CN1061813C - Soluble solid glyphosate preparation - Google Patents
Soluble solid glyphosate preparation Download PDFInfo
- Publication number
- CN1061813C CN1061813C CN97107058A CN97107058A CN1061813C CN 1061813 C CN1061813 C CN 1061813C CN 97107058 A CN97107058 A CN 97107058A CN 97107058 A CN97107058 A CN 97107058A CN 1061813 C CN1061813 C CN 1061813C
- Authority
- CN
- China
- Prior art keywords
- glyphosate
- soluble solid
- urea
- former powder
- preparation according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The present invention discloses a soluble solid glyphosate preparation which comprises a glyphosate ingredient. The present invention is different from the prior art that the glyphosate ingredient adopts the glyphosate raw powder, and is added with a surface active agent and a synergism solubilization additive; the glyphosate raw powder and the surface active agent respectively accounts for 20% to 70% and 4 to 12% of the total amount, and the synergism solubilization additive is the rest amount. The present invention has the advantages of little environment pollution, low cost, cheap selling price, easy transportation, package and storage and convenient carrying and use.
Description
The weed killer herbicide that the present invention relates to use on the agricultural is a kind of steriland herbicide, specifically, be a kind of be the water-soluble solid dosage forms of Main Ingredients and Appearance with the glyphosate technicals.
Glyphosate is all bigger unique steriland herbicide of China's output and consumption, domestic large tracts of land be used for mulberry, really, tea place and uncultivated area weeding, the export volume of glyphosate technicals is also bigger, is the main pesticide species of China's foreign exchange earning.But because glyphosate can not be water-soluble, prior preparation method mainly is to add isopropylamine etc. to dissolve to form glyphosate isopropyl amine salt etc., so that its final water soluble forms aqua.As U.S. broad-mouthed receptacle for holding liquid mountain all " farming reaches " board 41% glyphosate isopropyl amine salt aqua of company exploitation, the weed killer herbicide that China generally uses, effect is best at present exactly.China is because the auxiliary agent problem that adopts, the similar products of being produced on drug effect " farming reaches " for poor, therefore, the domestic market has been full of U.S.'s " farming reaches " 41% glyphosate isopropyl amine salt aqua weed killer herbicide, and this product is actually and utilizes the auxiliary agent that adds the U.S. after former powder of glyphosate that China produces and the isopropylamine dissolving to produce, therefore, how to utilize homemade auxiliary agent to produce highy potent herbicide and become the important topic of pendulum in face of China's pesticide producing industry.
The purpose of this invention is to provide a kind of good drug efficacy, cost low, pollute less, glyphosate soluble solids formulation easy to use.
Technical solution of the present invention is: a kind of soluble solid glyphosate preparation, contain the glyphosate composition, and the difference of itself and prior art is: what the glyphosate composition adopted is the former powder of glyphosate, and with addition of surfactant and synergy solubilising additive are arranged; The former powder of glyphosate, surfactant shared proportion in total amount is respectively 20%-70%, 4-12%, and all the other are synergy solubilising additive.
What the surfactant described in the present invention adopted is natural non-ionic surface active agent, or cationic surfactant, anion surfactant etc.
Non-ionic surface active agent described in the present invention adopts commercially available SDP (being natural non-ionic additive).
Certainly, also can adopt other proper auxiliary agent etc.
Synergy solubilising additive described in the present invention comprises synergy solubilizer and filler.Certainly, also can adopt other suitable component forms.
The prescription of the product described in the present invention is: the glyphosate 30-60% of purity more than 95%; SDP5-10%; Sulfuric acid amine 8-20%; Urea 10-30%; All the other are filler.Certainly, also can adopt other suitable prescription forms.As adopt other synergy solubilizer or single synergy solubilizer etc.
The concrete prescription of the product described in the present invention is: 95% glyphosate 30% (or other suitable purities or ratio); SDP7%; Sulfuric acid amine 10%; Urea 20%; All the other are the filler glauber salt.Certainly, also can adopt other suitable concrete prescriptions.As adopt suitable synergy to increase flux, and other suitable fillers etc.
The concrete prescription of the product described in the present invention also can be: 95% glyphosate 40% (or other suitable purities or ratio); SDP10% (or other suitable zwitterion auxiliary agents); Sulfuric acid amine 10%; Urea 30%; All the other are glauber salt.Certainly, also can adopt other suitable concrete prescription and proportionings.
The concrete prescription of the product described in the present invention also can be: 95% glyphosate 50%; SDP10%; Sulfuric acid amine 15%; Urea 20%; All the other are glauber salt etc.Certainly, also can adopt other suitable concrete prescription or proportionings.As adopt four kinds or six kinds or more kinds of components etc.
The concrete prescription of the product described in the present invention also can be: 95% glyphosate 20%; SDP9%; Sulfuric acid amine 15%; Urea 25%; All the other are glauber salt etc.Certainly, also can adopt other suitable concrete prescription or proportionings.As adopt other suitable fillers, other suitable auxiliary agents etc.
The form of the product described in the present invention is powdery or sheet, bulk and graininess etc.Certainly, also can adopt other suitable solid dosages.
Advantage of the present invention is: good drug efficacy, drug effect surpasses the existing world, domestic weed killer herbicide product with glyphosate content.Environmental pollution is few, cost is low, price is cheap, be easy to transportation, packing and store, be convenient for carrying and use.The present invention is owing to add surfactant, particularly after the nonionic natural agents, ruined hydroxyl obtains repairing, replenishing after making glyphosate become aqua with other dissolution with solvents, the diffusion of surfactant simultaneously, help and synergistic effect such as ooze, so its drug effect is increased, restrain in the dosage process range with 100-300 at mu as the solvable pulvis of 30% glyphosate, preventive effect to all kinds of weeds, particularly perennial weed slightly is better than or significantly is better than the effect that U.S.'s farming reaches the processing of 41% glyphosate isopropyl amine salt aqua.And overcome the existing aqua product cost height intrinsic, used shortcomings such as inconvenience at aspects such as transportation, packing, storages.Can directly drop into the i.e. all dissolvings of stirring a little through several minutes in the water, and not have precipitation.Advantage of the present invention also can be by table 1: " 30% glyphosate soluble powder and farming reach aqua herbicidal effect relatively (behind the medicine 5-15 days) ", and table 2: " 30% glyphosate soluble powder and farming reach aqua herbicidal effect relatively (behind the medicine 25 days) ", table 3: " weeds cover degree * and plant height before the dispenser ", table 4: " 14 days weeds preventive effects after the dispenser ", table 5: " 28 days weeds preventive effects after the dispenser " waits and is illustrated.
Below in conjunction with embodiment the present invention is described in further detail:
Example 1:
Prescription: the former powder 30% of 95% glyphosate;
SDP (Nantong FeiTian Chemical Industry Co.,Ltd's production and sales) 7%;
Sulfuric acid amine 10%;
Urea 20%;
All the other are the filler glauber salt.
Earlier the former powder of glyphosate is crushed to 80-100 day (or other appropriate particle size); then with former powder and synergy solubilizer (sulfuric acid amine, urea), fill chaste tree etc. by prescription stir pulvis; certainly; also can again pulvis be pressed into sheet, piece agent through forming machine; or in comminutor, be molded into the graininess formulation again, with convenient storage, transportation and packing, use.
Example 2:
Prescription: 95% glyphosate 40%;
SDP10％；
Sulfuric acid amine 10%;
Urea 30%;
All the other are glauber salt or other suitable fillers.
The same substantially precedent of preparation method, or adopt other suitable agricultural chemicals mixing manufacture methods.
Example 3:
Prescription: the former powder 50% of 95% glyphosate;
SDP10％；
Sulfuric acid amine 15%;
Urea 20%;
All the other are glauber salt.
The same substantially precedent of preparation method.
Example 4:
Prescription: 95% glyphosate 20%;
SDP9％；
Sulfuric acid amine 15%;
Urea 25%;
All the other are glauber salt etc.
Preparation method also can same precedent, or adopts other suitable fabrication methods.
The present invention also can adopt other suitable prescription or proportionings.As only adopting four kinds of base stocks, or adopt six kinds or more kinds of components etc.
Table 1 30% glyphosate soluble powder and farming reach relatively (behind the medicine 5～15 days) Yizheng, Jiangsu in 1997 of aqua herbicidal effect
| Handle (gram milliliter/mu) | Get over year living weeds | Perennial weed | 15 days herbs behind the medicine | |||||||||||||||||||||||
| Before the medicine | Behind the medicine 5 days | Behind the medicine 10 days | Behind the medicine 15 days | Before the medicine | Behind the medicine 10 days | Behind the medicine 15 days | Total strain number | Total removing imitated % | Cumulative correction removes imitates % | |||||||||||||||||
| A kind of monkey mentioned in ancient literature hair is blunt | Carolina Cranesbill Herb | Lyrate hemistepta herb | The pool loosestrife | Annual fleabane herb | Add up to | Add up to the strain number | Remove and imitate % | Add up to the strain number | Remove and imitate % | Add up to the strain number | Remove and imitate % | The weeds shepherd's purse | Herba Cyperi Glomerati | Paspalum distichum | Chinese lobelia | Add up to | Add up to the strain number | Remove and imitate % | Proofread and correct to remove and imitate % | Add up to the strain number | Remove and imitate % | Proofread and correct to remove and imitate % | ||||
| 300 41% farmings of 30% glyphosate, 100 30% glyphosates, 150 30% glyphosates, 200 30% glyphosates, 250 30% glyphosates reach 100 41% farmings and reach 200 41% farmings and reach 300 no medicines contrast (strain/0.5m2) | 2.3 3.5 1.0 3.3 4.5 3.8 2.8 1.8 3.3 | 5.3 7.8 5.5 4.5 5.3 5.8 3.3 4.8 4.5 | 3.3 3.5 4.3 3.8 5.3 4.0 5.3 5.8 4.5 | 1.8 3.8 4.3 3.8 1.5 2.3 1.5 1.3 2.8 | 4.3 3.3 3.8 2.5 3.8 4.5 5.3 5.0 4.3 | 17.0 21.9 18.9 17.9 20.4 20.4 18.2 18.7 19.4 | 6.5 3.5 1.0 0 0 10.5 0.3 0 19.4 | 61.8 84.0 94.7 100 100 48.5 98.5 100 | 0 0 0 0 0 3.3 0 0 19.4 | 100 100 100 100 100 83.8 100 100 | 0 0 0 0 0 0.8 0 0 19.4 | 100 100 100 100 100 96.1 100 100 | 13.5 14.5 15.0 13.0 13.5 15.8 15.5 11.5 14.5 | 11.3 13.8 12.3 14.2 10.3 13.0 11.3 13.8 3.3 | 5.3 3.8 4.0 2.3 2.8 2.3 2.5 2.8 3.3 | 2.3 1.8 1.5 2.0 1.8 1.0 1.3 1.8 2.0 | 32.4 33.9 32.8 31.5 28.4 32.1 30.6 29.9 33.1 | 28．5 20.8 10.5 5.5 1.3 30.3 13.3 2.3 53.3 | 12.0 38.6 68.0 82.5 95.4 5.6 56.5 92.3 | 45.4 61.6 80.1 89.5 97.2 41.4 73.0 95.3 | 28.8 22.5 10.8 3.5 0.8 31.3 14.5 2.0 68.8 | 11.1 33.6 67.1 88.9 97.2 2.5 52.6 93.3 | 55.0 66.8 83.5 94.4 98.6 51.2 76.3 96.7 | 28.8 22.5 10.8 3.5 0.8 32.1 14.5 2.0 88.2 | 4.7 59.7 79.1 92.9 98.4 38.9 70.3 95.9 | 65.3 76.0 87.5 95.8 99.0 63.6 82.3 97.6 |
Table 2 30% glyphosate soluble powder and farming reach relatively (behind the medicine 25 days) Yizheng, Jiangsu in 1997 of aqua herbicidal effect
| Handle (gram milliliter/mu) | Get over year living weeds | Perennial weed | 25 days herbs behind the medicine | ||||||||||||||||||
| Before the medicine | Behind the medicine 25 days | Before the medicine | Behind the medicine 25 days | Total strain number | Total removing imitated % | Cumulative correction removes imitates % | Total fresh weight (gram) | Total fresh weight removes imitates (%) | |||||||||||||
| Hair is blunt | Carolina Cranesbill Herb | Lyrate hemistepta herb | The pool loosestrife | Annual fleabane herb | Add up to | Add up to the strain number | Remove and imitate % | Wild water chestnut | Herba Cyperi Glomerati | Paspalum distichum | Chinese lobelia | Add up to | Add up to the strain number | Remove and imitate % | Just removing and imitating % | ||||||
| 300 41% farmings of 30% glyphosate, 100 30% glyphosates, 150 30% glyphosates, 200 30% glyphosates, 250 30% glyphosates reach 100 41% farmings and reach 200 41% farmings and reach 300 no medicines contrast (strain gram/0.5M2) | 2.3 3.5 1.0 3.3 4.5 3.8 2.8 1.8 3.3 | 5.3 7.8 5.5 4.5 5.3 5.8 3.3 4.8 4.5 | 3.3 3.5 4.3 3.8 5.3 4.0 5.3 5.8 4.5 | 1.8 3.8 4.3 3.8 1.5 2.3 1.6 1.3 2.8 | 4.3 3.3 3.8 2.5 3.8 4.5 5.3 5.0 4.3 | 17.0 21.9 18.9 7.9 20.4 20.4 8.2 8.7 19.4 | 0 0 0 0 0 0.8 0 0 19.4 | 100 100 100 100 100 96.1 100 100 | 13.5 4.5 15.0 3.0 3.5 5.8 5.5 1.5 14.5 | 1.3 13.8 12.3 4.2 0.3 3.0 1.3 3.8 3.3 | 5.3 3.8 4.0 2.3 2.8 2.3 2.5 2.8 3.3 | 2.3 1.8 1.5 2.0 1.8 1.0 1.3 1.8 2.0 | 32.4 33.9 32.8 31.5 28.4 32.1 30.6 29.9 33.1 | 33.5 29.3 12.8 0.8 0 40.5 17.5 0.8 83.5 | - 13.6 61.0 97.5 100 - 42.8 97.3 | 59.0 65.7 84.5 99.0 100 49.9 77.3 99.0 | 33.5 29.3 12.8 0.8 0 41.3 17.5％ 0.8 102.9 | 32.2 47.5 75.2 98.4 100 21.3 64.1 98.4 | 65.4 73.2 87.4 99.2 100 59.9 81.7 99.1 | 233.0 183.5 98.8 8.2 0 253.0 132.3 7.5 673.5 | 66.9 72.7 85.3 98.8 100 62.4 80.4 98.9 |
Weeds cover degree * and plant height before table 3 dispenser
*: cover degree (%) plant height (cm): a represents annual weed; O.y represents year living weeds more, and p represents perennial weed.
| Handle (gram/mu) | Green foxtail a | Achyranthes aspera a | Herba Lactucae Indicae o.y | Wild calabash radish o.y | Lady's-grass wormwood artemisia o.y | Paspalum distichum p | Bermuda grass p | Alternanthera philoxeroides p | Wild Radix Artemisia ordosicae p |
| 478 farmings of glyphosate 150 glyphosates 200 glyphosates 250 glyphosates reach 200 farmings and reach 350 contrasts (CK) | 3/20 1 1 10 11 5 4 | 5/80 13 5 2 4 0 8 | 1/30 1 3 0 1 0 4 | 13/50 7 3 5 8 5 8 | 10/60 9 11 20 16 20 21 | 2/30 2 3 2 2 2 2 | 5/10 6 12 10 8 5 13 | 6/30 5 5 0 3 0 3 | 0 13/50 10 0 0 0 10 |
14 days weeds preventive effects (%) after table 4. dispenser
*: contrasting data is weeds cover degree (%).
| Handle (gram/mu) | Dog tail clay ox grass knee a a | Herba Lactucae Indicae o.y | Wild calabash radish o.y | Lady's-grass wormwood artemisia o.y | Paspalum distichum p | Bermuda grass p | Alternanthera philoxeroides p | Wild Radix Artemisia ordosicae p |
| 478 farmings of glyphosate 150 glyphosates 200 glyphosates 250 glyphosates reach 200 farmings and reach 350 contrast * (CK) | 60bc 43c 85ab 83abc 90ab 95a 100a 95a 80b 20cd 100a 90ab 10c 8d | 47abc 37bc 63a 17c / 5c | 50abc 60ab 45bc 60ab 43bc 80a 8c | 40c 53bc 63bc 80ab 53bc 85a 25cd | 20cd 85a 85a 80ab 47c 80ab 5d | 25c 30c 65a 60ab 45bc 60ab 15c | 80b 90a 90a / 95a / 10c | / 30ab 50a / / / 10b |
28 days weeds preventive effects (%) after table 5. dispenser
*: the data in the contrast be weeds cover a degree (%)/plant height (cm).
| Handle (gram/mu) | Dog tail clay ox grass knee a a | Herba Lactucae Indicae o.y | Wild calabash radish o.y | Lady's-grass wormwood artemisia o.y | Paspalum distichum p | Bermuda grass p | Alternanthera philoxeroides p | Wild Radix Artemisia ordosicae p |
| 478 farmings of glyphosate 150 glyphosates 200 glyphosates 250 glyphosates reach 200 farmings and reach 350 contrasts (CK) * | 65c 65b 83b 92a 100a 90a 100a 90a 77c 83ab 100a / 36/55d 8/80c | 77a 62b 70ab 63b / 0.5/20c | 95a 96a 90ab 100a 95a 100a / | 50b 89a 89a 90a 90a 90a 8/50bc | 65c 80ab 90a 90a 77abc 90a 7/45d | 55b 64ab 78a 70ab 55b 70a 6/12c | 90a 80ab 90a / 95a / 5/30c | / 80ab 85a / / / 40/100c |
Claims (8)
1, a kind of soluble solid glyphosate preparation, contain the glyphosate composition, it is characterized in that: what the glyphosate composition adopted is the former powder of glyphosate, and in total amount: the former powder of glyphosate accounts for 20%-70%, natural non-ionic surface active agent SDP accounts for 4-12%, and all the other are synergy solubilising additive.
2, soluble solid glyphosate preparation according to claim 1 is characterized in that: synergy solubilising additive comprises synergy solubilizer and filler.
3, soluble solid glyphosate preparation according to claim 1 and 2 is characterized in that: the former powder 28.5-57% of glyphosate; SDP5-10%; Ammonium sulfate 8-20%; Urea 10-30%; All the other are filler.
4, and soluble solid glyphosate preparation according to claim 3, it is characterized in that: the former powder 28.5% of glyphosate; SDP7%; Ammonium sulfate 10%; Urea 20%; All the other are the filler glauber salt.
5, soluble solid glyphosate preparation according to claim 3 is characterized in that: the former powder 38% of glyphosate; SDP10%; Ammonium sulfate 10%; Urea 30%; All the other are glauber salt.
6, glyphosate soluble solid medicament form according to claim 3 is characterized in that: the former powder 47.5% of glyphosate; SDP10%; Ammonium sulfate 15%; Urea 20%; All the other are glauber salt.
7, soluble solid glyphosate preparation according to claim 3 is characterized in that: the former powder 19% of glyphosate, SDP9%; Ammonium sulfate 15%; Urea 25%; All the other are glauber salt.
8, soluble solid glyphosate preparation according to claim 1 and 2 is characterized in that: product be shaped as powdery or sheet, bulk and graininess.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97107058A CN1061813C (en) | 1997-07-24 | 1997-07-24 | Soluble solid glyphosate preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97107058A CN1061813C (en) | 1997-07-24 | 1997-07-24 | Soluble solid glyphosate preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1181881A CN1181881A (en) | 1998-05-20 |
| CN1061813C true CN1061813C (en) | 2001-02-14 |
Family
ID=5169247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97107058A Expired - Fee Related CN1061813C (en) | 1997-07-24 | 1997-07-24 | Soluble solid glyphosate preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1061813C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101151971B (en) * | 2006-09-28 | 2011-02-09 | 捷马化工股份有限公司 | Method for producing glyphosate ammonium salt solid preparations |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990007275A1 (en) * | 1988-12-30 | 1990-07-12 | Monsanto Company | Improved glyphosate formulations |
| WO1992012637A1 (en) * | 1991-01-24 | 1992-08-06 | Monsanto Company | Improved glyphosate formulations |
| EP0498145A1 (en) * | 1991-02-08 | 1992-08-12 | Monsanto Europe S.A./N.V. | Solid glyphosate compositions and their use |
-
1997
- 1997-07-24 CN CN97107058A patent/CN1061813C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990007275A1 (en) * | 1988-12-30 | 1990-07-12 | Monsanto Company | Improved glyphosate formulations |
| WO1992012637A1 (en) * | 1991-01-24 | 1992-08-06 | Monsanto Company | Improved glyphosate formulations |
| EP0498145A1 (en) * | 1991-02-08 | 1992-08-12 | Monsanto Europe S.A./N.V. | Solid glyphosate compositions and their use |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1181881A (en) | 1998-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104117533B (en) | Containing selenium Agrotechnical formulation and the use in conjunction of heavy metal-polluted soil renovation agent | |
| CN101906001A (en) | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer | |
| CN105724399A (en) | Sterilization composition containing berberine and azoxystrobin | |
| KR20080033801A (en) | Tourmalin additive for enhancing absorption of inorganic and nutrient components and composite fertilizer comprising tourmalin | |
| CN1061813C (en) | Soluble solid glyphosate preparation | |
| CN105104391A (en) | Bactericidal composition containing berberine and oxine-copper | |
| CN114246179A (en) | Auxiliary agent suitable for microemulsion of high-salt system | |
| CN1064515C (en) | Soluble prophylactico-therapeutic agent for plant virus | |
| CN107365226B (en) | Synergistic composition of biogas slurry composite pesticide | |
| CN109321254A (en) | A kind of plant heavy metal barrier and preparation method thereof | |
| CN1826905A (en) | Compound pesticide of triperygium wilfordii alkaloid | |
| KR100329374B1 (en) | Water dispersable granule comprising paraquat dichloride and its manufacturing method | |
| CN1085884A (en) | Foliar fertilizer specially used for peanut | |
| CN103483081B (en) | A kind of foliage fertilizer improving broad bean selenium rich ability | |
| CN114145305B (en) | Composition for preventing and treating citrus moss disease | |
| CN1226928C (en) | Aju water dispersion granule and production method thereof | |
| CN1062639A (en) | Root element and manufacture method thereof | |
| CN1100738C (en) | Multifunctional compound fertilizer foumula and preparing method | |
| CN1613312A (en) | Agricultural bactericide containing cyclosulfamuron and aureofuscin, its preparation and uses | |
| US20100173015A1 (en) | Compositions and methods for the absorption, chelation, and elimination of trace elements | |
| CN108774631B (en) | A kind of preparation method of rock kinases | |
| CN102823625B (en) | Insecticidal composition containing metarhizium anisopliae and tefluthrin | |
| DE4404860A1 (en) | Plant tonic for induction and improvement of resistance | |
| CN1173998A (en) | Compound feed antifermenting and antioxidizing agent and its production process | |
| CN1701665A (en) | Highly effective nanometer seed coating agent with low toxicity and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: ZHANG HONGXIU Free format text: FORMER OWNER: ZHANG HONGXIU; NANTONG FEITIAN CHEMICAL INDUSTRY CO.,LTD. Effective date: 20010730 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20010730 Patentee after: Zhang Hongxiu Patentee before: Zhang Hongxiu Patentee before: Nantong Feitian Chemical Industry Co., Ltd. |
|
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Nantong Feitian Chemical Industry Co., Ltd. Assignor: Zhang Hongxiu Contract fulfillment period: 2008.8.10 to 2017.7.24 contract change Contract record no.: 2008320001065 Denomination of invention: Soluble solid glyphosate preparation Granted publication date: 20010113 License type: Exclusive license Record date: 20081027 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.8.10 TO 2017.7.24; CHANGE OF CONTRACT Name of requester: NANTONG FEITIAN CHEMICAL INDUSTRY CO.,LTD. Effective date: 20081027 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20010214 Termination date: 20160724 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |