CN106139885A - A kind of preparation method of biologic packing material - Google Patents

A kind of preparation method of biologic packing material Download PDF

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Publication number
CN106139885A
CN106139885A CN201610654510.XA CN201610654510A CN106139885A CN 106139885 A CN106139885 A CN 106139885A CN 201610654510 A CN201610654510 A CN 201610654510A CN 106139885 A CN106139885 A CN 106139885A
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rice
silica gel
variable color
packing material
biologic packing
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CN201610654510.XA
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CN106139885B (en
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吴美燕
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Guangdong Qiankai Environmental Protection Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Cosmetics (AREA)
  • Fodder In General (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

The present invention relates to the preparation method of a kind of biologic packing material, variable color silica gel and indigenous microorganism stock solution are joined in Organic substance according to certain mass ratio, adds certain moisture, ferment at a certain temperature to mildew, obtain biologic packing material.Raw material of the present invention is easy to get, low cost, and the effect that eliminates the unusual smell is obvious, and can keep the skin wet according to color change.

Description

A kind of preparation method of biologic packing material
Technical field
The present invention relates to the preparation method of a kind of biologic packing material.
Background technology
Gas biologic packing material action principle in the market be the chemical substance in foul smell is first passed through filler gas/ Liquid phase is transferred to by gas phase in liquid interface;Abnormal flavour chemicals in waste gas are diffused into the biomembrane of biologic packing material by liquid phase;Biology is filled out Microorganism in the biomembrane that material surface is formed is gas with foreign flavor molecular oxidation, and biomembrane can cause the nutrient such as nitrogen or phosphorus simultaneously Matter and the diffusion of oxygen and absorption.Biofiltration is converted into titanium dioxide by the above three stage the polluter in waste gas Carbon, water, inorganic salt, mineral etc., thus reach the purpose that abnormal flavour purifies.Micro-life is can be seen that from biologic packing material action principle Thing eliminates the unusual smell the Transformation Engineering having to pass through a gas phase to liquid phase, and this process must have the existence of water, and water is micro-life The essential condition of thing existence.And biologic packing material in the market, there is no the product of a kind of reaction microbe stuffing moisture directly perceived.
Summary of the invention
The technical problem to be solved is to provide the preparation method of a kind of biologic packing material, and the present invention has excellence Decomposition function, and can intuitively react moisture situation in biologic packing material.
In order to solve above-mentioned technical problem, the present invention by the following technical solutions:
The preparation method of a kind of biologic packing material, it is characterised in that follow the steps below:
1), prepare indigenous microorganism stock solution: by water content 40%~65% rice put in gas-permeable container, rice accounts for ventilative The 30%~60% of vessel volume, gas-permeable container upper cover rice paper is also tightened, by gas-permeable container back-off in the rice having white liquid to overflow On stubble, making rice contact with the white liquid on rice stubble, placement to rice becomes pink sposh state, by pink sposh shape The rice of state is put in gas impermeable container and adds brown sugar, zinc sulfate and potassium dihydrogen phosphate mixing, the rice of pink sposh state The mass ratio of meal, brown sugar, zinc sulfate and potassium dihydrogen phosphate is 100:30~60:0.1~1:0.1~1, covers rice paper and tightens, Being positioned in 15~30 DEG C of environment, to altar, mixture becomes liquid, i.e. obtains indigenous microorganism stock solution;
2), biologic packing material is prepared: variable color silica gel and indigenous microorganism stock solution joined according to certain mass ratio and fill Organic substance Fermentation tank in, and add water, variable color silica gel, indigenous microorganism stock solution and organic mass ratio are 4~15:0.5~5:80 ~94, the water content of variable color silica gel, indigenous microorganism stock solution and organic mixture is 40%~60%, in temperature 20~35 Under the conditions of DEG C, stirring a material every 3~6 hours, and keep moisture consistent, fermentation, to long white hair, obtains biologic packing material;
Described variable color silica gel is without the orange silica gel of cobalt with without the one in cobalt blue silica gel;
Described Organic substance is the one in branch, bark, leaves, Pericarppium arachidis hypogaeae, wheat straw, Testa oryzae and the bean cake pulverized or arbitrary proportion Two or more.
Variable color silica gel is powder variable color silica gel, and mesh number is 20~100 mesh.
Rice water content described in step 1) is 60%, and rice accounts for the 40% of gas-permeable container volume;Pink sposh state The mass ratio of rice, brown sugar, zinc sulfate and potassium dihydrogen phosphate is 100:45:0.1:0.2.
Step 2) described in Organic substance be that the Folium Populi Pseudo-simonii pulverized and Testa oryzae are according to the compositions of 6:1;Variable color silica gel is without cobalt Blue silica gel, mesh number is 80 mesh;Variable color silica gel, indigenous microorganism stock solution and organic mass ratio are 6:1:43;Water content is 55%, temperature 28 DEG C, stirred once every 4 hours.
Invent and there is following Advantageous Effects:
1, the present invention uses the indigenous Caulis et Folium Oryzae bacterium of nature to be fermenation raw liquid, original inhabitants Caulis et Folium Oryzae bacterium have the most powerful vitality and Capacity of decomposition, and adapt to the change of external environment.
2, the present invention can react the moisture in microbe stuffing intuitively by the addition of variable color silica gel, and operator can root Change according to the color of microbe stuffing and keep the skin wet, to ensure the effectiveness of microbe stuffing.Filler color is under normal circumstances Navy blue, is accomplished by when becoming light blue keeping the skin wet to navy blue.
3, the present invention adds variable color silica gel, owing to variable color silica gel adsorption is high, Organic substance preferably can be adsorbed The degraded of biofilm surface, beneficially indigenous microorganism, can recover again variable color silica gel after the organic matter degradation of absorption Absorbability, can reach a kind of benign cycle.
Detailed description of the invention
The present invention is further illustrated below in conjunction with instantiation.
Embodiment 1
By water content 60% rice put in gas-permeable container, rice accounts for the 40% of gas-permeable container volume, gas-permeable container upper cover Rice paper is also tightened, and by gas-permeable container back-off on the rice stubble having white liquid to overflow, rice stubble punctures rice paper and makes on rice and rice stubble White liquid contact, to rice become pink sposh state, by pink sposh state rice put into gas impermeable container In and add brown sugar, zinc sulfate and potassium dihydrogen phosphate mixing, the pink rice of sposh state, brown sugar, zinc sulfate and di(2-ethylhexyl)phosphate The mass ratio of hydrogen potassium is 100:45:0.1:0.2, covers rice paper and tightens, and is positioned in 28 DEG C of environment, and to altar, mixture becomes Liquid, i.e. obtains indigenous microorganism stock solution;
Prepare biologic packing material: the variable color silica gel of 80 mesh and indigenous microorganism stock solution are joined according to certain mass ratio fill organic In the fermentation tank of thing, and adding water, the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mass ratio are 6:1:43, The water content of the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mixture is 55%, under the conditions of temperature 28 DEG C, Stirring a material every 4 hours, and keep moisture consistent, fermentation, to long white hair, obtains biologic packing material.
Embodiment 2
By water content 60% rice put in gas-permeable container, rice accounts for the 40% of gas-permeable container volume, gas-permeable container upper cover Rice paper is also tightened, and by gas-permeable container back-off on the rice stubble having white liquid to overflow, makes the white liquid on rice and rice stubble connect Touch, to rice become pink sposh state, by pink sposh state rice put in gas impermeable container and add brown sugar, Zinc sulfate and potassium dihydrogen phosphate mixing, the mass ratio of the pink rice of sposh state, brown sugar, zinc sulfate and potassium dihydrogen phosphate is 100:45:0.1:0.2, covers rice paper and tightens, and is positioned in 28 DEG C of environment, and to altar, mixture becomes liquid, i.e. obtains soil Write microorganism stock solution;
Prepare biologic packing material: the variable color silica gel of 80 mesh and indigenous microorganism stock solution are joined according to certain mass ratio fill organic In the fermentation tank of thing, and adding water, the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mass ratio are 4:1:45, The water content of the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mixture is 55%, under the conditions of temperature 28 DEG C, Stirring a material every 4 hours, and keep moisture consistent, fermentation, to long white hair, obtains biologic packing material.
Embodiment 3
By water content 60% rice put in gas-permeable container, rice accounts for the 40% of gas-permeable container volume, gas-permeable container upper cover Rice paper is also tightened, and by gas-permeable container back-off on the rice stubble having white liquid to overflow, makes the white liquid on rice and rice stubble connect Touch, to rice become pink sposh state, by pink sposh state rice put in gas impermeable container and add brown sugar, Zinc sulfate and potassium dihydrogen phosphate mixing, the mass ratio of the pink rice of sposh state, brown sugar, zinc sulfate and potassium dihydrogen phosphate is 100:45:0.1:0.2, covers rice paper and tightens, and is positioned in 28 DEG C of environment, and to altar, mixture becomes liquid, i.e. obtains soil Write microorganism stock solution;
Prepare biologic packing material: the variable color silica gel of 80 mesh and indigenous microorganism stock solution are joined according to certain mass ratio fill organic In the fermentation tank of thing, and adding water, the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mass ratio are 5:1:44, The water content of the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mixture is 55%, under the conditions of temperature 28 DEG C, Stirring a material every 4 hours, and keep moisture consistent, fermentation, to long white hair, obtains biologic packing material.
Embodiment 4
By water content 60% rice put in gas-permeable container, rice accounts for the 40% of gas-permeable container volume, gas-permeable container upper cover Rice paper is also tightened, and by gas-permeable container back-off on the rice stubble having white liquid to overflow, makes the white liquid on rice and rice stubble connect Touch, to rice become pink sposh state, by pink sposh state rice put in gas impermeable container and add brown sugar, Zinc sulfate and potassium dihydrogen phosphate mixing, the mass ratio of the pink rice of sposh state, brown sugar, zinc sulfate and potassium dihydrogen phosphate is 100:45:0.1:0.2, covers rice paper and tightens, and is positioned in 28 DEG C of environment, and to altar, mixture becomes liquid, i.e. obtains soil Write microorganism stock solution;
Prepare biologic packing material: the variable color silica gel of 80 mesh and indigenous microorganism stock solution are joined according to certain mass ratio fill organic In the fermentation tank of thing, and adding water, the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mass ratio are 7:1:42, The water content of the variable color silica gel of 80 mesh, indigenous microorganism stock solution and organic mixture is 55%, under the conditions of temperature 28 DEG C, Stirring a material every 4 hours, and keep moisture consistent, fermentation, to long white hair, obtains biologic packing material.
Organic substance described in embodiment 1 to 4 is that the Folium Populi Pseudo-simonii pulverized and Testa oryzae are according to the compositions of 6:1.
Beneficial effects of the present invention is further illustrated below in conjunction with experimental data:
1, experiment material to be tested
1 materials and methods:
1.1 test sites: Yantai Power Plant.
1.2 experiments process tail gas: tail gas is mainly composed of sulfur dioxide.
1.3 materials to be tested: for common biologic packing material (in addition to not adding variable color silica gel, other manufacture method and embodiment 1 phase Together), embodiment 1, embodiment 2, embodiment 3 and embodiment 4 do effectiveness comparison.
1.4 EXPERIMENTAL DESIGN: test sets 5 process, repeats for 2 times, and the most common biologic packing material is (except not adding variable color silica gel Outward, other manufacture method is same as in Example 1), embodiment 1, embodiment 2, embodiment 3 and embodiment 4, place respectively 10 days, 20 days and 30 days detection sulfur dioxide in tail gas content.Wherein common biologic packing material (in addition to not adding variable color silica gel, other making side Method is same as in Example 1) at the 20th day because vent gas treatment is the most up to standard, change, the embodiment of the present invention 1 to 4 is the 18th~21 It color becomes light blue, owing to microbe stuffing is per se with the face having flue gas wherein embodiment 2 and 3 in color and microorganism tower Complexion changedization is not it is obvious that the 21st day exceeds standard the moisture just supplemented because of detection sulfur dioxide, supplements afterwards microbial activity and is also subject to Impact, is continuing with through keeping the skin wet to navy blue, and Tail gas measuring meets the requirements always.
This experiment other management in addition to experiment biologic packing material difference are the most consistent.
2 results and analysis
Embodiment 1, embodiment 2, embodiment 3, embodiment 4 and common biologic packing material (in addition to not adding variable color silica gel, other making side Method is same as in Example 1) process and compare, embodiment 1, embodiment 2, embodiment 3 and embodiment 4 process tail gas effect and are significantly better than Common biologic packing material (in addition to not adding variable color silica gel, other manufacture method is same as in Example 1), data are shown in Table 1.
Table 1 respectively processes sulfur dioxide data in vent gas treatment
The embodiment 1 to 4 can prepared at equal conditions by table 1, due to variable color silica gel and the difference of starter addition, and The effect of performance is slightly different, owing to the change of embodiment 2 and 3 color is not it is obvious that mend it after testing result is defective Water-filling divides, and embodiment 2 and 3 disposal ability is affected as can be seen from the data, and embodiment 4 is few because of Organic substance relatively embodiment 1, Also it is affected in its disposal ability of later stage, consolidated statement 1, it can be deduced that the color change of embodiment 1 substantially, and is stablized, real Execute example 1 effect best.

Claims (4)

1. the preparation method of a biologic packing material, it is characterised in that follow the steps below:
1), prepare indigenous microorganism stock solution: by water content 40%~65% rice put in gas-permeable container, rice accounts for ventilative The 30%~60% of vessel volume, gas-permeable container upper cover rice paper is also tightened, by gas-permeable container back-off in the rice having white liquid to overflow On stubble, making rice contact with the white liquid on rice stubble, placement to rice becomes pink sposh state, by pink sposh shape The rice of state is put in gas impermeable container and adds brown sugar, zinc sulfate and potassium dihydrogen phosphate mixing, the rice of pink sposh state The mass ratio of meal, brown sugar, zinc sulfate and potassium dihydrogen phosphate is 100:30~60:0.1~1:0.1~1, covers rice paper and tightens, Being positioned in 15~30 DEG C of environment, to altar, mixture becomes liquid, i.e. obtains indigenous microorganism stock solution;
2), biologic packing material is prepared: variable color silica gel and indigenous microorganism stock solution joined according to certain mass ratio and fill Organic substance Fermentation tank in, and add water, variable color silica gel, indigenous microorganism stock solution and organic mass ratio are 4~15:0.5~5:80 ~94, the water content of variable color silica gel, indigenous microorganism stock solution and organic mixture is 40%~60%, in temperature 20~35 Under the conditions of DEG C, stirring a material every 3~6 hours, and keep moisture consistent, fermentation, to long white hair, obtains biologic packing material;
Described variable color silica gel is without the orange silica gel of cobalt with without the one in cobalt blue silica gel;
Described Organic substance is the one in branch, bark, leaves, Pericarppium arachidis hypogaeae, wheat straw, Testa oryzae and the bean cake pulverized or arbitrary proportion Two or more.
2. the preparation method of biologic packing material as claimed in claim 1, it is characterised in that: variable color silica gel is powder variable color silica gel, Mesh number is 20~100 mesh.
3. the preparation method of biologic packing material as claimed in claim 1, it is characterised in that: rice water content described in step 1) is 60%, rice accounts for the 40% of gas-permeable container volume;The pink rice of sposh state, brown sugar, zinc sulfate and the matter of potassium dihydrogen phosphate Amount ratio is 100:45:0.1:0.2.
4. the preparation method of biologic packing material as claimed in claim 1, it is characterised in that: step 2) described in Organic substance for pulverizing Folium Populi Pseudo-simonii and Testa oryzae according to the compositions of 6:1;Variable color silica gel is without cobalt blue silica gel, and mesh number is 80 mesh;Variable color silica gel, original inhabitants Microorganism stock solution and organic mass ratio are 6:1:43;Water content is 55%, temperature 28 DEG C, stirs once every 4 hours.
CN201610654510.XA 2016-08-11 2016-08-11 A kind of preparation method of biologic packing material Active CN106139885B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1445013A (en) * 2002-03-19 2003-10-01 广东省微生物研究所 Biologic deodorization method and its device
CN101036856A (en) * 2006-03-15 2007-09-19 中国科学院生态环境研究中心 Combined type biodegradation-absorbing and separating waste gas processing device and the operation method
CN102658005A (en) * 2012-05-16 2012-09-12 程道远 Novel humidity-sensitive color change drying agent
KR101273956B1 (en) * 2010-09-08 2013-06-11 삼영이노텍주식회사 Powder contained minerals and the manufacturing method
CN105784704A (en) * 2016-03-11 2016-07-20 国家电网公司 Portable color display device for flue gas humidity

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1445013A (en) * 2002-03-19 2003-10-01 广东省微生物研究所 Biologic deodorization method and its device
CN101036856A (en) * 2006-03-15 2007-09-19 中国科学院生态环境研究中心 Combined type biodegradation-absorbing and separating waste gas processing device and the operation method
KR101273956B1 (en) * 2010-09-08 2013-06-11 삼영이노텍주식회사 Powder contained minerals and the manufacturing method
CN102658005A (en) * 2012-05-16 2012-09-12 程道远 Novel humidity-sensitive color change drying agent
CN105784704A (en) * 2016-03-11 2016-07-20 国家电网公司 Portable color display device for flue gas humidity

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Inventor after: Wen Xiaoni

Inventor after: Yu Haiqing

Inventor after: Jiang Xiaohua

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Address after: 221300 No. 1 Zhangjiagang East Road, Yitang Town, Pizhou City, Xuzhou City, Jiangsu Province

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Patentee before: Pizhou Binhe SME Management Service Co., Ltd.