠檬酸，搅拌0.8h，洗涤4次，干燥得到水溶性抗磨纳米颗粒。
防锈添加剂按如下工艺进行制备：按重量份将2.5份马来海松酸酐、3份二乙醇胺和5份氢氧化钾混合均匀，在氮气保护下，升温至155℃，保温2.5h，冷却至室温得到防锈添加剂。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种抗磨防锈金属切削液，其特征在于，其原料按重量份包括：蓖麻油20-30份、石油磺酸钠5-15份、烷基酚聚氧乙烯醚2-8份、烷基醇酰胺3-5份、二烷基二硫代氨基甲酸钼1-5份、二烷基亚磷酸酯2-6份、二壬基聚氧乙烯醚磷酸锌3-5份、三乙醇胺硼酸酯1-4份、油酸2-5份、二烷基二硫代磷酸1-3份、硫化物硫脲2-5份、N-酰基氨基酸三乙醇胺1-6份、水溶性抗磨纳米颗粒3-5份、异噻唑啉酮1-4份、磷酸三丁酯2-6份、防锈添加剂1-4份、水6-12份。
2.根据权利要求1所述的抗磨防锈金属切削液，其特征在于，水溶性抗磨纳米颗粒按如下工艺进行制备：将La(NO3)3溶液和NaF溶液混合均匀，于50-60℃水浴磁力搅拌0.5-1.5h，冷却至室温，然后加入氨水，接着加入FeCl2溶液和FeCl3溶液混合均匀，搅拌20-40min，然后加入柠檬酸，搅拌0.5-1.5h，洗涤2-4次，干燥得到水溶性抗磨纳米颗粒。
3.根据权利要求1或2所述的抗磨防锈金属切削液，其特征在于，水溶性抗磨纳米颗粒的制备工艺中，La(NO3)3溶液、NaF溶液、氨水、FeCl2溶液、FeCl3溶液和柠檬酸的质量比为2-5：3-6：1-4：3-5：1-3：2-4。
4.根据权利要求1-3任一项所述的抗磨防锈金属切削液，其特征在于，防锈添加剂按如下工艺进行制备：将马来海松酸酐、二乙醇胺和氢氧化钾混合均匀，在氮气保护下，升温至150-170℃，保温1-3h，冷却至室温得到防锈添加剂。
5.根据权利要求1-4任一项所述的抗磨防锈金属切削液，其特征在于，防锈添加剂的制备工艺中，马来海松酸酐、二乙醇胺和氢氧化钾的重量比为1-3：2-5：3-6。
6.根据权利要求1-5任一项所述的抗磨防锈金属切削液，其特征在于，其原料按重量份包括：蓖麻油22-28份、石油磺酸钠8-12份、烷基酚聚氧乙烯醚3-7份、烷基醇酰胺3.5-4.5份、二烷基二硫代氨基甲酸钼2-4份、二烷基亚磷酸酯3-5份、二壬基聚氧乙烯醚磷酸锌3.5-4.5份、三乙醇胺硼酸酯2-3份、油酸3-4份、二烷基二硫代磷酸1.5-2.5份、硫化物硫脲3-4份、N-酰基氨基酸三乙醇胺2-5份、水溶性抗磨纳米颗粒3.5-4.5份、异噻唑啉酮2-3份、磷酸三丁酯3-5份、防锈添加剂2-3份、水8-10份。
7.根据权利要求1-6任一项所述的抗磨防锈金属切削液，其特征在于，其原料按重量份包括：蓖麻油25份、石油磺酸钠10份、烷基酚聚氧乙烯醚5份、烷基醇酰胺4份、二烷基二硫代氨基甲酸钼3份、二烷基亚磷酸酯4份、二壬基聚氧乙烯醚磷酸锌4份、三乙醇胺硼酸酯2.5份、油酸3.5份、二烷基二硫代磷酸2份、硫化物硫脲3.5份、N-酰基氨基酸三乙醇胺3.5份、水溶性抗磨纳米颗粒4份、异噻唑啉酮2.5份、磷酸三丁酯4份、防锈添加剂2.5份、水9份。
CN201610549119.3A 2016-07-13 2016-07-13 一种抗磨防锈金属切削液 Withdrawn CN106244291A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610549119.3A CN106244291A (zh) 2016-07-13 2016-07-13 一种抗磨防锈金属切削液

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610549119.3A CN106244291A (zh) 2016-07-13 2016-07-13 一种抗磨防锈金属切削液

Publications (1)

Publication Number Publication Date
CN106244291A true CN106244291A (zh) 2016-12-21

Family

ID=57613854

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610549119.3A Withdrawn CN106244291A (zh) 2016-07-13 2016-07-13 一种抗磨防锈金属切削液

Country Status (1)

Country Link
CN (1) CN106244291A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142138A (zh) * 2017-04-06 2017-09-08 天长市润达金属防锈助剂有限公司 一种防锈改性金属切削液
CN108753417A (zh) * 2018-07-02 2018-11-06 嘉兴市国龙石油化工有限公司 一种多功能铝用金属加工液及其制备方法
CN111205916A (zh) * 2020-03-11 2020-05-29 中轻日化科技有限公司 一种环保型水基金属切削液及其制备方法
CN111876226A (zh) * 2020-07-21 2020-11-03 嘉斐科技(武汉)股份有限公司 一种水溶性冲压拉伸润滑剂及其制备方法
CN113862065A (zh) * 2021-10-14 2021-12-31 广州市车优汽车用品有限公司 一种汽车用润滑油组合物及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164283A (zh) * 2014-08-19 2014-11-26 清华大学 微乳金属切削液
CN105330562A (zh) * 2015-12-09 2016-02-17 九江天赐高新材料有限公司 一种脂肪酰基氨基酸三乙醇胺盐的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164283A (zh) * 2014-08-19 2014-11-26 清华大学 微乳金属切削液
CN105330562A (zh) * 2015-12-09 2016-02-17 九江天赐高新材料有限公司 一种脂肪酰基氨基酸三乙醇胺盐的制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张杰: ""水溶性三氟化镧及其复合纳米微粒的制备和摩擦学行为研究"", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *
王慧媛: ""新型防锈剂马来海松酸醇酰胺的制备及其应用研究"", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142138A (zh) * 2017-04-06 2017-09-08 天长市润达金属防锈助剂有限公司 一种防锈改性金属切削液
CN108753417A (zh) * 2018-07-02 2018-11-06 嘉兴市国龙石油化工有限公司 一种多功能铝用金属加工液及其制备方法
CN111205916A (zh) * 2020-03-11 2020-05-29 中轻日化科技有限公司 一种环保型水基金属切削液及其制备方法
CN111876226A (zh) * 2020-07-21 2020-11-03 嘉斐科技(武汉)股份有限公司 一种水溶性冲压拉伸润滑剂及其制备方法
CN113862065A (zh) * 2021-10-14 2021-12-31 广州市车优汽车用品有限公司 一种汽车用润滑油组合物及其制备方法
CN113862065B (zh) * 2021-10-14 2022-06-21 广州市车优汽车用品有限公司 一种汽车用润滑油组合物及其制备方法

Similar Documents

Publication Publication Date Title
CN106244291A (zh) 一种抗磨防锈金属切削液
CN101921653B (zh) 一种合成高温润滑脂及其制备方法
CN102533418B (zh) 环保型微乳切削液
CN102757852B (zh) 轧制润滑剂组合物及其用途
CN104031732B (zh) 油水气三相微量润滑系统专用微量润滑剂及其制备方法
CN103113970B (zh) 一种水溶性准干切削液及其制备方法和用途
CN105368410A (zh) 钻井液用润滑剂
CN102719306A (zh) 绿色微乳型金属切削液及其制备方法
CN103468354B (zh) 一种防锈切削液及其制备方法
CN104450130A (zh) 金属切削液及其制备方法
CN106459823A (zh) 水溶性金属加工油和金属加工用冷却剂
CN102994194B (zh) 一种合成多效润滑添加剂及其制备方法
CN106244295A (zh) 一种极压润滑性金属切削液
CN102559351B (zh) 一种汽车子午线轮胎钢帘线湿拉润滑剂
CN108913311A (zh) 柴油发动机的润滑油组合物
CN106190478A (zh) 一种安全防锈防腐金属切削液
CN104120009A (zh) 一种适用于多种金属的水性切削液及其制备方法
CN106244296A (zh) 一种具有优异防锈性能的金属切削液
CN104403769A (zh) 一种多功能切削液及其制备方法
CN104073324B (zh) 一种防锈抗磨极压乳化油
CN107418673A (zh) 一种基于聚异丁烯基琥珀酸酐的新型乳化体系的切削液及其制备方法和应用
CN106190480A (zh) 一种高润滑性能的防锈金属切削液
CN104531307A (zh) 一种切削液及制备方法
CN104120017A (zh) 一种渗透力强防锈性能好的水基切削液及其制备方法
CN106190481A (zh) 一种具有优异抗磨极压性能的镁铝合金切削液

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20161221

WW01 Invention patent application withdrawn after publication