CN107033437A - A kind of PPM environmental friendly materials and preparation method thereof - Google Patents
A kind of PPM environmental friendly materials and preparation method thereof Download PDFInfo
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- CN107033437A CN107033437A CN201710351003.3A CN201710351003A CN107033437A CN 107033437 A CN107033437 A CN 107033437A CN 201710351003 A CN201710351003 A CN 201710351003A CN 107033437 A CN107033437 A CN 107033437A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of PPM environmental friendly materials, the PPM environmental friendly materials include the component of following mass parts：75 85 parts of calcium carbonate, 15 25 parts of vector resin, 35 parts of dispersant, 35 parts of lubricant, 35 parts of coupling agent, 13 parts of antioxidant, 35 parts of stabilizer, 10 20 parts of sepiolite, 10 20 parts of quartz sand.PPM environmental friendly materials of the present invention have good function effect, its preparing raw material is easy to get, cost is low, quality is high, technical maturity, be easy to promote, effect it is notable, it can be widely applied to plastic products manufacture field, especially in plastics package industry, agripast industry and materials for construction industry, actual requirement is met.
Description
Technical field
The present invention relates to a kind of PPM environmental friendly materials and preparation method thereof, belong to environmental friendly material and fabricating technology
Field.
Background technology
Environmental friendly material mainly has several：（1）Substantially nontoxic type, refer to it is natural, itself without or it is few poisonous
Harmful material, the ornament materials for only having carried out without pollution simple processing, such as gypsum, talcum powder, sandstone, timber, Mou Xietian
Right stone material etc.；（2）Low toxicity, low emission type, refer to control the product of poisonous and harmful substances by technological means such as processing, synthesis
Gather gentle On The Drug Release, because its toxicity is slight, do not constitute the ornament materials of danger to human health, such as burst size of methanal is relatively low, reach
Lumber core, glued board, fiberboard to national standard etc..Science and technology and detection means can not determine and assess its murder by poisoning at present
The material of material influence, such as environment-friendly type emulsion paint, environment-friendly type paint chemical synthetic material, these materials are being currently nontoxic nothing
Harmful, but with the development of science and technology, the possibility assert again is might have in the future.
China is one of limestone deposit resource-rich country in the world, in addition to Shanghai, Hong Kong, Macao, in each province, straight
Linchpin city, autonomous region are distributed.According to former State Bureau of Building Materials Industry's geology center count, national limestone distribution area up to 43.8 ten thousand Km2,
Account for area 1/20.Part oil plastics are substituted using inorganic filling materials such as calcium carbonate, while saving petroleum resources
Reduce material cost, it has also become the trend of plastic industry development.Calcium carbonate can be widely applied to rubber, coating, papermaking, plastics,
The fields such as ink.But China and in the world the efficient technique of rainwater utilization slower development to calcium carbonate, for a long time, using in the plastic
Calcium carbonate be all to fill based on 20% or so, do not play really improve the processability of plastics, to improve plastic products stable
Property and the reduction effect such as plastic products cost.
The content of the invention
The present invention, should exactly in view of the deficienciess of the prior art, provide a kind of PPM environmental friendly materials and preparation method thereof
PPM environmental friendly materials have good function effect, and its preparing raw material is easy to get, cost is low, quality is high, technical maturity, be easy to push away
Extensively, effect significantly, can be widely applied to plastic products manufacture field, especially in plastics package industry, agripast industry and modeling
Expect building material industry, meet actual requirement.
To solve the above problems, the technical solution used in the present invention is as follows：
A kind of PPM environmental friendly materials, the PPM environmental friendly materials include the component of following mass parts：75-85 parts of calcium carbonate, load
15-25 parts of body resin, 3-5 parts of dispersant, 3-5 parts of lubricant, 3-5 parts of coupling agent, 1-3 parts of antioxidant, 3-5 parts of stabilizer,
10-20 parts of sepiolite, 10-20 parts of quartz sand.
As the improvement of above-mentioned technical proposal, the calcium carbonate is the transparent calcite calcium carbonate of needle-like, and its fineness is 1000
The mesh of mesh -3000, draw ratio is 6:1-12:1.
As the improvement of above-mentioned technical proposal, the vector resin is polypropylene, polyethylene or the mixture of the two, and two
Percentage by weight is that polypropylene is 20-50% when person mixes, and polyethylene is 50-80%.
As the improvement of above-mentioned technical proposal, the dispersant is Stearyl Amine, the double Stearyl Amines of vinyl, barium stearate, hard
The one or more of resin acid calcium and zinc stearate；The lubricant is paraffin, Tissuemat E, OPE and low molecule amount
One or more in polypropylene wax；The coupling agent is in aluminate coupling agent, titanate coupling agent and silane coupler
It is one or more.
Specifically, a kind of preparation method of PPM environmental friendly materials is as follows：
Carried out Step 1: first match to add in split coating machine according to parts by weight by calcium carbonate, dispersant and coupling agent simultaneously
Coating modification；
Step 2: modified be put into banburying in banbury simultaneously and mix with vector resin, lubricant, antioxidant again；
Step 3: banburying mixture and surplus stock in step 2 are inserted in wet mixer, raw material is stirred, is beaten
Processing, vapours is then passed through under conditions of 150 DEG C and carries out heat modification, is reused nano-shearing machine and is carried out shear treatment,
Form feed liquid；
Step 4: the feed liquid that step 3 is obtained is heated into boiling, evaporation moisture concentration feed liquid to formation softening environment-friendly materials；
Step 5: the softening environment-friendly materials progress that step 4 is obtained is natural air cooled；
Step 6: will be machined out by air-cooled environment-friendly materials to powdered, the environmentally friendly green woods of PPM of the present invention are produced
Material.
Compared with prior art, implementation result of the invention is as follows by the present invention：
The invention provides a kind of PPM environmental friendly materials and preparation method thereof, the PPM environmental friendly materials have good function work
With, its preparing raw material is easy to get, cost is low, quality is high, technical maturity, be easy to promote, effect significantly, can be widely applied to plastics system
Product manufacture field, especially in plastics package industry, agripast industry and materials for construction industry, meets actual requirement.
Note：PPM environmental friendly materials produced by the present invention tool extremely excellent ultraviolet resistance, resistance to ozone and chemical-resistant characteristic,
And enhance the PPM environmental friendly materials tensile strength and fracture elongation is big.
Embodiment
Illustrate present disclosure below in conjunction with specific embodiments.
Embodiment 1
A kind of PPM environmental friendly materials, the PPM environmental friendly materials include the component of following mass parts：75 parts of calcium carbonate, carrier tree
15 parts of fat, 3 parts of dispersant, 3 parts of lubricant, 3 parts of coupling agent, 1 part of antioxidant, 3 parts of stabilizer, 10 parts of sepiolite, quartz sand
10 parts.
Further with improvement, the calcium carbonate is the transparent calcite calcium carbonate of needle-like, and its fineness is 1000 mesh, and draw ratio is
6:1。
Further with improvement, the vector resin is polypropylene, polyethylene or the mixture of the two, and is weighed during the two mixing
It is that polypropylene is 20% to measure percentage, and polyethylene is 50%.
Further with improvement, the dispersant is Stearyl Amine, the double Stearyl Amines of vinyl, barium stearate, calcium stearate and hard
The one or more of resin acid zinc；The lubricant is in paraffin, Tissuemat E, OPE and low-molecular-weight polypropylene wax
One or more；The coupling agent is the one or more in aluminate coupling agent, titanate coupling agent and silane coupler.
Specifically, the preparation method of the PPM environmental friendly materials is as follows：
Carried out Step 1: first match to add in split coating machine according to parts by weight by calcium carbonate, dispersant and coupling agent simultaneously
Coating modification；
Step 2: modified be put into banburying in banbury simultaneously and mix with vector resin, lubricant, antioxidant again；
Step 3: banburying mixture and surplus stock in step 2 are inserted in wet mixer, raw material is stirred, is beaten
Processing, vapours is then passed through under conditions of 150 DEG C and carries out heat modification, is reused nano-shearing machine and is carried out shear treatment,
Form feed liquid；
Step 4: the feed liquid that step 3 is obtained is heated into boiling, evaporation moisture concentration feed liquid to formation softening environment-friendly materials；
Step 5: the softening environment-friendly materials progress that step 4 is obtained is natural air cooled；
Step 6: will be machined out by air-cooled environment-friendly materials to powdered, the environmentally friendly green woods of PPM of the present invention are produced
Material.
The invention provides a kind of PPM environmental friendly materials and preparation method thereof, the PPM environmental friendly materials have good function
Property effect, its preparing raw material is easy to get, cost is low, quality is high, technical maturity, be easy to promote, effect significantly, can be widely applied to modeling
Material products manufacture field, especially in plastics package industry, agripast industry and materials for construction industry, meets actual requirement.
Note：PPM environmental friendly materials produced by the present invention tool extremely excellent ultraviolet resistance, resistance to ozone and chemical-resistant characteristic,
And enhance the PPM environmental friendly materials tensile strength and fracture elongation is big.
Embodiment 2
A kind of PPM environmental friendly materials, the PPM environmental friendly materials include the component of following mass parts：80 parts of calcium carbonate, carrier tree
20 parts of fat, 4 parts of dispersant, 4 parts of lubricant, 4 parts of coupling agent, 2 parts of antioxidant, 4 parts of stabilizer, 15 parts of sepiolite, quartz sand
15 parts.
Further with improvement, the calcium carbonate is the transparent calcite calcium carbonate of needle-like, and its fineness is 2000 mesh, and draw ratio is
9:1。
Further with improvement, the vector resin is polypropylene, polyethylene or the mixture of the two, and is weighed during the two mixing
It is that polypropylene is 35% to measure percentage, and polyethylene is 65%.
Further with improvement, the dispersant is Stearyl Amine, the double Stearyl Amines of vinyl, barium stearate, calcium stearate and hard
The one or more of resin acid zinc；The lubricant is in paraffin, Tissuemat E, OPE and low-molecular-weight polypropylene wax
One or more；The coupling agent is the one or more in aluminate coupling agent, titanate coupling agent and silane coupler.
Specifically, the preparation method of the PPM environmental friendly materials is as follows：
Carried out Step 1: first match to add in split coating machine according to parts by weight by calcium carbonate, dispersant and coupling agent simultaneously
Coating modification；
Step 2: modified be put into banburying in banbury simultaneously and mix with vector resin, lubricant, antioxidant again；
Step 3: banburying mixture and surplus stock in step 2 are inserted in wet mixer, raw material is stirred, is beaten
Processing, vapours is then passed through under conditions of 150 DEG C and carries out heat modification, is reused nano-shearing machine and is carried out shear treatment,
Form feed liquid；
Step 4: the feed liquid that step 3 is obtained is heated into boiling, evaporation moisture concentration feed liquid to formation softening environment-friendly materials；
Step 5: the softening environment-friendly materials progress that step 4 is obtained is natural air cooled；
Step 6: will be machined out by air-cooled environment-friendly materials to powdered, the environmentally friendly green woods of PPM of the present invention are produced
Material.
The invention provides a kind of PPM environmental friendly materials and preparation method thereof, the PPM environmental friendly materials have good function
Property effect, its preparing raw material is easy to get, cost is low, quality is high, technical maturity, be easy to promote, effect significantly, can be widely applied to modeling
Material products manufacture field, especially in plastics package industry, agripast industry and materials for construction industry, meets actual requirement.
Note：PPM environmental friendly materials produced by the present invention tool extremely excellent ultraviolet resistance, resistance to ozone and chemical-resistant characteristic,
And enhance the PPM environmental friendly materials tensile strength and fracture elongation is big.
Embodiment 3
A kind of PPM environmental friendly materials, the PPM environmental friendly materials include the component of following mass parts：85 parts of calcium carbonate, carrier tree
25 parts of fat, 5 parts of dispersant, 5 parts of lubricant, 5 parts of coupling agent, 3 parts of antioxidant, 5 parts of stabilizer, 20 parts of sepiolite, quartz sand
20 parts.
Further with improvement, the calcium carbonate is the transparent calcite calcium carbonate of needle-like, and its fineness is 3000 mesh, and draw ratio is
12:1。
Further with improvement, the vector resin is polypropylene, polyethylene or the mixture of the two, and is weighed during the two mixing
It is that polypropylene is 50% to measure percentage, and polyethylene is 80%.
Further with improvement, the dispersant is Stearyl Amine, the double Stearyl Amines of vinyl, barium stearate, calcium stearate and hard
The one or more of resin acid zinc；The lubricant is in paraffin, Tissuemat E, OPE and low-molecular-weight polypropylene wax
One or more；The coupling agent is the one or more in aluminate coupling agent, titanate coupling agent and silane coupler.
Specifically, the preparation method of the PPM environmental friendly materials is as follows：
Carried out Step 1: first match to add in split coating machine according to parts by weight by calcium carbonate, dispersant and coupling agent simultaneously
Coating modification；
Step 2: modified be put into banburying in banbury simultaneously and mix with vector resin, lubricant, antioxidant again；
Step 3: banburying mixture and surplus stock in step 2 are inserted in wet mixer, raw material is stirred, is beaten
Processing, vapours is then passed through under conditions of 150 DEG C and carries out heat modification, is reused nano-shearing machine and is carried out shear treatment,
Form feed liquid；
Step 4: the feed liquid that step 3 is obtained is heated into boiling, evaporation moisture concentration feed liquid to formation softening environment-friendly materials；
Step 5: the softening environment-friendly materials progress that step 4 is obtained is natural air cooled；
Step 6: will be machined out by air-cooled environment-friendly materials to powdered, the environmentally friendly green woods of PPM of the present invention are produced
Material.
The invention provides a kind of PPM environmental friendly materials and preparation method thereof, the PPM environmental friendly materials have good function
Property effect, its preparing raw material is easy to get, cost is low, quality is high, technical maturity, be easy to promote, effect significantly, can be widely applied to modeling
Material products manufacture field, especially in plastics package industry, agripast industry and materials for construction industry, meets actual requirement.
Note：PPM environmental friendly materials produced by the present invention tool extremely excellent ultraviolet resistance, resistance to ozone and chemical-resistant characteristic,
And enhance the PPM environmental friendly materials tensile strength and fracture elongation is big.
Above content is made for the present invention in conjunction with specific embodiments describes in detail, it is impossible to assert that the present invention is specific real
Apply and be only limitted to these explanations.For those skilled in the art, before present inventive concept is not departed from
Put, some simple deduction or replace can also be made, the scope of protection of the invention should be all considered as belonging to.
Claims (5)
1. a kind of PPM environmental friendly materials, it is characterised in that：The PPM environmental friendly materials include the component of following mass parts：Carbonic acid
75-85 parts of calcium, 15-25 parts of vector resin, 3-5 parts of dispersant, 3-5 parts of lubricant, 3-5 parts of coupling agent, 1-3 parts of antioxidant,
3-5 parts of stabilizer, 10-20 parts of sepiolite, 10-20 parts of quartz sand.
2. a kind of PPM environmental friendly materials according to claim 1, it is characterised in that：The calcium carbonate is the transparent side's solution of needle-like
Carbolic acid calcium, its fineness is the mesh of 1000 mesh -3000, and draw ratio is 6:1-12:1.
3. a kind of PPM environmental friendly materials according to claim 1, it is characterised in that：The vector resin is polypropylene, poly- second
Alkene or the mixture of the two, and percentage by weight is that polypropylene is 20-50% during the two mixing, polyethylene is 50-80%.
4. a kind of PPM environmental friendly materials according to claim 1, it is characterised in that：The dispersant is Stearyl Amine, ethene
The double Stearyl Amines of base, barium stearate, the one or more of calcium stearate and zinc stearate；The lubricant is paraffin, polyethylene
One or more in wax, OPE and low-molecular-weight polypropylene wax；The coupling agent is aluminate coupling agent, metatitanic acid
One or more in ester coupling agent and silane coupler.
5. a kind of preparation method of PPM environmental friendly materials according to claim 1-4, it is characterised in that：The preparation method
It is as follows：
Carried out Step 1: first match to add in split coating machine according to parts by weight by calcium carbonate, dispersant and coupling agent simultaneously
Coating modification；
Step 2: modified be put into banburying in banbury simultaneously and mix with vector resin, lubricant, antioxidant again；
Step 3: banburying mixture and surplus stock in step 2 are inserted in wet mixer, raw material is stirred, is beaten
Processing, vapours is then passed through under conditions of 150 DEG C and carries out heat modification, is reused nano-shearing machine and is carried out shear treatment,
Form feed liquid；
Step 4: the feed liquid that step 3 is obtained is heated into boiling, evaporation moisture concentration feed liquid to formation softening environment-friendly materials；
Step 5: the softening environment-friendly materials progress that step 4 is obtained is natural air cooled；
Step 6: will be machined out by air-cooled environment-friendly materials to powdered, the environmentally friendly green woods of PPM of the present invention are produced
Material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710351003.3A CN107033437A (en) | 2017-05-18 | 2017-05-18 | A kind of PPM environmental friendly materials and preparation method thereof |
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| CN201710351003.3A CN107033437A (en) | 2017-05-18 | 2017-05-18 | A kind of PPM environmental friendly materials and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109111153A (en) * | 2018-08-22 | 2019-01-01 | 河南东贵电子科技有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
| CN109135053A (en) * | 2018-07-17 | 2019-01-04 | 徐州益康环保科技有限公司 | A kind of PPM environmental friendly material and preparation method thereof |
| CN109734998A (en) * | 2018-12-25 | 2019-05-10 | 天长市富信电子有限公司 | A kind of signal transmssion line thermoplastic elastic material and preparation method thereof |
| CN117447125A (en) * | 2023-10-27 | 2024-01-26 | 浙江晶引电子科技有限公司 | Environment-friendly material for ultrathin flexible film packaging substrate and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479046A (en) * | 2016-09-28 | 2017-03-08 | 广东碧盛环球环保材料有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
-
2017
- 2017-05-18 CN CN201710351003.3A patent/CN107033437A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479046A (en) * | 2016-09-28 | 2017-03-08 | 广东碧盛环球环保材料有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135053A (en) * | 2018-07-17 | 2019-01-04 | 徐州益康环保科技有限公司 | A kind of PPM environmental friendly material and preparation method thereof |
| CN109111153A (en) * | 2018-08-22 | 2019-01-01 | 河南东贵电子科技有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
| CN109734998A (en) * | 2018-12-25 | 2019-05-10 | 天长市富信电子有限公司 | A kind of signal transmssion line thermoplastic elastic material and preparation method thereof |
| CN117447125A (en) * | 2023-10-27 | 2024-01-26 | 浙江晶引电子科技有限公司 | Environment-friendly material for ultrathin flexible film packaging substrate and preparation method thereof |
| CN117447125B (en) * | 2023-10-27 | 2024-04-05 | 浙江晶引电子科技有限公司 | Environment-friendly material for ultrathin flexible film packaging substrate and preparation method thereof |
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Application publication date: 20170811 |