CN106223569A - A kind of composite floor board - Google Patents
A kind of composite floor board Download PDFInfo
- Publication number
- CN106223569A CN106223569A CN201610415402.7A CN201610415402A CN106223569A CN 106223569 A CN106223569 A CN 106223569A CN 201610415402 A CN201610415402 A CN 201610415402A CN 106223569 A CN106223569 A CN 106223569A
- Authority
- CN
- China
- Prior art keywords
- parts
- composite
- backing material
- functional layer
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
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- B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
- B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
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- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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- B29C48/92—Measuring, controlling or regulating
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- B32B21/02—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
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Abstract
The invention provides a kind of composite board, including the upper surface functional layer of backing material plate and the upper surface being covered in described backing material plate.The composite board that the present invention provides can select suitable upper surface functional layer according to the actual requirements, both can economize on resources, and have again higher functional and practicality.
Description
Technical field
The invention belongs to building material field, particularly to a kind of composite board.
Background technology
At present, Traditional Wood floor mostly is solid floor, and the use of solid wood floor can consume a large amount of timber, causes ring
Border is destroyed, and the cost on floor also remains high.Therefore, the succedaneum seeking existing solid wooden floor board is very
It is necessary.
Polrvinyl chloride (PVC), as one of general-purpose plastics being most widely used, is applied to Building wood for a long time
Material field, such as sheet material or tubing.In sheet material field, conventional PVC board includes hard PVC and soft
PVC, both plasticizer loading is different, thus causes both character the most different, the former plasticizer loading
Less than 10%, and the plasticizer loading of the latter is 30~70%.
Plasticizer is the industrial macromolecular material auxiliary agent being widely used, and adds this material in plastic processing, can
So that its pliability strengthens, it is easy to processing.From the point of view of plasticizer chemically textural classification, generally comprise aliphatic dibasic acid
The many esters of gallic acid of esters, Phthalates, benzene, benzoates, polyhydric alcohol esters, chlorinated hydrocarbons, epoxies,
Citric acid ester type, polyesters etc. are multiple.Wherein, the most frequently used plasticizer is phthalate or phthalic acid
Salt, such as phthalic acid two (2-ethyl hexyl) ester (DEHP), dibutyl phthalate (DBP) etc..
Plasticizer has certain toxicity to human body, and along with long-term use can slowly escape, to people from PVC material
Body health impacts.Owing to the plasticizer loading in hard PVC is less, its for flexible PVC more
Health environment-friendly, can be as indoor decoration board life-time service.
Hard PVC sheet material also have high fire-retardance, do not absorb water, the feature such as repeatable utilization, therefore in building materials field,
Especially sheet material field, has a wide range of applications.But traditional hard PVC there is also obvious shortcoming, such as hardness
Height, it is as sheet material, and especially during floor, sense of touch comfort level is not enough.Additionally, traditional hard PVC color is single,
Poor visual effect.These shortcomings make traditional hard PVC cannot meet people to want for comfort level and visual effect
Ask, the building materials market being applied to low side that therefore can only be more.It addition, traditional PVC board is considered adding man-hour
Its aesthetic property and practicality, generally require at its finish coatings, so that japanning is bonded in PVC board securely
Surface, needs to increase before painting the link of adherence, and the most first one layer of brush is respectively provided with preferable adhesion with PVC and japanning
Adhesive agent, this make tradition PVC board processing complex.
Summary of the invention
Because the drawbacks described above of prior art, it is an object of the invention to provide a kind of relative healths environmental protection, sense of touch
Comfortable, the composite board of visual appearance.The composite board of the present invention can also be according to the actual requirements to its surface at
Reason, to reach higher functional and practicality.
The technical solution adopted in the present invention is: a kind of composite board, including backing material plate and be covered in described backing material plate
The upper surface functional layer of upper surface.
Preferably, the component of described backing material plate includes stone powder or wood flour, and plastics.
Preferably, in described backing material plate, plasticizer loading is less than 10% or not plasticizer-containing.
Preferably, described plastics are PVC.
Preferably, the composition by weight of described backing material plate includes: PVC100 part, stone powder or wood flour 210~270 parts.
Preferably, described backing material plate is formed by following ingredients by weight: PVC 100 parts, stone powder or wood flour 210~270
Part, stabilizer 2~6 parts, stearic acid 0.2~0.8 part, PE wax 0.2~0.8 part, chlorinated polyethylene 1~5 parts, ACR
Modifying agent 0.5~2 parts, titanium dioxide 1~5 parts, OB-1 brightening agent 0.01~0.05 part.
Preferably, described backing material plate is formed by following ingredients by weight: PVC 100 parts, stone powder or wood flour 240
Part, stabilizer 4 parts, stearic acid 0.5 part, 0.5 part of PE wax, chlorinated polyethylene 3 parts, ACR modifying agent 1 part,
Titanium dioxide 3 parts, 0.03 part of OB-1 brightening agent.
Preferably, the composition by weight of described backing material plate includes: PVC100 part, perlite 50~80 parts, stone powder
Or wood flour 210~270 parts.
Preferably, described backing material plate is formed by following ingredients by weight: PVC 100 parts, perlite 50~80 parts,
Stone powder or wood flour 160~190 parts, stabilizer 2~6 parts, stearic acid 0.2~0.8 part, PE wax 0.2~0.8 part, chlorination
Polyethylene 1~5 parts, ACR modifying agent 0.5~2 parts, titanium dioxide 1~5 parts, OB-1 brightening agent 0.01~0.05 part.
Preferably, described backing material plate is formed by following ingredients by weight: PVC 100 parts, perlite 65 parts, stone
Powder or wood flour 175 parts, stabilizer 4 parts, stearic acid 0.5 part, 0.5 part of PE wax, chlorinated polyethylene 5 parts, ACR
Modifying agent 1 part, titanium dioxide 3 parts, 0.03 part of OB-1 brightening agent.
Preferably, described upper surface functional layer be veneer, bamboo-wood plyboard, calcium carbonate plate, calcium silicate board, plasterboard,
One in lucite, metallic plate, plastic plate, cystosepiment.
Preferably, the thickness of described backing material plate is 0.2~30mm, and the thickness of described upper surface functional layer is 0.1~15mm.
Preferably, the thickness of described backing material plate is 1~20mm, and the thickness of described upper surface functional layer is 0.5~5mm.
Preferably, described upper surface functional layer and substrate layer use adhesive bonding, and described adhesive is AB glue, ring
Epoxy resins adhesive, phenolic resin glue, polyurethane adhesive, SGA, PES polyester adhesive, PA polyamide glue, PE
Polyethylene glue, EVA ethylene-vinyl acetate copolymer glue, styrene and block copolymer hot melt adhesive stick, urea aldehyde
One or more in resin glue, pressure sensitive adhesive or alkyd ester gum.
Preferably, the preparation method of described composite board also includes: strengthen described upper surface function by the way of colding pressing
Bonding between layer and described substrate layer.
Preferably, cold pressing described in and carry out at normal temperatures.
Preferably, the pressure colded pressing described in is 8~12kg/cm2。
Preferably, the time colded pressing described in is 40~60min.
Preferably, described composite board also includes the paint film protective layer covering the upper surface in described upper surface functional layer.
Preferably, described paint film protective layer by by UV paint rolling applying or showering in the upper table of described upper surface functional layer
Face is formed.
Preferably, the thickness of described paint film protective layer is 0.08~0.25mm.
Preferably, the thickness of described paint film protective layer is 0.12~0.18mm.
Preferably, containing alumina particle or the particles of silicon carbide that particle diameter is 20~300 μm in described paint film protective layer.
Preferably, containing alumina particle or the particles of silicon carbide that particle diameter is 75~200 μm in described paint film protective layer.
Preferably, wherein said alumina particle or particles of silicon carbide are at least partially embedded described UV coating.
Preferably, the concrete preparation process of described paint film protective layer includes:
1) coating roller or coater is used to coat one layer of UV coating at the upper surface of described upper surface functional layer, as
Carry bisque;
2) in one layer of alumina particle of the uniform spreading of upper surface or the particles of silicon carbide of uncured UV coating, and use
UV light is irradiated, and carries bisque described in semi-solid preparation;
3) use coating roller or coater to be coated with one layer of described UV coating on the load bisque of described semi-solid preparation, make
For whiting layer, and UV light is used to be irradiated, to be fully cured described load bisque and described whiting layer.
Preferably, described composite board also includes the lower surface functional layer being covered in the lower surface of described backing material plate.
Preferably, described lower surface functional layer be plank, veneer, bamboo-wood plyboard, calcium carbonate plate, calcium silicate board,
One in plasterboard, lucite, metallic plate, plastic plate, cystosepiment.
Preferably, described plank or composite plate and substrate layer use the second adhesive bonding, described lower surface functional layer with
Substrate layer uses adhesive bonding, and described adhesive is AB glue, epoxyn, phenolic resin glue, poly-ammonia
Ester gum, SGA, PES polyester adhesive, PA polyamide glue, PE polyethylene glue, EVA ethylene-vinyl acetate are altogether
In polymers glue, styrene and block copolymer hot melt adhesive stick, urea-formaldehyde resin adhesive, pressure sensitive adhesive or alkyd ester gum
One or more.
Preferably, described composite board also includes the mucigel being covered in the lower surface of described lower surface functional layer.
Preferably, described mucigel is water soluble acrylic acid ester pressure-sensitive, waterborne polyurethane pressure-sensitive adhesives, solvent-borne type rubber
Pressure sensitive adhesive, solvent-type acrylic ester pressure-sensitive, emulsion-type rubber pressure sensitive glue, emulsion-type type acrylate pressure-sensitive adhesive or UV
One in glue.
Preferably, described UV glue is made up of the raw material of following mass percent:
Oligomer 30-50%, activated monomer 40-60%, light trigger 3-10%, auxiliary agent 1-10%;
Wherein, described oligomer be urethane acrylate, PBAA ester, epoxy acrylate, pure third
One or more in olefin(e) acid resin, polyester acrylate;
Described activated monomer is one or more in simple function group, difunctional, multi-functional acrylate;
Described light trigger is one or more in free radical photo-initiation.
Preferably, described UV glue is made up of the raw material of following mass percent:
Oligomer 40%, activated monomer 50%, light trigger 6%, auxiliary agent 5%.
Preferably, described monofunctional acrylates's ester is isobornyl methacrylate, isobornyl acrylate or 2 (2-
Ethoxy ethoxy) ethylacrylic acid;
Described bifunctional acrylate is tri (propylene glycol) diacrylate, 1.6-hexanediyl ester or three
Cyclodecane Dimethanol Diacrylate;
Described multi-functional acrylate's activated monomer is trimethylolpropane trimethacrylate, trimethylolpropane tris third
One or more in olefin(e) acid ester, pentaerythritol triacrylate, dipentaerythritol acrylate.
Preferably, the one during described auxiliary agent is adhesion promoter, defoamer, levelling agent, wetting agent, antioxidant
Or it is several.
Preferably, described adhesion promoter is that silane coupler Y-forms water glycerin ether oxygen propyl trimethoxy silicane, Y-
Aminopropyl triethoxysilane, Y-methacryloxypropyl trimethoxy silane, Y-methacryloxypropyl
Triethoxysilane, N-(B-aminoethyl)-Y-aminopropyl trimethoxysilane and acrylate phosphate 2-hydroxyl second
One or more in methyl acrylate phosphate ester, methacrylic acid phosphoric acid ester;
Described defoamer is silicone defoamer;
Described levelling agent is silicone levelling agent;
Described wetting agent is modified polydimethylsiloxane;
Described antioxidant is Hinered phenols antioxidant.
Preferably, described auxiliary agent is Macrogol 2000.
Preferably, described light trigger be 2 hydroxy-2-methyl-1-phenyl-1-acetone, 1-hydroxy-cyciohexyl benzophenone, 2,
4,6-trimethylbenzoy-dipheny phosphine oxides, double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide, 2,
4,6-tri-methyl benzophenones, 4-methyl benzophenone, 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone
In one or more.
Preferably, have snap close on described backing material plate or on composite board, upper surface functional layer has chamfering.
Preferably, the preparation method of described composite board also includes: strengthen described upper and lower surface by the way of hot pressing
Bonding between functional layer and described substrate layer.
Preferably, one layer of mould release membrance is also included below described mucigel.
The composite board that the present invention provides can select suitable upper surface functional layer according to the actual requirements, both can save
Resource, has again higher functional and practicality.
Detailed description of the invention
Composite board provided by the present invention includes backing material plate and is covered in the upper surface function of upper surface of described backing material plate
Layer.
The upper surface functional layer being covered in substrate sheet surface can be according to sheet material sense of touch, visual effect and functional effect etc.
Actual demand selects.Such as, in order to reach sense of touch and the visual effect of natural stype, can be selected for veneer or bamboo wood
The sheet material that composite plate etc. are made up of natural material.In order to reach hale and hearty and ice-cold sense of touch and the glossiness visual effect of richness,
Can be selected for the sheet metals such as corrosion resistant plate, aluminium alloy plate, titanium alloy sheet.In order to reach soft and gentle sense of touch or slow
The functional effects such as punching, insulation, can be selected for cystosepiment.In order to reach the functional effect such as high-strength light, fire-proof and thermal-insulation, can
Select calcium carbonate plate, calcium silicate board or plasterboard.For the effect that certain is special, it is also possible to select poly (methyl methacrylate) plate.
The sense of touch harder in order to improve hard PVC, can be selected for plastics, such as flexible PVC sheet material, although also contains soft
Matter PVC, but use flexible PVC sheet material to want environment protection health than simple.Visible, the lagging layer of the present invention is positioned at sheet material
Surface, it is provided that sense of touch, visual effect and the functional effect needed for sheet material, and flexible and changeable, be adaptable to difference
Demand.Particularly when select material costly, such as select metallic plate time, use cheap rigid PVC substrate
Substitute pure metallic plate and can not only be substantially reduced cost and the weight of sheet material, moreover it is possible to keep the sense of touch of sheet metal and regard
Feel effect.
Can be combined by adhesive between backing material plate and upper surface functional layer, adhesive is to be applicable to hard PVC
Polymer adhesive, such as AB glue, epoxyn or urea-formaldehyde resin adhesive etc..When selecting adhesive, principle
On should select, with base material and lagging layer, all there is the adhesive of stronger adhesion.Such as conventional acrylic acid, epoxy or
Polyurethanes AB glue has the wide suitability, can be used for plastics and plastics, plastics and metal, metal and metal
Between combination.Polyurethane tackifier, it is adaptable to PVC, TPR, rubber, nylon cloth, ABS, synthetic
The PU cooperation materials such as leather bonding.
In addition to the simple combination using above-mentioned adhesive, applicants have unexpectedly found that, it is also possible to be additionally aided with hot pressing or
The mode colded pressing so that the combination between backing material plate and upper surface functional layer is the most firm.It addition, when the upper table selected
When surface function layer is some material, even can not be combined by adhesive between backing material plate and upper surface functional layer,
But combined by the mode such as co-extrusion or hot pressing.Such as, when upper surface functional layer selects flexible PVC plate, can not
Binding agent is used only to use the mode of hot pressing or co-extrusion to be combined.In this case, bi-material is at interface
Place due to heat fusing partial fusion together, its sticking effect condition control proper time even better than use binding agent.
Upper surface functional layer is covered in the surface of backing material plate by the sheet material of the present invention, relative to the table of traditional PVC board
For the processing of face, the link of adherence can be saved.This is because PVC is generally to face finish material (such as paint)
Associativity is poor, in order to avoid coming off of face finish material, it usually needs increased adherence before carrying out surface modification
Link.And the sheet material of the present invention covers upper surface functional layer on the surface of PVC, thus surface is modified and transfers to
On upper surface functional layer, and the material of upper surface functional layer is generally preferable to the associativity of face finish material, it is not necessary to
Carry out adherence, thus eliminate the adherence link of tradition PVC board.
The composite board of the present invention in addition to including backing material plate and upper surface functional layer, can wrap further below at backing material plate
Including lower surface functional layer and other layer, such as bed course or mucigel, bed course fits in backing material plate or lower surface functional layer
Lower surface.Especially when the sheet material of the present invention uses as floor, bed course can provide more comfortable feel, more quiet
The effect of sound and the compatibility of more preferable ground.
For the ease of the installation of sheet material of the present invention, the edge of backing material plate can have the snap close being easy between sheet material connect.Lock
Button can use form commonly used in the art, such as patent WO2015118451A1, CN102051973A,
Various snap closes disclosed in CN103932510A, CN104619936A, CN104854286A, US9193137B2
Form.
In order to further enhance the sense of touch of sheet material of the present invention, visual effect or functional, can upper in upper surface functional layer
Surface is further processed, such as, carry out brush wear resistant paint process so that the sheet material of the present invention has widely function
Property, meet the demand of user individual customization.
Below in conjunction with specific embodiments, the present invention is more clearly described.
Embodiment 1
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is veneer functional layer.
(1) preparation of PVC base plate
PVC base plate is formed by following ingredients by weight: PVC 100 parts, wood flour 240 parts, stabilizer 4 parts,
Stearic acid 0.5 part, 0.5 part of PE wax, chlorinated polyethylene 3 parts, ACR modifying agent 1 part, titanium dioxide 3 parts, OB-1
0.03 part of brightening agent.Wherein, PVC, stabilizer, stearic acid, PE wax, chlorinated polyethylene, ACR modifying agent,
Titanium dioxide, OB-1 brightening agent are all regular industrial raw material.The granular size of wood flour is 0.1~2mm, the wood of various timber
All can consider to be worth doing, preferably white oak wood flour.
The expressing technique step of the PVC base plate of the present embodiment is: stirred at 40 DEG C by the raw material of said ratio all
Even mixing;After having stirred, transfer the material in plastic extruding molding machine and be heated to 150-160 DEG C, wanting according to processing
The thickness asked adjusts the size of roll gap.Head is met to be extruded into single-layer slab by narrow after the fully plasticizing of screw rod.Again by
Can trimming rolling molding after the cooling further of the deflector roll of a segment distance after three-roller calendar cooling sizing.
The thickness of the backing material plate that the present embodiment prepares can adjust according to the actual requirements, and the backing material plate generally as floor is permissible
Adjusting thickness is 0.2~30mm, and thickness more often is 1~20mm.
The shore hardness D of backing material plate that the present embodiment prepares up to about 70, hot rolling song as little as ± 1.2mm, absorb water matter
Amount change as little as ± 0.5%, water boiling resistance 5 grades.
The backing material plate not plasticizer-containing that the present embodiment prepares, beneficially environmental protection and the needs of health, according to this enforcement
Example disclosure, in order to reduce the hardness of backing material plate, increases and tramples comfort, and those skilled in the art can also root
According to being actually needed the plasticizer adding certain content, the weight/mass percentage composition of plasticizer is no more than 10%.
(2) patch veneer functional layer
Veneer functional layer select white oak skin, as floor, veneer functional layer thickness be 0.1~2.0mm all can, more often
Be 0.5~5mm.Adhesive selects conventional polyurethanes PUR.Concrete manufacture method comprises the following steps:
A) upper surface of PVC base plate is cleared up, the lower surface of veneer functional layer is cleared up;
The upper surface of the PVC base plate b) cleared up in step a uniformly coats polyurethane hot melt;
C) lower surface of veneer functional layer and the upper surface of PVC base plate are fit together;
D) the above-mentioned PVC base plate fit together and veneer functional layer are placed on cold press cold pressing 40~60 minutes.
(3) other processes
Those skilled in the art can carry out other process according to being specifically actually needed to the composite board in this embodiment,
For example, it is possible to opening lock catch (is such as referred to Application No. 201380055155.9, denomination of invention on PVC base plate
Method opening lock catch for disclosing in the Chinese patent application of " composite water-proof floor and wall cover plate ").Can also be at upper surface
Chamfering is opened in functional layer.
The upper surface of veneer functional layer can also further be modified by those skilled in the art, such as mopping, with
Meet sheet material vision or the demand of function.
Composite board prepared by this embodiment uses the mode of PVC base plate patch veneer functional layer, has both saved wood
Material, can realize again the effect equal with solid wooden floor board.Because veneer itself is preferable, therefore for the adhesion property of paint
Process without the surface of rigid PVC substrate being carried out extra adherence as tradition PVC board.
As the deformation of this specific embodiment, veneer functional layer can also use bamboo-wood plyboard.Veneer functional layer also may be used
To be replaced by metallic plate or cystosepiment, the raw material of PVC base plate does not use wood flour.If employing metallic plate, for
Increase the comfort level trampled, can be properly added the plasticizer of certain content;If employing cystosepiment, then need not
Add plasticizer.
Embodiment 2
Composite board in this specific embodiment include backing material plate, the upper surface functional layer being covered in the upper surface of backing material plate,
Covering uses adhesive bonding at the paint film protective layer of the upper surface of upper surface functional layer, upper surface functional layer and substrate layer,
Paint film protective layer is by being formed UV paint rolling applying in the upper surface of upper surface functional layer.Wherein, backing material plate is PVC
Backing material plate, upper surface functional layer is veneer functional layer, and the Main Function of paint film protective layer is to strengthen anti-wear performance.
(1) preparation of PVC base plate
Making step is same as in Example 1.
(2) patch veneer functional layer
Making step is same as in Example 1.
(3) coating paint film protective layer
Paint film protective layer includes wear-resisting load bisque, wear-resisting whiting layer, alumina particle.
The raw material of wear-resisting load bisque includes: amino acrylic resin 70%, auxiliary agent 0.1%, diluent acrylate 5%,
Implant 15%, light trigger alpha-alcohol ketone more than 0.01% numerical value is all weight percentage, and wherein auxiliary agent includes levelling
Agent, defoamer, adhesive agent, wetting agent, inhibitor.Above raw material is all industry convenient source.
The raw material of wear-resisting whiting layer includes: polyoxyalkylene acrylate resin 60%, auxiliary agent 0.4%, diluent polyacrylic acid
Ester 20%, implant 19.5% and light trigger amino ketones 0.1%, wherein auxiliary agent includes levelling agent, defoamer, close
Agent, wetting agent, inhibitor.Above raw material is all industry convenient source.
The mean diameter of alumina particle be 20~300 μm all can, more preferably 75~200 μm.
The technique of coating paint film protective layer is:
A) epoxy acrylic resin is heated in 60~120 DEG C of temperature ranges liquid, pours in Scattered Kettle;
B) the liquid epoxy acrylic resin obtained in step a) is sequentially added into light trigger reactive amines, dilute
Release agent acrylate and auxiliary agent, in 20~40r/s at the uniform velocity lower stirrings until uniformly, obtaining wear-resisting load bisque coating;
C) use coating roller by the wear-resisting load bisque paint spraying obtained in step b) to step 2) plate prepared
The upper surface of the veneer functional layer of material, obtains wear-resisting load bisque, and during roller coating, the speed of conveyer belt is set to
5-20m/min;
D) abrasion-resistant powder aluminium oxide is uniformly spread the surface to the most dry wear-resisting load bisque, and further heating so that oxygen
Change aluminum portions ground and sink into wear-resisting load bisque;
E) using the uviol lamp coating to obtaining in step d) to carry out solidification to be dried, the parameter that solidification is dried is arranged
For: the speed of conveyer belt is 5-20m/min;The height of uviol lamp distance conveyer belt is 10-35cm;
F) on abrasion-resistant powder, wear-resisting whiting coating is covered by roller coating again;Use uviol lamp that wear-resisting whiting layer is entered
Row solidification is dried, and the parameter that solidification is dried is set to: the speed of conveyer belt is 5-20m/min;Uviol lamp distance passes
The height sending band is 10-35cm.
In this embodiment, the thickness of paint film protective layer can control 0.08~0.25mm as required, more preferably
Ground, controls 0.12~0.18mm.
Compared with Example 1, its wearing coefficient of the wearing layer in the present embodiment increases, and wear-resisting effect significantly increases
Add:
Test according to ASTM D 4060 and GB/T 15036.1-200 standard, use TABLE abrasion
Instrument is tested:
Embodiment 1 preparation meet floor: S-33 emery cloth strip, standard≤0.08g/100r;1000 go round and round a millstone the standard of wearing;
Composite floor board prepared by the present embodiment: S-33 emery cloth strip, standard≤0.08g/100r;2000 go round and round a millstone the standard of wearing.
(4) other processes
Those skilled in the art can carry out other process according to being specifically actually needed to the composite board in this embodiment,
For example, it is possible to opening lock catch (is such as referred to Application No. 201380055155.9, denomination of invention on PVC base plate
Method opening lock catch for disclosing in the Chinese patent application of " composite water-proof floor and wall cover plate "), it is also possible at upper surface
Chamfering is opened in functional layer.
As the deformation of this specific embodiment, alumina particle can also substitute by particles of silicon carbide.
Embodiment 3
Composite board in this specific embodiment include backing material plate, the upper surface functional layer being covered in the upper surface of backing material plate,
Cover upper surface functional layer upper surface paint film protective layer, be covered in the lower surface of backing material plate lower surface functional layer,
It is covered in the mucigel of the lower surface of lower surface functional layer, upper surface functional layer and lower surface functional layer to use with substrate layer
Adhesive bonds, and paint film protective layer is by being formed UV paint rolling applying in the upper surface of upper surface functional layer.Wherein,
Backing material plate is PVC base plate, and upper surface functional layer and lower surface functional layer are veneer functional layer, the master of paint film protective layer
Act on is to strengthen anti-wear performance.
(1) preparation of PVC base plate
Making step is same as in Example 1.
(2) surface veneer functional layer and lower surface plank functional layer are sticked
Making step is same as in Example 1.
(3) coating paint film protective layer
Making step is same as in Example 2.
(4) patch mucigel
Mucigel mainly uses UV pressure sensitive adhesive, and it concretely comprises the following steps:
A) lower surface of lower surface veneer functional layer is cleared up, it is ensured that gluing material surface is totally dried;
B) UV pressure-sensitive glue is coated with or silk-screen is at the lower surface of lower surface veneer functional layer, it is ensured that glue-line uniform bubble-free,
Gluing thickness 0.1~about 1mm;More preferably 0.15~about 0.5mm.
C) mould release membrance, then photocuring, photocuring energy: 1500mj/cm are covered in the glue surface being coated with or silk-screen is good2,
Hardening time can be according to environmental difference from Row sum-equal matrix.
Composite board in this specific embodiment, in addition to providing upper surface veneer functional layer, additionally provides lower surface plank
Functional layer, because lower surface plank functional layer is also bonded in PVC base plate with adhesive, so can improve and trample
Comfort.The plank that lower surface functional layer is used can be made by various timber, because not being user finding, right
The exterior quality no requirement (NR) of plank.The plank using quality softer can further improve the comfort trampled.Following table
The plank that surface function layer is used can also replace by various composite plates.Lower surface functional layer can also directly use gluing
Agent (such as UV glue), no longer pastes other functional layer.
Use the composite board of mucigel when mounted can greatly convenient construction, have only to mucigel during construction
The mould release membrance of lower surface is torn, and then composite floor board is placed directly against ground.In this specific embodiment, viscose
Laminating is at the lower surface of lower surface functional layer.Deformation as this specific embodiment, it is also possible to do not use lower surface function
Layer, is directly attached to the lower surface of PVC base plate by mucigel.
As the deformation of this specific embodiment, UV pressure sensitive adhesive can also replace with water-borne pressure sensitive adhesive or emulsion-type pressure sensitive adhesive.
When using water-borne pressure sensitive adhesive or emulsion-type pressure sensitive adhesive, during preparation, need not photocuring step.
Embodiment 4
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is calcium silicate board.
(1) preparation of PVC base plate
PVC base plate is formed by following ingredients by weight: PVC 100 parts, stone powder 240 parts, stabilizer 4 parts,
Stearic acid 0.5 part, 0.5 part of PE wax, chlorinated polyethylene 3 parts, ACR modifying agent 1 part, titanium dioxide 3 parts, OB-1
0.03 part of brightening agent.Wherein, PVC, stabilizer, stearic acid, PE wax, chlorinated polyethylene, ACR modifying agent,
Titanium dioxide, OB-1 brightening agent are all regular industrial raw material.The granular size of stone powder is 0.01~0.5mm, various conventional
Industrial stone powder all can, preferably Paris white.
The expressing technique step of the PVC base plate of the present embodiment is: stirred at 40 DEG C by the raw material of said ratio all
Even mixing;After having stirred, transfer the material in plastic extruding molding machine and be heated to 150-160 DEG C, wanting according to processing
The thickness asked adjusts the size of roll gap.Head is met to be extruded into single-layer slab by narrow after the fully plasticizing of screw rod.Again by
Can trimming rolling molding after the cooling further of the deflector roll of a segment distance after three-roller calendar cooling sizing.
The thickness of the backing material plate that the present embodiment prepares can adjust according to the actual requirements, and the backing material plate generally as floor is permissible
Adjusting thickness is 0.2~30mm, and thickness more often is 1~20mm.
The shore hardness D of backing material plate that the present embodiment prepares up to about 83, hot rolling song as little as ± 1.4mm, absorb water matter
Amount change as little as ± 0.5%, water boiling resistance 5 grades.
The backing material plate not plasticizer-containing that the present embodiment prepares, beneficially environmental protection and the needs of health, according to this enforcement
Example disclosure, in order to reduce the hardness of backing material plate, increases and tramples comfort, and those skilled in the art can also root
According to being actually needed the plasticizer adding certain content, the weight/mass percentage composition of plasticizer is no more than 10%.
(2) patch calcium silicate board
As floor, calcium silicate board thickness be 0.1~2.0mm all can, more usually 0.5~5mm.Adhesive is selected
AB glue.The concrete manufacture method of employing AB glue is:
A) upper surface of PVC base plate is cleared up, the lower surface of calcium silicate board is cleared up;
The upper surface of the PVC base plate b) cleared up in step a uniformly coats one layer of A glue or B relatively, at silicon
The lower surface of acid calcium plate the most uniformly coats one layer of B glue or A glue;
C) lower surface of calcium silicate board and the upper surface of PVC base plate are fit together.
Above-mentioned steps b can also be first by A glue and B glue substantially equal-volume ground mix homogeneously, will be mixed within 3 minutes
A glue and B glue after conjunction are evenly applied to the upper surface of PVC base plate and/or the lower surface of calcium silicate board, then stand
I.e. carry out above-mentioned steps C.AB glue can also substitute with epoxyn.
(3) other processes
Those skilled in the art can carry out other process according to being specifically actually needed to the composite board in this embodiment,
For example, it is possible to opening lock catch (is such as referred to Application No. 201380055155.9, denomination of invention on PVC base plate
Method opening lock catch for disclosing in the Chinese patent application of " composite water-proof floor and wall cover plate "), it is also possible at upper surface
Chamfering is opened in functional layer.
The upper surface of calcium silicate board can also further be modified by those skilled in the art, such as mopping, with full
Foot is to sheet material vision or the demand of function.
Composite floor board prepared by this embodiment uses the mode of PVC base plate patch calcium silicate board, has both saved stone material,
The effect equal with rock land plate can be realized again.
As the deformation of this specific embodiment, calcium silicate board can also be replaced by calcium carbonate plate, plasterboard, organic glass
Glass.
Embodiment 5
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is flexible PVC plate.
(1) preparation of PVC base plate
PVC base plate is formed by following ingredients by weight: PVC 100 parts, stabilizer 4 parts, stearic acid 0.5
Part, 0.5 part of PE wax, chlorinated polyethylene 3 parts, ACR modifying agent 1 part, titanium dioxide 3 parts, OB-1 brightening agent 0.03
Part.Wherein, PVC, stabilizer, stearic acid, PE wax, chlorinated polyethylene, ACR modifying agent, titanium dioxide, OB-1
Brightening agent is all regular industrial raw material.
The expressing technique step of the PVC base plate of the present embodiment is: stirred at 40 DEG C by the raw material of said ratio all
Even mixing;After having stirred, transfer the material in plastic extruding molding machine and be heated to 150-160 DEG C, wanting according to processing
The thickness asked adjusts the size of roll gap.Head is met to be extruded into single-layer slab by narrow after the fully plasticizing of screw rod.Again by
Can trimming rolling molding after the cooling further of the deflector roll of a segment distance after three-roller calendar cooling sizing.
The thickness of the backing material plate that the present embodiment prepares can adjust according to the actual requirements, and the backing material plate generally as floor is permissible
Adjusting thickness is 0.2~30mm, and thickness more often is 1~20mm.
The shore hardness D of backing material plate that the present embodiment prepares up to about 83, hot rolling song as little as ± 0.8mm, absorb water matter
Amount change as little as ± 0.5%, water boiling resistance 5 grades.
The backing material plate not plasticizer-containing that the present embodiment prepares, beneficially environmental protection and the needs of health.
(2) preparation of flexible PVC plate
Flexible PVC plate, unlike the composition of PVC base plate, adds on the basis of the composition of PVC base plate
Mass percent is the plasticizer of 5%~10%, as floor, the thickness of flexible PVC plate be 0.1~2.0mm all can,
More usually 0.5~5mm.
(3) patch flexible PVC plate
Making step is identical with the technique pasting calcium silicate board in embodiment 4.
Alternatively, the flexible PVC plate in this embodiment also can not use adhesive, but directly by hard PVC base
Material plate and flexible PVC plate co-extrusion form double-decker.
(4) other processes
Those skilled in the art can carry out other process according to being specifically actually needed to the composite board in this embodiment,
For example, it is possible to opening lock catch (is such as referred to Application No. 201380055155.9, denomination of invention on PVC base plate
Method opening lock catch for disclosing in the Chinese patent application of " composite water-proof floor and wall cover plate "), in upper surface functional layer
On open chamfering.
The upper surface of calcium silicate board can also further be modified by those skilled in the art, such as mopping, with full
Foot is to sheet material vision or the demand of function.
The mixed binding of this embodiment hard PVC and the respective advantage of flexible PVC, hard PVC is that sheet material provides
Stronger intensity and less plasticizer loading, and flexible PVC compensate for, and hard PVC is hard, sense of touch is the best
Shortcoming.
Embodiment 6
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is poly (methyl methacrylate) plate.
(1) preparation of PVC base plate
Preparation method is same as in Example 1.
(2) patch poly (methyl methacrylate) plate
As floor, lucite plate thickness be 0.1~2.0mm all can, more usually 0.5~5mm.Adhesive is selected
Use SGA.Concrete manufacture method comprises the following steps:
A) upper surface of PVC base plate is cleared up, the lower surface of poly (methyl methacrylate) plate is cleared up;
The upper surface of the PVC base plate b) cleared up in step a uniformly coats SGA;
C) lower surface of poly (methyl methacrylate) plate and the upper surface of PVC base plate are fit together.
(3) other processes
Those skilled in the art can carry out other process according to being specifically actually needed to the composite board in this embodiment,
For example, it is possible to opening lock catch (is such as referred to Application No. 201380055155.9, denomination of invention on PVC base plate
Method opening lock catch for disclosing in the Chinese patent application of " composite water-proof floor and wall cover plate "), in upper surface functional layer
On open chamfering.
Embodiment 7
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is veneer functional layer.
(1) preparation of PVC base plate
Preparation method is same as in Example 1.
(2) patch veneer functional layer
Concrete steps are same as in Example 1.
(3) hot pressing
The sheet material that step (2) prepares is placed on hot press hot pressing 10~20 minutes, hot pressing temperature 60-80 DEG C, so
After from hot press take out cooling and shaping.
Applicants have unexpectedly found that, the composite board that composite board prepared by this embodiment is prepared relative to embodiment 1,
Upper surface functional layer has had beyond thought lifting with the bonding force of substrate layer.With reference to GB: GB/T6329-1996 glue
The mensuration of stick banjo fixing butt jointing hot strength;GB/T6328-1999 adhesive shearing impact Strength Testing Methods;
The mensuration (rigid material is to rigid material) of GB/T7124-2008 adhesive tensile shear strength, makes embodiment 1
Composite board prepared by standby composite board and the present embodiment carries out the test of hot strength, shear strength and peel strength,
Result shows, the hot strength of the composite floor board that composite floor board prepared by the present embodiment is prepared relative to embodiment 1, cuts
Shearing stress and peel strength have the lifting of more than 20%.
Embodiment 8
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is veneer functional layer.
(1) preparation of PVC base plate
PVC base plate is formed by following ingredients by weight: PVC 100 parts, wood flour 210 parts, stabilizer 2 parts,
Stearic acid 0.2 part, 0.2 part of PE wax, chlorinated polyethylene 1 part, ACR modifying agent 0.5 part, titanium dioxide 1 part, OB-1
0.01 part of brightening agent.Wherein, PVC, stabilizer, stearic acid, PE wax, chlorinated polyethylene, ACR modifying agent,
Titanium dioxide, OB-1 brightening agent are all regular industrial raw material.The granular size of wood flour is 0.1~2mm, the wood of various timber
All can consider to be worth doing, preferably white oak wood flour.
The expressing technique step of the PVC base plate of the present embodiment is: stirred at 40 DEG C by the raw material of said ratio all
Even mixing;After having stirred, transfer the material in plastic extruding molding machine and be heated to 150-160 DEG C, wanting according to processing
The thickness asked adjusts the size of roll gap.Head is met to be extruded into single-layer slab by narrow after the fully plasticizing of screw rod.Again by
Can trimming rolling molding after the cooling further of the deflector roll of a segment distance after three-roller calendar cooling sizing.
The thickness of the backing material plate that the present embodiment prepares can adjust according to the actual requirements, and the backing material plate generally as floor is permissible
Adjusting thickness is 0.2~30mm, and thickness more often is 1~20mm.
The shore hardness D of backing material plate that the present embodiment prepares up to about 73, hot rolling song as little as ± 0.5mm, absorb water matter
Amount change as little as ± 0.5%, water boiling resistance 5 grades.
The backing material plate not plasticizer-containing that the present embodiment prepares, beneficially environmental protection and the needs of health, according to this enforcement
Example disclosure, in order to reduce the hardness of backing material plate, increases and tramples comfort, and those skilled in the art can also root
According to being actually needed the plasticizer adding certain content, the weight/mass percentage composition of plasticizer is no more than 10%.
(2) patch veneer functional layer
Concrete steps are same as in Example 1.
The component of the PVC base plate of composite board prepared by the present embodiment is different with embodiment 1, in addition to PVC,
The content of other components is lower than embodiment 1, but the hardness of composite board of final preparation, hot rolling are bent, water suction quality becomes
Change, the performance of water boiling resistance similar to Example 1.
Embodiment 9
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is veneer functional layer.
(1) preparation of PVC base plate
PVC base plate is formed by following ingredients by weight: PVC 100 parts, wood flour 270 parts, stabilizer 6 parts,
Stearic acid 0.8 part, 0.8 part of PE wax, chlorinated polyethylene 5 parts, ACR modifying agent 2 parts, titanium dioxide 5 parts, OB-1
0.05 part of brightening agent.Wherein, PVC, stabilizer, stearic acid, PE wax, chlorinated polyethylene, ACR modifying agent,
Titanium dioxide, OB-1 brightening agent are all regular industrial raw material.The granular size of wood flour is 0.1~2mm, the wood of various timber
All can consider to be worth doing, preferably white oak wood flour.
The expressing technique step of the PVC base plate of the present embodiment is: stirred at 40 DEG C by the raw material of said ratio all
Even mixing;After having stirred, transfer the material in plastic extruding molding machine and be heated to 150-160 DEG C, wanting according to processing
The thickness asked adjusts the size of roll gap.Head is met to be extruded into single-layer slab by narrow after the fully plasticizing of screw rod.Again by
Can trimming rolling molding after the cooling further of the deflector roll of a segment distance after three-roller calendar cooling sizing.
The thickness of the backing material plate that the present embodiment prepares can adjust according to the actual requirements, and the backing material plate generally as floor is permissible
Adjusting thickness is 0.2~30mm, and thickness more often is 1~20mm.
The shore hardness D of backing material plate that the present embodiment prepares up to about 72, hot rolling song as little as ± 0.6mm, absorb water matter
Amount change as little as ± 0.5%, water boiling resistance 5 grades.
The backing material plate not plasticizer-containing that the present embodiment prepares, beneficially environmental protection and the needs of health, according to this enforcement
Example disclosure, in order to reduce the hardness of backing material plate, increases and tramples comfort, and those skilled in the art can also root
According to being actually needed the plasticizer adding certain content, the weight/mass percentage composition of plasticizer is no more than 10%.
(2) patch veneer functional layer
Concrete steps are same as in Example 1.
The component of the PVC base plate of composite board prepared by the present embodiment is different with embodiment 1, in addition to PVC,
The content of other components is higher than embodiment 1, but the hardness of composite board of final preparation, hot rolling are bent, water suction quality becomes
Change, the performance of water boiling resistance similar to Example 1.
Embodiment 10
Composite board in this specific embodiment includes backing material plate and is covered in the upper surface function of upper surface of backing material plate
Layer, upper surface functional layer and substrate layer employing adhesive bonding, wherein, backing material plate is PVC base plate, upper surface merit
Ergosphere is veneer functional layer.
(1) preparation of PVC base plate
PVC base plate is formed by following ingredients by weight: PVC 100 parts, perlite 65 parts, wood flour 175
Part, stabilizer 4 parts, stearic acid 0.5 part, 0.5 part of PE wax, chlorinated polyethylene 5 parts, ACR modifying agent 1 part,
Titanium dioxide 3 parts, 0.03 part of OB-1 brightening agent.Wherein, PVC, perlite, stabilizer, stearic acid, PE wax,
Chlorinated polyethylene, ACR modifying agent, titanium dioxide, OB-1 brightening agent are all regular industrial raw material.The granule of wood flour is big
Little is 0.1~2mm, the wood flour of various timber all can, preferably white oak wood flour.
The expressing technique step of the PVC base plate of the present embodiment is: stirred at 40 DEG C by the raw material of said ratio all
Even mixing;After having stirred, transfer the material in plastic extruding molding machine and be heated to 150-160 DEG C, wanting according to processing
The thickness asked adjusts the size of roll gap.Head is met to be extruded into single-layer slab by narrow after the fully plasticizing of screw rod.Again by
Can trimming rolling molding after the cooling further of the deflector roll of a segment distance after three-roller calendar cooling sizing.
The thickness of the backing material plate that the present embodiment prepares can adjust according to the actual requirements, and the backing material plate generally as floor is permissible
Adjusting thickness is 0.2~30mm, and thickness more often is 1~20mm.
The shore hardness D of backing material plate that the present embodiment prepares up to about 81, hot rolling song as little as ± 0.6mm, absorb water matter
Amount change as little as ± 0.4%, water boiling resistance 5 grades.
The backing material plate not plasticizer-containing that the present embodiment prepares, beneficially environmental protection and the needs of health, according to this enforcement
Example disclosure, in order to reduce the hardness of backing material plate, increases and tramples comfort, and those skilled in the art can also root
According to being actually needed the plasticizer adding certain content, the weight/mass percentage composition of plasticizer is no more than 10%.
(2) patch veneer functional layer
Concrete steps are same as in Example 1.
The component of the PVC base plate of composite board prepared by the present embodiment is different with embodiment 1, with the addition of part
Perlite, the hardness of composite board of final preparation, hot rolling are bent, the performance of water suction mass change is relative to embodiment 1
Promote.
The preferred embodiment of the present invention described in detail above.Should be appreciated that the ordinary skill of this area is without wound
The property made work just can make many modifications and variations according to the design of the present invention.Therefore, all technology in the art
Personnel can be obtained by logical analysis, reasoning or limited test the most on the basis of existing technology
The technical scheme arrived, all should be in the protection domain being defined in the patent claims.
Claims (41)
1. a composite board, it is characterised in that: include backing material plate and be covered in the upper table of upper surface of described backing material plate
Surface function layer.
Composite board the most according to claim 1, it is characterised in that: the component of described backing material plate include stone powder or
Wood flour, and plastics.
Composite board the most according to claim 2, it is characterised in that: in described backing material plate, plasticizer loading
Less than 10% or not plasticizer-containing.
Composite board the most according to claim 2, it is characterised in that: described plastics are PVC.
Composite board the most according to claim 4, it is characterised in that: the composition by weight bag of described backing material plate
Include: PVC100 part, stone powder or wood flour 210~270 parts.
Composite board the most according to claim 5, it is characterised in that: following by by weight of described backing material plate
Composition is formed: PVC 100 parts, stone powder or wood flour 210~270 parts, stabilizer 2~6 parts, stearic acid 0.2~0.8 part,
PE wax 0.2~0.8 part, chlorinated polyethylene 1~5 parts, ACR modifying agent 0.5~2 parts, titanium dioxide 1~5 parts, OB-1
Brightening agent 0.01~0.05 part.
Composite board the most according to claim 6, it is characterised in that: following by by weight of described backing material plate
Composition is formed: PVC 100 parts, stone powder or wood flour 240 parts, stabilizer 4 parts, stearic acid 0.5 part, PE wax 0.5
Part, chlorinated polyethylene 3 parts, ACR modifying agent 1 part, titanium dioxide 3 parts, 0.03 part of OB-1 brightening agent.
Composite board the most according to claim 4, it is characterised in that: the composition by weight bag of described backing material plate
Include: PVC100 part, perlite 50~80 parts, stone powder or wood flour 210~270 parts.
9. composite board as claimed in claim 8, it is characterised in that: described backing material plate is by following one-tenth by weight
Divide and formed: PVC 100 parts, perlite 50~80 parts, stone powder or wood flour 160~190 parts, stabilizer 2~6 parts, firmly
Fat acid 0.2~0.8 part, PE wax 0.2~0.8 part, chlorinated polyethylene 1~5 parts, ACR modifying agent 0.5~2 parts, titanium white
Powder 1~5 parts, OB-1 brightening agent 0.01~0.05 part.
10. composite board as claimed in claim 9, it is characterised in that: following by by weight of described backing material plate
Composition is formed: PVC 100 parts, perlite 65 parts, stone powder or wood flour 175 parts, stabilizer 4 parts, stearic acid 0.5
Part, 0.5 part of PE wax, chlorinated polyethylene 5 parts, ACR modifying agent 1 part, titanium dioxide 3 parts, OB-1 brightening agent 0.03
Part.
11. composite boards according to claim 1, it is characterised in that: described upper surface functional layer be veneer,
In bamboo-wood plyboard, calcium carbonate plate, calcium silicate board, plasterboard, lucite, metallic plate, plastic plate, cystosepiment
One.
12. composite boards according to claim 1, it is characterised in that: the thickness of described backing material plate is
0.2~30mm, the thickness of described upper surface functional layer is 0.1~15mm.
13. composite boards according to claim 12, it is characterised in that: the thickness of described backing material plate is 1~20mm,
The thickness of described upper surface functional layer is 0.5~5mm.
14. composite boards according to claim 1, it is characterised in that: described upper surface functional layer and substrate layer
Employing adhesive bond, described adhesive be AB glue, epoxyn, phenolic resin glue, polyurethane adhesive,
SGA, PES polyester adhesive, PA polyamide glue, PE polyethylene glue, EVA ethylene-vinyl acetate copolymer glue,
One or several in styrene and block copolymer hot melt adhesive stick, urea-formaldehyde resin adhesive, pressure sensitive adhesive or alkyd ester gum
Kind.
15. composite boards according to claim 14, it is characterised in that: the preparation method of described composite board is also
Including: by the way of colding pressing, strengthen the bonding between described upper surface functional layer and described substrate layer.
16. composite boards according to claim 15, it is characterised in that cold pressing described in: and carry out at normal temperatures.
17. composite boards according to claim 16, it is characterised in that the pressure colded pressing described in: exists
8~12kg/c.
18. composite boards according to claim 17, it is characterised in that the time colded pressing described in: is 40~60min.
19. composite board according to claim 1, it is characterised in that: described composite board also includes covering
The paint film protective layer of the upper surface of described upper surface functional layer.
20. composite boards according to claim 19, it is characterised in that: described paint film protective layer is by by UV
Paint rolling applying or showering are formed in the upper surface of described upper surface functional layer.
21. composite boards according to claim 20, it is characterised in that: the thickness of described paint film protective layer is
0.08~0.25mm.
22. composite board according to claim 21, it is characterised in that: the thickness of described paint film protective layer is
0.12~0.18mm.
23. composite boards according to claim 19, it is characterised in that: containing particle diameter in described paint film protective layer
It is alumina particle or the particles of silicon carbide of 20~300 μm.
24. composite boards according to claim 23, it is characterised in that: containing particle diameter in described paint film protective layer
It is alumina particle or the particles of silicon carbide of 75~200 μm.
25. composite boards as claimed in claim 24, it is characterised in that: wherein said alumina particle or corundum
Granule is at least partially embedded described UV coating.
26. composite boards as claimed in claim 25, it is characterised in that: described paint film protective layer specifically prepare step
Suddenly include:
1) coating roller or coater is used to coat one layer of UV coating at the upper surface of described upper surface functional layer, as
Carry bisque;
2) in one layer of alumina particle of the uniform spreading of upper surface or the particles of silicon carbide of uncured UV coating, and use
UV light is irradiated, and carries bisque described in semi-solid preparation;
3) use coating roller or coater to be coated with one layer of described UV coating on the load bisque of described semi-solid preparation, make
For whiting layer, and UV light is used to be irradiated, to be fully cured described load bisque and described whiting layer.
27. composite boards according to claim 19, it is characterised in that: described composite board also includes being covered in
The lower surface functional layer of the lower surface of described backing material plate.
28. composite boards according to claim 27, it is characterised in that: described lower surface functional layer be plank,
Veneer, bamboo-wood plyboard, calcium carbonate plate, calcium silicate board, plasterboard, lucite, metallic plate, plastic plate, bubble
One in foam plate.
29. composite boards according to claim 28, it is characterised in that: described lower surface functional layer and substrate layer
Employing adhesive bond, described adhesive be AB glue, epoxyn, phenolic resin glue, polyurethane adhesive,
SGA, PES polyester adhesive, PA polyamide glue, PE polyethylene glue, EVA ethylene-vinyl acetate copolymer glue,
One or several in styrene and block copolymer hot melt adhesive stick, urea-formaldehyde resin adhesive, pressure sensitive adhesive or alkyd ester gum
Kind.
30. composite boards according to claim 27, it is characterised in that: described composite board also includes being covered in
The mucigel of the lower surface of described lower surface functional layer.
31. composite floor boards according to claim 30, it is characterised in that: described mucigel is water soluble acrylic acid
Ester pressure-sensitive, waterborne polyurethane pressure-sensitive adhesives, solvent-borne type rubber pressure sensitive glue, solvent-type acrylic ester pressure-sensitive, emulsion-type
One in rubber pressure sensitive glue, emulsion-type type acrylate pressure-sensitive adhesive or UV glue.
32. composite boards according to claim 31, it is characterised in that: described UV glue is by following percent mass
The raw material composition of ratio:
Oligomer 30-50%, activated monomer 40-60%, light trigger 3-10%, auxiliary agent 1-10%;
Wherein, described oligomer be urethane acrylate, PBAA ester, epoxy acrylate, pure third
One or more in olefin(e) acid resin, polyester acrylate;
Described activated monomer is one or more in simple function group, difunctional, multi-functional acrylate;
Described light trigger is one or more in free radical photo-initiation.
33. composite boards according to claim 32, it is characterised in that: described UV glue is by following percent mass
The raw material composition of ratio:
Oligomer 40%, activated monomer 50%, light trigger 6%, auxiliary agent 5%.
34. composite boards according to claim 32, it is characterised in that: described monofunctional acrylates's ester is first
Base isobornyl acrylate, isobornyl acrylate or 2 (2-ethoxy ethoxy) ethylacrylic acid;
Described bifunctional acrylate is tri (propylene glycol) diacrylate, 1.6-hexanediyl ester or three
Cyclodecane Dimethanol Diacrylate;
Described multi-functional acrylate's activated monomer is trimethylolpropane trimethacrylate, trimethylolpropane tris third
One or more in olefin(e) acid ester, pentaerythritol triacrylate, dipentaerythritol acrylate.
35. composite boards according to claim 32, it is characterised in that: described auxiliary agent be adhesion promoter,
One or more in defoamer, levelling agent, wetting agent, antioxidant.
36. composite boards according to claim 35, it is characterised in that: described adhesion promoter is that silane is even
Connection agent Y-forms water glycerin ether oxygen propyl trimethoxy silicane, Y-aminopropyl triethoxysilane, Y-methacryloxy
Propyl trimethoxy silicane, Y-methacryloxypropyl, N-(B-aminoethyl)-Y-ammonia third
Base trimethoxy silane and acrylate phosphate 2-HEMA phosphate ester, metering system acid phosphoric acid
One or more in ester;
Described defoamer is silicone defoamer;
Described levelling agent is silicone levelling agent;
Described wetting agent is modified polydimethylsiloxane;
Described antioxidant is Hinered phenols antioxidant.
37. composite boards according to claim 35, it is characterised in that: described auxiliary agent is Macrogol 2000.
38. composite boards according to claim 32, it is characterised in that: described light trigger is 2 hydroxyl-2-
Methyl isophthalic acid-phenyl-1-acetone, 1-hydroxy-cyciohexyl benzophenone, 2,4,6-trimethylbenzoy-dipheny phosphine oxides,
Double (2,4,6-trimethylbenzoyl) phenyl phosphine oxide, 2,4,6-tri-methyl benzophenones, 4-methyldiphenyl first
One or more in ketone, 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone.
39. composite boards according to claim 30, it is characterised in that: on described backing material plate or on composite board
Have snap close, upper surface functional layer has chamfering.
40. composite boards according to claim 14, it is characterised in that: the preparation method of described composite board is also
Including: by the way of hot pressing, strengthen the bonding between described upper surface functional layer and described substrate layer.
41. composite boards according to claim 30, it is characterised in that: also include one layer below described mucigel
Mould release membrance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2017/071155 WO2017121389A1 (en) | 2016-01-15 | 2017-01-13 | Composite floor |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN2016100293266 | 2016-01-15 | ||
CN201610029326 | 2016-01-15 |
Publications (1)
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CN106223569A true CN106223569A (en) | 2016-12-14 |
Family
ID=57519455
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CN201610415402.7A Pending CN106223569A (en) | 2016-01-15 | 2016-06-14 | A kind of composite floor board |
CN201610720296.3A Pending CN106976351A (en) | 2016-01-15 | 2016-08-24 | A kind of three-dimensional lamina and sheet material for sheet material |
CN201610805155.1A Active CN106401121B (en) | 2016-01-15 | 2016-09-06 | A kind of ornament materials with fast-growing headblock layer |
CN201610805186.7A Pending CN106978061A (en) | 2016-01-15 | 2016-09-06 | A kind of wear-resisting load bisque coating, wearing layer and its preparation method and application |
CN201610853135.1A Pending CN106977833A (en) | 2016-01-15 | 2016-09-26 | Polyvinyl chloride composite materials and its processing method |
CN201611170837.6A Pending CN106978062A (en) | 2016-01-15 | 2016-12-16 | It is a kind of for skid resistant course of sheet material and preparation method thereof |
CN201710029309.7A Pending CN106978063A (en) | 2016-01-15 | 2017-01-16 | A kind of bright bisque Coating material composition, bright bisque and its preparation method and application |
CN201710029307.8A Pending CN107057099A (en) | 2016-01-15 | 2017-01-16 | A kind of patterned layer and sheet material for sheet material |
CN201710033932.XA Pending CN106976289A (en) | 2016-01-15 | 2017-01-16 | A kind of bottom surface has the sheet material of adhesive layer |
CN201710033934.9A Pending CN106674823A (en) | 2016-01-15 | 2017-01-16 | Cushion-bearing board |
CN201710029136.9A Pending CN106977835A (en) | 2016-01-15 | 2017-01-16 | RPVC composite and its processing method |
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Application Number | Title | Priority Date | Filing Date |
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CN201610720296.3A Pending CN106976351A (en) | 2016-01-15 | 2016-08-24 | A kind of three-dimensional lamina and sheet material for sheet material |
CN201610805155.1A Active CN106401121B (en) | 2016-01-15 | 2016-09-06 | A kind of ornament materials with fast-growing headblock layer |
CN201610805186.7A Pending CN106978061A (en) | 2016-01-15 | 2016-09-06 | A kind of wear-resisting load bisque coating, wearing layer and its preparation method and application |
CN201610853135.1A Pending CN106977833A (en) | 2016-01-15 | 2016-09-26 | Polyvinyl chloride composite materials and its processing method |
CN201611170837.6A Pending CN106978062A (en) | 2016-01-15 | 2016-12-16 | It is a kind of for skid resistant course of sheet material and preparation method thereof |
CN201710029309.7A Pending CN106978063A (en) | 2016-01-15 | 2017-01-16 | A kind of bright bisque Coating material composition, bright bisque and its preparation method and application |
CN201710029307.8A Pending CN107057099A (en) | 2016-01-15 | 2017-01-16 | A kind of patterned layer and sheet material for sheet material |
CN201710033932.XA Pending CN106976289A (en) | 2016-01-15 | 2017-01-16 | A kind of bottom surface has the sheet material of adhesive layer |
CN201710033934.9A Pending CN106674823A (en) | 2016-01-15 | 2017-01-16 | Cushion-bearing board |
CN201710029136.9A Pending CN106977835A (en) | 2016-01-15 | 2017-01-16 | RPVC composite and its processing method |
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WO (1) | WO2017121389A1 (en) |
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Also Published As
Publication number | Publication date |
---|---|
CN106978061A (en) | 2017-07-25 |
WO2017121389A1 (en) | 2017-07-20 |
CN106977833A (en) | 2017-07-25 |
CN106401121B (en) | 2018-10-16 |
CN107057099A (en) | 2017-08-18 |
CN106401121A (en) | 2017-02-15 |
CN106977835A (en) | 2017-07-25 |
CN106976289A (en) | 2017-07-25 |
CN106978063A (en) | 2017-07-25 |
CN106976351A (en) | 2017-07-25 |
CN106978062A (en) | 2017-07-25 |
CN106674823A (en) | 2017-05-17 |
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