CN106220169B - Modified lead nickle niobate-lead titanate piezoelectric ceramics and preparation method thereof - Google Patents
Modified lead nickle niobate-lead titanate piezoelectric ceramics and preparation method thereof Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 8
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 7
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000470 constituent Substances 0.000 claims abstract description 3
- 238000005245 sintering Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- 229910052573 porcelain Inorganic materials 0.000 claims description 10
- 229910052593 corundum Inorganic materials 0.000 claims description 9
- 239000010431 corundum Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 230000010287 polarization Effects 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims description 8
- 238000000498 ball milling Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003979 granulating agent Substances 0.000 claims description 3
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 238000005469 granulation Methods 0.000 claims 2
- 230000003179 granulation Effects 0.000 claims 2
- 239000006104 solid solution Substances 0.000 abstract description 6
- 230000008878 coupling Effects 0.000 abstract description 5
- 238000010168 coupling process Methods 0.000 abstract description 5
- 238000005859 coupling reaction Methods 0.000 abstract description 5
- 229910052712 strontium Inorganic materials 0.000 abstract description 4
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract description 4
- 238000006467 substitution reaction Methods 0.000 abstract description 4
- 229910052727 yttrium Inorganic materials 0.000 abstract description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical group [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract description 3
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- -1 yttrium metal oxide Chemical class 0.000 abstract 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 15
- 150000002500 ions Chemical group 0.000 description 13
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 3
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical group [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000001238 wet grinding Methods 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000012254 powdered material Substances 0.000 description 2
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 2
- 229910000018 strontium carbonate Inorganic materials 0.000 description 2
- 208000020584 Polyploidy Diseases 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- XMFOQHDPRMAJNU-UHFFFAOYSA-N lead(II,IV) oxide Inorganic materials O1[Pb]O[Pb]11O[Pb]O1 XMFOQHDPRMAJNU-UHFFFAOYSA-N 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- GNMQOUGYKPVJRR-UHFFFAOYSA-N nickel(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Ni+3].[Ni+3] GNMQOUGYKPVJRR-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- PZFKDUMHDHEBLD-UHFFFAOYSA-N oxo(oxonickeliooxy)nickel Chemical compound O=[Ni]O[Ni]=O PZFKDUMHDHEBLD-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001427 strontium ion Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
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Abstract
The invention discloses a kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, chemical constituents are as follows: Pb1‑xMex(Ni1/3Nb2/3)0.326(ZryTi1‑y)0.674O3+ 3%PbO+3%NiO+zwt%A；Me is any one or two kinds in strontium and neodymium in formula, A be antimony and yttrium metal oxide any one.Piezoelectric ceramics of the present invention passes through doping strontium and neodymium, antimony or yttrium form substitution solid solution, obtain the 0.326PNN-0.647PZT piezoelectric ceramics with preferable comprehensive performance, the piezoelectric ceramics has excellent piezoelectricity dielectric properties, higher Curie temperature and electromechanical coupling factor；Meanwhile preparation method is simple, raw material easily obtains, industrially applicable.
Description
Technical field
The present invention relates to field of electronic components manufacturing, and in particular to a kind of modified lead nickle niobate-lead zirconate titanate piezoelectric pottery
Porcelain and preparation method thereof.
Background technique
Piezoelectric ceramics is a kind of widely used ceramic material, because of its stable mechanical property and excellent electrical property
Can, preparation process is simple, cost is relatively low and is incorporated in sharp light or organisms, military information and aviation extensively etc..After second
After world war finds barium titanate piezoelectric ceramics, the beginning of the fifties lead zirconate titanate (PZT) system is found, and is developed so far piezoelectricity field
Application is exactly at most PZT series piezoelectric ceramic.However, it is common to use piezoelectric material be mainly lead zirconates (PZ), lead titanates
(PT) polyploid being combined with the relaxation ferroelectrics such as lead magnesio-niobate (PMN), lead zinc niobate (PZN) and lead nickle niobate (PNN)
System, the comprehensive performances such as piezoelectricity, dielectric, Curie temperature of these materials are not able to satisfy industrial demand, with traditional pottery
The piezoelectric ceramics that porcelain preparation process develops a kind of high comprehensive performance is just provided with important industrial practical application meaning.
PNN-PZT ceramics have the characteristics of " flexible material ", such as high piezoelectric modulus, relatively high electromechanical coupling
Number, high dielectric constant, low mechanical quality factor etc..The Curie temperature and piezoelectric constant of PZT ceramics are relatively high, and PNN
Dielectric constant is high, but its Curie temperature is but -120 DEG C, by the compound of PZT and PNN, can prepare a kind of higher pressure electricity
With the ceramics of dielectric properties, while Curie temperature is unlikely to too low again, meets the requirement of industrial application.Such as Publication No.
The patent of invention of CN102659404A discloses low-temperature sintering lead nickle niobate-lead titanate piezoelectric ceramics and preparation method thereof, should
Technology discloses raw material Pb3O4, Ni2O3, Nb2O5, ZrO2, TiO2 and CuO, dry by adding water-powered roller to grind, synthesis, tabletting, row
Glue, sintering, is obtained, but its dielectric properties and piezoelectric property are bad by techniques such as galactic poles.
Currently, to there are mainly two types of the improved methods of PNN-PZT system ceramic performance: modification by ion-doping and improving preparation work
Skill.Due to traditional ceramic preparation process because its simple process, it is at low cost, preparation ceramic performance it is good the advantages that, improve ceramics
The method of performance is mainly modification by ion-doping.In perovskite ABO3 structure, A can be incorporated heteroion replacement with B ions
Form substitution solid solution, the lead ion substitution of Nd ion and Sr ion pair A can be improved the dielectric properties of ceramics, Y-ion with
After the replacement of B ions of Sb ion pair forms solid solution, ceramic piezoelectric property is greatly improved.To PNN-PZT system ceramics
By adjusting Zr/Ti ratio near quasi- homotype phase boundary, doping vario-property ion, and find optimum process condition accurately etc. is expected to
Obtain the piezoelectric ceramics of comprehensive electrical better performances.
Summary of the invention
In order to overcome the deficiencies in the prior art, the present invention provide it is a kind of have high tension electricity coefficient, good dielectric constant, compared with
Modification lead nickle niobate-lead titanate piezoelectric ceramics of high electromechanical coupling factor and preparation method thereof.
To achieve the goals above, the present invention is achieved through the following technical solutions:
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, chemical constituent are as follows: Pb1-xMex(Ni1/3Nb2/3)0.326
(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；Me is any one or two kinds in strontium and neodymium in formula, A be antimony and
The metal oxide of yttrium any one；0≤x≤0.05 in formula, 0.418≤y≤0.441,0≤z≤1.0.
Preferably, the Me is neodymium, and A is antimony, x=0.015, y=0.433, z=0.75.
A kind of preparation method of modified lead nickle niobate-lead titanate piezoelectric ceramics, comprising the following steps:
(1) prepared by wet feed: weighing raw material mixing sufficiently according to stoichiometry, dehydrated alcohol mixing and ball milling 4-8h is added, obtains
To wet feed；
(2) pre-burning forms: after the wet feed drying in step (1), being placed in corundum crucible and covers, at 750-850 DEG C
After temperature lower calcination 1-4h, then dehydrated alcohol mixing and ball milling 4-8h is used to obtain secondary wet feed, will be added after the drying of secondary wet feed
After granulating agent is granulated, dry-pressing formed is blank；
(3) sintering polarization: gained blank is placed on corundum plate in batch-type furnace after 550 DEG C of heat preservation 3-5h, blank is set
Obtain porcelain billet in 1100~1300 DEG C of sintering 1-3h in buried powder on corundum plate, then by porcelain billet by after silver electrode in 30 DEG C of silicone oil pole
Change processing 5~10 minutes to get.
Preferably, raw material described in step (1) is following components: PbO, NiO, Nb2O5、TiO2、ZrO2、Nd2O3、SrCO3、
Y2O3And Sb2O3。
Preferably, granulating agent described in step (2) is polyvinyl alcohol.
Preferably, 1.5~2kV/mm of polarizing voltage of polarization process described in step (3).
The beneficial effects of the present invention are: based on lead nickle niobate-lead zirconate titanate, it joined neodymium (Nd) in the feed,
Strontium (Sr), the elements such as antimony (Sb) and yttrium (Y), is synthesized using conventional solid synthetic method, is sintered, pass through doping vario-property and technique
Adjustment, form substitution solid solution, since the ionic radius of neodymium is 0.129nm, the ionic radius of Pb2+ is 0.119nm.For
The big ion of radius will occupy the position of lead (A ions) into after solid solution.Simultaneously as neodymium ion price is high, occupy
After lead ion, structure cell just will appear superfluous positive charge.Therefore, in order to keep electroneutral that will accordingly generate lead vacancy,
Lattice also will appear distortion.At this point, electric domain wall easy movement.So after neodymium ion doped, the bullet of PNN-PZT piezoceramic material
Property ratio of slenderness and dielectric constant can become larger.
Similarly, Sb ion due to ionic radius it is smaller, into the position the B ion position that will occupy perovskite structure after solid solution
It sets.And due to the unstability of Sb3+, during the sintering process+trivalent Sb ion can transform into the Sb ion of+5 valences, with height
Valence state carries out the position the B ion for replacing+4 valences, to keep electroneutral that can still generate lead vacancy, becomes easier to ferroelectric domain steering,
It is promoted after Sb ion doping so as to cause the piezoelectricity dielectric properties of PNN-PZT piezoelectric ceramics.Grain is mixed used in the present invention
The 0.326PNN-0.647PZT piezoelectric ceramics with preferable comprehensive performance is obtained after son, which has excellent piezoelectricity
Dielectric properties, higher Curie temperature and electromechanical coupling factor；Meanwhile preparation method is simple, raw material easily obtains, and has industry real
The property used.
Detailed description of the invention
Fig. 1 is lead nickle niobate-Lead Zirconate Titanate ceramic material X-ray diffractogram prepared by embodiment 15；Diffraction in figure
Peak and standard card compare, and what is obtained is the perovskite structure of pure phase, and no miscellaneous phase occurs.
Fig. 2 is lead nickle niobate-Lead Zirconate Titanate ceramic material stereoscan photograph prepared by embodiment 15；Crystalline substance in photo
Grain size μm is differed from 1 μm to 8, and crystal boundary is high-visible, and porosity is on the low side, and ceramic structure is finer and close.
Fig. 3 is lead nickle niobate-Lead Zirconate Titanate ceramic material dielectric temperature curve prepared by embodiment 12.Figure dielectric is normal
The corresponding temperature of number peak value is 190 DEG C, i.e. Curie temperature.
Specific embodiment
Combined with specific embodiments below and attached drawing come present invention be described in more detail.
Embodiment 1
A kind of preparation method of modified lead nickle niobate-lead titanate piezoelectric ceramics, comprising the following steps:
(1) ingredient: with commercially available analysis pure PbO, NiO, Nb2O5、TiO2、ZrO2、Nd2O3、SrCO3、Y2O3And Sb2O3For original
Material, stoichiometrically after ingredient, being put into ball grinder using dehydrated alcohol is to obtain within medium wet-milling 4 hours wet feed and to dry；
(2) pre-burning: the mixed powder after will be dry in step (1) is placed in alumina crucible, is compacted, is covered, box
In 800 DEG C of calcining 2h in furnace, repeats wet-milling and once obtain preburning powdered material；
(3) it tabletting: after preburning powdered material is ground, then using dehydrated alcohol as solvent wet-milling 8 hours, is added after dry
The polyvinyl alcohol (PVA) of 5wt%~10wt% is granulated into the fine sand grain of mobility, dry-pressing formed under 10~20MPa pressure,
The blank being pressed into is the disk of 1 centimetre of diameter, about 1 millimeter of thickness；
(4) dumping: the disk blank being pressed into being placed on corundum plate and is put into batch-type furnace, and 550 DEG C keep the temperature 4 hours, heating
Rate is 3~6 DEG C/min, carries out the exclusion of organic matter；
(5) it is sintered: dumping blank being placed on corundum plate and covers son, material is buried with similar powder and buries burning, heating rate 3
~6 DEG C/min, it is sintered 2 hours to obtain porcelain billet at 1250 DEG C, naturally cools to room temperature with furnace；
(6) it polarizes: by obtained porcelain billet by polarization process 5~10 minutes, polarization are electric in 30 DEG C of silicone oil after silver electrode
Pressure is 1.5~2kV/mm；The piezoelectric ceramic piece completed that polarizes carries out the survey of piezoelectricity and mechanical-electric coupling performance according to the standard of IRE
Examination.
Embodiment 2
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, chemical composition are as follows:
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to embodiment
1 preparation method, according to different stoichiometries, wherein x=0.005, y=0.426, z=0.
Embodiment 3
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, chemical composition are as follows:
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to embodiment
1 preparation method, according to different stoichiometries, wherein x=0.01, y=0.426, z=0.
Embodiment 4
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, chemical composition are as follows:
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to embodiment
1 preparation method, according to different stoichiometries, wherein x=0.015, y=0.426, z=0.
Embodiment 5
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, chemical composition are as follows:
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to embodiment
1 preparation method, according to different stoichiometries, wherein x=0.02, y=0.426, z=0.
Embodiment 6
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb0.985-xNd0.015Srx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to
The preparation method of embodiment 1, according to different stoichiometries, wherein x=0.00, y=0.426, z=0.
Embodiment 7
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb0.985-xNd0.015Srx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to
The preparation method of embodiment 1, according to different stoichiometries, wherein x=0.01, y=0.426, z=0.
Embodiment 8
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb0.985-xNd0.015Srx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to
The preparation method of embodiment 1, according to different stoichiometries, wherein x=0.03, y=0.426, z=0.
Embodiment 9
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb0.985-xNd0.015Srx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；According to
The preparation method of embodiment 1, according to different stoichiometries, wherein x=0.05, y=0.426, z=0.
Embodiment 10
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Y2O3, according to embodiment 1
Preparation method, wherein sintering temperature be 1150 DEG C, x=0.015, y=0.426, z=0.
Embodiment 11
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Y2O3, according to embodiment 1
Preparation method, wherein sintering temperature be 1150 DEG C, x=0.015, y=0.426, z=0.1.
Embodiment 12
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Y2O3, according to embodiment 1
Preparation method, wherein sintering temperature be 1150 DEG C, x=0.015, y=0.426, z=0.3.
Embodiment 13
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Y2O3, according to embodiment 1
Preparation method, wherein sintering temperature be 1150 DEG C, x=0.015, y=0.426, z=0.5.
Embodiment 14
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Sb2O3, according to embodiment
1 preparation method, wherein sintering temperature is 1300 DEG C, x=0.015, y=0.433, z=0.5.
Embodiment 15
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Sb2O3, according to embodiment
1 preparation method, wherein sintering temperature is 1300 DEG C, x=0.015, y=0.433, z=0.75.
Embodiment 16
A kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, consisting of,
Pb1-xNdx(Ni1/3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%Sb2O3, according to embodiment
1 preparation method, wherein sintering temperature is 1300 DEG C, x=0.015, y=0.433, z=1.00.
The dielectric and voltage performance of testing example 2-16, the results are shown in Table 1:
Table 1
As can be seen from Table 1, work as x=0.015, when y=0.433, z=0.75, A doping neodymiums when B doping Sb, are burnt
Junction temperature is 1300 DEG C, optimal performance: εT 33/ε0=5540, d33=880pC/N, kp=0.65.
Claims (5)
1. a kind of modified lead nickle niobate-lead titanate piezoelectric ceramics, it is characterised in that: chemical constituent are as follows: Pb1-xMex(Ni1/ 3Nb2/3)0.326(ZryTi1-y)0.674O3+ 3%PbO+3%NiO+zwt%A；
The Me is neodymium, and A is the oxide of antimony, x=0.015, y=0.433, z=0.75；
The preparation methods of the ceramics the following steps are included:
(1) prepared by wet feed: weighing raw material mixing sufficiently according to stoichiometry, dehydrated alcohol mixing and ball milling 4-8h is added, obtains wet
Material；
(2) pre-burning forms: after the wet feed drying in step (1), being placed in corundum crucible and covers, in 750-850 DEG C of temperature
After lower calcining 1-4h, then dehydrated alcohol mixing and ball milling 4-8h is used to obtain secondary wet feed, granulation will be added after the drying of secondary wet feed
After agent is granulated, dry-pressing formed is blank；
(3) sintering polarization: gained blank is placed on corundum plate in batch-type furnace after 550 DEG C of heat preservation 3-5h, blank is placed in just
Buried powder obtains porcelain billet in 1100~1300 DEG C of sintering 1-3h on beautiful plate, then by porcelain billet by after silver electrode in 30 DEG C of silicone oil at polarization
Reason 5~10 minutes to get.
2. a kind of preparation method of modified lead nickle niobate-lead titanate piezoelectric ceramics according to claim 1, feature exist
In: the following steps are included:
(1) prepared by wet feed: weighing raw material mixing sufficiently according to stoichiometry, dehydrated alcohol mixing and ball milling 4-8h is added, obtains wet
Material；
(2) pre-burning forms: after the wet feed drying in step (1), being placed in corundum crucible and covers, in 750-850 DEG C of temperature
After lower calcining 1-4h, then dehydrated alcohol mixing and ball milling 4-8h is used to obtain secondary wet feed, granulation will be added after the drying of secondary wet feed
After agent is granulated, dry-pressing formed is blank；
(3) sintering polarization: gained blank is placed on corundum plate in batch-type furnace after 550 DEG C of heat preservation 3-5h, blank is placed in just
Buried powder obtains porcelain billet in 1100~1300 DEG C of sintering 1-3h on beautiful plate, then by porcelain billet by after silver electrode in 30 DEG C of silicone oil at polarization
Reason 5~10 minutes to get.
3. the preparation method of modified lead nickle niobate-lead titanate piezoelectric ceramics according to claim 2, it is characterised in that:
Raw material described in step (1) is following components: PbO, NiO, Nb2O5、TiO2、ZrO2、Nd2O3And Sb2O3。
4. the preparation method of modified lead nickle niobate-lead titanate piezoelectric ceramics according to claim 3, it is characterised in that:
Granulating agent described in step (2) is polyvinyl alcohol.
5. the preparation method of modified lead nickle niobate-lead titanate piezoelectric ceramics according to claim 3, it is characterised in that:
1.5~2kV/mm of polarizing voltage of polarization process described in step (3).
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| CN107216130B (en) * | 2017-06-06 | 2019-08-06 | 西安电子科技大学 | A kind of preparation method of PHT-PNN piezoceramic material |
| CN107986782B (en) * | 2017-11-21 | 2020-01-03 | 歌尔股份有限公司 | Doped modified lead zirconate titanate piezoelectric ceramic and preparation method thereof |
| CN111747743B (en) * | 2020-06-12 | 2022-08-12 | 广州凯立达电子股份有限公司 | Spherical piezoelectric ceramic and preparation method thereof |
| CN111875374A (en) * | 2020-08-06 | 2020-11-03 | 湖北大学 | Low-temperature sintered niobium-nickel-lead zirconate titanate piezoelectric ceramic material and preparation method thereof |
| CN112457008A (en) * | 2020-12-04 | 2021-03-09 | 中国船舶重工集团公司第七一五研究所 | Large-strain piezoelectric ceramic material and preparation method thereof |
| CN114436652B (en) * | 2022-01-28 | 2023-05-16 | 厦门乃尔电子有限公司 | Lead zirconate titanate-lead niobium tantalum magnesium acid piezoelectric ceramic material and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1840105A1 (en) * | 2004-12-22 | 2007-10-03 | Murata Manufacturing Co., Ltd. | Piezoelectric porcelain composition and piezoelectric actuator |
| CN101265089A (en) * | 2008-04-15 | 2008-09-17 | 湖北大学 | Doping plasticizing lead zirconate titanate piezoelectricity ignition ceramic material and preparation method thereof |
| CN101805183A (en) * | 2010-03-02 | 2010-08-18 | 中国科学院上海硅酸盐研究所 | A low-temperature sintered Pb (Ni1/3Nb2/3) O3-Pb (Zr, ti) O3ceramic powder and its prepn |
| CN101863660A (en) * | 2010-06-11 | 2010-10-20 | 天津大学 | La2O3-doped lead zinc niobate-lead zirconate titanate piezoelectric ceramic |
| CN101870583A (en) * | 2010-06-08 | 2010-10-27 | 天津大学 | Lead zirconate titanate piezoelectric ceramic with additional antimony oxide |
| CN102659404A (en) * | 2012-05-02 | 2012-09-12 | 天津大学 | Plumbum niobate-nicklate (PNN)-plumbum zirconate titanate (PZT) piezoelectric ceramic capable of being sintered at low temperature and preparation method thereof |
-
2016
- 2016-07-14 CN CN201610553904.6A patent/CN106220169B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1840105A1 (en) * | 2004-12-22 | 2007-10-03 | Murata Manufacturing Co., Ltd. | Piezoelectric porcelain composition and piezoelectric actuator |
| CN101265089A (en) * | 2008-04-15 | 2008-09-17 | 湖北大学 | Doping plasticizing lead zirconate titanate piezoelectricity ignition ceramic material and preparation method thereof |
| CN101805183A (en) * | 2010-03-02 | 2010-08-18 | 中国科学院上海硅酸盐研究所 | A low-temperature sintered Pb (Ni1/3Nb2/3) O3-Pb (Zr, ti) O3ceramic powder and its prepn |
| CN101870583A (en) * | 2010-06-08 | 2010-10-27 | 天津大学 | Lead zirconate titanate piezoelectric ceramic with additional antimony oxide |
| CN101863660A (en) * | 2010-06-11 | 2010-10-20 | 天津大学 | La2O3-doped lead zinc niobate-lead zirconate titanate piezoelectric ceramic |
| CN102659404A (en) * | 2012-05-02 | 2012-09-12 | 天津大学 | Plumbum niobate-nicklate (PNN)-plumbum zirconate titanate (PZT) piezoelectric ceramic capable of being sintered at low temperature and preparation method thereof |
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