CN108949027A - Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material and preparation method thereof - Google Patents
Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material and preparation method thereof Download PDFInfo
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- CN108949027A CN108949027A CN201810539271.2A CN201810539271A CN108949027A CN 108949027 A CN108949027 A CN 108949027A CN 201810539271 A CN201810539271 A CN 201810539271A CN 108949027 A CN108949027 A CN 108949027A
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- environment
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- friendly type
- type aqueous
- coiled material
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to water-proof self-adhesion coiled material technical fields, and in particular to environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material of one kind and preparation method thereof.The water-proof self-adhesion coiled material includes self-adhesion glue film, the macromolecule resin sheet layer being arranged on self-adhesion glue film and the environment-friendly type aqueous uncured modified asphalt waterproofing paint layer being arranged on macromolecule resin sheet layer, waterproof coating layer includes each component of following parts by weight: 100 parts of anion rubber elastomer modified emulsifying asphalt, 4~6 parts of anion SBR latex, 6~7 parts of anion polychloroprene latex, 0.5~1 part of hydrophobing agent, 0.5~1 part of defoaming agent, 0.5~1 part of dispersing agent, 0.5~1 part of wetting agent, 0.5~1 part of smoke suppressant and 1~1.5 part of inorganic salts.Aqueous uncured modified asphalt waterproofing self-adhesive coiled material provided by the present invention will not solidify long-time is placed after construction, keep original performance of waterproof material, can be improved the service life of waterproof layer, and environmentally friendly.
Description
Technical field
The invention belongs to water-proof self-adhesion coiled material technical fields, and in particular to a kind of environment-friendly type aqueous uncured modified pitch is anti-
Water self-adhesive coiled material and preparation method thereof.
Background technique
Aqueous uncured modified asphalt waterproofing self-adhesive coiled material will not solidify long-time is placed after construction, keep anti-
Original performance of water material, can be improved the service life of waterproof layer.It " is never solidified " performance and is mainly determined with its solid content
It is fixed.Aqueous uncured modified asphalt waterproofing self-adhesive coiled material itself solid content be 99% or more, without adding solvent, therefore apply
It will not solidify after work even across long-time and keep its property.
Summary of the invention
To solve the deficiencies in the prior art, the present invention provides a kind of environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesions
Coiled material and preparation method thereof.Even if aqueous uncured modified asphalt waterproofing self-adhesive coiled material provided by the present invention is long after construction
Between place and will not solidify, keep original performance of waterproof material, can be improved the service life of waterproof layer, and environmentally friendly.
Technical solution provided by the present invention is as follows:
A kind of environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including self-adhesion glue film, setting are in the self-adhesion
Macromolecule resin sheet layer on glue film and be arranged on the macromolecule resin sheet layer environment-friendly type aqueous uncured change
Property asphalt waterproofing paint layer, which is characterized in that the environment-friendly type aqueous uncured modified asphalt waterproofing paint layer includes following heavy
Measure each component of part: 100 parts of anion rubber elastomer modified emulsifying asphalt, 4~6 parts of anion SBR latex, 6~7 parts
Anion polychloroprene latex, 0.5~1 part of hydrophobing agent, 0.5~1 part of defoaming agent, 0.5~1 part of dispersing agent, 0.5~1 part
Wetting agent, 0.5~1 part of smoke suppressant and 1~1.5 part of inorganic salts.
EVA, LDPE, HDPE or ECB etc. may be selected in macromolecule resin sheet layer.
Aqueous uncured modified asphalt waterproofing self-adhesive coiled material provided by the present invention is placed even if long-time after construction
It will not solidify, keep original performance of waterproof material, can be improved the service life of waterproof layer, and environmentally friendly.
Specifically, the anion rubber elastomer modified emulsifying asphalt includes each component of following mass percent: base
Matter pitch 80~90%, SBR rubber powder l~4%, NBR rubber powder 3~7%, polythene wax emulsion 2~5%, modified siloxane 1
~5%, anion emulsifier 2~3%, nonionic surfactant 0.5~2%.
Specifically, the wetting agent is any one in alkylnaphthalene sulfonate, AD-01 or 104E.It can be by commercially available
Mode obtain, such as AD-01,104E of American Gas Chemical Company etc.
Specifically, the defoaming agent is BYK-024.It can be obtained by commercially available mode, such as the BYK- of BYK company
024。
Specifically, the dispersing agent is any one in epoxidized soybean oil, aromatic naphtha or readymade oil.
Specifically, the smoke suppressant is expansible graphite or SBS.
Specifically, the hydrophobing agent is wax emulsion.
Specifically, the inorganic salts are calcium chloride or magnesium chloride.
The present invention also provides a kind of preparation methods of environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including
Following steps: according to formula ratio, anion rubber elastomer modified emulsifying asphalt is small in 150~175 DEG C of mixing shearings 1~2
When obtain pitch mixed liquor, by anion SBR latex, anion polychloroprene latex, hydrophobing agent, defoaming agent, dispersing agent, wetting agent,
Smoke suppressant and inorganic salts are heated to 75~80 DEG C, are emulsified after mixing by colloid mill, and cooling discharging is up to environment-friendly type aqueous
Environment-friendly type aqueous uncured modified asphalt waterproofing paint is coated on macromolecule resin sheet material by uncured modified asphalt waterproofing paint
On layer, then by macromolecule resin sheet layer be attached on self-adhesion glue film to get environment-friendly type aqueous uncured modified asphalt waterproofing from
Viscous coiled material.
Based on the above-mentioned technical proposal, environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material can be prepared.Water
Property uncured modified asphalt waterproofing self-adhesive coiled material will not solidify long-time is placed after construction, keep the original of waterproof material
There is performance, can be improved the service life of waterproof layer, and environmentally friendly.
Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material provided by the present invention has the advantage that
1) never solidify, solidfied material content dry greatly 98%, without volatile matter, gelatinous original shape is remained after construction
State;
2) corrosion resistant, high-low temperature resistant, extension property are outstanding;It is nontoxic, tasteless, pollution-free, non-ignitable in fire:
3) flexibility is good, can construct in moisture substrate, and can bond with any foreign matter;
4) elongation percentage is high, is suitable for base and deforms;
Modified asphalt waterproof self-adhesive coiled material provided by the present invention can be not only used for newly-built waterproof layer, it can also be used to repair impaired
Waterproof layer due to it have seal itself ability, can self-healing waterproof layer damaged portion.Its cured modified asphalt waterproofing applies
Material need not do maintenance processing to waterproof layer, shorten the construction time: waterproof immediately after perfusion, even if being easy maintenance in diverse seam
Also there are excellent workability and impermeability in area.
Specific embodiment
The principles and features of the present invention are described below, and illustrated embodiment is served only for explaining the present invention, is not intended to
It limits the scope of the invention.
Embodiment 1
Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including self-adhesion glue film, setting are in the self-adhesion glue film
On macromolecule resin sheet layer and the environment-friendly type aqueous uncured modified drip that is arranged on the macromolecule resin sheet layer
Green waterproof coating layer, environment-friendly type aqueous uncured modified asphalt waterproofing paint layer include each component of following parts by weight: 100 parts
Anion rubber elastomer modified emulsifying asphalt, 6 parts of anion SBR latex, 6 parts of anion polychloroprene latex, 1 part hydrophobic
Agent, 0.5 part of defoaming agent, 1 part of dispersing agent, 0.5 part of wetting agent, 1 part of smoke suppressant and 1 part of inorganic salts.
Anion rubber elastomer modified emulsifying asphalt includes each component of following mass percent: matrix pitch 90%,
SBR rubber powder l%, NBR rubber powder 3%, polythene wax emulsion 2%, modified siloxane 1%, anion emulsifier 2%, it is non-from
Sub- surfactant 1%.
Wetting agent is alkylnaphthalene sulfonate.
Defoaming agent is BYK-024.
Dispersing agent is epoxidized soybean oil.
Smoke suppressant is expansible graphite.
Hydrophobing agent is wax emulsion.
Inorganic salts are magnesium chloride.
According to formula ratio, anion rubber elastomer modified emulsifying asphalt is sheared 1 hour in 175 DEG C of mixing and obtains pitch
Mixed liquor, by anion SBR latex, anion polychloroprene latex, hydrophobing agent, defoaming agent, dispersing agent, wetting agent, smoke suppressant and nothing
Machine salt is heated to 80 DEG C, is emulsified after mixing by colloid mill, and cooling discharging is up to environment-friendly type aqueous uncured modified pitch
Environment-friendly type aqueous uncured modified asphalt waterproofing paint is coated on macromolecule resin sheet layer by water-repellent paint, then by high score
Subtree rouge sheet layer is attached on self-adhesion glue film to get environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material 1.
Embodiment 2
Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including self-adhesion glue film, setting are in the self-adhesion glue film
On macromolecule resin sheet layer and the environment-friendly type aqueous uncured modified drip that is arranged on the macromolecule resin sheet layer
Green waterproof coating layer, environment-friendly type aqueous uncured modified asphalt waterproofing paint layer include each component of following parts by weight: 100 parts
Anion rubber elastomer modified emulsifying asphalt, 4 parts of anion SBR latex, 7 parts of anion polychloroprene latex, 0.5 part dredge
Aqua, 1 part of defoaming agent, 0.5 part of dispersing agent, 1 part of wetting agent, 0.5 part of smoke suppressant and 1.5 parts of inorganic salts.
Anion rubber elastomer modified emulsifying asphalt includes each component of following mass percent: matrix pitch 80%,
SBR rubber powder 4%, NBR rubber powder 7%, polythene wax emulsion 3%, modified siloxane 1%, anion emulsifier 3%, it is non-from
Sub- surfactant 2%.
Wetting agent is AD-01.
Defoaming agent is BYK-024.
Dispersing agent is aromatic naphtha.
Smoke suppressant is SBS.
Hydrophobing agent is wax emulsion.
Inorganic salts are calcium chloride.
According to formula ratio, anion rubber elastomer modified emulsifying asphalt is sheared 2 hours in 150 DEG C of mixing and obtains pitch
Mixed liquor, by anion SBR latex, anion polychloroprene latex, hydrophobing agent, defoaming agent, dispersing agent, wetting agent, smoke suppressant and nothing
Machine salt is heated to 75 DEG C, is emulsified after mixing by colloid mill, and cooling discharging is up to environment-friendly type aqueous uncured modified pitch
Environment-friendly type aqueous uncured modified asphalt waterproofing paint is coated on macromolecule resin sheet layer by water-repellent paint, then by high score
Subtree rouge sheet layer is attached on self-adhesion glue film to get environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material 2.
Embodiment 3
Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including self-adhesion glue film, setting are in the self-adhesion glue film
On macromolecule resin sheet layer and the environment-friendly type aqueous uncured modified drip that is arranged on the macromolecule resin sheet layer
Green waterproof coating layer, environment-friendly type aqueous uncured modified asphalt waterproofing paint layer include each component of following parts by weight: 100 parts
Anion rubber elastomer modified emulsifying asphalt, 5 parts of anion SBR latex, 6 parts of anion polychloroprene latex, 1 part hydrophobic
Agent, 1 part of defoaming agent, 0.5 part of dispersing agent, 0.5 part of wetting agent, 0.5 part of smoke suppressant and 1 part of inorganic salts.
Anion rubber elastomer modified emulsifying asphalt includes each component of following mass percent: matrix pitch 85%,
It is SBR rubber powder 2%, NBR rubber powder 4%, polythene wax emulsion 3%, modified siloxane 3.5%, anion emulsifier 2%, non-
Ionic surface active agent 0.5%.
Wetting agent is 104E.
Defoaming agent is BYK-024.
Dispersing agent is readymade oil.
Smoke suppressant is SBS.
Hydrophobing agent is wax emulsion.
Inorganic salts are calcium chloride or magnesium chloride.
According to formula ratio, anion rubber elastomer modified emulsifying asphalt is sheared 1.5 hours in 165 DEG C of mixing and is dripped
Green mixed liquor, by anion SBR latex, anion polychloroprene latex, hydrophobing agent, defoaming agent, dispersing agent, wetting agent, smoke suppressant and
Inorganic salts are heated to 78 DEG C, are emulsified after mixing by colloid mill, and cooling discharging is up to environment-friendly type aqueous uncured modified drip
Environment-friendly type aqueous uncured modified asphalt waterproofing paint is coated on macromolecule resin sheet layer by green water-repellent paint, then will be high
Molecule resin sheet layer is attached on self-adhesion glue film to get environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material 3.
Comparative example 1
Environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including self-adhesion glue film, setting are in the self-adhesion glue film
On macromolecule resin sheet layer and the environment-friendly type aqueous uncured modified drip that is arranged on the macromolecule resin sheet layer
Green waterproof coating layer, environment-friendly type aqueous uncured modified asphalt waterproofing paint layer include each component of following parts by weight: 60 parts
Anion rubber elastomer modified emulsifying asphalt, 5 parts of anion SBR latex, 6 parts of anion polychloroprene latex, 1 part hydrophobic
Agent, 1 part of defoaming agent, 0.5 part of dispersing agent, 0.5 part of wetting agent, 0.5 part of smoke suppressant and 1 part of inorganic salts.
Anion rubber elastomer modified emulsifying asphalt includes each component of following mass percent: matrix pitch 85%,
It is SBR rubber powder 2%, NBR rubber powder 4%, polythene wax emulsion 3%, modified siloxane 3.5%, anion emulsifier 2%, non-
Ionic surface active agent 0.5%.
Wetting agent is 104E.
Defoaming agent is BYK-024.
Dispersing agent is readymade oil.
Smoke suppressant is SBS.
Hydrophobing agent is wax emulsion.
Inorganic salts are calcium chloride or magnesium chloride.
According to formula ratio, anion rubber elastomer modified emulsifying asphalt is sheared 1.5 hours in 165 DEG C of mixing and is dripped
Green mixed liquor, by anion SBR latex, anion polychloroprene latex, hydrophobing agent, defoaming agent, dispersing agent, wetting agent, smoke suppressant and
Inorganic salts are heated to 78 DEG C, are emulsified after mixing by colloid mill, and cooling discharging is up to environment-friendly type aqueous uncured modified drip
Environment-friendly type aqueous uncured modified asphalt waterproofing paint is coated on macromolecule resin sheet layer by green water-repellent paint, then will be high
Molecule resin sheet layer is attached on self-adhesion glue film to get environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material 4.
The performance test results of each embodiment and comparative example are as follows:
As can be seen from the above data, environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material provided by the present invention
It has excellent performance, there is good tensile strength and deformability.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, including self-adhesion glue film, setting are in the self-adhesive
Macromolecule resin sheet layer on film and it is arranged in environment-friendly type aqueous uncured modified on the macromolecule resin sheet layer
Asphalt waterproofing paint layer, which is characterized in that the environment-friendly type aqueous uncured modified asphalt waterproofing paint layer includes following weight
Part each component: 100 parts of anion rubber elastomer modified emulsifying asphalt, 4~6 parts of anion SBR latex, 6~7 parts
Anion polychloroprene latex, 0.5~1 part of hydrophobing agent, 0.5~1 part of defoaming agent, 0.5~1 part of dispersing agent, 0.5~1 part
Wetting agent, 0.5~1 part of smoke suppressant and 1~1.5 part of inorganic salts.
2. environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material according to claim 1, which is characterized in that described
Anion rubber elastomer modified emulsifying asphalt includes each component of following mass percent: matrix pitch 80~90%, SBR rubber
Rubber powder l~4%, NBR rubber powder 3~7%, polythene wax emulsion 2~5%, modified siloxane 1~5%, anion emulsifier 2
~3%, nonionic surfactant 0.5~2%.
3. environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material according to claim 2, it is characterised in that: described
Wetting agent is any one in alkylnaphthalene sulfonate, AD-01 or 104E.
4. environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material according to claim 2, it is characterised in that: described
Defoaming agent is BYK-024.
5. environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material according to claim 2, it is characterised in that: described
Dispersing agent is any one in epoxidized soybean oil, aromatic naphtha or readymade oil.
6. environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material according to claim 2, it is characterised in that: described
Smoke suppressant is expansible graphite or SBS.
7. environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material according to claim 2, it is characterised in that: described
Hydrophobing agent be wax emulsion.
8. according to any environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material of claim 2 to 7, feature exists
In: the inorganic salts are calcium chloride or magnesium chloride.
9. a kind of preparation method of environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesive coiled material, which is characterized in that including following
Step: according to formula ratio, anion rubber elastomer modified emulsifying asphalt is sheared 1~2 hour in 150~175 DEG C of mixing
To pitch mixed liquor, by anion SBR latex, anion polychloroprene latex, hydrophobing agent, defoaming agent, dispersing agent, wetting agent, suppression cigarette
Agent and inorganic salts are heated to 75~80 DEG C, are emulsified after mixing by colloid mill, and cooling discharging is up to environment-friendly type aqueous non-solid
Change modified waterproof asphalt material, environment-friendly type aqueous uncured modified asphalt waterproofing paint is coated on macromolecule resin sheet layer
On, then macromolecule resin sheet layer is attached on self-adhesion glue film to get environment-friendly type aqueous uncured modified asphalt waterproofing self-adhesion
Coiled material.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111101658A (en) * | 2019-12-27 | 2020-05-05 | 唐山东方雨虹防水技术有限责任公司 | Modified asphalt waterproof coiled material and preparation method thereof |
CN111205770A (en) * | 2020-01-03 | 2020-05-29 | 中国化工株洲橡胶研究设计院有限公司 | Water-based environment-friendly modified asphalt waterproof coating liquid coiled material and production method thereof |
CN111793436A (en) * | 2020-07-20 | 2020-10-20 | 上海三棵树防水技术有限公司 | Single-component asphalt-based water-based non-cured rubber asphalt waterproof coating and preparation method thereof |
CN111808529A (en) * | 2020-07-16 | 2020-10-23 | 上海三棵树防水技术有限公司 | Aqueous base layer treating agent and preparation method thereof |
CN113717657A (en) * | 2021-09-26 | 2021-11-30 | 江苏凯伦建材股份有限公司 | High-water-resistance environment-friendly waterproof sealant and preparation method and application thereof |
CN114293385A (en) * | 2021-12-30 | 2022-04-08 | 广西青龙化学建材有限公司 | High-performance in-situ-made high-polymer coiled material and manufacturing method thereof |
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CN106398536A (en) * | 2016-09-18 | 2017-02-15 | 科顺防水科技股份有限公司 | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof |
CN107262346A (en) * | 2017-04-28 | 2017-10-20 | 江阴正邦化学品有限公司 | A kind of construction method of stacked coating water-proof system |
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CN106398536A (en) * | 2016-09-18 | 2017-02-15 | 科顺防水科技股份有限公司 | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof |
CN107262346A (en) * | 2017-04-28 | 2017-10-20 | 江阴正邦化学品有限公司 | A kind of construction method of stacked coating water-proof system |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111101658A (en) * | 2019-12-27 | 2020-05-05 | 唐山东方雨虹防水技术有限责任公司 | Modified asphalt waterproof coiled material and preparation method thereof |
CN111205770A (en) * | 2020-01-03 | 2020-05-29 | 中国化工株洲橡胶研究设计院有限公司 | Water-based environment-friendly modified asphalt waterproof coating liquid coiled material and production method thereof |
CN111808529A (en) * | 2020-07-16 | 2020-10-23 | 上海三棵树防水技术有限公司 | Aqueous base layer treating agent and preparation method thereof |
CN111793436A (en) * | 2020-07-20 | 2020-10-20 | 上海三棵树防水技术有限公司 | Single-component asphalt-based water-based non-cured rubber asphalt waterproof coating and preparation method thereof |
CN113717657A (en) * | 2021-09-26 | 2021-11-30 | 江苏凯伦建材股份有限公司 | High-water-resistance environment-friendly waterproof sealant and preparation method and application thereof |
CN113717657B (en) * | 2021-09-26 | 2023-11-28 | 江苏凯伦建材股份有限公司 | High-water-resistance environment-friendly waterproof sealant and preparation method and application thereof |
CN114293385A (en) * | 2021-12-30 | 2022-04-08 | 广西青龙化学建材有限公司 | High-performance in-situ-made high-polymer coiled material and manufacturing method thereof |
CN114293385B (en) * | 2021-12-30 | 2024-02-02 | 广西青龙化学建材有限公司 | High-performance high-molecular coiled material and manufacturing method thereof |
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Application publication date: 20181207 |