CN106221378A - 一种掺杂石墨烯导电油墨 - Google Patents

一种掺杂石墨烯导电油墨 Download PDF

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CN106221378A
CN106221378A CN201610732751.1A CN201610732751A CN106221378A CN 106221378 A CN106221378 A CN 106221378A CN 201610732751 A CN201610732751 A CN 201610732751A CN 106221378 A CN106221378 A CN 106221378A
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朱燕华
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    • C09D11/10—Printing inks based on artificial resins
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Abstract

本发明公开了一种掺杂石墨烯导电油墨，由以下份数的原料组分组成：10‑15份氮掺杂石墨烯、10‑12份硼掺杂石墨烯、10‑12份磷掺杂石墨烯、6‑8份乙炔黑、3‑5份山梨酸钾、5‑6份聚丙烯酸钠、6‑8份邻苯二甲酸二丁酯、6‑8松焦油、3‑5份石蜡油、4‑6份氧化铁、2‑3份碳酸铜、3‑4份氢氧化钙、3‑4份氯化镁、8‑10份聚氨酯改性环氧树脂、8‑10份氯醋树脂、8‑10份PVC糊树脂、10‑15份去离子水。该掺杂石墨烯导电油墨成本低廉、导电性能优异、稳定性高。

Description

一种掺杂石墨烯导电油墨
技术领域
本发明涉及一种电子技术材料的技术领域，尤其涉及一种掺杂石墨烯导电油墨。
背景技术
导电油墨是由金属导电微粒（银、铜、碳，通常为银）分散在连结料中形成的一种导电性复合材料，印刷到承印物上之后，起到导线、天线和电阻的作用。导电油墨是生产有机印刷线路板（薄膜）最基础、也是最关键的原料，其在薄膜开关面板、键盘、柔性导电排线、电子屏蔽、射频识别等领域的应用越来越广泛，是决定着有机印刷电子产品成败的关键原料之一。
现有的导电油墨很多是由贵金属导电微粒所组成，价格昂贵，而且除银粉以外的其他金属粉很容易氧化而降低导电性。而碳粉的导电油墨虽然成本低廉，但导电性较差，限制了其应用。
发明内容
本发明的目的是为了克服上现有述现有技术的缺点，提供一种掺杂石墨烯导电油墨，该掺杂石墨烯导电油墨成本低廉、导电性能优异、稳定性高。
本发明解决其技术问题所采用的技术方案是：一种掺杂石墨烯导电油墨，由以下份数的原料组分组成：10-15份氮掺杂石墨烯、10-12份硼掺杂石墨烯、10-12份磷掺杂石墨烯、6-8份乙炔黑、3-5份山梨酸钾、5-6份聚丙烯酸钠、6-8份邻苯二甲酸二丁酯、6-8松焦油、3-5份石蜡油、4-6份氧化铁、2-3份碳酸铜、3-4份氢氧化钙、3-4份氯化镁、8-10份聚氨酯改性环氧树脂、8-10份氯醋树脂、8-10份PVC糊树脂、10-15份去离子水。
进一步的，各原料组分的份数为：10份氮掺杂石墨烯、10份硼掺杂石墨烯、10份磷掺杂石墨烯、6份乙炔黑、3份山梨酸钾、5份聚丙烯酸钠、6份邻苯二甲酸二丁酯、6松焦油、3份石蜡油、4份氧化铁、2份碳酸铜、3份氢氧化钙、3份氯化镁、8份聚氨酯改性环氧树脂、8份氯醋树脂、8份PVC糊树脂、10份去离子水。
或者是，各原料组分的份数为: 15份氮掺杂石墨烯、12份硼掺杂石墨烯、12份磷掺杂石墨烯、8份乙炔黑、5份山梨酸钾、6份聚丙烯酸钠、8份邻苯二甲酸二丁酯、8松焦油、5份石蜡油、6份氧化铁、3份碳酸铜、4份氢氧化钙、4份氯化镁、10份聚氨酯改性环氧树脂、10份氯醋树脂、10份PVC糊树脂、15份去离子水。
综上所述，本发明的掺杂石墨烯导电油墨成本低廉、导电性能优异、稳定性高，同时制备工艺简单、环保无污染。
具体实施方式
实施例1
本实施例1所描述的一种掺杂石墨烯导电油墨，由以下份数的原料组分组成：10份氮掺杂石墨烯、10份硼掺杂石墨烯、10份磷掺杂石墨烯、6份乙炔黑、3份山梨酸钾、5份聚丙烯酸钠、6份邻苯二甲酸二丁酯、6松焦油、3份石蜡油、4份氧化铁、2份碳酸铜、3份氢氧化钙、3份氯化镁、8份聚氨酯改性环氧树脂、8份氯醋树脂、8份PVC糊树脂、10份去离子水。
实施例2
本实施例2所描述的一种掺杂石墨烯导电油墨，由以下份数的原料组分组成：15份氮掺杂石墨烯、12份硼掺杂石墨烯、12份磷掺杂石墨烯、8份乙炔黑、5份山梨酸钾、6份聚丙烯酸钠、8份邻苯二甲酸二丁酯、8松焦油、5份石蜡油、6份氧化铁、3份碳酸铜、4份氢氧化钙、4份氯化镁、10份聚氨酯改性环氧树脂、10份氯醋树脂、10份PVC糊树脂、15份去离子水。
以上所述，仅是本发明的较佳实施例而已，并非对本发明的技术方案作任何形式上的限制。凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰，均仍属于本发明的技术方案的范围内。

Claims (3)

1.一种掺杂石墨烯导电油墨，其特征在于，由以下份数的原料组分组成：10-15份氮掺杂石墨烯、10-12份硼掺杂石墨烯、10-12份磷掺杂石墨烯、6-8份乙炔黑、3-5份山梨酸钾、5-6份聚丙烯酸钠、6-8份邻苯二甲酸二丁酯、6-8松焦油、3-5份石蜡油、4-6份氧化铁、2-3份碳酸铜、3-4份氢氧化钙、3-4份氯化镁、8-10份聚氨酯改性环氧树脂、8-10份氯醋树脂、8-10份PVC糊树脂、10-15份去离子水。
2.根据权利要求1所述的一种掺杂石墨烯导电油墨，其特征在于，各原料组分的份数为：10份氮掺杂石墨烯、10份硼掺杂石墨烯、10份磷掺杂石墨烯、6份乙炔黑、3份山梨酸钾、5份聚丙烯酸钠、6份邻苯二甲酸二丁酯、6松焦油、3份石蜡油、4份氧化铁、2份碳酸铜、3份氢氧化钙、3份氯化镁、8份聚氨酯改性环氧树脂、8份氯醋树脂、8份PVC糊树脂、10份去离子水。
3.根据权利要求1所述的一种掺杂石墨烯导电油墨，其特征在于，各原料组分的份数为: 15份氮掺杂石墨烯、12份硼掺杂石墨烯、12份磷掺杂石墨烯、8份乙炔黑、5份山梨酸钾、6份聚丙烯酸钠、8份邻苯二甲酸二丁酯、8松焦油、5份石蜡油、6份氧化铁、3份碳酸铜、4份氢氧化钙、4份氯化镁、10份聚氨酯改性环氧树脂、10份氯醋树脂、10份PVC糊树脂、15份去离子水。
CN201610732751.1A 2016-08-27 2016-08-27 一种掺杂石墨烯导电油墨 Pending CN106221378A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110655634A (zh) * 2019-11-13 2020-01-07 万华化学集团股份有限公司 高阻燃聚氨酯泡沫组合料及其制成的高阻燃聚氨酯泡沫
US20220363931A1 (en) * 2019-06-25 2022-11-17 Kansas State University Research Foundation Nano-inks of carbon nanomaterials for printing and coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220363931A1 (en) * 2019-06-25 2022-11-17 Kansas State University Research Foundation Nano-inks of carbon nanomaterials for printing and coating
CN110655634A (zh) * 2019-11-13 2020-01-07 万华化学集团股份有限公司 高阻燃聚氨酯泡沫组合料及其制成的高阻燃聚氨酯泡沫
CN110655634B (zh) * 2019-11-13 2022-04-19 万华化学集团股份有限公司 高阻燃聚氨酯泡沫组合料及其制成的高阻燃聚氨酯泡沫

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