CN106149405B - A kind of preparation method of coloured silk Liang and products thereof and application - Google Patents
A kind of preparation method of coloured silk Liang and products thereof and application Download PDFInfo
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- CN106149405B CN106149405B CN201510185743.5A CN201510185743A CN106149405B CN 106149405 B CN106149405 B CN 106149405B CN 201510185743 A CN201510185743 A CN 201510185743A CN 106149405 B CN106149405 B CN 106149405B
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Abstract
The invention belongs to textile material technical fields, it is related to a kind of preparation method of coloured silk Liang and products thereof and application, the invention discloses a kind of new color Liang, preparation method shines greig including primary, secondary leaching, boils silk fabric, leaching solarization, excessively black, sand washing, primary, secondary dyeing and sofening treatment step.Compared with prior art, the method for the invention is simple for process, with short production cycle, meets nowadays low-carbon, environmental protection, energy-efficient theory；The use of consumptive material in dyeing course has been saved, but has equally reached identical preparation effect so that the cost of technique declines, and has catered to the demand of the market groups of bigger；The color Liang of preparation compensates for the shortcomings that gambiered Guangdong silk fabric shade is single, and not only color fastness is higher but also bright in colour by the color Liang prepared through the present invention, and application of gambiered Guangdong silk fabric on clothes is made to have more practicability and great market prospects.
Description
Technical field
The invention belongs to textile material technical fields, are related to a kind of preparation method of coloured silk Liang, and in particular to a kind of coloured silk Liang's
Preparation method and products thereof and application.
Background technology
Gambiered Guangdong silk is also known as gambiered Guangdong gauze, is a kind of ancient Han nationality plant dyeing face that weaving and dyeing and finishing make by hand in Guangdong Province
Material has the history of more than 100 years, and due to its manufacture craft uniqueness, rare numbers, Production Time is long, it is desirable that it is highly skilled,
There is smooth, the pleasantly cool, degerming of dress, expelling parasite, with health role to skin, because coating slowly comes off exposing after dress
The isabelline background color past is known as soft gold by form.It using Real Silk Habotai is bottom base through natural dye yam juice that traditional gambiered Guangdong silk, which is,
Weaving with the mineral instrumentality in sludge and the front gloss black that is formed and reverse side matt coffee color again after dip dyeing solarization
Fabric.It is used as the dye yam of dyestuff, main component is to be easy to oxidative deformation to generate the polyphenol of freezing action and tannin (tannin matter),
Itself can do Chinese herbal medicine.There are the wearability such as nice and cool, sweat proof, washable, sun-proof, antibacterial with gambiered Guangdong silk that dye yam is dyed.It is mesh
Pure plant and the silk fabrics of mineral dyeing and finishing in former world textile.Canton gauze gambiered starts in last century the seventies because of society's dress
Custom changes and external textile enters market and fades away.But it is carried with the development of science and technology with people's living standard
Height, people gradually change the subject demands of clothes to environmental protection, the direction to go back to nature.Especially in recent years, it is pseudo-classic, literary
Skill, it is plain wear the fashionable whole world of theory, be pierced by comfortable, healthy and taste, be theory and demand of the current people to clothes.
But the color of traditional gambiered Guangdong silk is relatively simple and Boardy Feeling, the coffee-like dichromatism of only positive black and reverse side,
This causes application of the gambiered Guangdong silk in design and on clothes to have great limitation.And in the prior art, the preparation of gambiered Guangdong silk
Technique and its complexity take and long, and cost is higher, limit the consumer group, therefore offer is a kind of simple for process, time-consuming short, into
This is cheap, and the diversified preparation method of quality becomes the task of top priority in gambiered Guangdong silk production extension process.
Invention content
The defects of it is an object of the invention to overcome the prior art, and provide a kind of preparation process simple, cost savings,
It is of good quality, and the not only wearability with gambiered Guangdong silk but also the method for the color Liang with different colours.
To achieve the above object, the present invention provides a kind of preparation method of coloured silk Liang, includes the following steps：
(1) greig is shone in primary leaching：It is 1 according to mass ratio under room temperature:1-5 becomes the dye yam stem tuber of crushing and water preparation
First dye yam soak, and greig 8-12h is impregnated with it, it then by greig natural-dehydration and is laid on meadow, sweeps the even silk fabric
The dye yam soak on base surface is exposed to the sun to dry；
(2) greig is shone in secondary leaching：Under room temperature, according to mass ratio 2-4:100 become the dye yam stem tuber of crushing and water preparation
Second dye yam soak is impregnated with the second dye yam soak through step (1) treated greig 1-2min, then by greig
Natural-dehydration is simultaneously laid on meadow, sweeps the dye yam soak on the even greig surface, and sunlight dries；It repeats above-mentioned leaching and shines step 5-
20 times；
(3) silk fabric is boiled：The second dye yam soak is added in into saucepan and through step (2) treated greig, in 40-45
It is turned in DEG C and boils 3-7min, then natural-dehydration is placed in drying on meadow；
(4) greig is shone in leaching：The greig obtained in leaching solarization step (3) is repeated under room temperature 4-6 times；
(5) it is excessively black：Under the state that is protected from light, the mud of metal ion and inorganic anion is applied to through at step (4)
On one surface of second order of the greig after reason, and by the greig doubling, avoid light place 20-45min on sand ground, silk fabric is then cleaned up
The mud on base surface and being refitted on meadow is dried, then soak institute with the second dye yam soak with the sunlight of 1-3h after sunrise
Greig is stated, the side for having smeared mud is dried upward；
(6) sand washing：By through step (5), treated that greig is placed in that sand washing softness agent content is to be impregnated in the water of 3-9g/L
30-50min, then adding in sand washing powder thereto makes the content of sand washing powder in solution be 4-17g/L, at room temperature sand washing 40-
Then 70min is cleaned up and is dehydrated in weak acid and after sand washing solution by greig；
(7) primary dyeing：Reactive dye, levelling agent and the greig that is handled through step (6) into the water and are heated to 45-
55 DEG C, 15-30min is kept the temperature, wherein, the mass ratio of greig, reactive dye and levelling agent is 100-150：2-3：0.2-0.4,
Bath raio is 1：17-19；Then to reactive dye, levelling agent aqueous solution in add in anhydrous sodium sulphate, carbonic acid is then added in into solution
Sodium makes the content of sodium carbonate in solution be 16-21g/L, and greig is washed with water after 30-40min；
(8) secondary dyeing：Acid dyes and the greig handled through step (7) are added to the water, after room temperature dip dyeing 5-10min
Sodium sulphate is added in, temperature is risen to 90 DEG C by room temperature in 40min and keeps the temperature 30min, color fixing agent is added in after washing with water, then
It is washed with water clean and dries；Wherein the mass ratio of greig, acid dyes, sodium sulphate and color fixing agent is 100：1-2.2：2-4：
1-2, bath raio 1：17-20；
(9) sofening treatment：By softening agent and through step (8), treated, and greig is added to the water, and impregnates 1- at 40-45 DEG C
2 hours, then cleaning, drying；Wherein the content of softening agent be 6-17g/L, bath raio 1:17-20.
Further, the saucepan described in the step (3) is copper pot.
In the step (4), it is a surface of second order of the greig in brownish red to shine the terminal of dye, nail scratch or rubbing not
It fades.
Metal ion described in the step (5) in mud includes Fe2+、Al3+、K+、Na+、Ca2+、Mg2+、Ti3+、Mn2+、
V3+、Ba2+、Sr+、Li+、Cr3+、Pb2+、Zn2+、Cu2+、Ni3+、Co3+；The inorganic anion includes Cl-、PO4 3-、HCOO-With
NO3 -；FeSO in mud4It reacts with dye yam, participates in effective FeSO of reaction4With step (4) treated greig mass ratio
For 0.5-2：100.
Weak acid in the step (6) is formic acid or acetic acid.
In the step (7), the content of anhydrous sodium sulphate in the solution is 45-80g/L, and wherein anhydrous sodium sulphate is divided into three parts of additions,
Every 15min plus portion.
Reactive dye described in the step (7) are BF type reactive dye, and the levelling agent is polyoxyethylene ether, fat
It is one or more in alcohol, alkyl phenol or aliphatic alcohol sulfate；The acid dyes in the step (8) is azo dyes,
It is one or more in anthraquinone dye or kiton colors；The color fixing agent is dicyandiamide formaldehyde resin.
The softening agent in the step (9) is block polyether.
The present invention also provides a kind of coloured silk Liang, to be prepared according to the preparation method.
The present invention also provides a kind of application of preparation method of coloured silk Liang in dyeing textiles field.
Compared with prior art, the beneficial effects of the invention are as follows：
(1) coloured silk Liang preparation methods of the present invention have saved the process spilt and shine greig relative to the prior art, reduce
Cost, improves dip dyeing efficiency, meets energy-saving and environment-friendly new concept；It is the color Liang fine textures of preparation, rich in color, and through this
Not only color fastness is higher but also bright in colour by color Liang prepared by invention, and application of gambiered Guangdong silk fabric on clothes is made to have the hair of bigger
Exhibition prospect.
(2) coloured silk Liang preparation methods of the present invention, repetition dip dyeing number is less, and without boil with soaking solarization again again, is protecting
On the basis of the coloring for having demonstrate,proved color Liang, process is further saved, reduces cost, there is energy-saving consumption-reducing, is accorded with
Close the requirement of today's society low-carbon production.
(3) preparation method of coloured silk Liang of the present invention, greig doubling and silk fabric after covering mud in step (5)
Base, which is positioned on sand ground, to be reacted, and being provided to guarantee mud, (moisture of mud is about in the state of moistening
36.2%) tannin ingredient of the ferrous ion in mud only with greig surface within effective time, is allowed to react, is formed glossy
Black.
Specific embodiment
In order to more fully understand the present invention technology contents, with reference to specific embodiment to technical scheme of the present invention into
One step introduction and explanation.
Embodiment 1
The present embodiment provides a kind of preparation methods of coloured silk Liang, include the following steps：
(1) greig is shone in primary leaching：It is 1 according to mass ratio under room temperature:The dye yam stem tuber of crushing and water are prepared and become the by 1
One dye yam soak, and greig 8h is impregnated with it, it then by greig natural-dehydration and is laid on meadow, the even silk fabric is swept with certain herbaceous plants with big flowers leaf
The dye yam soak on base surface is exposed to the sun to dry；
(2) greig is shone in secondary leaching：Under room temperature, according to mass ratio 2:The dye yam stem tuber of crushing and water are prepared and become the by 100
Two dye yam soaks are impregnated with the second dye yam soak through step (1) treated greig 1min, then by greig nature
It is dehydrated and is laid on meadow, the dye yam soak on the even greig surface is swept with certain herbaceous plants with big flowers leaf, sunlight dries；It repeats above-mentioned leaching and shines step
5 times；
(3) silk fabric is boiled：The second dye yam soak is added in into copper pot and through step (2) treated greig, at 40 DEG C
In turn over and boil 3min, then natural-dehydration and shakeout in being dried on meadow；
(4) greig is shone in leaching：The greig obtained in leaching solarization step (3) is repeated under room temperature 4 times, a surface of second order of the greig is in
Brownish red, nail scratches or rubbing is not faded；
(5) it is excessively black：It is distinctive not through life using Foshans such as the South Sea, Shuande, Foshan, three water under the state that is protected from light
The grey black river surge silt mud containing natural green alum (i.e. ferrous sulfate) of refuse pollution is applied to that treated through step (4)
On one surface of second order of greig, moisture is about 36.2% in mud, and by the greig doubling, avoid light place on sand ground
Then 20min is cleaned up the mud on greig surface and is refitted on meadow and dried with the sunlight in 1h after sunrise, then described in
Second dye yam soak soaks the greig, and the side for having smeared mud is dried upward；Preferably, by gained greig in the moon
It is stored 3 months under light, the natural conditions divulged information, makes black gelatinous tannic acid ferrous iron reaction more abundant, it is more shiny black；In mud metal from
Attached bag includes Fe2+、Al3+、K+、Na+、Ca2+、Mg2+、Ti3+、Mn2+、V3+、Ba2+、Sr2+、Li+、Cr3+、Pb2+、Zn2+、Cu2+、Ni3+、
Co3+；The inorganic anion includes SO4 2-、Cl-、PO4 3-、HCOO-And NO3 ,FeSO in mud4It reacts, participates in dye yam
Effective FeSO of reaction4It is 0.5 with step (4) treated greig mass ratio：100；.
(6) sand washing：By through step (5), treated that greig is placed in that sand washing consistent lubricant content is to impregnate 30- in the water of 3g/L
50min then adds in sand washing powder thereto, and the content for making sand washing powder in solution is 4g/L, at room temperature sand washing 40-70min, so
It is cleaned up and is dehydrated in formic acid and after sand washing solution by greig afterwards；
(7) primary dyeing：By BF types reactive dye, polyoxyethylene ether and the greig that is handled through step (6) into the water simultaneously
45 DEG C are heated to, keeps the temperature 15min, wherein, the mass ratio of greig, BF types reactive dye and polyoxyethylene ether is 100：2：0.2,
Bath raio is 1：17；Then to BF types reactive dye, polyoxyethylene ether aqueous solution in add in anhydrous sodium sulphate in three times, every 15 minutes
Add once, finally make the content of anhydrous sodium sulphate in the solution for 45g/L, sodium carbonate is then added in into solution makes sodium carbonate in solution
Content for 16g/L, wash with water greig after 30min；
(8) secondary dyeing：Azo dyes and the greig handled through step (7) are added to the water, added after room temperature dip dyeing 5min
Enter sodium sulphate, temperature is risen to 90 DEG C by room temperature in 40min and keep the temperature 30min, color fixing agent dicyandiamide is added in after washing with water
Then formaldehyde resin is washed with water clean and dries；The wherein matter of greig, azo dyes, sodium sulphate and dicyandiamide formaldehyde resin
The ratio between amount is 100：1：2：1, bath raio 1：17；
(9) sofening treatment：By block polyether class softening agent and through step (8), treated, and greig is added to the water, at 40 DEG C
It is lower to impregnate 1 hour, then cleaning, drying；Wherein the content of block polyether be 6g/L, bath raio 1:17.
Embodiment 2
The present embodiment provides a kind of preparation methods of coloured silk Liang, include the following steps：
(1) greig is shone in primary leaching：It is 1 according to mass ratio under room temperature:The dye yam stem tuber of crushing and water are prepared and become the by 3
One dye yam soak, and greig 10h is impregnated with it, it then by its natural-dehydration and is laid on meadow, the even silk fabric is swept with certain herbaceous plants with big flowers leaf
The dye yam soak on base surface is exposed to the sun to dry；
(2) greig is shone in secondary leaching：Under room temperature, according to mass ratio 3:The dye yam stem tuber of crushing and water are prepared and become the by 100
Two dye yam soaks are impregnated with the second dye yam soak through step (1) treated greig 1.5min, then by its nature
It is dehydrated and is laid on meadow, the dye yam soak on the even greig surface is swept with certain herbaceous plants with big flowers leaf, sunlight dries；It repeats above-mentioned leaching and shines step
12 times；
(3) silk fabric is boiled：The second dye yam soak is added in into copper pot and through step (2) treated greig, at 42 DEG C
In turn over and boil 5min, then natural-dehydration and shakeout in being dried on meadow；
(4) greig is shone in leaching：The greig obtained in leaching solarization step (3) is repeated under room temperature 5 times, a surface of second order of the greig is in
Brownish red, nail scratches or rubbing is not faded；
(5) it is excessively black：It is distinctive not through life using Foshans such as the South Sea, Shuande, Foshan, three water under the state that is protected from light
The grey black river surge silt mud containing natural green alum (i.e. ferrous sulfate) of refuse pollution is applied to that treated through step (4)
On one surface of second order of greig, moisture is about 36.2% in mud, and by the greig doubling, avoid light place on sand ground
Then 33min is cleaned up the mud on greig surface and is refitted on meadow and dried with the sunlight in 2h after sunrise, then described in
Second dye yam soak soaks the greig, and the side for having smeared mud is dried upward；Preferably, by gained greig in the moon
It is stored 4 months under light, the natural conditions divulged information, makes black gelatinous tannic acid ferrous iron reaction more abundant, it is more shiny black；In mud metal from
Attached bag includes Fe2+、Al3+、K+、Na+、Ca2+、Mg2+、Ti3+、Mn2+、V3+、Ba2+、Sr2+、Li+、Cr3+、Pb2+、Zn2+、Cu2+、Ni3+、
Co3+；The inorganic anion includes SO4 2-、Cl-、PO4 3-、HCOO-And NO3 ,FeSO in mud4It reacts, participates in dye yam
Effective FeSO of reaction4It is 0.7 with step (4) treated greig mass ratio：100；.
(6) sand washing：By through step (5), treated that greig is placed in that sand washing consistent lubricant content is to impregnate 40min in the water of 6g/L,
Then adding in sand washing powder thereto makes the content of sand washing powder in solution be 10g/L, and sand washing 55min, then uses formic acid at room temperature
Greig is cleaned up and is dehydrated after neutralizing sand washing solution；
(7) primary dyeing：By BF types reactive dye, fatty alcohol and induced by alkyl hydroxybenzene levelling agent and the silk fabric handled through step (6)
Base into the water and is heated to 50 DEG C, keeps the temperature 22min, wherein, the mass ratio of greig, BF types reactive dye and polyoxyethylene ether
It is 120：2.5：0.3, bath raio 1：18；Then into the aqueous solution of BF types reactive dye, fatty alcohol and induced by alkyl hydroxybenzene levelling agent
Anhydrous sodium sulphate is added in three times, it is every 15 minutes plus primary, finally make the content of anhydrous sodium sulphate in the solution for 65g/L, then to molten
Sodium carbonate is added in liquid, the content for making sodium carbonate in solution is 19g/L, and greig is washed with water after 35min；
(8) secondary dyeing：Anthraquinone dye and the greig handled through step (7) are added to the water, added after room temperature dip dyeing 7min
Enter sodium sulphate, temperature is risen to 90 DEG C by room temperature in 40min and keep the temperature 30min, color fixing agent dicyandiamide is added in after washing with water
Then formaldehyde resin is washed with water clean and dries；The wherein matter of greig, anthraquinone dye, sodium sulphate and dicyandiamide formaldehyde resin
The ratio between amount is 100：1.6：3：1.5, bath raio 1：19；
(9) sofening treatment：By block polyether class softening agent and through step (8), treated, and greig is added to the water, at 42 DEG C
It is lower to impregnate 1.5 hours, then cleaning, drying；Wherein the content of block polyether be 12g/L, bath raio 1:18.
Embodiment 3
The present embodiment provides a kind of preparation methods of coloured silk Liang, include the following steps：
(1) greig is shone in primary leaching：It is 1 according to mass ratio under room temperature:The dye yam stem tuber of crushing and water are prepared and become the by 5
One dye yam soak, and greig 12h is impregnated with it, it then by its natural-dehydration and is laid on meadow, the even silk fabric is swept with certain herbaceous plants with big flowers leaf
The dye yam soak on base surface is exposed to the sun to dry；
(2) greig is shone in secondary leaching：Under room temperature, according to mass ratio 4:The dye yam stem tuber of crushing and water are prepared and become the by 100
Two dye yam soaks are impregnated through step (1) treated greig 2min with the second dye yam soak, then take off it naturally
Water is simultaneously laid on meadow, and the dye yam soak on the even greig surface is swept with certain herbaceous plants with big flowers leaf, and sunlight dries；It repeats above-mentioned leaching and shines step 20
It is secondary；
(3) silk fabric is boiled：The second dye yam soak is added in into copper pot and through step (2) treated greig, at 45 DEG C
In turn over and boil 7min, then natural-dehydration and shakeout in being dried on meadow；
(4) greig is shone in leaching：The greig obtained in leaching solarization step (3) is repeated under room temperature 6 times, a surface of second order of the greig is in
Brownish red, nail scratches or rubbing is not faded；
(5) it is excessively black：It is distinctive not through life using Foshans such as the South Sea, Shuande, Foshan, three water under the state that is protected from light
The grey black river surge silt mud containing natural green alum (i.e. ferrous sulfate) of refuse pollution is applied to that treated through step (4)
On one surface of second order of greig, moisture is about 36.2% in mud, and by the greig doubling, avoid light place on sand ground
Then 45min is cleaned up the mud on greig surface and is refitted on meadow and dried with the sunlight in 3h after sunrise, then described in
Second dye yam soak soaks the greig, and the side for having smeared mud is dried upward；Preferably, by gained greig in the moon
It is stored 6 months under light, the natural conditions divulged information, makes black gelatinous tannic acid ferrous iron reaction more abundant, it is more shiny black；In mud metal from
Attached bag includes Fe2+、Al3+、K+、Na+、Ca2+、Mg2+、Ti3+、Mn2+、V3+、Ba2+、Sr2+、Li+、Cr3+、Pb2+、Zn2+、Cu2+、Ni3+、
Co3+；The inorganic anion includes SO4 2-、Cl-、PO4 3-、HCOO-And NO3 ,FeSO in mud4It reacts, participates in dye yam
Effective FeSO of reaction4It is 1.62 with step (4) treated greig mass ratio：100；
(6) sand washing：By through step (5), treated that greig is placed in that sand washing consistent lubricant content is to impregnate 50min in the water of 9g/L,
Then adding in sand washing powder thereto makes the content of sand washing powder in solution be 17g/L, and sand washing 70min, then uses formic acid at room temperature
Greig is cleaned up and is dehydrated after neutralizing sand washing solution；
(7) primary dyeing：By BF types reactive dye, induced by alkyl hydroxybenzene levelling agent and through step (6) handle greig be put into water
In and be heated to 55 DEG C, keep the temperature 30min, wherein, the mass ratio of greig, BF types reactive dye and induced by alkyl hydroxybenzene levelling agent is
150：3：0.4, bath raio 1：19；Then to BF types reactive dye, induced by alkyl hydroxybenzene levelling agent aqueous solution in three times add in member
Bright powder, it is every 15 minutes plus primary, the content of anhydrous sodium sulphate in the solution is finally made then to add in carbonic acid into solution for 80g/L
Sodium makes the content of sodium carbonate in solution be 21g/L, and greig is washed with water after 40min；
(8) secondary dyeing：Kiton colors and the greig handled through step (7) are added to the water, room temperature dip dyeing 10min
After add in sodium sulphate, temperature is risen to 90 DEG C by room temperature in 40min and keeps the temperature 30min, it is double that color fixing agent is added in after washing with water
Then cyanamide formaldehyde resin is washed with water clean and dries；Wherein greig, azo dyes, sodium sulphate and dicyandiamide formaldehyde resin
Mass ratio be 100：2.2：4：2, bath raio 1：20；
(9) sofening treatment：By block polyether class softening agent and through step (8), treated, and greig is added to the water, at 45 DEG C
It is lower to impregnate 1 hour, then cleaning, drying；Wherein the content of block polyether be 17g/L, bath raio 1:20.
Comparative example
This comparative example provides the preparation method of a kind of coloured silk Liang, includes the following steps：
(1) greig is shone in primary leaching：It is 1 according to mass ratio under room temperature:The dye yam stem tuber of crushing and water are prepared and become the by 1
One dye yam soak, and greig 8h is impregnated with it, it then by greig natural-dehydration and is laid on meadow, the even silk fabric is swept with certain herbaceous plants with big flowers leaf
The dye yam soak on base surface is exposed to the sun to dry；
(2) solarization greig is spilt：It is 3 with the dye yam stem tuber of crushing and the mass ratio of water:200 the second dye yam liquid being formulated
Uniformly spill on greig handle through step (1), be then laid on meadow and be exposed to the sun to do；Repetition, which is spilt, shines greig 5 times；
(3) greig is shone in secondary leaching：Under room temperature, according to mass ratio 2:The dye yam stem tuber of crushing and water are prepared and become the by 100
Three dye yam soaks are impregnated through step (1) treated greig 1min with the third dye yam soak, then take off it naturally
Water is simultaneously laid on meadow, and the dye yam soak on the even greig surface is swept with certain herbaceous plants with big flowers leaf, and sunlight dries；It repeats above-mentioned leaching and shines step 5
It is secondary；
(4) silk fabric is boiled：The second dye yam soak is added in into copper pot and through step (2) treated greig, at 40 DEG C
In turn over and boil 3min, then natural-dehydration and shakeout in being dried on meadow；
(4) greig is shone in leaching：The greig obtained in leaching solarization step (3) is repeated under room temperature 4 times, a surface of second order of the greig is in
Brownish red, nail scratches or rubbing is not faded；
(5) it repeats leaching and shines greig 12 times, it is primary then to repeat to boil silk fabric, and then repeating time leaching, to shine greig primary；
(6) it is excessively black：It is distinctive not through life using Foshans such as the South Sea, Shuande, Foshan, three water under the state that is protected from light
The grey black river surge silt mud containing natural green alum (i.e. ferrous sulfate) of refuse pollution is applied to that treated through step (5)
On one surface of second order of greig, and by the greig doubling, avoid light place 20min on sand ground, greig surface is then cleaned up
Mud and being refitted on meadow is dried, then soak the greig with the second dye yam soak with the sunlight in 1h after sunrise,
The side for having smeared mud is dried upward；Preferably, gained greig is stored 3 under cloudy light, the natural conditions divulged information
Month, make black gelatinous tannic acid ferrous iron reaction more abundant, it is more shiny black；
(7) sand washing：By through step (6), treated that greig is placed in that sand washing consistent lubricant content is to impregnate 30- in the water of 3g/L
50min then adds in sand washing powder thereto, and the content for making sand washing powder in solution is 4g/L, at room temperature sand washing 40-70min, so
It is cleaned up and is dehydrated in formic acid and after sand washing solution by greig afterwards；
(8) primary dyeing：By BF types reactive dye, polyoxyethylene ether and the greig that is handled through step (7) into the water simultaneously
45 DEG C are heated to, keeps the temperature 15min, wherein, the mass ratio of greig, BF types reactive dye and polyoxyethylene ether is 100：2：0.2,
Bath raio is 1：17；Then to BF types reactive dye, polyoxyethylene ether aqueous solution in add in anhydrous sodium sulphate in three times, every 15 minutes
Add once, finally make the content of anhydrous sodium sulphate in the solution for 45g/L, sodium carbonate is then added in into solution makes sodium carbonate in solution
Content for 16g/L, wash with water greig after 30min；
(9) secondary dyeing：Azo dyes and the greig handled through step (8) are added to the water, added after room temperature dip dyeing 5min
Enter sodium sulphate, temperature is risen to 90 DEG C by room temperature in 40min and keep the temperature 30min, color fixing agent dicyandiamide is added in after washing with water
Then formaldehyde resin is washed with water clean and dries；The wherein matter of greig, azo dyes, sodium sulphate and dicyandiamide formaldehyde resin
The ratio between amount is 100：1：2：1, bath raio 1：17；
(10) sofening treatment：By block polyether class softening agent and through step (9), treated, and greig is added to the water, at 40 DEG C
It is lower to impregnate 1 hour, then cleaning, drying；Wherein the content of block polyether be 6g/L, bath raio 1:17.
According to the color fastness of color Liang obtained in standard GB/T/T 8427-1998 testing example 1-3 and comparative example：
After color Liang samples are placed under sunlight the 14d that is exposed to the sun, using the color fastness of YG611 type solarization climate tests instrument test each sample, knot
Fruit is as follows：
It is from the above data, it can be seen that excellent using the color Liang color fastness that coloured silk Liang preparation methods described herein are prepared
The obtained color fastness of color Liang samples is shone with repeatedly leaching by spilling to shine in comparative example, not only fast light, good weatherability also as save
Process reduces production cost, energy-saving consumption-reducing.
It is described above only with embodiment come the technology contents that further illustrate the present invention, in order to which reader is easier to understand,
But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this
Bright protection.
Claims (3)
1. a kind of preparation method of coloured silk Liang, which is characterized in that include the following steps：
(1) greig is shone in primary leaching：It is 1 according to mass ratio under room temperature:1-5, which prepares the dye yam stem tuber of crushing and water, becomes first
Dye yam soak, and greig 8-12h is impregnated with it, it then by greig natural-dehydration and is laid on meadow, sweeps the even greig table
The dye yam soak in face is exposed to the sun to dry；
(2) greig is shone in secondary leaching：Under room temperature, according to mass ratio 2-4:100 prepare the dye yam stem tuber of crushing and water as second
Dye yam soak is impregnated with the second dye yam soak through step (1) treated greig 1-2min, then by greig nature
It is dehydrated and is laid on meadow, sweep the dye yam soak on the even greig surface, sunlight dries；It repeats above-mentioned leaching and shines step 5-20
It is secondary；
(3) silk fabric is boiled：The second dye yam soak is added in into saucepan and through step (2) treated greig, in 40-45 DEG C
It turns over and boils 3-7min, then natural-dehydration is placed in drying on meadow；
(4) greig is shone in leaching：The greig obtained in leaching solarization step (3) is repeated under room temperature 4-6 times；
(5) it is excessively black：Under the state that is protected from light, the mud of metal ion and inorganic anion is applied to after step (4) processing
Greig a surface of second order on, and by the greig doubling, avoid light place 20-45min on sand ground, then clean up greig table
The mud in face and being refitted on meadow is dried, then soak the silk fabric with the second dye yam soak with the sunlight of 1-3h after sunrise
Base dries the side for having smeared mud upward；
(6) sand washing：By through step (5), treated that greig is placed in that sand washing softness agent content is to impregnate 30- in the water of 3-9g/L
50min, then adding in sand washing powder thereto makes the content of sand washing powder in solution be 4-17g/L, at room temperature sand washing 40-70min,
Then it is cleaned up and is dehydrated in weak acid and after sand washing solution by greig；
(7) primary dyeing：Reactive dye, levelling agent and the greig that is handled through step (6) into the water and are heated to 45-55
DEG C, 15-30min is kept the temperature, wherein, the mass ratio of greig, reactive dye and levelling agent is 100-150：2-3：0.2-0.4, bath
Than being 1：17-19；Then to reactive dye, levelling agent aqueous solution in add in anhydrous sodium sulphate, sodium carbonate is then added in into solution,
The content for making sodium carbonate in solution is 16-21g/L, and greig is washed with water after 30-40min；
(8) secondary dyeing：Acid dyes and the greig handled through step (7) are added to the water, added in after room temperature dip dyeing 5-10min
Temperature is risen to 90 DEG C by room temperature in 40min and keeps the temperature 30min, color fixing agent is added in after washing with water, is then used again by sodium sulphate
Washing is clean and dries；Wherein the mass ratio of greig, acid dyes, sodium sulphate and color fixing agent is 100：1-2.2：2-4：1-2,
Bath raio is 1：17-20；
(9) sofening treatment：By softening agent and through step (8), treated, and greig is added to the water, and it is small that 1-2 is impregnated at 40-45 DEG C
When, then cleaning, drying；Wherein the content of softening agent be 6-17g/L, bath raio 1:17-20；
Saucepan described in the step (3) is copper pot；
In the step (4), it is a surface of second order of the greig in brownish red to shine the terminal of dye, and nail scratches or rubbing is not fallen
Color；
Metal ion described in the step (5) in mud includes Fe2+、Al3+、K+、Na+、Ca2+、Mg2+、Ti3+、Mn2+、V3+、
Ba2+、Sr+、Li+、Cr3+、Pb2+、Zn2+、Cu2+、Ni3+、Co3+；The inorganic anion includes Cl-、PO4 3-、HCOO-And NO3 -；Mud
Fe SO in slurry4It reacts with dye yam, participates in effective FeSO of reaction4It is 0.5- with step (4) treated greig mass ratio
2：100；
Weak acid in the step (6) is formic acid or acetic acid；
In the step (7), the content of anhydrous sodium sulphate in the solution is 45-80g/L, and wherein anhydrous sodium sulphate is divided into three parts of additions, every
15min adds portion；
Reactive dye described in the step (7) are BF type reactive dye, and the levelling agent is polyoxyethylene ether, fatty alcohol, alkane
It is one or more in base phenol or aliphatic alcohol sulfate；The acid dyes in the step (8) is azo dyes, anthraquinone contaminates
It is one or more in material or kiton colors；The color fixing agent is dicyandiamide formaldehyde resin；
The softening agent in the step (9) is block polyether.
2. a kind of coloured silk Liang, which is characterized in that it is is prepared according to preparation method described in claim 1.
3. application of the preparation method of coloured silk Liang as described in claim 1 in dyeing textiles field.
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Cited By (1)
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| CN108914559A (en) * | 2018-09-18 | 2018-11-30 | 昆明滇艺非物质文化遗产研发有限公司 | A kind of production method of refrigerant gambiered Guangdong gauze |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022909A (en) * | 2017-05-17 | 2017-08-08 | 万秦君 | A kind of colouring method of dye yam fabric |
| CN110130123A (en) * | 2019-04-20 | 2019-08-16 | 深圳市易菲妮时装有限公司 | The preparation process of high-performance antimildew and antibacterial gelsemium cotton |
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| BRPI0703099A2 (en) * | 2007-08-13 | 2009-03-31 | Greicy Apolinario Costa Me | synthetic and vegetable dye for fiber / cotton, viscose, wool and silk fiber / fabric dyeing |
| CN102061631A (en) * | 2009-11-12 | 2011-05-18 | 上海甲秀工业设计有限公司 | Modern gambiered Canton gauze product processing and manufacturing method |
| CN102733182B (en) * | 2012-07-11 | 2014-04-09 | 周晓刚 | Process for producing double-sided gambiered Guangdong silk |
| CN103015232B (en) * | 2013-01-14 | 2015-01-28 | 深圳市梁子时装实业有限公司 | Method for preparing color Setaria viridis |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108914559A (en) * | 2018-09-18 | 2018-11-30 | 昆明滇艺非物质文化遗产研发有限公司 | A kind of production method of refrigerant gambiered Guangdong gauze |
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