KR20080033801A - Tourmalin additive for enhancing absorption of inorganic and nutrient components and composite fertilizer comprising tourmalin - Google Patents

Abstract

An agricultural composite fertilizer is provided to have easy handling property and long-term storage stability, promote the absorption of micro elements upon foliar application, and be produced in a simple manner and at low cost. An agricultural composite fertilizer in a water-soluble agent form comprises 50-99wt% of macro elements such as potassium, calcium, magnesium, nitrogen, and phosphoric acid, micro elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum, and cobalt, and optionally at least one component selected from saccharides, amino acids such as lysine, organic acids such as glutamic acid, seaweed extracts, and vitamins, and 1-50wt% of tourmaline as an absorption promoter of the above-mentioned components into a plant. Further, the tourmaline is in a form of 200 to 2000 mesh.

Description

TOURMALIN ADDITIVE FOR ENHANCING ABSORPTION OF INORGANIC AND NUTRIENT COMPONENTS AND COMPOSITE FERTILIZER COMPRISING TOURMALIN}

1 is a diagram illustrating the decomposition of harmful substances with the splitting effect of water molecule clusters by electrolysis by tourmaline.

The present invention relates to an absorption enhancer in plants such as cationic inorganic components such as calcium, anionic inorganic components such as phosphoric acid, sugars, amino acids such as lysine, organic acids such as glutamic acid, seaweed extract, and various nutritional components such as vitamins. As an active ingredient, additives for promoting absorption in plants of various trace elements that are difficult to absorb in plants by foliar fertilization such as various cations, anions and nutrients containing tourmaline as an active ingredient, a compound fertilizer containing the same, and a method of using the same It is about.

The present invention utilizes the property of tourmaline to divide the water molecule population small, so that a solution in which various inorganic and nutrient components are dissolved is well absorbed by the crops, thereby promoting plant absorption of these nutrients.

Leaf-based fertilization is a method of artificially absorbing the ingredients necessary for the growth of crops through the leaves of the crop. Green leaves are photosynthetic and respiratory through the pores to absorb and exchange carbon dioxide and oxygen. At this time, the material absorbed in the pores is used in the body for normal growth.

Foliar fertilization first became known in academia since Greece restored iron deficiency symptoms by applying iron to leaves. The unemployment of agricultural production began with the application of 2-8% ferric sulfide solution (FeSO4 · 7H2O) to the gastrointestinal disease that is common in pineapples in Hawaii around 1920.

Foliar fertilization is known as a very effective application method for the prevention and cure of physiological disorders because it can immediately supply the necessary inorganic components regardless of the condition of the soil or root of the plant and can be used quickly. However, there are some inorganic elements that are very difficult to absorb in water bodies. Particularly, bulk elements such as potassium, calcium, magnesium, nitrogen and phosphoric acid, monovalent or divalent cations, and trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum and cobalt, and glucose, sucrose, fructose and oligosaccharides Various sugars such as saccharides, amino acids such as lysine, organic acids such as glutamic acid and citric acid, seaweed extract, various vitamins such as vitamin A, vitamin B1 to B6, vitamin C, etc. are very difficult to absorb through leaf pores compared to other mass elements Because of this, there is a disadvantage that the water absorption rate is very low and the performance in the tissue is low. These components are not easily absorbed by plants and tend to be lost. Therefore, various researches for improving the absorption of the difficult to absorb components are in progress. The inventors of the present invention studied how to reduce the water molecules by reducing the mass of the water molecules through the pore of the crop if the clumps (water) of the water molecules are small. There are various methods such as hexagonal water, but it is not suitable for agriculture. After researching a more suitable method, it was noted that tourmaline used in ceramic balls, which are known to have a water purification function, can play such a role. It became.

The action and effects of tourmaline known to date include 1) electrostatic weak current generation, 2) weak current infiltration, 3) surfactant activation, 4) water activation, 5) tourmaline anion generation, 6) far infrared radiation , 7) mineral elution. Among these, the action of water shows that the hydrogen ions in the water molecules electrolyzed by the tourmaline are converted into hydrogen gas (H ₂ ) while being released as they combine with electrons attracted to the tourmaline electrode, thereby weakening the water (pH 7.2-7.5). . Alkalized water has a reducing power and is acidified, ie it comes into contact with the body's susceptible to antioxidant activity. In particular, water is made by gathering 6-7 clusters of H ₂ O, a combination of water molecules, and general water must combine dozens of clusters due to impurities. Water with large clusters has no taste and is difficult to be absorbed into the body. When tourmaline is added to water, electrolysis occurs, water clusters are decomposed, water molecules are smaller, and water is activated, so that permeability and absorption to skin and cells are increased, soft water is softened, and elution of ore elements turns into delicious ionized water.

Therefore, in view of the above characteristics, the present inventors have completed the present invention by studying the components that are difficult to absorb and transfer to plants to increase absorption in plants.

Accordingly, it is an object of the present invention to provide a method for promoting the absorption of components which are difficult to fulfill absorption in plants such as various inorganic components and nutritional components.

Another object of the present invention is to promote the absorption of tourmaline as an active ingredient for promoting the absorption of various minerals and nutrients such as cations and anions into the plant by using tourmaline to make water particles (clusters) small. It is to provide an additive for.

In order to achieve the above object, the present inventors have concentrated on the decomposition effect of water molecule Closter of tourmaline. As a result, the present inventors have found a method for effectively delivering trace elements such as various inorganic and nutrients in plants. The invention has been completed.

Ingredients that can promote absorption in the plant body by the method of the present invention include a large amount of elements such as potassium, calcium, magnesium, nitrogen, phosphoric acid, trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum, cobalt and sugars Examples include amino acids such as lysine, organic acids such as glutamic acid, seaweed extracts, vitamins, and the like, but these are merely exemplary, and are not particularly limited as long as the components are mixed and added with water as a solvent.

According to the present invention, there is provided a liquid fertilizer based on tourmaline and a compound fertilizer in the form of a water-soluble compound containing tourmaline with various trace and bulk urea components described above, and a method for their effective use. .

In the case of tourmaline liquid additives, an antisettling agent may be added to prevent the tourmaline from sinking.

In the case of using tourmaline to enhance the absorption of the bulk urea and trace urea as exemplified above, which is difficult to absorb in plants, the finer the powder of tourmaline, the larger the contact surface with water, but the effect will be maximized. In consideration of technical difficulties due to grinding, the powder size is preferably 200 to 2000 mesh.

The tourmaline additive of the present invention contains 1 to 50% by weight tourmaline and 50 to 99% by weight water as a liquid. If the amount of tourmaline is less than 1%, the amount of tourmaline is too low when dilution is used, and if the amount is greater than 50%, there is no difference in efficacy. Such tourmaline additive is used at a dilution of about 10 to 10,000 times, preferably 100 to 1,000 times, as needed.

In addition, the present invention is a bulk element such as potassium, calcium, magnesium, nitrogen, phosphoric acid and trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum, cobalt and amino acids such as sugars, lysine, organic acids such as glutamic acid, seaweed extract, The present invention also relates to an agricultural complex fertilizer in the form of an aqueous solution consisting of 50 to 99% by weight of at least one component selected from vitamins and 1 to 50% by weight of tourmaline as an in vivo plant absorption accelerator. If the tourmaline is less than 1%, as in the case of the tourmaline liquid additives above, the amount of tourmaline is too low when dilution is used, and if the 50% or more, there is no difference in efficacy, so the above range.

In one embodiment of the present invention in order to determine the absorption of calcium and various trace elements, the calcium or trace element receptor and tourmaline were diluted in water, respectively, and then foliar sprayed on leafy lettuce. The spraying concentration was about 300 ppm of calcium and 10 to 1000 ppm of tourmaline was diluted to compare the calcium content absorbed in the lettuce compared to the calcium treatment without added tourmaline.

Hereinafter, the present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.

Example 1

 Tourmaline liquid preparation manufacturing unit Raw material name Unit (%) Input amount per kg (g) Remarks Tourmaline 1000mesh AD 3030 Water 10 20 70 100 200 700 SNS Corporation SNS Corporation Anti-Sedimentation Agent system 100 1000

The ingredients of Table 1 were administered at the dosage described above, and other than tourmaline were also ground (325mesh), followed by homogeneous mixing to produce 1 Kg of tourmaline liquid.

 Calcium agent production unit Raw material name Unit (%) Input amount per kg (g) Remarks CaCl ₂ (CaO: 37.4%) Calcium Citrate (CaO: 25%) Citric Acid Sucrose Lysine Seaweed Extract Vitamin B ₁ White Carbon 70 15.5 2 2 1.2 2 0.8 6.5 700 155 20 20 12 20 8 65 CaO: 26.18% CaO: 3.875% Total: 30.05% system 100 1000

Example 2

 Tourmaline, trace element manufacturing unit Raw material name Unit (%) Input amount per kg (g) Remarks Tourmaline _{1,000mesh MnSO 4 · H 2 O CuSO} 4 · 5H 2 O Fe EDTA-Fe ZnSO 4 · 7H 2 OH 3 BO 3 10 5 5 20 30 30 100 50 50 200 300 300 system 100 1000

The dose was administered as described above, and components other than tourmaline were also pulverized (325mesh) and mixed homogeneously to produce 1 Kg of tourmaline receptor.

Test Example 1

100 ml (1000 ppm), 50 ml (500 ppm), 10 ml (100 ppm), 5 ml (50 ppm) and 1 ml (10 ppm), respectively, were added 10 g of 30% calcium receptor and 10% tourmaline 10% liquid. The rest was adjusted to 10 L total volume with water. The diluted solution was sprayed three times every four days from March 19, 2006 to hydroponic cultivation lettuce to extract all leaves of the test plot on March 31. The harvested leaves were washed with running water and dried in a hot air dryer. The dried samples were pulverized and wet decomposed to analyze calcium content of each treatment by ICP. The findings are as follows.

 Calcium Absorption of Lettuce by Tourmaline Concentration Tourmaline amount (ppm) Calcium Absorption (mg / kg) Absorption rate (%) Remarks 0 1000 (100ml / 10L) 500 (50ml / 10L) 100 (10ml / 10L) 50 (5ml / 10L) 10 (1ml / 10L) 1.36 1.39 1.48 1.51 1.46 1.37 100 102 109 111 107 101    100 ml, 50 ml, 10 ml, 5 ml, and 1 ml of tourmaline solution were added to a 300 ppm solution of calcium and diluted in water to a total volume of 10 L.

As can be seen from Table 4, when looking at the calcium content in the lettuce leaves of each treatment group of the calcium receptor and tourmaline liquid mixture of the present invention, the tourmaline 100ppm treatment of "Example 1" compared to the calcium receptor single sprayer The calcium absorption was about 11%. Therefore, it was found that the absorption of inorganic components in the plant was promoted by adding tourmaline rather than the spraying of calcium aqueous solution only.

Test Example 2

Example 2 The tourmaline microurea water-soluble fertilizers of the "microelement formulation" and "Example 2" formulations, except for the tourmaline component, were diluted 1000 times and sprayed three times every 4 days from March 19 to the hydroponic lettuce. It was. The trace elements absorbed in the lettuce leaves were collected on March 31 and all the leaves of the experimental section were washed with running water and dried in a hot air dryer. And the dry sample was pulverized and wet decomposed to analyze the trace element content of each treatment by ICP. The findings are as follows.

 Manganese, Iron, Copper, Zinc, Boron Absorption in Lettuce Dilution factor Mn (ppm) Fe (ppm) Cu (ppm) Zn (ppm) B (ppm) No treatment - 14 109.3 10 45 87.3 Trace Urea Fertilizer (except tourmaline) 1,000 times 29 (100) 136.0 (100) 23 (100) 112 (100) 137 (100) Example 2 Formulations 1,000 times 35 (121) 143.3 (105) 26 (113) 125 (112) 158 (115) (): Percentage value (absorption rate) comparing the treatment value for trace elements with 100

As can be seen in Table 5, the "Example 2" tourmaline microelement solubles and trace urea solubles of the present invention are sprayed separately and the trace element content in the lettuce leaves of each treatment group, "Example 2" Preparation 1000 The drainage treatment group had a higher absorption of Mn by about 21% compared to the microurea single sprayer. In addition, when looking at the Fe content absorbed in the lettuce leaf, the 1000 times treatment group of "Example 2" was a large amount of Mn absorption of about 5% compared to the microelement water-soluble single spray. In addition, when the absorbed Cu content of the 1000 times treatment group of “Example 2” was absorbed, the absorption amount of Cu was about 13% higher than that of the spraying device for the trace element receiving agent. In addition, the contents of Zn and B elements in the leaves were also increased by 12% and 15%, respectively. Therefore, it was found that the tourmaline-containing formulation of “Example 2” enhances the absorption of trace elements in plants, compared to the preparation for trace elements alone. The tourmaline mixed with trace urea acceptor was found to promote water absorption in the plant by making water particles, or clusters, smaller.

According to the present invention, there is no harm, and the bulk elements such as potassium, calcium, magnesium, nitrogen, phosphoric acid, and trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum, cobalt, etc. are not weakly absorbed by plants in conventional culture. Amino acids such as lysine, organic acids such as glutamic acid, seaweed extract, vitamins and the like to enhance the absorption of the components. The tourmaline hydration of the present invention can be expected to increase the absorption in the body by simple mixing with any product by foliar spray. In addition, the powder type is easy to package and transport, does not deteriorate for a long time, so the shelf life is long, there is no problem such as weak. Therefore, the effect of foliar fertilizer can be enhanced by the simple addition of the present invention. In addition, calcium, trace elements and tourmaline formulations are easy to use and can be produced at low prices, which can be economically beneficial to farmers.

Claims (6)

Selected from bulk urea such as potassium, calcium, magnesium, nitrogen and phosphoric acid, trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum and cobalt and optionally amino acids such as sugars and lysine, organic acids such as glutamic acid, seaweed extracts and vitamins An agricultural compound fertilizer in the form of a water-soluble agent, characterized in that it contains tourmaline as one or more components and as a promoter for absorption in plants of the aforementioned components. The compound fertilizer of claim 1, wherein the tourmaline is in the form of fine powder of 200 to 2,000 mesh. According to claim 1 or 2, wherein the compound fertilizer is a large amount of urea such as potassium, calcium, magnesium, nitrogen, phosphoric acid, trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum, cobalt and optionally sugars, Compound fertilizer consisting of 50 to 99% by weight of one or more components selected from amino acids such as lysine, organic acids such as glutamic acid, seaweed extract, vitamins, and tourmaline. Selected from bulk urea such as potassium, calcium, magnesium, nitrogen and phosphoric acid, trace elements such as silicon, iron, boron, manganese, zinc, copper, molybdenum and cobalt and optionally amino acids such as sugars and lysine, organic acids such as glutamic acid, seaweed extracts and vitamins Liquid tourmaline additive for promoting the absorption of one or more components in the plant body. The liquid tourmaline additive of claim 4 wherein the tourmaline is in the form of a fine powder of 200 to 2,000 mesh. The liquid tourmaline additive according to claim 4 or 5, wherein the liquid formulation comprises 1 to 50 wt% of tourmaline and 50 to 99 wt% of water.

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