CN106189428A - A kind of novel high-performance water-repellent paint - Google Patents
A kind of novel high-performance water-repellent paint Download PDFInfo
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- CN106189428A CN106189428A CN201610812835.6A CN201610812835A CN106189428A CN 106189428 A CN106189428 A CN 106189428A CN 201610812835 A CN201610812835 A CN 201610812835A CN 106189428 A CN106189428 A CN 106189428A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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Abstract
The invention discloses a kind of novel high-performance water-repellent paint, including following raw material: Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, aqueous acrylic emulsion, polyacrylamide solution, Tissuemat E, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, adhesion promoter, catalyst, initiator, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, thickening agent, coalescents, fire retardant.The coating of the present invention had both had adhesive force and the mechanical property of excellence, had again excellent resistance to water, resistance to ag(e)ing, crack resistance and a thermal adaptability, and the nonhazardous of product own, it is the novel high-performance water-repellent paint of a kind of excellent combination property.
Description
[technical field]
The invention belongs to coating technology of preparing neck, be specifically related to a kind of novel high-performance water-repellent paint.
[background technology]
Water-repellent paint is the material of a kind of liquid or semi liquid state, uses the construction technology such as brush or spraying on building surface, passes through
Chemical reaction forms a continuous print, has the thin film of certain elasticity and thickness, so can resist certain water pressure, from
And reach the purpose of waterproof and moistureproof.Water-repellent paint is a kind of special coating, and its particularity is that coating surface can be formed
One softness, waterproof, the Waterproof structural course of cracking resistance, stop that hydrone permeates externally to basic unit.
Building and structures in use, all can be affected by various natural causes, and build form and
Waterproof position is different, and suffered influence factor is the most different.As building roof waterproof layer is exposed in natural environment for a long time, by rain,
The erosion of snow, wind, frost, ultraviolet and air pollutants；Building under ground portion is not only chronically in water environment, but also
The repeated action of differential settlement to be born；Bridge is then intended to bear the alternate stress effect of frequent traffic load.Therefore, use
In the material of buildings waterproof, do not need only have the mechanical property under opposing complex stress effect, also need to be maintained at respectively simultaneously
The lasting stability of combination property under the influence of kind natural cause is long-term.Tradition Novel durable waterproof paint is waterproof, easily outside room
Cause aging, dry and cracked, deform, the phenomenon such as fracture；And waterproof for kitchen, lavatory etc., tired for complex-shaped place construction
Difficulty, and durability is poor, every few years needs to reprocess, and has both added expense, has upset again the orthobiosis of people.
[summary of the invention]
The present invention provides a kind of novel high-performance water-repellent paint, is used for outside room waterproof with solution tradition Novel durable waterproof paint,
Easily cause aging, dry and cracked, deform, the problem such as fracture.The coating of the present invention had both had adhesive force and the mechanical property of excellence, again
There is excellent resistance to water, resistance to ag(e)ing, crack resistance and thermal adaptability, and the nonhazardous of product own, it is a kind of combining
Close the novel high-performance water-repellent paint of excellent performance.
For solve above technical problem, the present invention by the following technical solutions:
A kind of novel high-performance water-repellent paint, in units of weight, including following raw material: Tert-butyl Methacrylate 105-136
Part, n propyl methacrylate 34-58 part, tributyl citrate 23-37 part, ethyl methacrylate 15-26 part, aqueous acrylamide
Yogurt liquid 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, calcium carbonate 4-8 part, Kaolin 3-6 part,
Pulvis Talci 2-5 part, polyester fiber 3-6 part, glass fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part,
Degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst
0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, disappear
Infusion 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3
Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part,
Fire retardant 1.2-1.5 part；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14-22 part, 2,
2-dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9
Part, calcium carbonate 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, synergistic
Agent 0.3-0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described novel high-performance water-repellent paint, comprises the following steps:
S1: by Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, polyethylene
Wax, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, point
Powder, wetting agent, adhesion promoter, catalyst, initiator mix, and are 120-150W at microwave power, and temperature is 88-95
DEG C, rotating speed is stirring 2.5-3h under 2400-3000r/min, prepares mixture a；
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares
Agent, optical brightener, defoamer, viscosifier, be 140-180W at microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/
Stir 3-5h under min, prepare mixture b；
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares
Thick dose, coalescents, fire retardant, be 130-200W at microwave power, temperature is 105-115 DEG C, and rotating speed is 200-400r/min
Lower stirring 2-4h, prepares mixture c；
The preparation method of described fire retardant, comprises the following steps:
S31: APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is 300-400r/min
5-8min, prepares mixture A；
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3-
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, calcium carbonate, antimony oxide, manganese oxide, bentonite, penetrating agent, association
Effect agent, is 400-600r/min at speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8-2.5h at being 83-89 DEG C,
Prepare mixture B；
S33: after the mixture B that step S32 prepares is cooled to room temperature, filters precipitate, is 3000-5000r/ at rotating speed
Under min, centrifugal drying is to water content≤4%, prepares fire retardant；
S4: mixture c step S3 prepared is melt extruded at 108-115 DEG C by extruder, and passes through crusher
Film-making, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 120-180 mesh sieve after pulverizing, and prepares novel high-performance water-repellent paint.
Further, described preservative is Liquid BPF-369.
Further, described antioxidant is antioxidant AT-330.
Further, described light stabilizer is light stabilizer HS-3101.
Further, described UV absorbent is oxybenzoic acid phenyl ester.
Further, described thickening agent is xanthan gum.
Further, described coalescents is Yi Siman coalescents.
The method have the advantages that
(1) coating of the present invention had both had adhesive force and the mechanical property of excellence, have again excellent resistance to water, resistance to ag(e)ing,
Crack resistance and thermal adaptability, and the nonhazardous of product own, be that the novel high-performance of a kind of excellent combination property is waterproof
Coating；
(2) the novel high-performance water-repellent paint of the present invention has weatherability, is widely used in the open airs such as guardrail, Men Ye, aluminium section bar
Coating metal surfaces.
[detailed description of the invention]
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the protection of the present invention
Scope, but it is not intended to protection scope of the present invention.
In an embodiment, described novel high-performance water-repellent paint, in units of weight, including following raw material: metering system
Tert-butyl acrylate 105-136 part, n propyl methacrylate 34-58 part, tributyl citrate 23-37 part, ethyl methacrylate
15-26 part, aqueous acrylic emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, calcium carbonate 4-8
Part, Kaolin 3-6 part, Pulvis Talci 2-5 part, polyester fiber 3-6 part, glass fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part,
Bamboo carbon fiber 2-5 part, degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter
0.3-0.5 part, catalyst 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, increasing
Photo etching 0.3-0.7 part, defoamer 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3
Part, antioxidant 0.2-0.3 part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, one-tenth
Film auxiliary agent 0.3-0.4 part, fire retardant 1.2-1.5 part；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF-369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents is Yi Siman coalescents；
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14-22 part, 2,
2-dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9
Part, calcium carbonate 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, synergistic
Agent 0.3-0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described novel high-performance water-repellent paint, comprises the following steps:
S1: by Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, polyethylene
Wax, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, point
Powder, wetting agent, adhesion promoter, catalyst, initiator mix, and are 120-150W at microwave power, and temperature is 88-95
DEG C, rotating speed is stirring 2.5-3h under 2400-3000r/min, prepares mixture a；
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares
Agent, optical brightener, defoamer, viscosifier, be 140-180W at microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/
Stir 3-5h under min, prepare mixture b；
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares
Thick dose, coalescents, fire retardant, be 130-200W at microwave power, temperature is 105-115 DEG C, and rotating speed is 200-400r/min
Lower stirring 2-4h, prepares mixture c；
The preparation method of described fire retardant, comprises the following steps:
S31: APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is 300-400r/min
5-8min, prepares mixture A；
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3-
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, calcium carbonate, antimony oxide, manganese oxide, bentonite, penetrating agent, association
Effect agent, is 400-600r/min at speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8-2.5h at being 83-89 DEG C,
Prepare mixture B；
S33: after the mixture B that step S32 prepares is cooled to room temperature, filters precipitate, is 3000-5000r/ at rotating speed
Under min, centrifugal drying is to water content≤4%, prepares fire retardant；
S4: mixture c step S3 prepared is melt extruded at 108-115 DEG C by extruder, and passes through crusher
Film-making, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 120-180 mesh sieve after pulverizing, and prepares novel high-performance water-repellent paint.
Embodiment 1
A kind of novel high-performance water-repellent paint, in units of weight, including following raw material: Tert-butyl Methacrylate 120 parts, first
Base n-propyl 45 parts, tributyl citrate 30 parts, ethyl methacrylate 20 parts, aqueous acrylic emulsion 40 parts, poly-
Acrylamide solution 30 parts, Tissuemat E 30 parts, calcium carbonate 6 parts, Kaolin 5 parts, Pulvis Talci 4 parts, 5 parts of polyester fiber, glass
Fiber 4 parts, hydroxypropyl methyl cellulose 6 parts, bamboo carbon fiber 4 parts, degasser 0.6 part, dispersant 0.7 part, wetting agent 0.3 part,
Adhesion promoter 0.4 part, catalyst 0.2 part, initiator 0.1 part, vertical stricture of vagina agent 0.5 part, toughener 0.4 part, optical brightener 0.5
Part, defoamer 0.5 part, viscosifier 0.2 part, 1.2 parts of firming agent, preservative 0.2 part, 0.2 part of antioxidant, light stabilizer 0.1 part,
UV absorbent 0.2 part, thickening agent 0.5 part, coalescents 0.3 part, fire retardant 1.4 parts；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF-369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents is Yi Siman coalescents；
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 18 parts, 2,2-bis-
Methyl isophthalic acid, 3-propylidene dimethylacrylate 10 parts, APP 12 parts, tetramethylolmethane 7 parts, 8 parts of carbamide, calcium carbonate 4 parts,
Antimony oxide 8 parts, manganese oxide 4 parts, bentonite 2.5 parts, penetrating agent 0.7 part, synergist 0.4 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described novel high-performance water-repellent paint, comprises the following steps:
S1: by Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, polyethylene
Wax, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, point
Powder, wetting agent, adhesion promoter, catalyst, initiator mix, and are 135W at microwave power, and temperature is 92 DEG C, and rotating speed is
Stir 2.8h under 2800r/min, prepare mixture a；
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares
Agent, optical brightener, defoamer, viscosifier, be 160W at microwave power, and temperature is 120 DEG C, and rotating speed is stirring 4h under 500r/min,
Prepare mixture b；
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares
Thick dose, coalescents, fire retardant, be 180W at microwave power, temperature is 110 DEG C, rotating speed be under 300r/min stirring 3h, prepare
Mixture c；
The preparation method of described fire retardant, comprises the following steps:
S31: APP, 135 parts of water are added in microwave reactor, stirs 7min, system under speed of agitator is 350r/min
Obtain mixture A；
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3-
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, calcium carbonate, antimony oxide, manganese oxide, bentonite, penetrating agent, association
Effect agent, is 500r/min at speed of agitator, and microwave power is 160W, and temperature is stirring 2.2h at 86 DEG C, prepares mixture B；
S33: by step S32 prepare mixture B be cooled to room temperature after, by precipitate filter, under rotating speed is 4000r/min from
It is 4% that the heart is dried to water content, prepares fire retardant；
S4: mixture c step S3 prepared is melt extruded at 112 DEG C by extruder, and by crusher film-making,
Lamellar body is prepared after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 150 mesh sieve after pulverizing, and prepares novel high-performance water-repellent paint.
Embodiment 2
A kind of novel high-performance water-repellent paint, in units of weight, including following raw material: Tert-butyl Methacrylate 105 parts, first
Base n-propyl 34 parts, tributyl citrate 23 parts, ethyl methacrylate 15 parts, aqueous acrylic emulsion 32 parts, poly-
Acrylamide solution 24 parts, Tissuemat E 20 parts, calcium carbonate 4 parts, Kaolin 3 parts, Pulvis Talci 2 parts, 3 parts of polyester fiber, glass
Fiber 3 parts, hydroxypropyl methyl cellulose 4 parts, bamboo carbon fiber 2 parts, degasser 0.4 part, dispersant 0.5 part, wetting agent 0.2-0.
Part, adhesion promoter 0.3 part, catalyst 0.1 part, initiator 0.1 part, vertical stricture of vagina agent 0.3 part, toughener 0.2 part, optical brightener
0.3 part, defoamer 0.4 part, viscosifier 0.2 part, 0.8 part of firming agent, preservative 0.2 part, 0.2 part of antioxidant, light stabilizer 0.1
Part, UV absorbent 0.2 part, thickening agent 0.3 part, coalescents 0.3 part, fire retardant 1.2 parts；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF-369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents is Yi Siman coalescents；
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14 parts, 2,2-bis-
Methyl isophthalic acid, 3-propylidene dimethylacrylate 8 parts, APP 9 parts, tetramethylolmethane 4 parts, 6 parts of carbamide, calcium carbonate 2 parts, three
Aoxidize 6 parts of two antimony, manganese oxide 2 parts, bentonite 2 parts, penetrating agent 0.6 part, synergist 0.3 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described novel high-performance water-repellent paint, comprises the following steps:
S1: by Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, polyethylene
Wax, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, point
Powder, wetting agent, adhesion promoter, catalyst, initiator mix, and are 120W at microwave power, and temperature is 88 DEG C, and rotating speed is
Stir 3h under 2400r/min, prepare mixture a；
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares
Agent, optical brightener, defoamer, viscosifier, be 140W at microwave power, and temperature is 115 DEG C, and rotating speed is stirring 5h under 400r/min,
Prepare mixture b；
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares
Thick dose, coalescents, fire retardant, be 130W at microwave power, temperature is 105 DEG C, rotating speed be under 200r/min stirring 4h, prepare
Mixture c；
The preparation method of described fire retardant, comprises the following steps:
S31: APP, 120 parts of water are added in microwave reactor, stirs 8min, system under speed of agitator is 300r/min
Obtain mixture A；
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3-
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, calcium carbonate, antimony oxide, manganese oxide, bentonite, penetrating agent, association
Effect agent, is 400r/min at speed of agitator, and microwave power is 130W, and temperature is stirring 2.5h at 83 DEG C, prepares mixture B；
S33: by step S32 prepare mixture B be cooled to room temperature after, by precipitate filter, under rotating speed is 3000r/min from
It is 3% that the heart is dried to water content, prepares fire retardant；
S4: mixture c step S3 prepared is melt extruded at 108 DEG C by extruder, and by crusher film-making,
Lamellar body is prepared after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 120 mesh sieve after pulverizing, and prepares novel high-performance water-repellent paint.
Embodiment 3
A kind of novel high-performance water-repellent paint, in units of weight, including following raw material: Tert-butyl Methacrylate 136 parts, first
Base n-propyl 58 parts, tributyl citrate 37 parts, ethyl methacrylate 26 parts, aqueous acrylic emulsion 48 parts, poly-
Acrylamide solution 34 parts, Tissuemat E 40 parts, calcium carbonate 8 parts, Kaolin 6 parts, Pulvis Talci 5 parts, 6 parts of polyester fiber, glass
Fiber 5 parts, hydroxypropyl methyl cellulose 8 parts, bamboo carbon fiber 5 parts, degasser 0.8 part, dispersant 0.8 part, wetting agent 0.4 part,
Adhesion promoter 0.5 part, catalyst 0.3 part, initiator 0.2 part, vertical stricture of vagina agent 0.6 part, toughener 0.5 part, optical brightener 0.7
Part, defoamer 0.6 part, viscosifier 0.3 part, 1.5 parts of firming agent, preservative 0.3 part, 0.3 part of antioxidant, light stabilizer 0.2 part,
UV absorbent 0.3 part, thickening agent 0.6 part, coalescents 0.4 part, fire retardant 1.5 parts；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF-369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents is Yi Siman coalescents；
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 22 parts, 2,2-bis-
Methyl isophthalic acid, 3-propylidene dimethylacrylate 12 parts, APP 15 parts, tetramethylolmethane 10 parts, 9 parts of carbamide, calcium carbonate 5
Part, antimony oxide 10 parts, manganese oxide 6 parts, bentonite 3 parts, penetrating agent 0.8 part, synergist 0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described novel high-performance water-repellent paint, comprises the following steps:
S1: by Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, polyethylene
Wax, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, point
Powder, wetting agent, adhesion promoter, catalyst, initiator mix, and are 150W at microwave power, and temperature is 95 DEG C, and rotating speed is
Stir 2.5h under 3000r/min, prepare mixture a；
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares
Agent, optical brightener, defoamer, viscosifier, be 180W at microwave power, and temperature is 125 DEG C, and rotating speed is stirring 3h under 600r/min,
Prepare mixture b；
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares
Thick dose, coalescents, fire retardant, be 200W at microwave power, temperature is 115 DEG C, rotating speed be under 400r/min stirring 2h, prepare
Mixture c；
The preparation method of described fire retardant, comprises the following steps:
S31: APP, 150 parts of water are added in microwave reactor, stirs 5min, system under speed of agitator is 400r/min
Obtain mixture A；
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3-
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, calcium carbonate, antimony oxide, manganese oxide, bentonite, penetrating agent, association
Effect agent, is 600r/min at speed of agitator, and microwave power is 180W, and temperature is stirring 1.8h at 89 DEG C, prepares mixture B；
S33: by step S32 prepare mixture B be cooled to room temperature after, by precipitate filter, under rotating speed is 5000r/min from
It is 2% that the heart is dried to water content, prepares fire retardant；
S4: mixture c step S3 prepared is melt extruded at 1115 DEG C by extruder, and by crusher system
Sheet, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 180 mesh sieve after pulverizing, and prepares novel high-performance water-repellent paint.
The performance indications of the novel high-performance water-repellent paint that detection embodiment 1-3 prepares, result is as shown in the table.
As seen from the above table: the coating of the present invention had both had adhesive force and the mechanical property of excellence, have again excellent water-fast
Property, resistance to ag(e)ing, crack resistance and thermal adaptability, and the nonhazardous of product own, be the new of a kind of excellent combination property
Type high-performance waterproof paint.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led
For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace,
All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (7)
1. a novel high-performance water-repellent paint, it is characterised in that in units of weight, including following raw material: methacrylic acid
Tert-butyl ester 105-136 part, n propyl methacrylate 34-58 part, tributyl citrate 23-37 part, ethyl methacrylate 15-
26 parts, aqueous acrylic emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, calcium carbonate 4-8 part,
Kaolin 3-6 part, Pulvis Talci 2-5 part, polyester fiber 3-6 part, glass fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo
Carbon fibe 2-5 part, degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-
0.5 part, catalyst 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener
0.3-0.7 part, defoamer 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, anti-
Oxygen agent 0.2-0.3 part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, film forming help
Agent 0.3-0.4 part, fire retardant 1.2-1.5 part；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14-22 part, 2,
2-dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9
Part, calcium carbonate 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, synergistic
Agent 0.3-0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described novel high-performance water-repellent paint, comprises the following steps:
S1: by Tert-butyl Methacrylate, n propyl methacrylate, tributyl citrate, ethyl methacrylate, polyethylene
Wax, calcium carbonate, Kaolin, Pulvis Talci, polyester fiber, glass fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, point
Powder, wetting agent, adhesion promoter, catalyst, initiator mix, and are 120-150W at microwave power, and temperature is 88-95
DEG C, rotating speed is stirring 2.5-3h under 2400-3000r/min, prepares mixture a；
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares
Agent, optical brightener, defoamer, viscosifier, be 140-180W at microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/
Stir 3-5h under min, prepare mixture b；
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares
Thick dose, coalescents, fire retardant, be 130-200W at microwave power, temperature is 105-115 DEG C, and rotating speed is 200-400r/min
Lower stirring 2-4h, prepares mixture c；
The preparation method of described fire retardant, comprises the following steps:
S31: APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is 300-400r/min
5-8min, prepares mixture A；
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3-
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, calcium carbonate, antimony oxide, manganese oxide, bentonite, penetrating agent, association
Effect agent, is 400-600r/min at speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8-2.5h at being 83-89 DEG C,
Prepare mixture B；
S33: after the mixture B that step S32 prepares is cooled to room temperature, filters precipitate, is 3000-5000r/ at rotating speed
Under min, centrifugal drying is to water content≤4%, prepares fire retardant；
S4: mixture c step S3 prepared is melt extruded at 108-115 DEG C by extruder, and passes through crusher
Film-making, prepares lamellar body after cooling；
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing；
S6: pelletizing step S5 prepared crosses 120-180 mesh sieve after pulverizing, and prepares novel high-performance water-repellent paint.
Novel high-performance water-repellent paint the most according to claim 1, it is characterised in that described preservative is Liquid BPF-369.
Novel high-performance water-repellent paint the most according to claim 1, it is characterised in that described antioxidant is antioxidant AT-
330。
Novel high-performance water-repellent paint the most according to claim 1, it is characterised in that described light stabilizer is light stabilizer
HS-3101。
Novel high-performance water-repellent paint the most according to claim 1, it is characterised in that described UV absorbent is adjacent hydroxyl
Phenol benzoate.
Novel high-performance water-repellent paint the most according to claim 1, it is characterised in that described thickening agent is xanthan gum.
Novel high-performance water-repellent paint the most according to claim 1, it is characterised in that described coalescents is Yi Siman film forming
Auxiliary agent.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1393485A (en) * | 2001-06-29 | 2003-01-29 | 大赛璐化学工业株式会社 | Flame-retarded polyolefin resin composition |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
| CN104559373A (en) * | 2014-12-30 | 2015-04-29 | 青建集团股份公司 | Waterproof paint for external walls and preparation method of waterproof paint |
| CN105688360A (en) * | 2015-10-29 | 2016-06-22 | 陈闽玲 | Class-A fire extinguishing agent |
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2016
- 2016-09-09 CN CN201610812835.6A patent/CN106189428A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1393485A (en) * | 2001-06-29 | 2003-01-29 | 大赛璐化学工业株式会社 | Flame-retarded polyolefin resin composition |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
| CN104559373A (en) * | 2014-12-30 | 2015-04-29 | 青建集团股份公司 | Waterproof paint for external walls and preparation method of waterproof paint |
| CN105688360A (en) * | 2015-10-29 | 2016-06-22 | 陈闽玲 | Class-A fire extinguishing agent |
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Application publication date: 20161207 |