CN106190403A - A kind of low-carbon environment-friendly biomass fuel and preparation method - Google Patents

A kind of low-carbon environment-friendly biomass fuel and preparation method Download PDF

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Publication number
CN106190403A
CN106190403A CN201610658859.0A CN201610658859A CN106190403A CN 106190403 A CN106190403 A CN 106190403A CN 201610658859 A CN201610658859 A CN 201610658859A CN 106190403 A CN106190403 A CN 106190403A
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CN
China
Prior art keywords
parts
slag
auxiliary agent
grass
biomass fuel
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Pending
Application number
CN201610658859.0A
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Chinese (zh)
Inventor
哈云
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Anhui Changxin Biomass Energy Co Ltd
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Anhui Changxin Biomass Energy Co Ltd
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Priority to CN201610658859.0A priority Critical patent/CN106190403A/en
Publication of CN106190403A publication Critical patent/CN106190403A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The invention discloses a kind of low-carbon environment-friendly biomass fuel and preparation method, Artemisia integrifolia L. 32 45 parts, revolution grass 30 38 parts, grass 25 40 parts, tea grounds 10 15 parts, Semen Gossypii slag 15 20 parts, tung pomace 10 20 parts, Semen Allii Tuberosi slag 12 20 parts, Petiolus Trachycarpi slag 16 22 parts, agricultural crop straw 30 40 parts, auxiliary agent A 0.4 0.9 parts, auxiliary agent B 0.1 0.3 parts;Artemisia integrifolia L., revolution grass, grass, tea grounds, Semen Gossypii slag, tung pomace, Semen Allii Tuberosi slag, Petiolus Trachycarpi slag, recycling can will can be reduced they pollutions to environment, the injury to human body by the present invention.Meanwhile, the biomass fuel obtained also has the advantage that caloric value is high, noxious gas emission is few.

Description

A kind of low-carbon environment-friendly biomass fuel and preparation method
Technical field
The present invention relates to a kind of low-carbon environment-friendly biomass fuel, belong to clean energy resource field.
Background technology
Revolution grass is common weeds waterborne, and it is distributed wide model and easily large-scale outbreak, the process to revolution grass in rural area Abandoning after salvaging often or keep fowls, the reason that keeps fowls amount is little, if abandoning, long-time after can rot, affect environment.Willow Leaf Artemisia, grass are also the common weeds of rural area the edge of a field, and it is not had suitable processing method.Semen Gossypii slag, tung pomace, Semen Allii Tuberosi slag, palm fibre Palmitic acid slag is all remaining waste material in oil refining process, and among these possibly together with oil content, if simply doing conventional treatment, it is worth nothing Method obtains and maximizes.
Summary of the invention
It is an object of the present invention to provide a kind of biomass fuel and preparation method, can by Artemisia integrifolia L., revolution grass, grass, tea grounds, Semen Gossypii slag, tung pomace, Semen Allii Tuberosi slag, Petiolus Trachycarpi slag, recycling, reduce they pollutions to environment, the injury to human body.Meanwhile, To biomass fuel also there is the advantage that caloric value is high, noxious gas emission is few.
The solution of the present invention is as follows: a kind of low-carbon environment-friendly biomass fuel, is composed of the following raw materials by weight: Artemisia integrifolia L. 32-45 part, revolution grass 30-38 part, grass 25-40 part, tea grounds 10-15 part, Semen Gossypii slag 15-20 part, tung pomace 10-20 part, dish Seed slag 12-20 part, Petiolus Trachycarpi slag 16-22 part, crop stalk 30-40 part, auxiliary agent A 0.4-0.9 part, auxiliary agent B 1-3 part;
Described auxiliary agent A is prepared by following methods: carry out megasse cutting, pulverizing, then by it with Α-glucosidase, Cellulase starch defatting enzyme, ligninase, D-MANNOSE, Micromonospora chalcea, water put into mix and blend in round together, Then seal and ferment;Filter gained liquid after fermentation and be auxiliary agent A;Fermentation temperature is 58-65 DEG C, and fermentation time is 1- 2h;Megasse, water, Α-glucosidase, cellulase starch defatting enzyme, ligninase, D-MANNOSE, the weight of Micromonospora chalcea Amount ratio is 100:25-42:0.2-0.5:0.12-0.46:0.1-0.4:1-3:0.25-0.5;
Described auxiliary agent B is mixed by following percentage by weight raw material: copper trifluoromethanesulfcomposite 1-5%, mono phosphoric acid ester starch 12- 18%, microcrystalline Cellulose 4-9%, sodium lignin sulfonate 6-12%, lauryl trimethyl ammonium bromide 16-22%, niobium pentaoxide 0.45- 0.75%, nano indium oxide 11-16%, ferroso-ferric oxide 13-22%, stannous chloride 11-20%, ferric ammonium citrate 16-25%, remainder For kieselguhr.
Further, be composed of the following raw materials by weight: Artemisia integrifolia L. 39 parts, revolution grass 32 parts, grass 38 parts, tea grounds 12 parts, Semen Gossypii slag 17 parts, tung pomace 13 parts, Semen Allii Tuberosi slag 19 parts, Petiolus Trachycarpi slag 18 parts, crop stalk 33 parts, auxiliary agent A 0.6 part, auxiliary agent B 2 parts;
Further, it is composed of the following raw materials by weight: Artemisia integrifolia L. 45 parts, revolution grass 33 parts, grass 32 parts, tea grounds 13 parts, Semen Gossypii Slag 16 parts, tung pomace 15 parts, Semen Allii Tuberosi slag 16 parts, Petiolus Trachycarpi slag 18 parts, crop stalk 34 parts, auxiliary agent A 0.7 part, auxiliary agent B 1.6 Part;
Further, it is composed of the following raw materials by weight: Artemisia integrifolia L. 35 parts, revolution grass 36 parts, grass 28 parts, tea grounds 11 parts, Semen Gossypii Slag 20 parts, tung pomace 18 parts, Semen Allii Tuberosi slag 18 parts, Petiolus Trachycarpi slag 21 parts, crop stalk 37 parts, auxiliary agent A 0.6 part, auxiliary agent B 2.6 Part;
The preparation method of low-carbon environment-friendly biomass fuel is as follows:
A, carry out again drying, pulverizing after 3-5 days by Artemisia integrifolia L., revolution grass, grass conventional Exposure to Sunlight, obtain ground product A so that it is water content At 5-7%;
B, carry out drying, pulverizing by tea grounds, Semen Gossypii slag, tung pomace, Semen Allii Tuberosi slag, Petiolus Trachycarpi slag, crop stalk, obtain ground product B, make Its water content is at 4-8%;
C, by ground product A, ground product B, auxiliary agent A, auxiliary agent B mix homogeneously, then by granulator granulation, to obtain final product.
Cooperation by each raw material of the present invention so that biomass fuel have that caloric value is high, noxious gas emission is few Advantage.Owing to straw stalk and the dregs of fat there will be carbonization, burn incompletely phenomenon in combustion, auxiliary agent A that the present invention adds, help Agent B can extend comburant and oxygen time of contact, promotes burning, reduces the carbonation rate in combustion process, promotes heat transfer efficiency;, Meanwhile, soot emissions are few, and slagging scorification carbon content rate reduces, and improves atmospheric environment.
Detailed description of the invention
Auxiliary agent A by preparation
Carry out megasse cutting, pulverizing, then by itself and Α-glucosidase, cellulase starch defatting enzyme, ligninase, D- Mannose, Micromonospora chalcea, water put into mix and blend in round together, then seal and ferment;Filter after fermentation Gained liquid is auxiliary agent A;Fermentation temperature is 58-65 DEG C, and fermentation time is 1-2h;Megasse, water, Α-glucosidase, fibre Dimension element enzyme starch defatting enzyme, ligninase, D-MANNOSE, the weight ratio of Micromonospora chalcea are 100:25-42:0.2-0.5: 0.12-0.46:0.1-0.4:1-3:0.25-0.5;.
The preparation of auxiliary agent B
By copper trifluoromethanesulfcomposite 4%, mono phosphoric acid ester starch 14%, microcrystalline Cellulose 7%, sodium lignin sulfonate 10%, lauryl trimethyl Ammonium bromide 18%, niobium pentaoxide 0.66%, nano indium oxide 13%, ferroso-ferric oxide 18%, stannous chloride 16%, ferric ammonium citrate 22%, remainder mixes for kieselguhr.
Embodiment 1
A kind of low-carbon environment-friendly biomass fuel, is composed of the following raw materials by weight:
Artemisia integrifolia L. 39 parts, revolution grass 32 parts, grass 38 parts, tea grounds 12 parts, Semen Gossypii slag 17 parts, tung pomace 13 parts, Semen Allii Tuberosi slag 19 parts, Petiolus Trachycarpi slag 18 parts, crop stalk 33 parts, auxiliary agent A 0.6 part, auxiliary agent B 2 parts;
The preparation method of low-carbon environment-friendly biomass fuel is as follows:
A, carry out again drying, pulverizing after 3-5 days by Artemisia integrifolia L., revolution grass, grass conventional Exposure to Sunlight, obtain ground product A so that it is water content At 5-7%;
B, carry out drying, pulverizing by tea grounds, Semen Gossypii slag, tung pomace, Semen Allii Tuberosi slag, Petiolus Trachycarpi slag, crop stalk, obtain ground product B, make Its water content is at 4-8%;
C, by ground product A, ground product B, auxiliary agent A, auxiliary agent B mix homogeneously, then by granulator granulation, to obtain final product.
Embodiment 2
A kind of low-carbon environment-friendly biomass fuel, is composed of the following raw materials by weight: Artemisia integrifolia L. 45 parts, revolution grass 33 parts, grass 32 Part, tea grounds 13 parts, Semen Gossypii slag 16 parts, tung pomace 15 parts, Semen Allii Tuberosi slag 16 parts, Petiolus Trachycarpi slag 18 parts, crop stalk 34 parts, auxiliary agent A 0.7 part, auxiliary agent B 1.6 parts;
The preparation of low-carbon environment-friendly biomass fuel is with embodiment 1.
Embodiment 3
A kind of low-carbon environment-friendly biomass fuel, is composed of the following raw materials by weight: Artemisia integrifolia L. 35 parts, revolution grass 36 parts, grass 28 Part, tea grounds 11 parts, Semen Gossypii slag 20 parts, tung pomace 18 parts, Semen Allii Tuberosi slag 18 parts, Petiolus Trachycarpi slag 21 parts, crop stalk 37 parts, auxiliary agent A 0.6 part, auxiliary agent B 2.6 parts;
The preparation of low-carbon environment-friendly biomass fuel is with embodiment 1.
Comparative example 1
Compared with Example 1, without auxiliary agent A.
Comparative example 2
Compared with Example 1, without auxiliary agent B.
Comparative example 3
Compared with Example 1, without auxiliary agent A and auxiliary agent B.
To embodiment 1-3, the low-carbon environment-friendly biomass fuel of comparative example 1-3 gained, obtain following performance parameter:
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2 Comparative example 3
Combustion rate (%) ≥96.8 ≥97.3 ≥96.2 ≥78.3 ≥79.1 ≥61.9
The thermal efficiency (%) ≥77.1 ≥76.9 ≥76.8 ≥61.2 ≥62.5 ≥43.1
Moisture (%) ≤15.6 ≤14.9 ≤15.3 ≤18.3 ≤19.1 ≤35.3
Ash (%) ≤6.2 ≤5.8 ≤6.1 ≤9.8 ≤8.8 ≤13.2
Ignition temperature (DEG C) 366-372 370-383 369-375 412-419 425-429 483-492
Calorific value (J/kg) > 18936 > 18811 > 18572 > 12550 > 13247 > 9630
Blackness of the exhaust (lingemann grade) < 1 < 1 < 1 < 2 < 2 < 3
Although above the detailed description of the invention to the present invention give detailed description and explanation, but it should be noted that we According to the conception of the present invention, above-mentioned embodiment can be carried out various equivalence to change and amendment, produced by it, function is still Without departing from description contained spiritual time, all should be within protection scope of the present invention.

Claims (5)

1. a low-carbon environment-friendly biomass fuel, it is characterised in that be composed of the following raw materials by weight:
Artemisia integrifolia L. 32-45 part, revolution grass 30-38 part, grass 25-40 part, tea grounds 10-15 part, Semen Gossypii slag 15-20 part, tung pomace 10-20 part, Semen Allii Tuberosi slag 12-20 part, Petiolus Trachycarpi slag 16-22 part, crop stalk 30-40 part, auxiliary agent A 0.4-0.9 part, auxiliary agent B 1-3 part;
Described auxiliary agent A is prepared by following methods: carry out megasse cutting, pulverizing, then by it with Α-glucosidase, Cellulase starch defatting enzyme, ligninase, D-MANNOSE, Micromonospora chalcea, water put into mix and blend in round together, Then seal and ferment;Filter gained liquid after fermentation and be auxiliary agent A;Fermentation temperature is 58-65 DEG C, and fermentation time is 1- 2h;Megasse, water, Α-glucosidase, cellulase starch defatting enzyme, ligninase, D-MANNOSE, the weight of Micromonospora chalcea Amount ratio is 100:25-42:0.2-0.5:0.12-0.46:0.1-0.4:1-3:0.25-0.5;
Described auxiliary agent B is mixed by following percentage by weight raw material: copper trifluoromethanesulfcomposite 1-5%, mono phosphoric acid ester starch 12- 18%, microcrystalline Cellulose 4-9%, sodium lignin sulfonate 6-12%, lauryl trimethyl ammonium bromide 16-22%, niobium pentaoxide 0.45- 0.75%, nano indium oxide 11-16%, ferroso-ferric oxide 13-22%, stannous chloride 11-20%, ferric ammonium citrate 16-25%, remainder For kieselguhr.
A kind of low-carbon environment-friendly biomass fuel the most according to claim 1, it is characterised in that by following raw material group Become:
Artemisia integrifolia L. 39 parts, revolution grass 32 parts, grass 38 parts, tea grounds 12 parts, Semen Gossypii slag 17 parts, tung pomace 13 parts, Semen Allii Tuberosi slag 19 parts, Petiolus Trachycarpi slag 18 parts, crop stalk 33 parts, auxiliary agent A 0.6 part, auxiliary agent B 2 parts.
A kind of low-carbon environment-friendly biomass fuel the most according to claim 1, it is characterised in that by following raw material group Become:
Artemisia integrifolia L. 45 parts, revolution grass 33 parts, grass 32 parts, tea grounds 13 parts, Semen Gossypii slag 16 parts, tung pomace 15 parts, Semen Allii Tuberosi slag 16 parts, Petiolus Trachycarpi slag 18 parts, crop stalk 34 parts, auxiliary agent A 0.7 part, auxiliary agent B 1.6 parts.
A kind of low-carbon environment-friendly biomass fuel the most according to claim 1, it is characterised in that by following raw material group Become:
Artemisia integrifolia L. 35 parts, revolution grass 36 parts, grass 28 parts, tea grounds 11 parts, Semen Gossypii slag 20 parts, tung pomace 18 parts, Semen Allii Tuberosi slag 18 parts, Petiolus Trachycarpi slag 21 parts, crop stalk 37 parts, auxiliary agent A 0.6 part, auxiliary agent B 2.6 parts.
5. the preparation method according to the arbitrary described low-carbon environment-friendly biomass fuel of claim 1-4 is as follows:
A, carry out again drying, pulverizing after 3-5 days by Artemisia integrifolia L., revolution grass, grass conventional Exposure to Sunlight, obtain ground product A so that it is water content At 5-7%;
B, carry out drying, pulverizing by tea grounds, Semen Gossypii slag, tung pomace, Semen Allii Tuberosi slag, Petiolus Trachycarpi slag, crop stalk, obtain ground product B, make Its water content is at 4-8%;
C, by ground product A, ground product B, auxiliary agent A, auxiliary agent B mix homogeneously, then by granulator granulation, to obtain final product.
CN201610658859.0A 2016-08-12 2016-08-12 A kind of low-carbon environment-friendly biomass fuel and preparation method Pending CN106190403A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101463283A (en) * 2008-05-31 2009-06-24 陶小勇 Environment protection coal-saving agent for cement vertical kiln
CN101475864A (en) * 2009-01-19 2009-07-08 赵楠 Non-sodium chloride environment-friendly type coal-saving combustion adjuvant special for cement
CN101486935A (en) * 2009-02-20 2009-07-22 颜道友 Honeycomb briquette
CN102061212A (en) * 2009-11-16 2011-05-18 中冶建筑研究总院有限公司 Fire coal efficient catalysis combustion-supporting agent and preparation method and use method thereof
WO2015003230A1 (en) * 2013-07-12 2015-01-15 Hristo Atanasov Kovachki Method for catalyzing the combustion of carbon-containing solid fuels
CN104877714A (en) * 2015-05-25 2015-09-02 李明阳 Biological combustion-supporting material as well as preparation method and application thereof
CN105112118A (en) * 2015-09-01 2015-12-02 滁州科菁生物科技有限公司 Raw material pretreatment technology used for biomass fuel

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101463283A (en) * 2008-05-31 2009-06-24 陶小勇 Environment protection coal-saving agent for cement vertical kiln
CN101475864A (en) * 2009-01-19 2009-07-08 赵楠 Non-sodium chloride environment-friendly type coal-saving combustion adjuvant special for cement
CN101486935A (en) * 2009-02-20 2009-07-22 颜道友 Honeycomb briquette
CN102061212A (en) * 2009-11-16 2011-05-18 中冶建筑研究总院有限公司 Fire coal efficient catalysis combustion-supporting agent and preparation method and use method thereof
WO2015003230A1 (en) * 2013-07-12 2015-01-15 Hristo Atanasov Kovachki Method for catalyzing the combustion of carbon-containing solid fuels
CN104877714A (en) * 2015-05-25 2015-09-02 李明阳 Biological combustion-supporting material as well as preparation method and application thereof
CN105112118A (en) * 2015-09-01 2015-12-02 滁州科菁生物科技有限公司 Raw material pretreatment technology used for biomass fuel

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Application publication date: 20161207