CN106186950A - A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and preparation method thereof - Google Patents
A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and preparation method thereof Download PDFInfo
- Publication number
- CN106186950A CN106186950A CN201610557490.4A CN201610557490A CN106186950A CN 106186950 A CN106186950 A CN 106186950A CN 201610557490 A CN201610557490 A CN 201610557490A CN 106186950 A CN106186950 A CN 106186950A
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- China
- Prior art keywords
- mortar
- hour
- leakage
- waterproofing
- mouldproof
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Building Environments (AREA)
Abstract
The invention discloses a kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar, add nano ferriferrous oxide and carried out organically-modified, reduce surface and can make it have facially amphiphilic, utilize three-dimensional protective effect to make nanoparticle be homogeneously dispersed in mortar to be difficult to reunite, improve the comprcssive strength of product, the most compound with polymer styrene-acrylic emulsion and polypropylene fibre again, by physics and chemical action, improve polypropylene fibre surface can, cohesive force between itself and mortar is improved, inhibit the generation of micro-crack in early days well, thus improve the impermeability of product, rupture strength and durability；The present invention also adds in raw material other effective additives of compatibility again to by modified for Boiler Ash, the each component of mortar is uniformly dispersed not free settling, significantly improve the water resistance of leak stopping mortar, the waterproofing and leakage-stopping mortar prepared has antibacterial and mouldproof, water-fast, high seepage-resistant grade and comprcssive strength, ageing resistance is good, easy construction, with low cost, environmental protection.
Description
Technical field
The present invention relates to building material technical field, particularly relate to a kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and making side thereof
Method.
Background technology
Leakage of buildings problem is the common quality defect that building more highlights, and tracing it to its cause is architectural engineering xoncrete structure
Because the reasons such as autogenous shrinkage, temperature deformation, design defect or construction produce crack, cause seepage, thus cause roof leakage, wall
Wall seepage, rendering layer obscission, not only upset orthobiosis and the work of people, and directly influence whole solitary building
In service life, waterproofing and leakage-stopping mortar arises at the historic moment.Waterproofing and leakage-stopping mortar, with high grade cement, sand, stone as raw material, mixes multiple high score
Sub-additive, by adjusting match ratio, is improved cement pore structure, increases various raw-material density, or shunk by compensation
Improve the anti-crack and anti-seepage ability of concrete.
Waterproofing and leakage-stopping mortar is widely used in China, and manufacturing enterprise is numerous, from the point of view of base material essence, mainly with aluminate
Cement based or portland cement sill are base material.Aluminate cement later strength in wet condition can reduce, and silicate
There is length setting time, early strength development and slowly and produce the fundamental issues such as contraction after hardening in cement, thus increasing is added in research
The new waterproof leak stopping mortar of strong material is significant.
Polypropylene fibre has the advantage such as easy construction, with low cost, resistance to chemical attack, mixes as reinforcing material
In cement mortar, it is possible to reduce mortar is the generation of micro-crack in hardening process, and stop or delay it to extend, thus effectively carrying
The tensile strength of high mortar.But polypropylene fibre smooth surface, surface can without any active group on low, strand, and
Surface hydrophobicity, causes it poor with cement matrix adhesive property.Exist simultaneously as PP fiber reinforced cement mortar is internal
A large amount of holes, cause cement-hydrate, polypropylene fibre and aggregate interracial contact abundant not, reduce the durable of cement mortar
Performance, these all have influence on polypropylene fibre application effect in cement-based material, constrain its range of application.To this end, it is " poly-
The tacryl impact on polymer cement mortar performance " use a certain amount of styrene-acrylic emulsion of admixture to PP fiber reinforced cement sand
Slurry is modified, and result shows: admixture polypropylene fibre and styrene-acrylic emulsion are remarkably improved the rupture strength of cement mortar simultaneously
And anti-permeability performance, when polypropylene fiber is 0.6kg/m3, styrene-acrylic emulsion volume is when being 10%, compared with benchmark mortar specimen,
Its 28d rupture strength and impermeability pressure increase 29.20% and 400% respectively.But, use the water that the processing method in literary composition obtains
The comprcssive strength of cement mortar is low, also needs to be modified.
Nano material possesses skin effect, small-size effect, quantum size effect, macroparticle tunnel-effect, and these are special
Different character makes it in polymer modification, improves in coating, binder performance and becomes irreplaceable material, and the present invention uses nanometer
Material adds in raw material to styrene-acrylic emulsion is the most modified, with improve product comprcssive strength, water-fast impervious, anticorrosion is resistance to always
The performances such as change, but these special natures of nano material there is also certain limitation, such as due to small size can be big than table
Easily reunite, cause disperseing uneven, thus be necessary to be then added in raw material, to change the nano material added is in addition modified
The all technical of kind product.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and
Manufacture method.
The present invention is achieved by the following technical solutions:
A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar, is prepared by the raw materials in: Portland cement 22-23, fluvial sand
46-48, attapulgite 14-16, Boiler Ash 16-18, polypropylene fibre 4-6, monkey grass 2-3, styrene-acrylic emulsion 7-9, waterglass
3.5-4.5, chitosan 1.4-1.7, pentyl acetate 8-10, dimethylethanolamine 2.4-2.6, nano ferriferrous oxide 1.2-1.4,
Suitable quantity of water.
The manufacture method of described a kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar, comprises the following steps:
(1) under nitrogen protection by pentyl acetate heated and boiled, add nano ferriferrous oxide and keep temperature to stir 1-2 hour,
Filtration, washing after drying, add waterglass, chitosan grinding 20-30 minute, freezing 3-5 hour at subzero 15-20 DEG C, system
Obtain organic modified nano ferroso-ferric oxide；
(2) Boiler Ash being put in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing is to neutral, and 30-50 DEG C of vacuum is done
Dry, add dimethylethanolamine ultrasonic disperse and within 2-3 hour, obtain aminated modified Boiler Ash, add monkey grass ultrasonic grinding
30-50 minute, obtain modified Boiler Ash；
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, organic modified nano ferroso-ferric oxide are put into high mixed
Machine high speed stirs 1-2 hour, is cooled to room temperature, add Portland cement, fluvial sand, modified Boiler Ash and other remain into
Dividing and grind 1-2 hour, discharging, wherein the ratio of mud is 1: 0.4.
The invention have the advantage that the present invention adds nano ferriferrous oxide and carried out organically-modified, reduce surface
Can make it have facially amphiphilic, utilize three-dimensional protective effect to make nanoparticle be homogeneously dispersed in mortar and be difficult to reunite,
Improve the comprcssive strength of product, more compound with polymer styrene-acrylic emulsion and polypropylene fibre, made by physics and chemistry
With, improve polypropylene fibre surface can so that the cohesive force between itself and mortar improves, and inhibits early stage micro-crack well
Produce, thus improve the impermeability of product, rupture strength and durability；The present invention also adds raw material to by modified for Boiler Ash
In other effective additives of compatibility again so that each component of mortar is uniformly dispersed not free settling, hence it is evident that improve the anti-of leak stopping mortar
Aqueous energy, prepared waterproofing and leakage-stopping mortar has antibacterial and mouldproof, water-fast, high seepage-resistant grade and comprcssive strength, ageing resistance
Good, easy construction, with low cost, environmental protection.
Detailed description of the invention
A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar, is prepared by the raw materials in: Portland cement 22, fluvial sand
46, attapulgite 14, Boiler Ash 16, polypropylene fibre 4, monkey grass 2, styrene-acrylic emulsion 7, waterglass 3.5, chitosan 1.4, second
Acid pentyl ester 8, dimethylethanolamine 2.4, nano ferriferrous oxide 1.2, suitable quantity of water.
The manufacture method of described a kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar, comprises the following steps:
(1) under nitrogen protection by pentyl acetate heated and boiled, add nano ferriferrous oxide and keep temperature to stir 1-2 hour,
Filtration, washing after drying, add waterglass, chitosan grinding 20-30 minute, freezing 3-5 hour at subzero 15-20 DEG C, system
Obtain organic modified nano ferroso-ferric oxide；
(2) Boiler Ash being put in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing is to neutral, and 30-50 DEG C of vacuum is done
Dry, add dimethylethanolamine ultrasonic disperse and within 2-3 hour, obtain aminated modified Boiler Ash, add monkey grass ultrasonic grinding
30-50 minute, obtain modified Boiler Ash；
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, organic modified nano ferroso-ferric oxide are put into high mixed
Machine high speed stirs 1-2 hour, is cooled to room temperature, add Portland cement, fluvial sand, modified Boiler Ash and other remain into
Dividing and grind 1-2 hour, discharging, wherein the ratio of mud is 1: 0.4.
Utilizing the present invention to prepare its 28d rupture strength of waterproofing and leakage-stopping mortar is that 8.52MPa, 28d comprcssive strength is
44.12MPa, impermeability pressure is 1.12 MPa.
Claims (2)
1. an antibacterial and mouldproof waterproofing and leakage-stopping mortar, it is characterised in that be prepared by the raw materials in: normal silicate water
Mud 22-23, fluvial sand 46-48, attapulgite 14-16, Boiler Ash 16-18, polypropylene fibre 4-6, monkey grass 2-3, phenylpropyl alcohol breast
Liquid 7-9, waterglass 3.5-4.5, chitosan 1.4-1.7, pentyl acetate 8-10, dimethylethanolamine 2.4-2.6, nanometer four aoxidize
Three-iron 1.2-1.4, suitable quantity of water.
The manufacture method of a kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar the most according to claim 1, it is characterised in that include with
Lower step:
(1) under nitrogen protection by pentyl acetate heated and boiled, add nano ferriferrous oxide and keep temperature to stir 1-2 hour,
Filtration, washing after drying, add waterglass, chitosan grinding 20-30 minute, freezing 3-5 hour at subzero 15-20 DEG C, system
Obtain organic modified nano ferroso-ferric oxide；
(2) Boiler Ash being put in 60-80 DEG C of ultrasonic disperse 1-2 hour in concentrated hydrochloric acid, washing is to neutral, and 30-50 DEG C of vacuum is done
Dry, add dimethylethanolamine ultrasonic disperse and within 2-3 hour, obtain aminated modified Boiler Ash, add monkey grass ultrasonic grinding
30-50 minute, obtain modified Boiler Ash；
(3) styrene-acrylic emulsion being heated to 80-90 DEG C, addition polypropylene fibre, organic modified nano ferroso-ferric oxide are put into high mixed
Machine high speed stirs 1-2 hour, is cooled to room temperature, add Portland cement, fluvial sand, modified Boiler Ash and other remain into
Dividing and grind 1-2 hour, discharging, wherein the ratio of mud is 1: 0.4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610557490.4A CN106186950A (en) | 2016-07-15 | 2016-07-15 | A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610557490.4A CN106186950A (en) | 2016-07-15 | 2016-07-15 | A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106186950A true CN106186950A (en) | 2016-12-07 |
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| CN201610557490.4A Pending CN106186950A (en) | 2016-07-15 | 2016-07-15 | A kind of antibacterial and mouldproof waterproofing and leakage-stopping mortar and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108546056A (en) * | 2018-03-23 | 2018-09-18 | 常德市万福达环保节能建材有限公司 | A kind of waterproofing and leakage-stopping mortar |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103819153A (en) * | 2013-12-31 | 2014-05-28 | 安徽省美域节能环保技术应用有限公司 | Anti-freeze composite cement mortar |
-
2016
- 2016-07-15 CN CN201610557490.4A patent/CN106186950A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103819153A (en) * | 2013-12-31 | 2014-05-28 | 安徽省美域节能环保技术应用有限公司 | Anti-freeze composite cement mortar |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108546056A (en) * | 2018-03-23 | 2018-09-18 | 常德市万福达环保节能建材有限公司 | A kind of waterproofing and leakage-stopping mortar |
| CN108546056B (en) * | 2018-03-23 | 2020-11-10 | 常德市万福达环保节能建材有限公司 | Waterproof leaking stoppage mortar |
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Application publication date: 20161207 |