CN106243806A - A kind of water proof anti-soil protection spray and preparation method thereof - Google Patents
A kind of water proof anti-soil protection spray and preparation method thereof Download PDFInfo
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- CN106243806A CN106243806A CN201610627738.XA CN201610627738A CN106243806A CN 106243806 A CN106243806 A CN 106243806A CN 201610627738 A CN201610627738 A CN 201610627738A CN 106243806 A CN106243806 A CN 106243806A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of water proof anti-soil protection spray and preparation method thereof, relates to a kind of mixture compound.Include following components by mass percentage: ptfe micropowder 10% 15%, fatty alcohol-polyoxyethylene ether 5% 10%, glycolic acid 20% 25%, copper oleate 10% 15%, polyvinyl butyral resin 10% 15%, 1-propenol-3 20% 25%, non-ion fluorin carbon surface active agent 3% 5%, LPG propellant 10% 15%.The water proof anti-soil protection spray of the present invention after spray coating, has the excellent properties such as good Folium Nelumbinis double hydrophobicity, self-cleaning, hydrophobicity, water proofing property, resistance to soiling, scrub resistances.
Description
Technical field
The present invention relates to a kind of mixture compound, be specially a kind of water proof anti-soil protection spray and preparation method thereof.
Background technology
Water proof anti-soil protection spray is the aqueous dispersion of a kind of mixture compound, and it is a kind of special to be formed after film forming
Water-resistant structure (change contact angle), makes body surface have extremely strong hydrophobic, hydrophobic, water resistance.Water proof anti-soil is protected at present
Protecting spray kind more, generally silicone emulsion, it joins in emulsion paint as additive, has addition certain
Requirement, is affected if measuring effect at least, can affect painting quality at most if measured, and price is higher, is not suitable for
Some low-grade materials use.Ludox environmental protection, cheap is easy to get, and surface can be played hydrophobic after organic-silicon-modified
Effect, Recent study is enlivened.But, modified Ludox character is unstable, and hydrophobic effect is the most unsatisfactory.Therefore it is badly in need of
A kind of water proof anti-soil cheap, that range is wide protects spray.
Summary of the invention
It is an object of the invention to provide a kind of cheap, waterproof, hydrophobic performance is superior, widely used one is waterproof anti-
Dirty protection spray.
It is a further object of the present invention to provide the preparation method of this water proof anti-soil a kind of protection spray.
The technical scheme realizing above-mentioned purpose is: a kind of water proof anti-soil protection spray, includes following group by mass percentage
Point: ptfe micropowder 10%-15%, fatty alcohol-polyoxyethylene ether 5%-10%, glycolic acid 20%-25%, copper oleate 10%-
15%, polyvinyl butyral resin 10%-15%, 1-propenol-3 20%-25%, non-ion fluorin carbon surface active agent 3%-5%, LPG propellant
10%-15%。
Further, No. CAS of described ptfe micropowder is: 9002-84-0, point
Minor: (C2F4)n；Ptfe micropowder has the features such as effective fiber length, intensity is high, plasticity is big, calenderability is good,
The compatibility of water proof anti-soil protection spray plays preferable film forming protective effect, additionally it is possible to form special water-resistant structure.
Further, No. CAS of described fatty alcohol-polyoxyethylene ether is: 68131-39-5, molecular formula: C12H25O.
(C2H4O)n；In the molecule of fatty alcohol-polyoxyethylene ether, ethyoxyl number artificially can adjust during synthesis, therefore can prepare
A series of different performances and the nonionic surfactant of purposes.Ether is a most important class nonionic surfactant, molecule
In ehter bond be difficult to be destroyed by acid, alkali, so stability is higher, water solublity is preferable, electrolyte-resistant, it is easy to biodegradation, foam
Little.
Further, No. CAS of described glycolic acid is: 79-14-1, molecular formula be: C2H4O3；Glycolic acid may be used for dye
The crosslinking couplant of whole wool fiber and cellulose fabric or the crosslinking catalyst containing carboxylated fiber fabric;Also can be used as bonding
The dispensing of agent, petroleum demulsifier, welding compound and coating and synthesize multiple chemical assistant etc..
Further, No. CAS of described copper oleate is: 1120-44-1, molecular formula be: C36H66CuO4；Copper oleate molecule
Measure the least, be mainly used in increasing the soil resistance dissolving film forming in the compatibility of water proof anti-soil protection spray.
Further, No. CAS of described polyvinyl butyral resin is: 63148-65-2, molecular formula: C16H28O5；It is one
Planting thermal plasticity high polymer, hydroscopicity is less than 4%, and against weather is strong；There is superior resistance to water, adhesion inhibiting properties and mobility,
As the protective material of protective coating in the compatibility of water proof anti-soil protection spray.
Further, No. CAS of described 1-propenol-3 is: 107-18-6, molecular formula: C3H6O；1-propenol-3 is as water proof anti-soil
One of raw material of protection spray, Main Function is: make spray form hydrophobic protecting film, with the performance that it is superior, to waterproof layer shape
Become huge protective effect.
Further, No. CAS of described LPG propellant is: 157621-61-9, molecular formula: C2H6O；LPG propellant is often
Pressure boiling point is less than room temperature, and vapour pressure is high, and when the valve of packing container is opened, pressure can reduce suddenly, and the liquid of the inside is former
Material drastically gasifies with propellant, by means of the pressure of propellant by the mixing raw material in packing container with vaporific ejection.
LPG propellant protects one of raw material of spray as water proof anti-soil, is injection power resources, the most also has dilute
Release the purposes of solvent.
Non-ion fluorin carbon surface active agent is the primary raw material of water proof anti-soil protection spray, and its nonpolar base component is
Hydrocarbon chain, easily with combination, polar portion is polyoxyethylene chain, easily produces row with water hydrogen chain and dredges；Non-ion fluorin carbon surface active
Agent is the Main Ingredients and Appearance of water proof anti-soil protection spray, and surface hydrophobicity film forming is formed and plays decision important function, fluorine carbon table by it
Face activating agent is most important kind in special surfactant, refers to that the hydrogen atom in the hydrocarbon chain of hc-surfactant is whole
Or part is replaced by fluorine atoms, i.e. fluorocarbon chain instead of hydrocarbon chain, and therefore the nonpolar group in surfactant is the most hydrophobic
Character and the performance of unique oleophobic.
The preparation method of above-mentioned water proof anti-soil protection spray, it is characterised in that: comprise the technical steps that:
1) in first ptfe micropowder and fatty alcohol-polyoxyethylene ether being injected agitator by corresponding proportioning and fully mix thoroughly；
2) add glycolic acid by corresponding proportioning again, and stir；
3) it is sequentially added into copper oleate, polyvinyl butyral resin, 1-propenol-3, non-ion fluorin carbon surface active agent four by corresponding proportioning again
Planting raw material, four kinds of raw materials in adding procedure, are both needed to be stirred simultaneously, after four kinds of raw materials have added, are both needed to stir,
Finally obtain spray feed liquid；
4) spray feed liquid is filled in aerosol container bottle；
5) in the aerosol container bottle installing spray feed liquid, fill LPG propellant by corresponding proportioning, i.e. make a kind of water proof anti-soil
Protection spray.
Further, step 1)-5) be both needed in the indoor of aeration-drying, temperature is to carry out in 20 DEG C of-28 DEG C of environment.
Further, also on aerosol container bottle, spray valve is installed additional between step 4) and step 5).
Further, described aerosol container bottle is made with tinplate for material, is resistant to amounts of pressurized gaseous 15Mpa.
Beneficial effects of the present invention:
1, the water proof anti-soil protection spray penetration of the present invention is extremely strong, acts on leather and textile fiber, makes leather and weaving
Product are the most affine with water, produce lotus leaf effect；Can effectively Water-proof and oil-proof, dust-proof, antifouling and Anti-fade.As in new leather and weaving
Product use before spraying, leather and textile service life can be extended, keep attractive in appearance, better.
2, the water proof anti-soil protection spray of the present invention can also add in coating, can be formed a kind of special at coating film formation surface
Different water-resistant structure (change contact angle), makes coating surface have extremely strong hydrophobic, hydrophobic, waterproof effect.Do not affect film simultaneously
Breathability;Both avoid the recoatability difficulty of organic silicon hydrophobic material, it also avoid the situation of other water-repelling agent poor air permeability.
3, the water proof anti-soil protection spray of the present invention after spray coating, has good Folium Nelumbinis double hydrophobicity, self-cleaning, hydrophobic
The excellent properties such as property, water proofing property, resistance to soiling, scrub resistance.
4, the water proof anti-soil protection spray of the present invention has the characteristic of Environmental Safety, and applied widely.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to
Limit the present invention.
Embodiment 1
A kind of water proof anti-soil protection spray, includes following components by mass percentage: ptfe micropowder 10%, poly alkyl alcohol
Oxygen vinyl Ether 10% glycolic acid 20%, copper oleate 10%, polyvinyl butyral resin 15%, 1-propenol-3 22%, non-ion fluorin carbon surface are lived
Property agent 3%, LPG propellant 10%.
Embodiment 2
A kind of water proof anti-soil protection spray, includes following components by mass percentage: ptfe micropowder 15%, poly alkyl alcohol
Oxygen vinyl Ether 5%, glycolic acid 25%, copper oleate 10%, polyvinyl butyral resin 10%, 1-propenol-3 20%, non-ion fluorin carbon surface are lived
Property agent 5%, LPG propellant 10%.
Embodiment 3
A kind of water proof anti-soil protection spray, includes following components by mass percentage: ptfe micropowder 10%, poly alkyl alcohol
Oxygen vinyl Ether 5% glycolic acid 20%, copper oleate 15%, polyvinyl butyral resin 10%, 1-propenol-3 20%, non-ion fluorin carbon surface are lived
Property agent 5%, LPG propellant 15%.
Embodiment 4
A kind of water proof anti-soil protection spray, includes following components by mass percentage: ptfe micropowder 12%, poly alkyl alcohol
Oxygen vinyl Ether 5% glycolic acid 20%, copper oleate 13%, polyvinyl butyral resin 10%, 1-propenol-3 25%, non-ion fluorin carbon surface are lived
Property agent 5%, LPG propellant 10%.
No. CAS of ptfe micropowder in embodiment 1,2,3,4 is: 9002-84-0, molecular formula: (C2F4)n；Fat
No. CAS of polyoxyethylenated alcohol is: 68131-39-5, molecular formula: C12H25O.(C2H4O)n；No. CAS of glycolic acid is: 79-
14-1, molecular formula be: C2H4O3；No. CAS of copper oleate is: 1120-44-1, molecular formula be: C36H66CuO4；Polyvinyl alcohol contracts
No. CAS of butyraldehyde is: 63148-65-2, molecular formula: C16H28O5；No. CAS of 1-propenol-3 is: 107-18-6, molecular formula: C3H6O；
No. CAS of LPG propellant is: 157621-61-9, molecular formula: C2H6O。
The preparation method of the water proof anti-soil protection spray of embodiment 1,2,3,4:
1) in first ptfe micropowder and fatty alcohol-polyoxyethylene ether being injected agitator by corresponding proportioning and fully mix thoroughly；
2) add glycolic acid by corresponding proportioning again, and stir；
3) it is sequentially added into copper oleate, polyvinyl butyral resin, 1-propenol-3, non-ion fluorin carbon surface active agent four by corresponding proportioning again
Planting raw material, four kinds of raw materials in adding procedure, are both needed to be stirred simultaneously, after four kinds of raw materials have added, are both needed to stir,
Finally obtain spray feed liquid；
4) spray feed liquid is filled in aerosol container bottle；
5) in the aerosol container bottle installing spray feed liquid, fill LPG propellant by corresponding proportioning, i.e. make a kind of water proof anti-soil
Protection spray.
Step 1)-5) be both needed in the indoor of aeration-drying, temperature is to carry out in 20 DEG C of-28 DEG C of environment.
The application of the water proof anti-soil protection spray of the present invention:
1, water proof anti-soil protection spray may be used for outdoor new leather and the basic nursing of textile, makes new leather and textile tool
There is the characteristic of good, excellent, lasting waterproof and anti-soil.Wherein outdoor new leather includes that all kinds of leather is (containing turning over velour leather, frosted
Skin, skin) make leather shoes, fur clothing, the leatherware such as leather glove, textile include clothing that various outdoor textile fabric makes,
Shoes and hats, knapsack, tent etc..Soiling protective spray is not suitable for coat of paint and silver end skin.
2, water proof anti-soil protection spray can also add in coating, can form a kind of special water resistant knot at coating film formation surface
Structure (change contact angle), makes coating surface have extremely strong hydrophobic, hydrophobic, waterproof effect, does not affect the breathability of film simultaneously;
Both avoid the recoatability difficulty of organic silicon hydrophobic material, it also avoid the situation of other water-repelling agent poor air permeability.Really make painting
Material has the excellent properties such as good Folium Nelumbinis double hydrophobicity, self-cleaning, hydrophobicity, water proofing property, resistance to soiling, scrub resistances.Through crowd
React after the application of many coating production enterprises, after adding this product in emulsion paint (coating), compare with like product, every
Performance is superior to like product.
3, water proof anti-soil protection spray can join various water paint, water-soluble resin, aqueous emulsion resin, aqueous face
Material, water color ink etc., make the said goods have self-cleaning, hydrophobicity, water proofing property, resistance to soiling, scrub resistance.
4, water proof anti-soil protection spray can be also used for sand airborne dust firming agent.
5, water proof anti-soil protection spray can be also used for ceramics, plays plasticising, lubrication.
The spraying method of water proof anti-soil protection spray: guarantee body surface cleaning, be dried, fully to shake up before spray, from
Object distance 15-20 centimetre, is uniformly sprayed on body surface until surface wettability.For strengthening hydrophobic function, can spray twice,
The 10-20 minute interval time of twice.After having sprayed, ability contact liq after being at least dried 0.5-4 hour, for accelerating to be dried
Time, it is possible to the use of drying plant.
For glass, plastics, the surface of leather shoes, water proof anti-soil is preferably protected spray be sprayed in microfiber cloth, then
Wipe on the surface of glass, plastics, leather shoes to homogeneous transparent again and do bright.
Claims (10)
1. a water proof anti-soil protection spray, it is characterised in that: include following components by mass percentage: politef is micro-
Powder 10%-15%, fatty alcohol-polyoxyethylene ether 5%-10%, glycolic acid 20%-25%, copper oleate 10%-15%, polyvinyl butyral resin
10%-15%, 1-propenol-3 20%-25%, non-ion fluorin carbon surface active agent 3%-5%, LPG propellant 10%-15%.
A kind of surface waterproofing soiling protective spray the most according to claim 1, it is characterised in that: described politef is micro-
No. CAS of powder is: 9002-84-0, molecular formula: (C2F4)n；No. CAS of described fatty alcohol-polyoxyethylene ether is: 68131-39-5,
Molecular formula: C12H25O.(C2H4O)n。
A kind of surface waterproofing soiling protective spray the most according to claim 1, it is characterised in that: No. CAS of described glycolic acid
For: 79-14-1, molecular formula be: C2H4O3；No. CAS of described copper oleate is: 1120-44-1, molecular formula be: C36H66CuO4。
A kind of surface waterproofing soiling protective spray the most according to claim 1, it is characterised in that: described polyvinyl alcohol contracting fourth
No. CAS of aldehyde is: 63148-65-2, molecular formula: C16H28O5。
A kind of surface waterproofing soiling protective spray the most according to claim 1, it is characterised in that: the CAS of described 1-propenol-3
Number it is: 107-18-6, molecular formula: C3H6O。
A kind of surface waterproofing soiling protective spray the most according to claim 1, it is characterised in that: described LPG propellant
No. CAS is: 157621-61-9, molecular formula: C2H6O。
7. the preparation method of the water proof anti-soil protection spray described in claim 1, it is characterised in that: comprise the technical steps that:
1) in first ptfe micropowder and fatty alcohol-polyoxyethylene ether being injected agitator by corresponding proportioning and fully mix thoroughly；
2) add glycolic acid by corresponding proportioning again, and stir；
3) it is sequentially added into copper oleate, polyvinyl butyral resin, 1-propenol-3, non-ion fluorin carbon surface active agent four by corresponding proportioning again
Planting raw material, four kinds of raw materials in adding procedure, are both needed to be stirred simultaneously, after four kinds of raw materials have added, are both needed to stir,
Finally obtain spray feed liquid；
4) spray feed liquid is filled in aerosol container bottle；
5) in the aerosol container bottle installing spray feed liquid, fill LPG propellant by corresponding proportioning, i.e. make a kind of water proof anti-soil
Protection spray.
The preparation method of water proof anti-soil the most according to claim 7 protection spray, it is characterised in that: step 1)-5) it is both needed to
In the indoor of aeration-drying, temperature be that 20 DEG C of-28 DEG C of environment are carried out.
9. the preparation method of spray is protected according to the water proof anti-soil described in claim 7 or 8, it is characterised in that: step 4)-step
Rapid 5) also on aerosol container bottle, spray valve is installed additional between.
The preparation method of water proof anti-soil the most according to claim 9 protection spray, it is characterised in that: described aerosol container
Bottle is made with tinplate for material, is resistant to amounts of pressurized gaseous 15Mpa.
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| CN201610627738.XA CN106243806B (en) | 2016-08-03 | 2016-08-03 | A kind of water proof anti-soil protection spray and preparation method thereof |
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| CN201610627738.XA CN106243806B (en) | 2016-08-03 | 2016-08-03 | A kind of water proof anti-soil protection spray and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106883692A (en) * | 2017-03-23 | 2017-06-23 | 东莞市蓝琼实业投资有限公司 | Vehicle glass thermal insulation protection spray and its production technology |
| CN107778939A (en) * | 2017-10-27 | 2018-03-09 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN109024093A (en) * | 2018-09-29 | 2018-12-18 | 佛山科学技术学院 | A kind of environment-friendly antibacterial wallpaper |
| CN115595064A (en) * | 2022-11-02 | 2023-01-13 | 郑州市超前涂料有限公司（Cn） | Natural self-cleaning antifouling paint and preparation method thereof |
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| CN103450727A (en) * | 2013-09-20 | 2013-12-18 | 云南银峰新材料有限公司 | Preparation method of fluoroalkyl chain-containing nano super-amphiphobic coating |
| CN103849276A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Preparation method of waterproof coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103849276A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Preparation method of waterproof coating |
| CN103450727A (en) * | 2013-09-20 | 2013-12-18 | 云南银峰新材料有限公司 | Preparation method of fluoroalkyl chain-containing nano super-amphiphobic coating |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106883692A (en) * | 2017-03-23 | 2017-06-23 | 东莞市蓝琼实业投资有限公司 | Vehicle glass thermal insulation protection spray and its production technology |
| CN107778939A (en) * | 2017-10-27 | 2018-03-09 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN107778939B (en) * | 2017-10-27 | 2019-09-24 | 浙江绿岛科技有限公司 | Aerial fog type super-amphiphobic nano antifouling agent and preparation method thereof |
| CN109024093A (en) * | 2018-09-29 | 2018-12-18 | 佛山科学技术学院 | A kind of environment-friendly antibacterial wallpaper |
| CN115595064A (en) * | 2022-11-02 | 2023-01-13 | 郑州市超前涂料有限公司（Cn） | Natural self-cleaning antifouling paint and preparation method thereof |
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| CN106243806B (en) | 2018-07-10 |
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