CN106190478A - 一种安全防锈防腐金属切削液 - Google Patents

一种安全防锈防腐金属切削液 Download PDF

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CN106190478A
CN106190478A CN201610549693.9A CN201610549693A CN106190478A CN 106190478 A CN106190478 A CN 106190478A CN 201610549693 A CN201610549693 A CN 201610549693A CN 106190478 A CN106190478 A CN 106190478A
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parts
boric acid
antirust
safe
metalworking fluid
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林伟
江海涛
江海波
江浩
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Tianchang Runda Metal Antirust Auxiliary Co Ltd
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Abstract

本发明公开了一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油20‑40份、有机硼酸酯5‑15份、脂肪酸咪唑啉硼酸单酯2‑6份、含硫硼酸酯1‑4份、丙三醇聚氧乙烯醚3‑5份、季铵盐1‑6份、聚丙烯酸钠2‑5份、煤油1‑4份、钼酸钠1‑4份、三乙醇胺2‑8份、复合硼酸酯防锈剂1‑5份、极压抗磨添加剂2‑5份、水3‑9份、苯甲酸钠4‑6份。本发明的金属切削液成份安全，无污染，具有优异的防锈防腐性能。

Description

一种安全防锈防腐金属切削液
技术领域
本发明涉及一种金属切削液，尤其涉及一种安全防锈防腐金属切削液。
背景技术
切削液是一种用在金属切、削、磨加工过程中，用来冷却和润滑刀具和加工件的工业用液体。机械加工中大量使用金属切削液，一般要求其具有润滑、冷却、清洗和防锈作用。常用切削液可分为三类：切削油、乳化液和防绣切削水。油基切削液使用油料量大，浪费油料资源，并造成环境污染；而乳化切削液通过加人水制成乳化液来降低油的使用量，减少污染，降低成本。
现有技术中金属切削液的安全性，防锈性能和防腐性能无法满足实际使用过程中的需求，因此亟需开发一种安全防锈防腐金属切削液来解决现有技术中的问题。
发明内容
为解决背景技术中存在的技术问题，本发明提出一种安全防锈防腐金属切削液，成份安全，无污染，具有优异的防锈防腐性能。
本发明提出的一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油20-40份、有机硼酸酯5-15份、脂肪酸咪唑啉硼酸单酯2-6份、含硫硼酸酯1-4份、丙三醇聚氧乙烯醚3-5份、季铵盐1-6份、聚丙烯酸钠2-5份、煤油1-4份、钼酸钠1-4份、三乙醇胺2-8份、复合硼酸酯防锈剂1-5份、极压抗磨添加剂2-5份、水3-9份、苯甲酸钠4-6份。
优选地，极压抗磨添加剂按如下工艺进行制备：将月桂酸、三氧化铝、N-羟乙基乙二胺和甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至130-150℃，保温2-4h，然后升温至160-180℃，保温4-5h，然后降温至70-90℃，减压蒸馏静置得到物料a，然后向物料a中加入正丁醇、硼酸粉末和超细二氧化硅，通入氮气在氮气的保护下，升温至180-220℃，保温2-5h，减压蒸馏冷却至室温得到极压抗磨添加剂。
优选地，极压抗磨添加剂的制备工艺中，月桂酸、三氧化铝、N-羟乙基乙二胺、甲苯、正丁醇、硼酸粉末和超细二氧化硅的重量比为2-5：3-6：1-3：2-5；1-4：5-15：2-8。
优选地，复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比1-5：2-5：3-6混合而成。
优选地，蓖麻油、有机硼酸酯、脂肪酸咪唑啉硼酸单酯、含硫硼酸酯和丙三醇聚氧乙烯醚的重量比为25-35：8-12：3-5：2-3：3.5-4.5。
优选地，其原料按重量份包括：蓖麻油25-35份、有机硼酸酯8-12份、脂肪酸咪唑啉硼酸单酯3-5份、含硫硼酸酯2-3份、丙三醇聚氧乙烯醚3.5-4.5份、季铵盐2-5份、聚丙烯酸钠3-4份、煤油2-3份、钼酸钠2-3份、三乙醇胺3-7份、复合硼酸酯防锈剂2-4份、极压抗磨添加剂3-4份、水4-8份、苯甲酸钠4.5-5.5份。
优选地，其原料按重量份包括：蓖麻油30份、有机硼酸酯10份、脂肪酸咪唑啉硼酸单酯4份、含硫硼酸酯2.5份、丙三醇聚氧乙烯醚4份、季铵盐3.5份、聚丙烯酸钠3.5份、煤油2.5份、钼酸钠2.5份、三乙醇胺5份、复合硼酸酯防锈剂3份、极压抗磨添加剂3.5份、水6份、苯甲酸钠5份。
本发明的一种安全防锈防腐金属切削液，其原料包括蓖麻油、有机硼酸酯、脂肪酸咪唑啉硼酸单酯、含硫硼酸酯、丙三醇聚氧乙烯醚、季铵盐、聚丙烯酸钠、煤油、钼酸钠、三乙醇胺、复合硼酸酯防锈剂、极压抗磨添加剂、水和苯甲酸钠。其中以蓖麻油和煤油为油相基料，赋予本发明金属切削液优异的润滑性能，并配合上有机硼酸酯、脂肪酸咪唑啉硼酸单酯、含硫硼酸酯、丙三醇聚氧乙烯醚、季铵盐、聚丙烯酸钠、钼酸钠、三乙醇胺、水和苯甲酸钠作为助剂，进一步提高了本发明金属切削液的润滑和抗磨性能的同时，也提高了本发明金属切削液的防腐和杀菌性能，提高了本发明金属切削液的综合性能；其中复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按一定比例混合而成，油膜强度高，摩擦系数低，具有良好的减摩抗磨性能，环保无污染。其中极压抗磨添加剂以月桂酸、三氧化铝、N-羟乙基乙二胺、甲苯、正丁醇、硼酸粉末和超细二氧化硅为原料，制备得到的挤压抗磨添加剂有效提高了本发明金属切削液的润滑抗磨性能。本发明的金属切削液成份安全，无污染，具有优异的防锈防腐性能。
具体实施方式
下面结合具体实施例对本发明做出详细说明，应当了解，实施例只用于说明本发明，而不是用于对本发明进行限定，任何在本发明基础上所做的修改、等同替换等均在本发明的保护范围内。
具体实施方式中，蓖麻油的重量份可以为20份、21份、22份、23份、24份、25份、26份、27份、28份、29份、30份、31份、32份、33份、34份、35份、36份、37份、38份、39份、40份；有机硼酸酯的重量份可以为5份、6份、7份、8份、9份、10份、11份、12份、13份、14份、15份；脂肪酸咪唑啉硼酸单酯的重量份可以为2份、3份、4份、5份、6份；含硫硼酸酯的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份；丙三醇聚氧乙烯醚的重量份可以为3份、3.5份、4份、4.5份、5份；季铵盐的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份、4.5份、5份、5.5份、6份；聚丙烯酸钠的重量份可以为2份、2.5份、3份、3.5份、4份、4.5份、5份；煤油的重量份可以为1份、1.5份、2份、3份、3.5份、4份；钼酸钠的重量份可以为1份、1.5份、2份、2.5份、3份、3.5份、4份；三乙醇胺的重量份可以为2份、3份、4份、5份、6份、7份、8份；复合硼酸酯防锈剂的重量份可以为1份、2份、3份、4份、5份；极压抗磨添加剂的重量份可以为2份、2.5份、3份、3.5份、4份、4.5份、5份；水的重量份可以为3份、4份、5份、6份、7份、8份、9份；苯甲酸钠的重量份可以为4份、4.5份、5份、5.5份、6份。
实施例1
本发明提出的一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油30份、有机硼酸酯10份、脂肪酸咪唑啉硼酸单酯4份、含硫硼酸酯2.5份、丙三醇聚氧乙烯醚4份、季铵盐3.5份、聚丙烯酸钠3.5份、煤油2.5份、钼酸钠2.5份、三乙醇胺5份、复合硼酸酯防锈剂3份、极压抗磨添加剂3.5份、水6份、苯甲酸钠5份。
极压抗磨添加剂按如下工艺进行制备：按重量份将3.5份月桂酸、4.5份三氧化铝、2份N-羟乙基乙二胺和3.5份甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至140℃，保温3h，然后升温至170℃，保温4.5h，然后降温至80℃，减压蒸馏静置得到物料a，然后向物料a中加入2.5份正丁醇、10份硼酸粉末和5份超细二氧化硅，通入氮气在氮气的保护下，升温至200℃，保温3.5h，减压蒸馏冷却至室温得到极压抗磨添加剂。
复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比3：3.5：4.5混合而成。
实施例2
本发明提出的一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油20份、有机硼酸酯15份、脂肪酸咪唑啉硼酸单酯2份、含硫硼酸酯4份、丙三醇聚氧乙烯醚3份、季铵盐6份、聚丙烯酸钠2份、煤油4份、钼酸钠1份、三乙醇胺8份、复合硼酸酯防锈剂1份、极压抗磨添加剂5份、水3份、苯甲酸钠6份。
极压抗磨添加剂按如下工艺进行制备：按重量份将2份月桂酸、6份三氧化铝、1份N-羟乙基乙二胺和5份甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至130℃，保温4h，然后升温至160℃，保温5h，然后降温至70℃，减压蒸馏静置得到物料a，然后向物料a中加入4份正丁醇、5份硼酸粉末和8份超细二氧化硅，通入氮气在氮气的保护下，升温至180℃，保温5h，减压蒸馏冷却至室温得到极压抗磨添加剂。
复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比1：5：3混合而成。
实施例3
本发明提出的一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油40份、有机硼酸酯5份、脂肪酸咪唑啉硼酸单酯6份、含硫硼酸酯1份、丙三醇聚氧乙烯醚5份、季铵盐1份、聚丙烯酸钠5份、煤油1份、钼酸钠4份、三乙醇胺2份、复合硼酸酯防锈剂5份、极压抗磨添加剂2份、水9份、苯甲酸钠4份。
极压抗磨添加剂按如下工艺进行制备：按重量份将5份月桂酸、3份三氧化铝、3份N-羟乙基乙二胺和2份甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至150℃，保温2h，然后升温至180℃，保温4h，然后降温至90℃，减压蒸馏静置得到物料a，然后向物料a中加入1份正丁醇、15份硼酸粉末和2份超细二氧化硅，通入氮气在氮气的保护下，升温至220℃，保温2h，减压蒸馏冷却至室温得到极压抗磨添加剂。
复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比5：2：6混合而成。
实施例4
本发明提出的一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油25份、有机硼酸酯12份、脂肪酸咪唑啉硼酸单酯3份、含硫硼酸酯3份、丙三醇聚氧乙烯醚3.5份、季铵盐5份、聚丙烯酸钠3份、煤油3份、钼酸钠2份、三乙醇胺7份、复合硼酸酯防锈剂2份、极压抗磨添加剂4份、水4份、苯甲酸钠5.5份。
极压抗磨添加剂按如下工艺进行制备：按重量份将3份月桂酸、5份三氧化铝、1.5份N-羟乙基乙二胺和4份甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至135℃，保温3.5h，然后升温至165℃，保温5h，然后降温至75℃，减压蒸馏静置得到物料a，然后向物料a中加入3份正丁醇、8份硼酸粉末和3-7份超细二氧化硅，通入氮气在氮气的保护下，升温至215℃，保温3h，减压蒸馏冷却至室温得到极压抗磨添加剂。
复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比2：4：4混合而成。
实施例5
本发明提出的一种安全防锈防腐金属切削液，其原料按重量份包括：蓖麻油35份、有机硼酸酯8份、脂肪酸咪唑啉硼酸单酯5份、含硫硼酸酯2份、丙三醇聚氧乙烯醚4.5份、季铵盐2份、聚丙烯酸钠4份、煤油2份、钼酸钠3份、三乙醇胺3份、复合硼酸酯防锈剂4份、极压抗磨添加剂3份、水8份、苯甲酸钠4.5份。
极压抗磨添加剂按如下工艺进行制备：按重量份将4份月桂酸、4份三氧化铝、2.5份N-羟乙基乙二胺和3份甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至145℃，保温2.5h，然后升温至175℃，保温4h，然后降温至85℃，减压蒸馏静置得到物料a，然后向物料a中加入2份正丁醇、12份硼酸粉末和3份超细二氧化硅，通入氮气在氮气的保护下，升温至215℃，保温3h，减压蒸馏冷却至室温得到极压抗磨添加剂。
复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比4：3：5混合而成。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种安全防锈防腐金属切削液，其特征在于，其原料按重量份包括：蓖麻油20-40份、有机硼酸酯5-15份、脂肪酸咪唑啉硼酸单酯2-6份、含硫硼酸酯1-4份、丙三醇聚氧乙烯醚3-5份、季铵盐1-6份、聚丙烯酸钠2-5份、煤油1-4份、钼酸钠1-4份、三乙醇胺2-8份、复合硼酸酯防锈剂1-5份、极压抗磨添加剂2-5份、水3-9份、苯甲酸钠4-6份。
2.根据权利要求1所述的安全防锈防腐金属切削液，其特征在于，极压抗磨添加剂按如下工艺进行制备：将月桂酸、三氧化铝、N-羟乙基乙二胺和甲苯混合均匀，然后通入氮气，在氮气的作用下，升温至130-150℃，保温2-4h，然后升温至160-180℃，保温4-5h，然后降温至70-90℃，减压蒸馏静置得到物料a，然后向物料a中加入正丁醇、硼酸粉末和超细二氧化硅，通入氮气在氮气的保护下，升温至180-220℃，保温2-5h，减压蒸馏冷却至室温得到极压抗磨添加剂。
3.根据权利要求1或2所述的安全防锈防腐金属切削液，其特征在于，极压抗磨添加剂的制备工艺中，月桂酸、三氧化铝、N-羟乙基乙二胺、甲苯、正丁醇、硼酸粉末和超细二氧化硅的重量比为2-5：3-6：1-3：2-5；1-4：5-15：2-8。
4.根据权利要求1-3任一项所述的安全防锈防腐金属切削液，其特征在于，复合硼酸酯防锈剂由硼酸二乙醇胺酯、二元羧酸和有机醇胺按重量比1-5：2-5：3-6混合而成。
5.根据权利要求1-4任一项所述的安全防锈防腐金属切削液，其特征在于，蓖麻油、有机硼酸酯、脂肪酸咪唑啉硼酸单酯、含硫硼酸酯和丙三醇聚氧乙烯醚的重量比为25-35：8-12：3-5：2-3：3.5-4.5。
6.根据权利要求1-5任一项所述的安全防锈防腐金属切削液，其特征在于，其原料按重量份包括：蓖麻油25-35份、有机硼酸酯8-12份、脂肪酸咪唑啉硼酸单酯3-5份、含硫硼酸酯2-3份、丙三醇聚氧乙烯醚3.5-4.5份、季铵盐2-5份、聚丙烯酸钠3-4份、煤油2-3份、钼酸钠2-3份、三乙醇胺3-7份、复合硼酸酯防锈剂2-4份、极压抗磨添加剂3-4份、水4-8份、苯甲酸钠4.5-5.5份。
7.根据权利要求1-6任一项所述的安全防锈防腐金属切削液，其特征在于，其原料按重量份包括：蓖麻油30份、有机硼酸酯10份、脂肪酸咪唑啉硼酸单酯4份、含硫硼酸酯2.5份、丙三醇聚氧乙烯醚4份、季铵盐3.5份、聚丙烯酸钠3.5份、煤油2.5份、钼酸钠2.5份、三乙醇胺5份、复合硼酸酯防锈剂3份、极压抗磨添加剂3.5份、水6份、苯甲酸钠5份。
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057808A (zh) * 2017-04-06 2017-08-18 天长市润达金属防锈助剂有限公司 一种具有优异润滑性的金属切削液
CN107142138A (zh) * 2017-04-06 2017-09-08 天长市润达金属防锈助剂有限公司 一种防锈改性金属切削液
CN107164030A (zh) * 2017-04-06 2017-09-15 天长市润达金属防锈助剂有限公司 一种具有优异防腐性能的改性金属切削液
CN107254342A (zh) * 2017-04-21 2017-10-17 天长市润达金属防锈助剂有限公司 一种具有优异渗透性能的防锈金属切削液
CN108774600A (zh) * 2018-07-24 2018-11-09 山东威高药业股份有限公司 一种内镜清洗保湿剂及其制备方法
CN109652810A (zh) * 2019-02-28 2019-04-19 苏州纳孚林科金属表面技术有限公司 一种硼硫酸酯除锈剂

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102703196A (zh) * 2012-05-31 2012-10-03 天长市润达金属防锈助剂有限公司 一种环保水基金属切削液
CN102703194A (zh) * 2012-05-28 2012-10-03 上海福岛化工科技发展有限公司 铝镁合金切削液
CN104164283A (zh) * 2014-08-19 2014-11-26 清华大学 微乳金属切削液
CN104293471A (zh) * 2014-09-25 2015-01-21 巢湖广丰金属制品有限公司 一种环保型水基合成金属切削液
CN104877735A (zh) * 2015-05-11 2015-09-02 青岛保利康新材料有限公司 一种冷却性有色金属切削液
CN105695050A (zh) * 2014-11-28 2016-06-22 郭亚萍 一种金属切削液

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102703194A (zh) * 2012-05-28 2012-10-03 上海福岛化工科技发展有限公司 铝镁合金切削液
CN102703196A (zh) * 2012-05-31 2012-10-03 天长市润达金属防锈助剂有限公司 一种环保水基金属切削液
CN104164283A (zh) * 2014-08-19 2014-11-26 清华大学 微乳金属切削液
CN104293471A (zh) * 2014-09-25 2015-01-21 巢湖广丰金属制品有限公司 一种环保型水基合成金属切削液
CN105695050A (zh) * 2014-11-28 2016-06-22 郭亚萍 一种金属切削液
CN104877735A (zh) * 2015-05-11 2015-09-02 青岛保利康新材料有限公司 一种冷却性有色金属切削液

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
卢向阳: "含氮硼酸酯极压抗磨添加剂的合成及应用", 《中国优秀硕士学位论文全文数据库工程科技I辑》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057808A (zh) * 2017-04-06 2017-08-18 天长市润达金属防锈助剂有限公司 一种具有优异润滑性的金属切削液
CN107142138A (zh) * 2017-04-06 2017-09-08 天长市润达金属防锈助剂有限公司 一种防锈改性金属切削液
CN107164030A (zh) * 2017-04-06 2017-09-15 天长市润达金属防锈助剂有限公司 一种具有优异防腐性能的改性金属切削液
CN107254342A (zh) * 2017-04-21 2017-10-17 天长市润达金属防锈助剂有限公司 一种具有优异渗透性能的防锈金属切削液
CN108774600A (zh) * 2018-07-24 2018-11-09 山东威高药业股份有限公司 一种内镜清洗保湿剂及其制备方法
CN109652810A (zh) * 2019-02-28 2019-04-19 苏州纳孚林科金属表面技术有限公司 一种硼硫酸酯除锈剂

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