CN108117836A - A kind of graphene sprays rapid hardening root resistance rubber asphalt waterproof coating - Google Patents
A kind of graphene sprays rapid hardening root resistance rubber asphalt waterproof coating Download PDFInfo
- Publication number
- CN108117836A CN108117836A CN201810065897.4A CN201810065897A CN108117836A CN 108117836 A CN108117836 A CN 108117836A CN 201810065897 A CN201810065897 A CN 201810065897A CN 108117836 A CN108117836 A CN 108117836A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- weight
- graphene
- waterproof coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of graphenes to spray rapid hardening root resistance rubber asphalt waterproof coating, is made of component A and B component, wherein component A is made of following components and parts by weight：35 45 parts of emulsified asphalt, 25 35 parts of polychloroprene latex, 20 25 parts of styrene-butadiene latex, 12 22 parts of graphene oxide, 5 10 parts of root resistance agent, 35 parts of fire retardant, 0.02 0.05 parts of thickener, 0.01 0.03 parts of antifoaming agent, 0.03 0.05 parts of preservative, 0.05 0.1 parts of filler；B component is made of following components and parts by weight：15 20 parts of calcium chloride.The present invention can be such that whole each performance of product is improved.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of graphene sprays rapid hardening root resistance rubber-asphalt waterproof
Coating.
Background technology
Spraying rapid hardening rubber asphalt waterproof coating is referred to as liquid rubber in foreign countries, originates from the U.S.'s radium nineties in last century
It receives company, due to its excellent waterproof reliability, convenience for construction and the feature of environmental protection, Rapid Popularization is obtained in world wide.Closely
Nian Lai, the U.S., Canada, Russia, Israel, Belgium, South Korea, Thailand and Middle East have the product production and
Using.
At present research spraying rapid hardening rubber asphalt waterproof coating a direction be special-purpose emulsifying pitch preparation and
In production.Such as Chinese patent literature CN105949480A discloses a kind of spraying rubber-asphalt coating special-purpose emulsifying pitch, by
The component composition of following mass parts：Pitch 80~120, water 40~80, anionic asphalt emulsion 2~5, pH agent 0~3 and steady
Determine agent 0.1~1；The additive amount of the pH agent is not zero；The anionic asphalt emulsion is by sulfonate surfactant, carboxylic
At least two compoundings in Barbiturates surfactant and Sulfates surfactant obtain.
The spraying rubber asphalt waterproof coating special-purpose emulsifying pitch that CN105949480A is provided is in -10 DEG C of stable storings, energy
Compound rubber lotion carries out spraying operation at a temperature of -5 DEG C.
The content of the invention
In view of this, inventor does not select the research direction of special-purpose emulsifying pitch, and purpose, which is not lain in, works out one kind specially
With emulsified asphalt, it is still on the basis of conventional emulsified asphalt, works out a kind of overall performance that can make product and all obtain
The spraying rapid hardening rubber asphalt waterproof coating of raising.
For this purpose, inventor is made that experiment many times, many kinds of different components and dosage are tested, have paid creation
Property work, just obtained the present invention.
It is an object of the invention to provide the graphene sprays that a kind of whole each performance that can make product is all improved
Apply rapid hardening root resistance rubber asphalt waterproof coating.
Used technical solution is：
A kind of graphene sprays rapid hardening root resistance rubber asphalt waterproof coating, is made of component A and B component, wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
15-20 parts of calcium chloride.
Further, during site operation, the overall weight after the water of B component addition 75-80 parts by weight, the weight with component A
Amount is than being 1：6 are used cooperatively.
Graphene sprays rapid hardening root resistance rubber asphalt waterproof coating in spraying application, using dedicated twin-jet nozzle high pressure spray
Rifle equipment high pressure fan-shaped spray intersects component A and B component, hybrid reaction outside spray gun in covering of the fan in proportion, and coating can be with one
Secondary property spraying, moment demulsification and film-forming, the film excellent combination property of generation.Wherein component A is host agent, by emulsified asphalt
With anionic synthetic rubber such as polychloroprene latex and styrene-butadiene latex as continuous phase, can greatly enhance after water-repellent paint forms a film
Extensibility and puncture resistance.B component is curing agent, in order to ensure the convenience of the stability of the component and transport, selective chlorination
The solid, powdery of calcium.In construction, the water of scene addition 75-80 parts by weight is in B component.
In the technical solution of the present invention, graphene oxide is product of the powdered graphite after chemical oxidation and stripping, oxidation
Graphene is single atomic layer, can expand to some tens of pm on lateral dimension at any time.Graphene oxide have polymer,
Colloid, the characteristic of film and amphiphatic molecule and excellent mechanical property, can significantly improve product entirety tensile strength and
Elongation at break.
After oxidation processes, graphene oxide still keeps the layer structure of graphene, but in each layer of graphene list
On piece introduces many oxygroup functional groups.The introducing of these oxygroup functional groups causes it than single graphene-structured property more
Vivaciously, the degree of cross linking with other components is increased.By emulsified asphalt and anionic synthetic rubber such as polychloroprene latex and styrene-butadiene latex
It is present in as continuous phase in the layer structure of graphene, forms the micro- net structure of rubber modified bitumen, graphene oxide has
Both sexes (hydrophily and hydrophobicity) property, the compatibility of whole each component can be improved so that product is at low temperature, example
Such as also adapted under the conditions of the climatic environment of severe cold area.
Gap between the molecule and molecule of this micro- net structure simultaneously, width is only several nanometers, is prevented certainly
The transmission of hydrone in right boundary, so as to possess preferable water proofing property.
And under the action of graphene oxide, there is higher low temperature flexibility, tensile strength, resistance to height after coating drying and forming-film
Warm nature and elongation at break.
The fire retardant of the present invention adds the flame retardant property of product.The root resistance agent of the present invention, but it is excellent to be provided with product
Root-resistant puncturing.
The beneficial effects of the present invention are：
By multiple Adjustment Tests, the present invention has obtained a kind of whole each performance that can make product and has been improved
Graphene spraying rapid hardening root resistance rubber asphalt waterproof coating.
Specific embodiment
Technical scheme is further described with reference to embodiment, but is simply enumerated from the numerous experiments of applicant
Section Example, the present invention claims protection domain be not limited thereto.
Embodiment 1
A kind of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating of the present embodiment, by component A and B component group
Into, wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
15 parts of calcium chloride.
During site operation, B component adds the overall weight after the water of 75 parts by weight, and the weight ratio with component A is 1：6 match somebody with somebody
It closes and uses.
Embodiment 2
A kind of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating of the present embodiment, by component A and B component group
Into, wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
20 parts of calcium chloride.
During site operation, B component adds the overall weight after the water of 80 parts by weight, and the weight ratio with component A is 1：6 match somebody with somebody
It closes and uses.
Embodiment 3
A kind of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating of the present embodiment, by component A and B component group
Into, wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
18 parts of calcium chloride.
During site operation, B component adds the overall weight after the water of 77 parts by weight, and the weight ratio with component A is 1：6 match somebody with somebody
It closes and uses.
Embodiment 4
A kind of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating of the present embodiment, by component A and B component group
Into, wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
15-20 parts of calcium chloride.
During site operation, B component adds the overall weight after the water of 76 parts by weight, and the weight ratio with component A is 1：6 match somebody with somebody
It closes and uses.
Embodiment 5
A kind of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating of the present embodiment, by component A and B component group
Into, wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
18 parts of calcium chloride.
During site operation, B component adds the overall weight after the water of 78 parts by weight, and the weight ratio with component A is 1：6 match somebody with somebody
It closes and uses.
Comparative example 1
CN107043598A discloses a kind of embodiment for spraying rapid hardening rubber asphalt waterproof coating：
Step 1：Vulcanize the preparation of rubber latex：
It is calculated using the quality for vulcanizing rubber latex as 100%, 99.1% natural rubber latex is heated, is warming up to 40
℃；Stirring, the mass concentration for sequentially adding 0.3% is 50% sulphur dispersion, 0.1% mass concentration is 50% zinc oxide point
Granular media, 0.2% mass concentration are 50% accelerating agent ZDC dispersions, 0.15% mass concentration is that 50% antioxidant D NP disperses
Body, 0.15% mass concentration are 50% antioxidant MB dispersion；Cooling, makes temperature drop to room temperature.
Step 2：The preparation of liquid rubber pitch latex：
100kg liquid rubber pitch latex is prepared, the vulcanization rubber latex of gained will be prepared with step 1 the method
50kg, styrene-butadiene latex 10kg, anionic emulsifying 50# asphalt 30kg, fatty acid soaps 4kg, polycarboxylic acids ammonium salt 2kg, metallic soap
Antifoaming agent 1kg, antioxidant D NP1kg, dodecyl benzyl dimethyl ammonium chloride 2kg mixing are added in stirred tank, and pH is in 9- for control
12,40min is stirred under the conditions of 300 revs/min of rotating speed, you can obtains the liquid rubber pitch latex of 100kg.
Step 3：The preparation of coagulating agent：
1kg aluminium chloride is dissolved in 19kg water, after stirring 5min, obtains the coagulating agent 20kg that mass concentration is 5%.
In use, by liquid rubber pitch latex in mass ratio 1/5 made from coagulating agent made from step 3 and step 2
Ratio sprays.
By the spray of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating and comparative example 1 made from above example 1-5
Rapid hardening rubber asphalt waterproof coating is applied, when construction is sprayed, and to carrying out performance detection after coating drying and forming-film, obtains the following table 1：
Table 1
The spraying speed of graphene spraying rapid hardening root resistance rubber asphalt waterproof coating made from this each embodiment and comparative example 1
The detection method of gel rubber asphalt waterproofing paint is consistent, such as is tested using the standard of JC/T 2215-2015.
As can be known from the above table, graphene of the invention spraying rapid hardening root resistance rubber asphalt waterproof coating is in impermeability, stretching
Intensity, low temperature flexibility and elongation at break and on, than (the spraying rapid hardening rubber-asphalt waterproof of CN107043598A of comparative example 1
Coating) performance it is well very much, reach a kind of unexpected technique effect.
Claims (2)
1. a kind of graphene sprays rapid hardening root resistance rubber asphalt waterproof coating, which is characterized in that it is made of component A and B component,
Wherein,
Component A is made of following components and parts by weight：
B component is made of following components and parts by weight：
15-20 parts of calcium chloride.
2. graphene according to claim 1 sprays rapid hardening root resistance rubber asphalt waterproof coating, which is characterized in that applies at scene
Man-hour, B component add the overall weight after the water of 75-80 parts by weight, and the weight ratio with component A is 1：6 are used cooperatively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810065897.4A CN108117836B (en) | 2018-01-23 | 2018-01-23 | Graphene spraying rapid-hardening root-blocking rubber asphalt waterproof coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810065897.4A CN108117836B (en) | 2018-01-23 | 2018-01-23 | Graphene spraying rapid-hardening root-blocking rubber asphalt waterproof coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108117836A true CN108117836A (en) | 2018-06-05 |
| CN108117836B CN108117836B (en) | 2020-03-27 |
Family
ID=62233067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810065897.4A Active CN108117836B (en) | 2018-01-23 | 2018-01-23 | Graphene spraying rapid-hardening root-blocking rubber asphalt waterproof coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108117836B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363372A (en) * | 2020-04-17 | 2020-07-03 | 华光圣奥防水材料股份有限公司 | Root puncture-resistant self-healing waterproof coiled material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103627258A (en) * | 2012-08-23 | 2014-03-12 | 山东北方创信防水技术有限公司 | Spraying quick-setting rubber asphalt waterproof coating material |
| CN105440950A (en) * | 2015-12-16 | 2016-03-30 | 盘锦辽河油田金宇建筑材料有限公司 | Coating for anticorrosion and waterproofing, and preparation technology thereof |
| CN106398536A (en) * | 2016-09-18 | 2017-02-15 | 科顺防水科技股份有限公司 | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof |
| CN107365556A (en) * | 2016-05-12 | 2017-11-21 | 郑海生 | One kind spraying rapid hardening water-repellent paint and its production method |
-
2018
- 2018-01-23 CN CN201810065897.4A patent/CN108117836B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103627258A (en) * | 2012-08-23 | 2014-03-12 | 山东北方创信防水技术有限公司 | Spraying quick-setting rubber asphalt waterproof coating material |
| CN105440950A (en) * | 2015-12-16 | 2016-03-30 | 盘锦辽河油田金宇建筑材料有限公司 | Coating for anticorrosion and waterproofing, and preparation technology thereof |
| CN107365556A (en) * | 2016-05-12 | 2017-11-21 | 郑海生 | One kind spraying rapid hardening water-repellent paint and its production method |
| CN106398536A (en) * | 2016-09-18 | 2017-02-15 | 科顺防水科技股份有限公司 | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363372A (en) * | 2020-04-17 | 2020-07-03 | 华光圣奥防水材料股份有限公司 | Root puncture-resistant self-healing waterproof coiled material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108117836B (en) | 2020-03-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106398536B (en) | Anion-type water-thinned uncured rubber asphalt waterproof coating of one kind and preparation method thereof | |
| JP3175069B2 (en) | Rubber asphalt-based waterproofing composition | |
| CN103627258B (en) | Spraying quick-setting rubber asphalt waterproof coating material | |
| CN102965020B (en) | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting | |
| US20080038470A1 (en) | Surface coating compositions | |
| CN104342029B (en) | Method and coating film waterproof material for the coating film waterproof material for preparing and construct | |
| CA2716238C (en) | Method for producing coated rubber particles and coated rubber particles | |
| CA2784296C (en) | Surface coating compositions | |
| CN107868616A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN102965016A (en) | High-temperature resistant spray fast-setting rubber asphalt waterproof coating | |
| CN107365556A (en) | One kind spraying rapid hardening water-repellent paint and its production method | |
| CN102965014A (en) | Spraying rapid-hardening rubber asphalt water-proofing material for pitched roof | |
| CN107043598A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN110256965A (en) | A kind of spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN107964362B (en) | Spraying rapid-hardening rubber asphalt waterproof paint and construction method | |
| CN104312328A (en) | Rapid macromolecule machine-sprayable demulsification solidification filming waterproof coating and preparation method thereof | |
| CN108441119A (en) | A kind of spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN108949027A (en) | Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material and preparation method thereof | |
| CN102911602B (en) | Single-component polymer modified asphalt waterproofing paint and preparation method thereof | |
| CN105131837A (en) | Paint compound and preparation method thereof | |
| CN110016289A (en) | A kind of high performance polymer modified bitumen water-repellent paint and preparation method thereof | |
| CN108117836A (en) | A kind of graphene sprays rapid hardening root resistance rubber asphalt waterproof coating | |
| CN107022260B (en) | A kind of quick-drying flame retardant type water-repellent paint and preparation method thereof | |
| US20140364534A1 (en) | Cross-linked ethylene propylene diene terpolymer latex blend for improved coatings | |
| CN113881343A (en) | Cold-construction non-cured rubber asphalt waterproof coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190107 Address after: 361000 three of room 106, two Li 210, Hou Pu north, Xiamen, Fujian. Applicant after: Xiamen jialene Waterproofing Technology Co., Ltd. Address before: 361000 Huli two Li 209, Huli District, Xiamen, Fujian Applicant before: Xiamen Likasam Waterproof Engineering Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |