CN111205770A - Water-based environment-friendly modified asphalt waterproof coating liquid coiled material and production method thereof - Google Patents

Water-based environment-friendly modified asphalt waterproof coating liquid coiled material and production method thereof Download PDF

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Publication number
CN111205770A
CN111205770A CN202010006279.XA CN202010006279A CN111205770A CN 111205770 A CN111205770 A CN 111205770A CN 202010006279 A CN202010006279 A CN 202010006279A CN 111205770 A CN111205770 A CN 111205770A
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parts
water
coiled material
waterproof coating
coating liquid
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CN202010006279.XA
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唐聚宝
李红兰
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Zhuzhou Rubber Research and Design Institute Co Ltd of Chemchina
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Zhuzhou Rubber Research and Design Institute Co Ltd of Chemchina
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Priority to CN202010006279.XA priority Critical patent/CN111205770A/en
Publication of CN111205770A publication Critical patent/CN111205770A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a water-based environment-friendly modified asphalt waterproof coating liquid coiled material, which is used in the field of waterproof coatings and comprises the following components in parts by weight: 30-50 parts of emulsified asphalt, 20-30 parts of polymer composite latex, 20-25 parts of powder, 0.1-0.2 part of dispersing agent, 0.2-0.5 part of defoaming agent, 0.1-0.5 part of stabilizing agent, 5-20 parts of purified water, 0.2-0.5 part of thickening agent, 0.1-0.3 part of preservative and 0.1-0.3 part of anti-settling agent. The emulsified asphalt adopted by the invention is soap solution prepared by adding anionic or cationic emulsifier and stabilizer into water as a medium, and then emulsifying hot asphalt into stable emulsion in a high-speed shearing mode; then, the anionic emulsified asphalt or the cationic emulsified asphalt is modified and compounded by utilizing a high molecular synthetic material to generate the waterproof coating. The product of the patent not only has very high strength and good elongation, but also has comprehensive performances of water resistance, corrosion resistance, aging resistance, weather resistance and the like. The medium is water, and the organic solvent is not used, so that the method has great advantage in the aspect of environmental protection.

Description

Water-based environment-friendly modified asphalt waterproof coating liquid coiled material and production method thereof
Technical Field
The invention relates to the field of waterproof coatings, in particular to a water-based environment-friendly modified asphalt waterproof coating liquid coiled material and a production method thereof.
Background
In the production and construction processes of the traditional waterproof coating, a large amount of volatile organic solvents and organic substances are released, so that resources are wasted, the environment is polluted, and the harm to the health of human bodies is great. Since the 50 s, environmental pollution problems occurred in the united states. The 66-year regulation was made in 1966, the limit was imposed on volatile organic solvents, and the environmental protection agency was established in 1970. The currently available regulatory technology scope (RACT) is defined in the paint production and construction management technical guidelines (CTG) established by the environmental protection agency in 1977. More strictly, the upper limit of Volatile Organic Compounds (VOC) is also specified. In addition to the united states, europe and other countries have taken steps to limit VOC emission concentrations. With the enhancement of environmental protection, the restrictions on VOC are more severe. Therefore, some countries in Europe and America have been researched and improved to provide so-called "green" coatings and resins. The water paint uses little or no organic solvent, thus fundamentally eliminating or reducing the problem of environmental pollution.
Therefore, with the increasing requirements of environmental regulations of various countries on organic volatile matters, the use of solvent-based paint is greatly limited, and the requirements of society on environmental protection can be met only by the introduction of water-based environment-friendly coatings. Because of traditional pitch base coiled material's production can release a large amount of poisonous and harmful gas, and the construction is loaded down with trivial details, at first need prime with emulsified asphalt during the construction, and will use the coal tar cream of high temperature system of decocting to do the tie coat, it just can glue firmly still to use liquefied petroleum gas spray gun barbecue pitch coiled material, overlap joint treatment between coiled material and the coiled material also is difficult to accomplish perfectly, especially beam, special-shaped positions such as post do not carefully will produce the later stage phenomenon of leaking because of the problem of overlap joint a little, make whole waterproof coiled material layer play the waterproof effect that should not, place some places have forbidden production and use traditional pitch base coiled material at present. Through long-term observation cases and communication with constructors, in order to avoid the problem of water leakage caused by the problem of construction difficulty, a water-based environment-friendly modified asphalt waterproof coating liquid coiled material is researched in a targeted manner to replace the traditional asphalt coiled material.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a water-based environment-friendly modified asphalt waterproof coating liquid coil material and a production method thereof, wherein the coil material is a single-component self-drying coating, is convenient to construct, can be constructed after being unsealed, can be used for large-area spraying construction in an air or air-free spraying mode, can reduce the labor intensity of constructors and improve the construction efficiency; and because the whole film is integrally formed in the whole construction, the later stage water leakage phenomenon caused by the lap seam problem of the traditional coiled material can be avoided.
In order to solve the technical problems, the technical scheme of the invention is as follows:
an aqueous environment-friendly modified asphalt waterproof coating liquid coiled material comprises the following components in parts by weight: 30-50 parts of emulsified asphalt, 20-30 parts of polymer composite latex, 20-25 parts of powder, 0.1-0.2 part of dispersing agent, 0.2-0.5 part of defoaming agent, 0.1-0.5 part of stabilizing agent, 5-20 parts of purified water, 0.2-0.5 part of thickening agent, 0.1-0.3 part of preservative and 0.1-0.3 part of anti-settling agent.
Preferably, the composition comprises the following components in parts by weight: 30 parts of emulsified asphalt, 30 parts of polymer composite latex, 20 parts of powder, 0.1 part of dispersant, 0.2 part of defoamer, 0.1 part of stabilizer, 5 parts of purified water, 0.2 part of thickener, 0.1 part of preservative and 0.1 part of anti-settling agent.
Preferably, the emulsified asphalt is an anionic or cationic emulsified asphalt.
Preferably, the polymer composite latex comprises one or two of natural latex, acrylic emulsion, styrene-butadiene emulsion and chloroprene emulsion.
Preferably, the powder is 800-mesh heavy calcium powder or quartz powder.
Preferably, the dispersing agent is sodium polyacrylate, and the defoaming agent is mineral oil or an organic silicon defoaming agent.
Preferably, the stabilizer is an organic amine stabilizer, and the thickener is an acrylic acid associative thickener.
Preferably, the preservative is a s-triazine preservative, and the anti-settling agent is a carbomer anti-settling agent.
The invention also provides a method for preparing the aqueous environment-friendly modified asphalt waterproof coating liquid coiled material, which comprises the following steps of adding ① polymer composite latex, starting a stirrer, stirring at the rotation speed of 200-.
In conclusion, the invention has the following beneficial effects:
firstly, the emulsified asphalt adopted by the invention is a stable emulsion formed by adding an anionic or cationic emulsifier and a stabilizer into water as a medium to prepare a soap solution and then dispersing hot asphalt in the soap solution in a high-speed shearing manner; the medium is water, and no organic solvent is used, so that the method has great advantages in the aspects of environmental protection and price. Meanwhile, the method has the advantages of low market cost, simple method, energy conservation and long-term storage.
Secondly, the invention adopts the polymer composite latex to carry out composite modification on the emulsified asphalt, thereby improving the performances of the emulsified asphalt in the aspects of tensile strength, elongation, bonding strength, high and low temperature resistance, weather resistance and the like.
And thirdly, the aqueous environment-friendly modified asphalt waterproof coating liquid coiled material is in a liquid state, can be used in a brush coating mode, a roller rolling coating mode or a spray gun spraying mode during construction, can reduce the labor intensity of constructors, and improves the construction efficiency. The spraying, brushing or rolling coating is an integral construction integral film forming, and can avoid the later stage water leakage phenomenon caused by the seam overlapping problem of the traditional coiled material.
Fourthly, emulsified asphalt is used as a main base material, and the appearance of the film formed by the emulsified asphalt is as black and bright as that of an asphalt coiled material; the high-low temperature resistance of the water-based environment-friendly modified asphalt waterproof coating liquid coiled material after being dried and formed into a film is superior to that of the traditional asphalt coiled material by using a scheme of grafting and modifying polymer composite latex.
Detailed Description
Here, the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
In the description of the present invention, it should be noted that, unless otherwise explicitly stated or limited, the terms "mounted," "disposed," "connected," and the like are to be construed broadly, and for example, "connected" may be fixedly, detachably, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases by those skilled in the art
The embodiment I provides a water-based environment-friendly modified asphalt waterproof coating liquid coiled material which comprises the following components in parts by weight: 30 parts of emulsified asphalt, 20 parts of high-molecular composite latex formed by grafting natural latex and styrene-butadiene emulsion, 20 parts of heavy calcium powder, 0.1 part of polyacrylic acid sodium salt, 0.2 part of mineral oil defoamer, 0.1 part of organic amine stabilizer, 5 parts of purified water, 0.2 part of acrylic acid associative thickener, 0.1 part of s-triazine preservative and 0.1 part of carbomer anti-settling agent.
The second embodiment is a water-based environment-friendly modified asphalt waterproof coating liquid coiled material, which comprises the following components in parts by weight: 50 parts of emulsified asphalt, 30 parts of high-molecular composite latex formed by grafting acrylic emulsion and butylbenzene emulsion, 25 parts of heavy calcium powder, 0.2 part of polyacrylic acid sodium salt, 0.5 part of mineral oil defoamer, 0.5 part of organic amine stabilizer, 20 parts of purified water, 0.5 part of acrylic acid associative thickener, 0.3 part of s-triazine preservative and 0.3 part of carbomer anti-settling agent.
The third embodiment is a water-based environment-friendly modified asphalt waterproof coating liquid coiled material, which comprises the following components in parts by weight: 40 parts of emulsified asphalt, 25 parts of high-molecular composite latex formed by grafting styrene-butadiene emulsion and chloroprene emulsion, 23 parts of quartz powder, 0.15 part of polyacrylic acid sodium salt, 0.3 part of mineral oil defoamer, 0.3 part of organic amine stabilizer, 12 parts of purified water, 0.3 part of acrylic acid associative thickener, 0.2 part of s-triazine preservative and 0.2 part of carbomer anti-settling agent.
The fourth embodiment of the invention provides a water-based environment-friendly modified asphalt waterproof coating liquid coiled material, which comprises the following components in parts by weight: 30 parts of emulsified asphalt, 30 parts of macromolecular composite latex formed by grafting acrylic emulsion and natural latex, 20 parts of quartz powder, 0.1 part of polyacrylic acid sodium salt, 0.2 part of mineral oil defoamer, 0.1 part of organic amine stabilizer, 5 parts of purified water, 0.2 part of acrylic acid associative thickener, 0.1 part of s-triazine preservative and 0.1 part of carbomer anti-settling agent.
Example five, a modified asphalt waterproofing paint liquid coiled material of waterborne environmental protection contains the following components by weight: 33 parts of emulsified asphalt, 26 parts of macromolecular composite latex formed by grafting acrylic emulsion and chloroprene emulsion, 24 parts of quartz powder, 0.2 part of polyacrylic acid sodium salt, 0.5 part of organic silicon defoamer, 0.4 part of organic amine stabilizer, 16 parts of purified water, 0.3 part of acrylic associative thickener, 0.1 part of s-triazine preservative and 0.1 part of carbomer anti-settling agent.
Embodiment six, a modified asphalt waterproofing paint liquid coiled material of waterborne environmental protection contains the following components by weight: 40 parts of emulsified asphalt, 25 parts of natural latex, 23 parts of heavy calcium powder, 0.15 part of sodium polyacrylate, 0.3 part of mineral oil defoamer, 0.3 part of organic amine stabilizer, 12 parts of purified water, 0.3 part of acrylic acid associative thickener, 0.2 part of s-triazine preservative and 0.2 part of carbomer anti-settling agent.
The seventh embodiment provides a water-based environment-friendly modified asphalt waterproof coating liquid coiled material, which comprises the following components in parts by weight: 35 parts of emulsified asphalt, 30 parts of styrene-acrylic emulsion, 23 parts of heavy calcium carbonate powder, 0.15 part of sodium polyacrylate, 0.3 part of mineral oil defoamer, 0.3 part of organic amine stabilizer, 12 parts of purified water, 0.3 part of acrylic acid associative thickener, 0.2 part of s-triazine preservative and 0.2 part of carbomer anti-settling agent.
Example eight, a modified asphalt waterproofing paint liquid coiled material of waterborne environmental protection contains the following components by weight: 38 parts of emulsified asphalt, 25 parts of neoprene emulsion, 23 parts of quartz powder, 0.15 part of polyacrylic acid sodium salt, 0.3 part of organic silicon defoamer, 0.3 part of organic amine stabilizer, 12 parts of purified water, 0.5 part of acrylic acid associative thickener, 0.2 part of s-triazine preservative and 0.2 part of carbomer anti-settling agent.
Ninth embodiment, a water-based environment-friendly modified asphalt waterproof coating liquid coiled material comprises the following components in parts by weight: 44 parts of emulsified asphalt, 25 parts of acrylic emulsion, 23 parts of heavy calcium powder, 0.2 part of sodium polyacrylate, 0.3 part of mineral oil defoamer, 0.3 part of organic amine stabilizer, 12 parts of purified water, 0.5 part of acrylic acid associative thickener, 0.2 part of s-triazine preservative and 0.3 part of carbomer anti-settling agent.
The embodiment ten provides a preparation method of a water-based environment-friendly modified asphalt waterproof coating liquid coiled material, which comprises the following steps of firstly adding raw materials for polymer composite latex into ①, starting a stirrer, stirring at a rotation speed of 200 plus 300r/min, emulsifying, then sequentially adding a dispersing agent, an antifoaming agent and a stabilizing agent, keeping stirring for 5 minutes, after ② stirring is uniform, adding powder at a constant speed, checking the vortex condition of the stirrer when adding the powder, increasing the rotation speed to 250 plus 400r/min, after the powder is completely added, starting a wall scraping auxiliary machine, increasing the rotation speed to 300 plus 500r/min, dispersing at a high speed for 30-50 minutes, observing the material, stirring until the material is fine and particles are absent, adding emulsified asphalt into ③, stirring at a low speed of 200 plus 300r/min for 5 minutes, adding purified water into ④, stirring uniformly, slowly adding a thickening agent diluted with water, increasing the rotation speed to 300 plus 400r/min, continuously stirring for 15 minutes, adding a preservative and an anti-settling agent into ⑤ in sequence, stirring at a low speed of 300 plus 300r/min for 5 minutes, detecting ⑥, and packaging.
It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in the embodiments without departing from the principles and spirit of the invention, and the scope of the invention is to be accorded the broadest interpretation so as to encompass all such modifications and alterations as is within the broadest scope of the claims set forth herein.

Claims (9)

1. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material is characterized by comprising the following components in parts by weight: 30-50 parts of emulsified asphalt, 20-30 parts of polymer composite latex, 20-25 parts of powder, 0.1-0.2 part of dispersing agent, 0.2-0.5 part of defoaming agent, 0.1-0.5 part of stabilizing agent, 5-20 parts of purified water, 0.2-0.5 part of thickening agent, 0.1-0.3 part of preservative and 0.1-0.3 part of anti-settling agent.
2. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, is characterized by comprising the following components in parts by weight: 30 parts of emulsified asphalt, 30 parts of polymer composite latex, 20 parts of powder, 0.1 part of dispersant, 0.2 part of defoamer, 0.1 part of stabilizer, 5 parts of purified water, 0.2 part of thickener, 0.1 part of preservative and 0.1 part of anti-settling agent.
3. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, wherein: the emulsified asphalt is anionic or cationic emulsified asphalt.
4. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, wherein: the high-molecular composite latex comprises one or two of natural latex, acrylic emulsion, styrene-butadiene emulsion and chloroprene emulsion.
5. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, wherein: the powder material is 800-mesh coarse whiting powder or quartz powder.
6. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, wherein: the dispersing agent is sodium polyacrylate, and the defoaming agent is mineral oil or an organic silicon defoaming agent.
7. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, wherein: the stabilizer is an organic amine stabilizer, and the thickener is an acrylic acid associative thickener.
8. The water-based environment-friendly modified asphalt waterproof coating liquid coiled material as claimed in claim 1, wherein: the preservative is an s-triazine preservative, and the anti-settling agent is a carbomer anti-settling agent.
9. A production method of the aqueous environment-friendly modified asphalt waterproof coating liquid coiled material is characterized by comprising the following steps of ①, firstly adding the polymer composite latex, starting a stirrer, stirring at the rotation speed of 200-.
CN202010006279.XA 2020-01-03 2020-01-03 Water-based environment-friendly modified asphalt waterproof coating liquid coiled material and production method thereof Pending CN111205770A (en)

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CN112521858A (en) * 2020-12-09 2021-03-19 河北宇阳泽丽防水材料有限公司 Modified asphalt liquid waterproof coiled material and preparation method thereof
CN112852298A (en) * 2021-01-14 2021-05-28 陈涛 In-situ prepared modified liquid emulsified asphalt waterproof material, use method and waterproof coating
CN114369397A (en) * 2021-12-23 2022-04-19 广东腐蚀科学与技术创新研究院 Water-based asphalt waterproof liquid coiled material for roof seepage prevention and leakage repair and production process thereof
CN114591640A (en) * 2022-03-15 2022-06-07 厦门防水博士新材料有限公司 Emulsified asphalt double-film-forming liquid waterproof coiled material and preparation method thereof
CN114621678A (en) * 2022-03-29 2022-06-14 山东锦绣防水科技有限公司 Liquid coiled material waterproof paint and preparation method thereof
CN114874669A (en) * 2021-12-31 2022-08-09 东方雨虹民用建材有限责任公司 Energy-saving heat-preserving polymer modified asphalt waterproof coating and preparation method thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521858A (en) * 2020-12-09 2021-03-19 河北宇阳泽丽防水材料有限公司 Modified asphalt liquid waterproof coiled material and preparation method thereof
CN112852298A (en) * 2021-01-14 2021-05-28 陈涛 In-situ prepared modified liquid emulsified asphalt waterproof material, use method and waterproof coating
CN114369397A (en) * 2021-12-23 2022-04-19 广东腐蚀科学与技术创新研究院 Water-based asphalt waterproof liquid coiled material for roof seepage prevention and leakage repair and production process thereof
CN114874669A (en) * 2021-12-31 2022-08-09 东方雨虹民用建材有限责任公司 Energy-saving heat-preserving polymer modified asphalt waterproof coating and preparation method thereof
CN114591640A (en) * 2022-03-15 2022-06-07 厦门防水博士新材料有限公司 Emulsified asphalt double-film-forming liquid waterproof coiled material and preparation method thereof
CN114621678A (en) * 2022-03-29 2022-06-14 山东锦绣防水科技有限公司 Liquid coiled material waterproof paint and preparation method thereof
CN114958097A (en) * 2022-07-18 2022-08-30 吉士达建设集团有限公司 High-molecular permeable waterproof coating
CN116535974A (en) * 2023-05-11 2023-08-04 湖南神宇新材料有限公司 Rubber waterproof coating and preparation method and application thereof

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