CN106187087A - 基于花岗岩尾矿的饰面复合发泡陶瓷及其制备方法 - Google Patents
基于花岗岩尾矿的饰面复合发泡陶瓷及其制备方法 Download PDFInfo
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- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 239000010438 granite Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 27
- 239000004927 clay Substances 0.000 claims abstract description 17
- 230000004907 flux Effects 0.000 claims abstract description 15
- 239000004088 foaming agent Substances 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 14
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- 238000000034 method Methods 0.000 claims abstract description 6
- 239000004575 stone Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 13
- 239000012700 ceramic precursor Substances 0.000 claims description 6
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- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 208000031481 Pathologic Constriction Diseases 0.000 claims description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 4
- 239000010436 fluorite Substances 0.000 claims description 4
- 210000001215 vagina Anatomy 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000010451 perlite Substances 0.000 claims description 3
- 235000019362 perlite Nutrition 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
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- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 3
- 230000003247 decreasing effect Effects 0.000 abstract description 2
- 239000012774 insulation material Substances 0.000 abstract description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical group O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 2
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开了一种基于花岗岩尾矿的饰面复合发泡陶瓷及其制备方法，饰面复合发泡陶瓷,包括饰面层和发泡陶瓷，所述饰面层包括高透熔块55‑85％，黏土5‑20％，无机色料0‑10％；所述发泡陶瓷包括花岗岩尾矿60‑90％，黏土10‑25％，助熔剂1‑10％，发泡剂1‑10％,稳定剂0.5‑2％，解胶剂0‑2％。制备时，分别制备饰面层和发泡陶瓷，然后采用反铺料工艺制备饰面复合发泡陶瓷。本发明将饰面材料与发泡陶瓷一体化，可以减少外墙贴完保温材料之后再额外进行装饰的工序，这样既减少了施工工序有节约了大量成本，可以极大地减少施工成本和施工难度。
Description
技术领域
本发明涉及发泡陶瓷的人工合成领域，具体涉及一种基于花岗岩尾矿的饰面复合发泡陶瓷及其制备方法。
背景技术
目前市面上出现的一些花岗岩、大理石饰面发泡陶瓷一体板，是通过用有机胶水把经切割的天然花岗岩和大理石薄板，粘贴在发泡陶瓷基底上而制得，其防火性能差，易老化，粘贴层容易脱落，且成本较高，也不环保。
发明内容
为克服上述技术问题，本发明的目的在于提供一种具有高强度、高坚韧性的基于花岗岩尾矿的饰面复合发泡陶瓷及其制备方法。
所采用的技术方案为：
一种基于花岗岩尾矿的饰面复合发泡陶瓷,包括饰面层和发泡陶瓷，所述饰面层按重量百分比计，包括如下组份：高透熔块55-85％，黏土5-20％，无机色料0-10％，各组份含量百分数之和为100％；所述发泡陶瓷按重量百分比计，包括如下组份：花岗岩尾矿60-90％，黏土10-25％，助熔剂1-10％，发泡剂1-10％,稳定剂0.5-2％，解胶剂0-2％，各组分含量百分数之和为100％。
优选地，所述饰面层按重量百分比计，包括如下组份：高透熔块70-85％，黏土10-20％，无机色料0-10％；所述发泡陶瓷按重量百分比计，包括如下组份：花岗岩尾矿60-80％，黏土10-25％，助熔剂1-10％，发泡剂1-10％,稳定剂0.5-2％，解胶剂0-2％。
优选地，所述助熔剂包括煅烧滑石、生滑石、萤石中的一种或一种以上。
优选地，所述发泡剂包括膨胀珍珠岩、碳化硅、碳酸钙、碳粉、聚苯乙烯中的一种或一种以上。
优选地，所述的稳定剂为钇、铈的氧化物中的一种或一种以上。
优选地，所述饰面层为仿花岗岩釉面、仿大理石釉面或仿木纹釉面。
所述无机色料如氧化铁、锌黄或炭黑等，根据实际需要选择添加。所述高透熔块即高透明熔块，市面上有陶瓷专用的高透熔块。
一种上述任一方案所述的基于花岗岩尾矿的饰面复合发泡陶瓷的制备方法,包括如下步骤：
S1.制备饰面层：(1)按配方称量各种原料；(2)将各种原料破碎过筛；(3)将各种原料放入搅拌容器中混合均匀；
S2.制备发泡陶瓷：(1)按配方称量各种原料；(2)将各种原料放入球磨机中湿磨，得到一定细度的浆料；(3)用压力喷雾干燥塔对浆料进行干燥造粒，得到一定细度的空心球状发泡陶瓷前体料；
S3.制备饰面复合发泡陶瓷:
采用反铺料工艺，将S1得到的饰面层均匀布在耐高温模具上，再均匀铺上S2得到的发泡陶瓷前体料；将铺好料的模具在室温下放入烧结炉中，随炉升温至900-1500℃，保温1-3h；随炉冷却至室温，从炉中取出，经切割，打磨、抛光饰面，最终得到面复合发泡陶瓷。
优选地，制备饰面复合发泡陶瓷中，保温2h。
本发明的有益效果在于：
本发明将饰面材料与发泡陶瓷一体化，可以减少外墙贴完保温材料之后再额外进行装饰的工序，这样既减少了施工工序有节约了大量成本，可以极大地减少施工成本和施工难度。
本发明的饰面复合发泡陶瓷体积密度为300-800Kg/m3，抗压强度≥3MPa，抗折强度≥3MPa，导热系数≤0.1W/(m·K)，吸水率＜1％。
具体实施方式
下面通过具体的实施例对本发明进行详细说明，但这些例举性实施方式的用途和目的仅用来例举本发明，并非对本发明的实际保护范围构成任何形式的任何限定，更非将本发明的保护范围局限于此。
另外，除非特别说明，下面组分所用的百分比均为重量百分比。
实施例1
一种基于花岗岩尾矿的饰面复合发泡陶瓷,包括饰面层和发泡陶瓷，所述饰面层包括如下组份：高透熔块85％，黏土15％；所述发泡陶瓷包括如下组份：花岗岩尾矿63％，黏土15％，助熔剂10％，发泡剂10％,稳定剂2％。
所述助熔剂为煅烧滑石；
所述发泡剂为碳化硅；
所述稳定剂为钇氧化物和铈氧化物；
所述饰面层为仿花岗岩釉面。
制备方法如下：
S1.制备饰面层：(1)按配方称量各种原料；(2)将各种原料破碎过筛；(3)将各种原料放入搅拌容器中混合均匀；
S2.制备发泡陶瓷：(1)按配方称量各种原料；(2)将各种原料放入球磨机中湿磨，得到一定细度的浆料；(3)用压力喷雾干燥塔对浆料进行干燥造粒，得到一定细度的空心球状发泡陶瓷前体料；
S3.制备饰面复合发泡陶瓷:
采用反铺料工艺，将S1得到的饰面层均匀布在耐高温模具上，再均匀铺上S2得到的发泡陶瓷前体料；将铺好料的模具在室温下放入烧结炉中，随炉升温至900-1500℃，保温2h；随炉冷却至室温，从炉中取出，经切割，打磨、抛光饰面，最终得到面复合发泡陶瓷。
实施例2
一种基于花岗岩尾矿的饰面复合发泡陶瓷,包括饰面层和发泡陶瓷，所述饰面层包括如下组份：高透熔块80％，黏土20％，无机色料10％；所述发泡陶瓷包括如下组份：花岗岩尾矿80％，黏土10％，助熔剂4％，发泡剂4％,稳定剂1％，解胶剂1％。
所述助熔剂为生滑石。
所述发泡剂为膨胀珍珠岩。
所述稳定剂为钇氧化物和铈氧化物。
所述饰面层为仿大理石釉面。
制备方法参照实施例1。
实施例3
一种基于花岗岩尾矿的饰面复合发泡陶瓷,包括饰面层和发泡陶瓷，所述饰面层包括如下组份：高透熔块75％，黏土15％，无机色料10％；所述发泡陶瓷包括如下组份：花岗岩尾矿70％，黏土10％，助熔剂8％，发泡剂8％,稳定剂2％，解胶剂2％。
所述助熔剂为萤石。
所述发泡剂为碳粉。
所述稳定剂为钇氧化物和铈氧化物。
所述饰面层为仿木纹釉面。
制备方法参照实施例1。
实施例4
一种基于花岗岩尾矿的饰面复合发泡陶瓷,包括饰面层和发泡陶瓷，所述饰面层包括如下组份：高透熔块85％，黏土10％，无机色料5％；所述发泡陶瓷包括如下组份：花岗岩尾矿75％，黏土13％，助熔剂5％，发泡剂5％,稳定剂1％，解胶剂1％。
所述助熔剂为萤石。
所述发泡剂为聚苯乙烯。
所述稳定剂为钇氧化物和铈氧化物。
所述饰面层为仿木纹釉面。
制备方法参照实施例1。
将实施例1-实施例4制得的饰面复合发泡陶瓷进行测试，测试结果参见下表1。
表1
应当理解，这些实施例的用途仅用于说明本发明而非意欲限制本发明的保护范围。此外，也应理解，在阅读了本发明的技术内容之后，本领域技术人员可以对本发明作各种改动、修改和/或变型，所有的这些等价形式同样落于本申请所附权利要求书所限定的保护范围之内。
Claims (8)
1.一种基于花岗岩尾矿的饰面复合发泡陶瓷,其特征在于，包括饰面层和发泡陶瓷，所述饰面层按重量百分比计，包括如下组份：高透熔块55-85％，黏土5-20％，无机色料0-10％，各组份含量百分数之和为100％；所述发泡陶瓷按重量百分比计，包括如下组份：花岗岩尾矿60-90％，黏土10-25％，助熔剂1-10％，发泡剂1-10％,稳定剂0.5-2％，解胶剂0-2％，各组分含量百分数之和为100％。
2.根据权利要求1所述的基于花岗岩尾矿的饰面复合发泡陶瓷,其特征在于，所述饰面层按重量百分比计，包括如下组份：高透熔块70-85％，黏土10-20％，无机色料0-10％；所述发泡陶瓷按重量百分比计，包括如下组份：花岗岩尾矿60-80％，黏土10-25％，助熔剂1-10％，发泡剂1-10％,稳定剂0.5-2％，解胶剂0-2％。
3.根据权利要求1所述的基于花岗岩尾矿的饰面复合发泡陶瓷,其特征在于，所述助熔剂包括煅烧滑石、生滑石、萤石中的一种或一种以上。
4.根据权利要求1所述的基于花岗岩尾矿的饰面复合发泡陶瓷,其特征在于，所述发泡剂包括膨胀珍珠岩、碳化硅、碳酸钙、碳粉、聚苯乙烯中的一种或一种以上。
5.据权利要求1所述的基于花岗岩尾矿的饰面复合发泡陶瓷,其特征在于，所述的稳定剂为钇、铈的氧化物中的一种或一种以上。
6.根据权利要求1所述的基于花岗岩尾矿的饰面复合发泡陶瓷,其特征在于，所述饰面层为仿花岗岩釉面、仿大理石釉面或仿木纹釉面。
7.一种权利要求1-6任一所述的基于花岗岩尾矿的饰面复合发泡陶瓷的制备方法,其特征在于，包括如下步骤：
S1.制备饰面层：(1)按配方称量各种原料；(2)将各种原料破碎过筛；(3)将各种原料放入搅拌容器中混合均匀；
S2.制备发泡陶瓷：(1)按配方称量各种原料；(2)将各种原料放入球磨机中湿磨，得到一定细度的浆料；(3)用压力喷雾干燥塔对浆料进行干燥造粒，得到一定细度的空心球状发泡陶瓷前体料；
S3.制备饰面复合发泡陶瓷:
采用反铺料工艺，将S1得到的饰面层均匀布在耐高温模具上，再均匀铺上S2得到的发泡陶瓷前体料；将铺好料的模具在室温下放入烧结炉中，随炉升温至900-1500℃，保温1-3h；随炉冷却至室温，从炉中取出，经切割，打磨、抛光饰面，最终得到面复合发泡陶瓷。
8.根据权利要求7所述的基于花岗岩尾矿的饰面复合发泡陶瓷的制备方法,其特征在于，制备饰面复合发泡陶瓷中，保温2h。
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