CN106146948A - A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof - Google Patents

A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof Download PDF

Info

Publication number
CN106146948A
CN106146948A CN201610709935.6A CN201610709935A CN106146948A CN 106146948 A CN106146948 A CN 106146948A CN 201610709935 A CN201610709935 A CN 201610709935A CN 106146948 A CN106146948 A CN 106146948A
Authority
CN
China
Prior art keywords
friendly type
environment
rubber
agent
sizing material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610709935.6A
Other languages
Chinese (zh)
Inventor
李举平
黄小军
张�林
刘宗建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xi'an Space Flight Huayang Dynamoelectric Equipment Co Ltd
Original Assignee
Xi'an Space Flight Huayang Dynamoelectric Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xi'an Space Flight Huayang Dynamoelectric Equipment Co Ltd filed Critical Xi'an Space Flight Huayang Dynamoelectric Equipment Co Ltd
Priority to CN201610709935.6A priority Critical patent/CN106146948A/en
Publication of CN106146948A publication Critical patent/CN106146948A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
    • B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic

Abstract

nullThe invention discloses a kind of butyronitrile series environment-friendly type rubber floor covering sizing material，It is made up of following raw material by weight percentage: nitrile rubber 30%～35%，Zinc oxide 1.5%～1.7%，Stearic acid 0.3%～0.4%，Age resistor 405 0.6%～0.7%，Titanium dioxide 1.5%～3.1%，Potter's clay 9%～13.5%，Fire retardant HP8000～13.5%，Aluminium hydroxide 0～10.2%，Firebrake ZB 0～5.1%，Fire retardant BN 18C 0～5.1%，White carbon 4.5%～13.5%，Nano kaoline 13%～23.7%，Calcium carbonate superfine powder 0～18.4%，Antistatic additive 0.6%～0.7%，Dispersant 0.6%～0.7%，Flow promortor 0.5%～0.7%，Ultraviolet (UV) resistant agent 0.4%～0.55%，Antibacterial 0.4%～0.6%，Vulcanizing agent S 80 0.1%～0.2%，Accelerator 0.6～0.7%，Vulcanizing agent CLD 80 0.3%～0.35%，Pigment 0.3%～0.35%，Above component percentages summation is 100%，The invention also discloses the preparation method of butyronitrile series environment-friendly type rubber floor covering sizing material，The present invention solve present in prior art the anti-slippage of material、Nonelastic、The most water-fast、The most wear-resisting、Do not prevent fires、The most antibacterial、Price、Release harmful gas or the problem of radioactive element.

Description

A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of butyronitrile series environment-friendly type rubber floor covering sizing material, The invention still further relates to the preparation method of a kind of butyronitrile series environment-friendly type rubber floor covering sizing material.
Background technology
Rubber floor covering is a kind of following ground material having the potentiality that grow a lot, and at west european developed country, annual consumption is all At millions of square metres, China's rubber floor covering development speed and consumption also sharply increase, and every year with 20% speed increase. Along with the enforcement of country's " industrial powers 2025 ", " top grade, environmental protection, energy-conservation " type rubber floor covering will become from now on rubber material develop Main flow.The most traditional rubber ground material still can not meet requirements above, as the lowest in floor paint/floor wax class；Floor tile Skid resistance is poor, frangible, load-bearing is poor；The anti-slippage of stone floor, price, construction trouble, additionally some stone material contains radioelement Radon, has injury to human body；Timber floor color is single, non-moistureproof, the most water-fast, the most fire-retardant, and especially some floors inferior are contained in a large number The harmful gass etc. such as formaldehyde；Carpet price is high, it is difficult, the most water-fast, the most wear-resisting to maintain, do not prevent fires, some carpet feature of environmental protection inferior Difference, easy breed bacteria etc.；Stone mould floor tile fragmentation easy to wear, easy, easily pollute, the life-span is short；PVC plastic floor, is not durable, makes Obvious with middle decaying phenomenon, nonelastic etc..
Environment-friendly rubber floor uses environmental protection, free of contamination robber materials to coordinate environment-friendly rubber auxiliary agent to process Rubber.This product material therefor is all nontoxic, harmless environmental protection macromolecule material, so the environmental protection ground material that is otherwise known as.Rubber Adhesive floor, due to its high abrasion, high resiliency, anti-skidding, moistureproof, fire-retardant, antistatic, laying beautiful in colour, easy, easy cleaning maintenance etc. Feature, especially by different processing technology, can copy into stone material, terrazzo and wood floors pattern rubber floor covering, Tie up wonderful dimension skilful.It is applied to the fields such as industry, track traffic, airport, boats and ships and oil drilling, laboratory, antistatic.With Horizon Paint, floor wax, floor tile, stone floor, timber floor, carpet, stone mould floor tile, PVC floor is compared, and rubber floor covering has with Shangdi The characteristic that material is unmatched, rubber floor covering effectively overcomes the unfavorable factor on other floor, is following most to have market prospect Synthetic material floor.
Summary of the invention
It is an object of the invention to provide a kind of butyronitrile series environment-friendly type rubber floor covering sizing material, solve in prior art and exist The anti-slippage of ground material, nonelastic, the most water-fast, the most wear-resisting, do not prevent fires, the most antibacterial, price, release harmful gas or radioactive element Problem.
It is a further object of the present invention to provide the preparation method of a kind of butyronitrile series environment-friendly type rubber floor covering sizing material.
First technical scheme of the present invention is, a kind of butyronitrile series environment-friendly type rubber floor covering sizing material, by weight hundred Proportion by subtraction is made up of the active component of following raw material:
Nitrile rubber 30%～35%, zinc oxide 1.5%～1.7%, stearic acid 0.3%～0.4%, age resistor 405 0.6%～0.7%, titanium dioxide 1.5%～3.1%, potter's clay 9%～13.5%, fire retardant HP800 0～13.5%, hydroxide Aluminum 0～10.2%, Firebrake ZB 0～5.1%, fire retardant BN-18C 0～5.1%, white carbon 4.5%～13.5%, nanometer kaolinite Soil 13%～23.7%, calcium carbonate superfine powder 0～18.4%, antistatic additive 0.6%～0.7%, dispersant FC-303 0.6%～ 0.7%, flow promortor PEG4000 0.5%～0.7%, ultraviolet (UV) resistant agent UV-531 0.4%～0.55%, antibacterial CZ- KZ10 0.4%～0.6%, vulcanizing agent S-80 0.1%～0.2%, accelerator TBZTD 0.6～0.7%, vulcanizing agent CLD-80 0.3%～0.35%, pigment 0.3%～0.35%, the percentage composition summation of above component is 100%.
The feature of the present invention the first technical scheme also resides in,
Nitrile rubber is N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one therein.
Zinc oxide, stearic acid, environment-friendly type age resistor, titanium dioxide, potter's clay, fire retardant HP800, aluminium hydroxide, Firebrake ZB, resistance Combustion agent BN-18C, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV-531, antibacterial CZ-KZ10, vulcanizing agent S-80, accelerator TBZTD, vulcanizing agent CLD-80, face Material is environment-friendly rubber auxiliary agent.
Second technical scheme of the present invention is, the preparation side of a kind of butyronitrile series environment-friendly type rubber floor covering sizing material Method, specifically implements according to following steps:
Step 1, weigh raw material, weigh nitrile rubber 30%～35% according to percentage by weight, zinc oxide 1.5%～ 1.7%, stearic acid 0.3%～0.4%, environment-friendly type age resistor 405 0.6%～0.7%, titanium dioxide 1.5%～3.1%, potter's clay 9%～13.5%, fire retardant HP800 0～13.5%, aluminium hydroxide 0～10.2%, Firebrake ZB 0～5.1%, fire retardant BN- 18C 0～5.1%, white carbon 4.5%～13.5%, nano kaoline 13%～23.7%, calcium carbonate superfine powder 0～18.4%, Antistatic additive 0.6%～0.7%, dispersant FC-303 0.6%～0.7%, flow promortor PEG4000 0.5%～0.7%, Ultraviolet (UV) resistant agent UV-531 0.4%～0.55%, antibacterial CZ-KZ10 0.4%～0.6%, vulcanizing agent S-80 0.1%～ 0.2%, environment-friendly type accelerator TBZTD 0.6～0.7%, vulcanizing agent CLD-80 0.3%～0.35%, pigment 0.3%～ 0.35%, the percentage composition summation of above component is 100%；
Step 2, the nitrile rubber weighed in step 1 is plasticated: roll spacing controls 2～3mm, the time control 4～ 6min；
Step 3, step 2 is plasticated after nitrile rubber carry out pressing: roll spacing controls 4～6mm, the time control 1～ 3min；
Step 4, nitrile rubber after step 3 pressing it is sequentially added into small powder: zinc oxide, stearic acid, age resistor 405, Obtaining mixed rubber, roll spacing controls 6～8mm, and the time controls 1.5～2.5min；
Step 5, rubber compounding: on the basis of step 4, sequentially add small powder: titanium dioxide, potter's clay, aluminium hydroxide, boron Acid zinc, fire retardant HP800, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial CZ-KZ10, pigment, be then uniformly mixed, and roll spacing controls 6～8mm, Time controls 19～21min；
Step 6, by thin for the step 5 sizing material after mixing logical 3～4 times, roll spacing controls 1～2mm, the time control 3～ 5min；
Step 7, elastomeric compound add sulfur: by vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80 are sequentially added into Step 6 thin logical after glue stuff compounding in, then stir, the thinnest logical 3 times, roll spacing controls 1～2mm, and the time controls 3 ～5min；
Step 8, clot bottom sheet: will add elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls 8～10mm, the time controls 2～4min, obtains butyronitrile series environment-friendly type rubber floor covering sizing material.
The feature of the present invention the second technical scheme also resides in,
In step 1, nitrile rubber is N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one therein.
Zinc oxide, stearic acid, environment-friendly type age resistor, titanium dioxide, potter's clay, fire retardant HP800, aluminium hydroxide, boron in step 1 Acid zinc, fire retardant BN-18C, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV-531, antibacterial CZ-KZ10, vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80, pigment are environment-friendly rubber auxiliary agent.
In step 5, whole adition process divides 4 additions, each addition be titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, Fire retardant HP800, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial CZ-KZ10, the 1/4 of pigment total amount, add every time after, pan feeding to be added with mix Charging next time is being carried out after rubber is compatible.
The invention has the beneficial effects as follows, a kind of butyronitrile series environment-friendly type rubber floor covering sizing material, nitrile rubber be N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one of which, the rubber chemicals of use are environment-friendly rubber auxiliary agent, without dirty Dye, oil resistant, corrosion-resistant, anti-skidding, elastic, fire-retardant, antistatic, antibacterial, the preparation side of butyronitrile series environment-friendly type rubber floor covering sizing material Method, technique is simple, uses opening rubber mixing machine, low for equipment requirements.
Accompanying drawing explanation
Fig. 1 is the preparation method flow chart of the present invention a kind of butyronitrile series environment-friendly type rubber floor covering sizing material.
Detailed description of the invention
The present invention is described in detail with detailed description of the invention below in conjunction with the accompanying drawings.
One butyronitrile series environment-friendly type rubber floor covering sizing material of the present invention, by weight percentage by the active component of following raw material Composition:
Nitrile rubber 30%～35%, zinc oxide 1.5%～1.7%, stearic acid 0.3%～0.4%, environment-friendly type age resistor 405 0.6%～0.7%, titanium dioxide 1.5%～3.1%, potter's clay 9%～13.5%, fire retardant HP800 0～13.5%, hydrogen Aluminium oxide 0～10.2%, Firebrake ZB 0～5.1%, fire retardant BN-18C 0～5.1%, white carbon 4.5%～13.5%, nanometer Kaolin 13%～23.7%, calcium carbonate superfine powder 0～18.4%, antistatic additive 0.6%～0.7%, dispersant FC-303 0.6%～0.7%, flow promortor PEG40000.5%～0.7%, ultraviolet (UV) resistant agent UV-531 0.4%～0.55%, antibacterial Agent CZ-KZ10 0.4%～0.6%, vulcanizing agent S-80 0.1%～0.2%, environment-friendly type accelerator TBZTD 0.6～0.7%, Vulcanizing agent CLD-80 0.3%～0.35%, pigment 0.3%～0.35%, the percentage composition summation of above component is 100%.
Wherein, nitrile rubber is N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one therein.Zinc oxide, Stearic acid, environment-friendly type age resistor, titanium dioxide, potter's clay, fire retardant HP800, aluminium hydroxide, Firebrake ZB, fire retardant BN-18C, Linesless charcoal Black, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV- 531, antibacterial CZ-KZ10, vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80, pigment are environment-friendly type rubber Glue auxiliary agent.
The preparation method of butyronitrile series environment-friendly type rubber floor covering sizing material, uses opening rubber mixing machine, as it is shown in figure 1, specifically Implement according to following steps:
Step 1, weigh raw material, weigh nitrile rubber 30%～35% according to percentage by weight, zinc oxide 1.5%～ 1.7%, stearic acid 0.3%～0.4%, environment-friendly type age resistor 405 0.6%～0.7%, titanium dioxide 1.5%～3.1%, potter's clay 9%～13.5%, fire retardant HP800 0～13.5%, aluminium hydroxide 0～10.2%, Firebrake ZB 0～5.1%, fire retardant BN- 18C 0～5.1%, white carbon 4.5%～13.5%, nano kaoline 13%～23.7%, calcium carbonate superfine powder 0～18.4%, Antistatic additive 0.6%～0.7%, dispersant FC-303 0.6%～0.7%, flow promortor PEG4000 0.5%～0.7%, Ultraviolet (UV) resistant agent UV-531 0.4%～0.55%, antibacterial CZ-KZ10 0.4%～0.6%, vulcanizing agent S-80 0.1%～ 0.2%, environment-friendly type accelerator TBZTD 0.6～0.7%, vulcanizing agent CLD-80 0.3%～0.35%, pigment 0.3%～ 0.35%, the percentage composition summation of above component is 100%；
Step 2, the nitrile rubber weighed in step 1 is plasticated: roll spacing controls 2～3mm, the time control 4～ 6min；
Step 3, step 2 is plasticated after nitrile rubber carry out pressing: roll spacing controls 4～6mm, the time control 1～ 3min；
Step 4, nitrile rubber after step 3 pressing it is sequentially added into small powder: zinc oxide, stearic acid, age resistor 405, Obtaining mixed rubber, roll spacing controls 6～8mm, and the time controls 1.5～2.5min；
Step 5, rubber compounding: sequentially add on the basis of step 4 titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, Fire retardant HP800, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial CZ-KZ10, pigment, be then uniformly mixed, and roll spacing controls 6～8mm, Time controls 19～21min；
Step 6, by thin for the step 5 sizing material after mixing logical 3～4 times, roll spacing controls 1～2mm, the time control 3～ 5min；
Step 7, elastomeric compound add sulfur: by vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80 are sequentially added into Step 6 thin logical after glue stuff compounding in, then stir, the thinnest logical 3 times, roll spacing controls 1～2mm, and the time controls 3 ～5min；
Step 8, clot bottom sheet: will add elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls 8～10mm, the time controls 2～4min, obtains butyronitrile series environment-friendly type rubber floor covering sizing material.
In step 1, nitrile rubber is N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one therein.
Zinc oxide, stearic acid, environment-friendly type age resistor, titanium dioxide, potter's clay, fire retardant HP800, aluminium hydroxide, boron in step 1 Acid zinc, fire retardant BN-18C, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV-531, antibacterial CZ-KZ10, vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80, pigment are environment-friendly rubber auxiliary agent.
In step 5, whole adition process divides 4 additions, each addition be titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, Fire retardant HP800, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial CZ-KZ10, the 1/4 of pigment total amount, add every time after, pan feeding to be added with mix Charging next time is being carried out after rubber is compatible.
The butyronitrile series environment-friendly type rubber floor covering sizing material prepared by this formula have oil resistant, corrosion-resistant, elastic, antibacterial, Antistatic, fire-retardant, anti-skidding, environmental protection, the function such as pollution-free.Use figure as shown in Figure 1, it is adaptable to industry, track traffic, airport, The fields such as boats and ships and oil drilling, laboratory, antistatic.
Embodiment 1
Step 1, weighing raw material, weigh nitrile rubber 30.62%, zinc oxide 1.53%, stearic acid according to percentage by weight 0.31%, environment-friendly type age resistor 405 0.61%, titanium dioxide 3.06%, potter's clay 9.19%, fire retardant HP800 12.25%, in vain White carbon black 4.59%, nano kaoline 15.31%, calcium carbonate superfine powder 18.37%, antistatic additive 0.61%, dispersant FC-303 0.61%, flow promortor PEG4000 0.61%, ultraviolet (UV) resistant agent UV-531 0.46%, antibacterial CZ-KZ10 0.46%, sulfur Agent S-80 0.18%, environment-friendly type accelerator TBZTD 0.61%, vulcanizing agent CLD-80 0.31%, pigment 0.31%, above The percentage composition summation of component is 100%；
Step 2, the nitrile rubber weighed in step 1 is plasticated: roll spacing controls at 2mm, and the time controls at 6min；
Step 3, step 2 is plasticated after nitrile rubber carry out pressing: roll spacing controls at 6mm, and the time controls at 3min；
Step 4, nitrile rubber after step 3 pressing it is sequentially added into small powder: zinc oxide, stearic acid, age resistor 405, Obtaining mixed rubber, roll spacing controls at 8mm, and the time controls at 1.5min；
Step 5, rubber compounding: on the basis of step 4, sequentially add titanium dioxide, potter's clay, fire retardant HP800, Linesless charcoal Black, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial CZ-KZ10, pigment, be then uniformly mixed, and roll spacing controls at 6mm, and the time controls at 21min；
Step 6, by thin for the step 5 sizing material after mixing logical 4 times, roll spacing controls at 2mm, and the time controls at 5min；
Step 7, elastomeric compound add sulfur: by vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80 are sequentially added into Step 6 thin logical after glue stuff compounding in, then stir, the thinnest logical 3 times, roll spacing controls at 1mm, and the time controls 3min；
Step 8, clot bottom sheet: will add elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls At 8mm, the time controls at 4min, obtains butyronitrile series environment-friendly type rubber floor covering sizing material.
Embodiment 2
Step 1, weighing raw material, weigh nitrile rubber 33.72%, zinc oxide 1.69%, stearic acid according to percentage by weight 0.34%, environment-friendly type age resistor 405 0.67%, titanium dioxide 1.69%, potter's clay 10.11%, aluminium hydroxide 10.11%, Firebrake ZB 5.06%, fire retardant BN-18C 5.06%, white carbon 13.49%, nano kaoline 13.49%, antistatic additive 0.67%, point Powder FC-303 0.67%, flow promortor PEG4000 0.67%, ultraviolet (UV) resistant agent UV-531 0.51%, antibacterial CZ- KZ10 0.51%, vulcanizing agent S-800.2%, environment-friendly type accelerator TBZTD 0.67%, vulcanizing agent CLD-80 0.34%, pigment 0.34%, the percentage composition summation of above component is 100%；
Step 2, the nitrile rubber weighed in step 1 is plasticated: roll spacing controls at 3mm, and the time controls at 4min；
Step 3, step 2 is plasticated after nitrile rubber carry out pressing: roll spacing controls at 4mm, and the time controls at 1min；
Step 4, nitrile rubber after step 3 pressing are sequentially added into zinc oxide, stearic acid, age resistor 405, are mixed Closing rubber, roll spacing controls at 8mm, and the time controls at 2.5min；
Step 5, rubber compounding: sequentially add on the basis of step 4 titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, Fire retardant BN-18C, white carbon, nano kaoline, antistatic additive, dispersant FC-303, flow promortor PEG4000, uvioresistant Agent UV531, antibacterial CZ-KZ10, pigment, be then uniformly mixed, and roll spacing controls at 6mm, and the time controls at 21min；
Step 6, by thin for the step 5 sizing material after mixing logical 3 times, roll spacing controls at 1mm, and the time controls at 5min；
Step 7, elastomeric compound add sulfur: by vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80 are sequentially added into Step 6 thin logical after glue stuff compounding in, then stir, the thinnest logical 3 times, roll spacing controls at 2mm, and the time controls 3min；
Step 8, clot bottom sheet: will add elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls At 10mm, the time controls at 2min, obtains butyronitrile series environment-friendly type rubber floor covering sizing material.
Embodiment 3
Step 1, weighing raw material, weigh nitrile rubber 33.72%, zinc oxide 1.69%, stearic acid according to percentage by weight 0.34%, environment-friendly type age resistor 405 0.67%, titanium dioxide 1.69%, potter's clay 13.49%, fire retardant HP800 13.49%, in vain White carbon black 6.74%, nano kaoline 23.6%, antistatic additive 0.67%, dispersant FC-303 0.67%, flow promortor PEG4000 0.67%, ultraviolet (UV) resistant agent UV-531 0.51%, antibacterial CZ-KZ10 0.51%, vulcanizing agent S-80 0.2%, Environment-friendly type accelerator TBZTD 0.67%, vulcanizing agent CLD-80 0.34%, pigment 0.34%, the percentage composition of above component Summation is 100%；
Step 2, the nitrile rubber weighed in step 1 is plasticated: roll spacing controls at 2.5mm, and the time controls at 6min；
Step 3, step 2 is plasticated after nitrile rubber carry out pressing: roll spacing controls at 5mm, and the time controls at 3min；
Step 4, nitrile rubber after step 3 pressing are sequentially added into zinc oxide, stearic acid, age resistor 405, are mixed Closing rubber, roll spacing controls at 7mm, and the time controls at 2min；
Step 5, rubber compounding: on the basis of step 4, sequentially add small powder: titanium dioxide, potter's clay, fire retardant HP800, White carbon, nano kaoline, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial Agent CZ-KZ10, pigment, be then uniformly mixed, and roll spacing controls at 7mm, and the time controls at 20min；
Step 6, by thin for the step 5 sizing material after mixing logical 4 times, roll spacing controls at 2mm, and the time controls at 4min；
Step 7, elastomeric compound add sulfur: by vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80 are sequentially added into Step 6 thin logical after glue stuff compounding in, then stir, the thinnest logical 3 times, roll spacing controls at 2mm, and the time controls 4min；
Step 8, clot bottom sheet: will add elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls At 9mm, the time controls at 3min, obtains butyronitrile series environment-friendly type rubber floor covering sizing material.

Claims (7)

1. a butyronitrile series environment-friendly type rubber floor covering sizing material, it is characterised in that effective by following raw material by weight percentage Component forms:
Nitrile rubber 30%～35%, zinc oxide 1.5%～1.7%, stearic acid 0.3%～0.4%, environment-friendly type age resistor 405 0.6%～0.7%, titanium dioxide 1.5%～3.1%, potter's clay 9%～13.5%, fire retardant HP800 0～13.5%, hydroxide Aluminum 0～10.2%, Firebrake ZB 0～5.1%, fire retardant BN-18C 0～5.1%, white carbon 4.5%～13.5%, nanometer kaolinite Soil 13%～23.7%, calcium carbonate superfine powder 0～18.4%, antistatic additive 0.6%～0.7%, dispersant FC-303 0.6%～ 0.7%, flow promortor PEG4000 0.5%～0.7%, ultraviolet (UV) resistant agent UV-531 0.4%～0.55%, antibacterial CZ- KZ10 0.4%～0.6%, vulcanizing agent S-80 0.1%～0.2%, environment-friendly type accelerator TBZTD 0.6～0.7%, vulcanizing agent CLD-80 0.3%～0.35%, pigment 0.3%～0.35%, the percentage composition summation of above component is 100%.
A kind of butyronitrile series environment-friendly type rubber floor covering sizing material the most according to claim 1, it is characterised in that described butyronitrile rubber Glue is N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one therein.
A kind of butyronitrile series environment-friendly type rubber floor covering sizing material the most according to claim 1, it is characterised in that described oxidation Zinc, stearic acid, environment-friendly type age resistor, titanium dioxide, potter's clay, fire retardant HP800, aluminium hydroxide, Firebrake ZB, fire retardant BN-18C, White carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV-531, antibacterial CZ-KZ10, vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80, pigment are environment-friendly type Rubber chemicals.
4. the preparation method of a butyronitrile series environment-friendly type rubber floor covering sizing material, it is characterised in that specifically real according to following steps Execute:
Step 1, weigh raw material, weigh nitrile rubber 30%～35% according to percentage by weight, zinc oxide 1.5%～1.7%, firmly Fat acid 0.3%～0.4%, environment-friendly type age resistor 405 0.6%～0.7%, titanium dioxide 1.5%～3.1%, potter's clay 9%～ 13.5%, fire retardant HP800 0～13.5%, aluminium hydroxide 0～10.2%, Firebrake ZB 0～5.1%, fire retardant BN-18C 0 ～5.1%, white carbon 4.5%～13.5%, nano kaoline 13%～23.7%, calcium carbonate superfine powder 0～18.4%, antistatic Agent 0.6%～0.7%, dispersant FC-303 0.6%～0.7%, flow promortor PEG4000 0.5%～0.7%, uvioresistant Line agent UV-531 0.4%～0.55%, antibacterial CZ-KZ10 0.4%～0.6%, vulcanizing agent S-80 0.1%～0.2%, Environment-friendly type accelerator TBZTD 0.6～0.7%, vulcanizing agent CLD-80 0.3%～0.35%, pigment 0.3%～0.35%, with The percentage composition summation of upper component is 100%；
Step 2, the nitrile rubber weighed in described step 1 is plasticated: roll spacing controls 2～3mm, the time control 4～ 6min；
Step 3, described step 2 is plasticated after nitrile rubber carry out pressing: roll spacing controls 4～6mm, the time control 1～ 3min；
Step 4, nitrile rubber after described step 2 pressing are sequentially added into zinc oxide, stearic acid, age resistor 405, are mixed Closing rubber, roll spacing controls 6～8mm, and the time controls 1.5～2.5min；
Step 5, rubber compounding: on the basis of described step 4, sequentially add small powder: titanium dioxide, potter's clay, aluminium hydroxide, boron Acid zinc, fire retardant HP800, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV531, antibacterial CZ-KZ10, pigment, be then uniformly mixed, and roll spacing controls 6～8mm, Time controls 19～21min；
Step 6, by thin for the sizing material after mixing for described step 5 logical 3～4 times, roll spacing controls 1～2mm, the time control 3～ 5min；
Step 7, elastomeric compound add sulfur: by vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80 are sequentially added into described step Rapid 6 thin logical after glue stuff compounding in, then stir, the thinnest logical 3 times, roll spacing controls 1～2mm, the time control 3～ 5min；
Step 8, clot bottom sheet: will add elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing control 8～ 10mm, the time controls 2～4min, obtains butyronitrile series environment-friendly type rubber floor covering sizing material.
The preparation method of a kind of butyronitrile series environment-friendly type rubber floor covering sizing material the most according to claim 4, it is characterised in that In described step 1, nitrile rubber is N41E, NBR3305E, 2907E, N41E, 3308E, 2805E one therein.
The preparation method of a kind of butyronitrile series environment-friendly type rubber floor covering sizing material the most according to claim 4, it is characterised in that Zinc oxide, stearic acid, environment-friendly type age resistor, titanium dioxide, potter's clay, fire retardant HP800, aluminium hydroxide, boric acid in described step 1 Zinc, fire retardant BN-18C, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, ultraviolet (UV) resistant agent UV-531, antibacterial CZ-KZ10, vulcanizing agent S-80, environment-friendly type accelerator TBZTD, vulcanizing agent CLD-80, pigment are environment-friendly rubber auxiliary agent.
The preparation method of a kind of butyronitrile series environment-friendly type rubber floor covering sizing material the most according to claim 4, it is characterised in that In described step 5, whole adition process divides 4 additions, and each addition is titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire-retardant Agent HP800, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant FC-303, flow promortor PEG4000, anti- Ultraviolet agent UV531, antibacterial CZ-KZ10, the 1/4 of pigment total amount, add every time after, after pan feeding to be added is compatible with mixed rubber Carrying out charging next time.
CN201610709935.6A 2016-08-23 2016-08-23 A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof Pending CN106146948A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610709935.6A CN106146948A (en) 2016-08-23 2016-08-23 A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610709935.6A CN106146948A (en) 2016-08-23 2016-08-23 A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106146948A true CN106146948A (en) 2016-11-23

Family

ID=57343352

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610709935.6A Pending CN106146948A (en) 2016-08-23 2016-08-23 A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106146948A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110358161A (en) * 2019-08-02 2019-10-22 南京东润特种橡塑有限公司 A kind of high-strength colour Antistatic rubber plate and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10100943A (en) * 1996-09-26 1998-04-21 Asahi Corp Floor material for motor truck deck and manufacture thereof
CN102852314A (en) * 2011-06-30 2013-01-02 上海大巨龙蓬盖新材料有限公司 Manufacturing method of rubber patterned coiled material floor
CN104961938A (en) * 2015-06-26 2015-10-07 安徽顺驰电缆有限公司 Dampproof self-cleaning rubber floor and processing technology thereof
CN105524311A (en) * 2015-04-07 2016-04-27 上海加富新材料科技有限公司 High-conductive rubber floor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10100943A (en) * 1996-09-26 1998-04-21 Asahi Corp Floor material for motor truck deck and manufacture thereof
CN102852314A (en) * 2011-06-30 2013-01-02 上海大巨龙蓬盖新材料有限公司 Manufacturing method of rubber patterned coiled material floor
CN105524311A (en) * 2015-04-07 2016-04-27 上海加富新材料科技有限公司 High-conductive rubber floor
CN104961938A (en) * 2015-06-26 2015-10-07 安徽顺驰电缆有限公司 Dampproof self-cleaning rubber floor and processing technology thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110358161A (en) * 2019-08-02 2019-10-22 南京东润特种橡塑有限公司 A kind of high-strength colour Antistatic rubber plate and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106084502A (en) EPDM series environment-friendly type rubber floor covering sizing material and preparation method thereof
CN106336541A (en) Butylbenzene-series environment-friendly type rubber floor glue stock and preparation method thereof
MX2010009377A (en) Surface coverings containing reclaimed vct material, and methods and systems for making and using them.
CN109054190B (en) Shock-absorbing, wear-resisting and antibacterial rubber floor mat and preparation method thereof
CN104610855A (en) Aqueous deep-draw varnish and preparation technology thereof
CN109705497A (en) A kind of no aldehyde stone-plastic plate material
CN106380718A (en) Energy-saving and environment-friendly wood plastic material
CN106146948A (en) A kind of butyronitrile series environment-friendly type rubber floor covering sizing material and preparation method thereof
CN108019028A (en) A kind of SPC solid wooden compound floors
CN108909098B (en) Wear-resistant, flame-retardant and antistatic rubber floor mat and preparation method thereof
CN107033437A (en) A kind of PPM environmental friendly materials and preparation method thereof
CN201078075Y (en) Plastic and wood composite floor
CN106336547A (en) NV-series environment-friendly type rubber floor glue stock and preparation method thereof
CN106750468A (en) A kind of powdered rubber interleaving agent
CN102504438A (en) Color printed wood-plastic composite non-slip energy-saving floor tile and production method thereof
CN106082811A (en) Inorganic mildewing desiccating proof powder coating and preparation method thereof
CN105856784A (en) Multifunctional elastic rubber blanket and manufacturing method thereof
CN103224738A (en) Aqueous environmental protection edge sealing strip prinking ink and preparation method thereof
CN101270263A (en) Nano-composite dry powder marble wall art paint
CN101934880B (en) Environment-friendly water-proof packaging bag and manufacturing method thereof
CN104130518A (en) High-temperature-resistant and flame-retardant stone floor
CN204343136U (en) People's Bank of China's Anti-skid adhesive piece
CN104194178A (en) Formula of wood-imitation material
CN214400322U (en) Water-based acrylic acid bi-component coating layer
CN103275563A (en) Chlorinated rubber fireproof paint for wood material

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161123

RJ01 Rejection of invention patent application after publication