CN106137805A - A kind of pharmaceutical composition for skin moisture-keeping and preparation method thereof - Google Patents
A kind of pharmaceutical composition for skin moisture-keeping and preparation method thereof Download PDFInfo
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- CN106137805A CN106137805A CN201510124906.9A CN201510124906A CN106137805A CN 106137805 A CN106137805 A CN 106137805A CN 201510124906 A CN201510124906 A CN 201510124906A CN 106137805 A CN106137805 A CN 106137805A
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- skin
- pharmaceutical composition
- vitamin
- hyaluronic acid
- moisture
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Abstract
The present invention provides a kind of pharmaceutical composition with skin moisture-keeping effect and preparation method thereof.The pharmaceutical composition of the present invention is made up of red wine 2-40 part, sodium alginate 1-20 part, Aloe 1-20 part, stem and leaf of Radix Ginseng total saponins 0.01-0.5 part, vitamin C 0.01-0.5 part, vitamin e 0.01-0.5 part, Semen Tritici aestivi germ oil 0.01-0.5 part, collagen protein of fish skin 0.1-2 part, hyaluronic acid 0.1-2 part, the medicine of hyaluronic acid 0.1-2 part percentage by weight.Result of study shows, this pharmaceutical composition can significantly reduce moisture of skin and scatter and disappear, and increases keratodermatitis water content, has lasting moisturizing, lock water effect, skin opposing extraneous undesirable element invasion and attack can be increased, reduce the skin problem such as xerosis cutis, coarse, desquamation.
Description
Technical field
The invention belongs to medicine and household chemicals technical field, be specifically related to a kind of for skin
Pharmaceutical composition of skin moisturizing and preparation method thereof.
Background technology
Healthy skin should be smooth moist whippy.This gives the credit to a great extent
Moisture in skin.And the function of these outward appearance marks moisture-keeping system with skin own is relevant.
The function of moisture-keeping system is that the water content maintaining skin certain, and opposing is by internal and external factor pair
The infringements such as evaporation drying that skin is caused, even embrittlement.Green natural, goes back to nature
Become the much told tale of skin moisture-keeping, Chinese herbal medicine and modern polymer substance to provide to skin moisture-keeping
Ample resources.
The natural moisture preserving system that skin moisture-keeping mechanism is mainly in human body skin is mainly by water, fat
Class, nature moisturizing factor (NMF) form.Lipid is that stratiform is filled between horn cell,
Main Function is to form water barrier, prevents loss of moist.Lipid is apolar substance mostly,
Moisture can be limited flow at intraor extracellular and iuntercellular.The fat relevant with skin barrier function
Matter includes aphingolipid, free cholesterol and free fatty.Phosphorus in activated epidermis
Fat rich content, by basal layer in horny layer atomization, ceramide, cholesterol,
The content of fatty acid is gradually increased, and lipid profile also there occurs change, and in granular layer, lipid gathers
Combining in lamellated granule. when Granulosa cells is converted into corneocyte, these lipids are discharged
And it is filled in intercellular substance, define the barrier preventing loss of moist.When caused by a variety of causes
When lipid lacks, its water barrier action weakens, and runs off will increase through transepidermal water, occurs
Some low-molecular-weight things that xerosis cutis desquamation NMF can be combined with water in being present in horny layer
The general name of matter, including aminoacid, 2-pyrrolidone-5-carboxylic acid, lactate, carbamide, amine, uric acid,
Glycosamine, citrate, sodium, potassium, calcium and magnesium, phosphate, chlorine, sugar, organic acid, peptide
Class and the material of other the unknowns.NMF accounts for the 10% of corneocyte substrate, by infiltration
The water that pressure attracts hydrone and NMF to combine is a part relatively fixing in horny layer, content
The part water changed greatly is the most penetrating with horny layer and lipid barrier is relevant, and leads to
Thoroughly property is relevant to lipid between horn cell and the integrity of layer structure and feature again.Skin angle
The moisture of matter layer, to the various stimulations maintaining skin health, defence to be subject to from the external world, prevents
Skin aging and moisten, beauty treatment skin the most significant.
The architecture basics of skin barrier be mainly horny layer and epidermis lipid, natural moisture preserving because of
Son etc..Epidermis lipid includes ceramide, free cholesterol and free fatty etc..These
Lipid is at basal layer cell in horny layer atomization, and content is gradually increased, and arrives cutin
It is discharged to intercellular substance during layer, is formed and prevent the barrier nature moisturizing factor of loss of moist from being
Be decomposed to form by the filaggrin in epidermis, comprise aminoacid, 2-pyrrolidone-5-carboxylic acid,
The multiple low molecular weight substances such as urocanic acid, lactic acid carbamide, are combined with water in horny layer and tie up
Hold skin barrier function.
Wetting agent is in order to simulate the natural moisture preserving system being made up of in human body skin oil, water, NMF
System.Effect is to delay loss of moist, increases corium--and transepidermal water infiltration, temporary for skin
Time provide protection, reduce damage, promote repair process.Skin moisturizer by main component with
And other auxiliary elements composition.Main component include sealer, hygroscopic agent, hydrophilic matrix,
Preventing light agent and some special adding ingredients, and auxiliary element have emulsifying agent, preservative, spice,
Liposome etc..
The wetting agent used in skin protection cosmetics at present is mainly polyhydric alcohol, sorbitol, lactic acid
And sodium salt etc., mostly belonging to chemicals, green natural moisturizing has become beauty treatment in the present age and has protected
The theme of skin, therefore, people's yearning returns to nature, starts to pay attention to the method skin of nature beauty treatment
Skin moisture-retaining capacity reduction can cause skin barrier function to decline, and skin barrier function declines again can
Further result in skin moisture-keeping ability to reduce, to cause a vicious cycle.Therefore for just
For normal skin barrier function, moisturizing is to maintain skin physiology function, delay skin aging,
It is again to prevent and treat dermopathic important step.Moisturizing is the basis weight of weight again.
Contemporary society is universal due to beauty treatment, and all kinds of moisture-keeping cosmetics are a feast for the eyes, layer
Going out not poor, these cosmetics are made up of chemical substance mostly.Its toxic and side effects is the most more come
More cause uneasiness and the attention of people.Modern medicine beauty treatment relies on chemical drugs and operation mostly,
Also there is certain toxic and side effects.Many natural materials are had to have good performance of keeping humidity at present.
Simultaneously possibly together with the material of other effect nutritious to skin in these natural extracts.From sky
The natural excellent wetting agent generation with nutrition and moisturizing dual property so extracted in material
Chemosynthesis wetting agent, meets the requirement that people go back to nature.It it is following wetting agent development
Trend.There is the long history manufacturing and using natural plants cosmetics in China, abundant
Practical experience and technical advantage, and China vast territory and abundant resources, its uniqueness geographical environment and
Under weather conditions, grow many natural plants differed from one another.These plants are different because of it
Characteristic, be used for for a long time improving looks, there is Glycerin, prevent extraneous various having noxa
The element effect to skin injury.Delay skin aging, prevents and treats dermatopathy, and skin moisture-keeping is
Basis, Devoting Major Efforts To Developing natural Chinese medicine skin moisturizer is primary act.
Summary of the invention
For above-mentioned purpose, technical scheme is as follows:
The present invention provides a kind of pharmaceutical composition for skin moisture-keeping, this pharmaceutical composition by
Each raw material of following parts by weight extracts and is mixed to prepare: red wine 2-40 part, sodium alginate
1-20 part, Aloe 1-20 part, stem and leaf of Radix Ginseng total saponins 0.01-0.5 part, vitamin C 0.01-0.5
Part, vitamin e 0.01-0.5 part, Semen Tritici aestivi germ oil 0.01-0.5 part, collagen protein of fish skin
0.1-2 part, hyaluronic acid 0.1-2 part, hyaluronic acid 0.1-2 part.
Preferably, in this pharmaceutical composition, the parts by weight proportioning of each raw material is as follows: red wine
5-20 part, sodium alginate 2-10 part, Aloe 2-10 part, stem and leaf of Radix Ginseng total saponins 0.02-0.25
Part, vitamin C 0.02-0.25 part, vitamin e 0.02-0.25 part, Semen Tritici aestivi germ oil
0.02-0.25 part, collagen protein of fish skin 0.2-1 part, hyaluronic acid 0.2-1 part, hyaluronic acid 0.2-1
Part.
Meanwhile, the invention provides the preparation method of this pharmaceutical composition, its preparation method is:
Weigh each raw material, mix homogeneously according to parts by weight, obtain described pharmaceutical composition.
This pharmaceutical composition can also add acceptable carrier and/or excipient on galenic pharmacy,
As sodium carboxymethyl cellulose, carbomer, sodium polyacrylate, glycerol, propylene glycol, sorbitol,
HP-β-CD, polyoxyethylene hydrogenated Oleum Ricini RH40, polyoxyethylene hydrogenated Oleum Ricini
One or more in HS15, stearic acid, glyceryl monostearate etc., make and have skin U.S.
The medicine of white effect, health product, cosmetics, such as facial film, astringent, frost, emulsion, gel
Deng.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further described in detail, is given
Embodiment only for illustrating the present invention rather than in order to limit the scope of the present invention.
Embodiment 1
Weigh red wine 40g, sodium alginate 1g, Aloe 10g, stem and leaf of Radix Ginseng total saponins 0.3g,
Vitamin C 0.5g, vitamin e 0.5g, Semen Tritici aestivi germ oil 0.01g, collagen protein of fish skin
2.0g, hyaluronic acid 0.5g, hyaluronic acid 0.5g, carbomer 0.1g, water 80g, mixing is all
Even, 200 revs/min are centrifuged 5 minutes, are divided into 5 parts, are added separately in face paper, dress
Bag seals, and obtains moisture saver mask.
Embodiment 2
Weigh red wine 10g, sodium alginate 20g, Aloe 1g, stem and leaf of Radix Ginseng total saponins 0.01g,
Vitamin C 0.01g, vitamin e 0.01g, Semen Tritici aestivi germ oil 0.3g, collagen protein of fish skin
0.5g, hyaluronic acid 1g, hyaluronic acid 1g, add water 40g, mix homogeneously, adds the third two
Alcohol 20g, carbomer 1g, mix homogeneously, obtain moisturizing gel.
Embodiment 3
Weigh red wine 2g, sodium alginate 10g, Aloe 20g, stem and leaf of Radix Ginseng total saponins 0.5g,
Vitamin C 0.3g, vitamin e 0.3g, Semen Tritici aestivi germ oil 0.5g, collagen protein of fish skin 0.1g,
Hyaluronic acid 2g, hyaluronic acid 2g, water 100g mix homogeneously, it is heated to 70 DEG C；Separately take poly-
Oxygen ethylene hydrogenation Oleum Ricini HS152g, lanoline 50g, vaseline 10g addition extremely thawing,
Continue to be heated to 70 DEG C；Aqueous phase is slowly poured in oil phase, stirring while adding, complete to emulsifying
Entirely, let cool, obtain moisturizer.
Embodiment 4
Weigh red wine 20g, sodium alginate 15g, Aloe 15g, stem and leaf of Radix Ginseng total saponins
0.1g, vitamin C 0.5g, vitamin e 0.5g, Semen Tritici aestivi germ oil 0.4g, fish skin collagen
Albumen 1g, hyaluronic acid 0.1g, hyaluronic acid 0.1g, glycerol adding 10g, water 100g mixing is all
Even, it is heated to 70 DEG C；Separately take polyoxyethylene hydrogenated Oleum Ricini RH402g, lanoline 50g,
Vaseline 10g adds to melting, and continues to be heated to 70 DEG C；Aqueous phase is slowly poured in oil phase,
Stirring while adding, complete to emulsifying, let cool, obtain moisturizer.
Embodiment 5
Weigh red wine 30g, sodium alginate 5g, Aloe 5g, stem and leaf of Radix Ginseng total saponins 0.4g,
Vitamin C 0.4g, vitamin e 0.4g, Semen Tritici aestivi germ oil 0.1g, collagen protein of fish skin 1.5g,
Hyaluronic acid 1.5g, hyaluronic acid 1.5g, add sorbitol 20g, water 50g, carbomer
1g, mix homogeneously, obtain moisturizing gel.
Embodiment 6
Weigh red wine 20g, sodium alginate 5g, Aloe 10g, stem and leaf of Radix Ginseng total saponins 0.2g,
Vitamin C 0.5g, vitamin e 0.2g, Semen Tritici aestivi germ oil 0.03g, collagen protein of fish skin
2.0g, hyaluronic acid 0.5g, hyaluronic acid 0.5g, water 200g, mix homogeneously, it is divided into 5
Part, it being added separately in face paper, pack seals, and obtains moisture saver mask.
Embodiment 7
Weigh red wine 2g, sodium alginate 10g, Aloe 10g, stem and leaf of Radix Ginseng total saponins 0.2g,
Vitamin C 0.2g, vitamin e 0.2g, Semen Tritici aestivi germ oil 0.2g, collagen protein of fish skin 2.0g,
Hyaluronic acid 2g, hyaluronic acid 2g, add propylene glycol 10g, water 100g mix homogeneously, be heated to
70℃；Separately take polyoxyethylene hydrogenated Oleum Ricini RH405g, glyceryl monostearate 50g, sheep
Hair fat 50g, vaseline 10g add to melting, and continue to be heated to 70 DEG C；Aqueous phase is slowly fallen
Enter in oil phase, stirring while adding, complete to emulsifying, let cool, obtain moisturiser.
Embodiment 8
Weigh red wine 10g, sodium alginate 1g, Aloe 10g, stem and leaf of Radix Ginseng total saponins 0.3g,
Vitamin C 0.5g, vitamin e 0.5g, Semen Tritici aestivi germ oil 0.01g, collagen protein of fish skin
2.0g, hyaluronic acid 0.5g, hyaluronic acid 0.5g, water 200g mix homogeneously, it is heated to 70 DEG C；
Separately take polyoxyethylene hydrogenated Oleum Ricini RH4010g, lanoline 50g, vaseline 20g to add extremely
Melt, continue to be heated to 70 DEG C；Aqueous phase is slowly poured in oil phase, stirring while adding, extremely
Emulsifying is complete, lets cool, obtains moisturizer.
The present invention uses tests below to prove the moisture-keeping function of pharmaceutical composition, and this medicine group is described
Compound is for the foundation of skin moisture-keeping.
Experimenter: healthy volunteer's 4O name, all experimenters are by the non-wound of good skin
The inspection of wound property, without any skin and systemic disease history, recipient site skin is without exception, the most not
Smear other external preparation such as any external used medicine and cosmetics.
Test apparatus and requirement: indoor temperature 22 DEG C ± 1 DEG C；Humidity 50% ± 5%.Skin beauty water
Divide measuring instrument Corneometer CM825, Courage+Khazaka company of Germany；Percutaneous
Moisture content scatters and disappears measuring instrument Tewameter TM300, Courage+Khazaka company of Germany.
Test method:
1) selecting the left and right inboard arm of experimenter is Test sites (4cm at palm base portion 5cm
×4cm)。
2) moisture content of skin is used to test ComeometerCM825, moisture percutaneous by technical staff
Skin scatters and disappears and tests Tewameter TM300 measurement, averages, is designated as blank value.
3) experimenter smears sample at left and right arm Test sites.
4) experimenter is after make continuously to apply some make up l h, 2h, 4h, 6h and 8h, by
Technical staff uses moisture of skin tester CorneometerCM825, moisture to scatter and disappear through skin
Measuring instrument Tewameter TM300, measures 5 times respectively, averages.
5) numerical value that statistics subject position records every time, analyzes its moisture of skin and water
Changing Pattern is lost in dispersion.
The impact (%) on moisture content of skin of table 1 embodiment 1 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 25.2 | 49.8 | 42.3 | 35.3 | 28.2 |
| 2 | 28.4 | 47.6 | 44.5 | 38.2 | 30.6 |
| 3 | 26.8 | 50.6 | 45.2 | 34.3 | 28.5 |
| 4 | 29.5 | 48.2 | 42.6 | 37.6 | 31.6 |
| 5 | 28.6 | 49.3 | 40.7 | 38.5 | 29.8 |
The impact (%) on moisture content of skin of table 2 embodiment 2 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 28.2 | 45.6 | 41.3 | 36.2 | 29.3 |
| 2 | 29.3 | 47.6 | 45.5 | 37.6 | 30.7 |
| 3 | 27.6 | 48.2 | 43.7 | 35.6 | 29.5 |
| 4 | 29.2 | 46.4 | 44.3 | 36.4 | 31.2 |
| 5 | 27.4 | 45.5 | 42.4 | 35.7 | 29.7 |
The impact (%) on moisture content of skin of table 3 embodiment 3 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 25.6 | 41.3 | 39.5 | 35.2 | 28.6 |
| 2 | 26.2 | 40.5 | 38.2 | 36.6 | 29.8 |
| 3 | 25.8 | 42.9 | 40.8 | 34.7 | 26.4 |
| 4 | 26.6 | 43.6 | 42.6 | 35.4 | 28.6 |
| 5 | 22.7 | 44.7 | 41.7 | 36.4 | 25.7 |
The impact (%) on moisture content of skin of table 4 embodiment 4 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 25.2 | 44.6 | 38.4 | 35.1 | 28.1 |
| 2 | 26.1 | 45.3 | 39.2 | 34.6 | 31.6 |
| 3 | 22.3 | 44.2 | 38.7 | 32.5 | 27.2 |
| 4 | 24.9 | 41.6 | 36.9 | 33.4 | 30.6 |
| 5 | 26.8 | 42.5 | 35.2 | 37.6 | 34.6 |
The impact (%) on moisture content of skin of table 5 embodiment 5 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 23.4 | 43.1 | 42.1 | 39.4 | 30.1 |
| 2 | 25.8 | 44.3 | 40.3 | 34.8 | 29.3 |
| 3 | 26.4 | 43.1 | 40.4 | 34.6 | 29.4 |
| 4 | 28.4 | 45.1 | 42.4 | 36.4 | 32.4 |
| 5 | 28.4 | 46.6 | 45.4 | 37.3 | 30.5 |
The impact (%) on moisture content of skin of table 6 embodiment 6 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 26.1 | 48.4 | 41.3 | 39.3 | 30.2 |
| 2 | 26.4 | 46.4 | 45.4 | 38.4 | 34.6 |
| 3 | 28.4 | 51.3 | 45.1 | 36.4 | 31.2 |
| 4 | 24.6 | 49.8 | 44.3 | 38.4 | 33.2 |
| 5 | 25.4 | 48.4 | 45.4 | 37.4 | 30.4 |
The impact (%) on moisture content of skin of table 7 embodiment 7 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 26.5 | 39.9 | 36.4 | 34.3 | 30.1 |
| 2 | 24.5 | 40.4 | 38.4 | 36.4 | 28.2 |
| 3 | 26.4 | 41.6 | 46.4 | 40.5 | 31.2 |
| 4 | 24.3 | 45.6 | 44.6 | 38.1 | 34.5 |
| 5 | 27.2 | 41.1 | 40.2 | 37.6 | 31.0 |
The impact (%) on moisture content of skin of table 8 embodiment 8 sample
| Subject number | Before using | Use 1 hour | Use 2 hours | Use 4 hours | Use 8 hours |
| 1 | 24.6 | 41.3 | 36.2 | 33.1 | 26.2 |
| 2 | 24.6 | 46.2 | 38.5 | 34.6 | 30.3 |
| 3 | 26.4 | 46.1 | 37.4 | 34.3 | 29.5 |
| 4 | 26.2 | 45.1 | 36.4 | 35.4 | 28.6 |
| 5 | 28.2 | 46.2 | 36.4 | 35.4 | 31.6 |
Claims (5)
1. the pharmaceutical composition for skin moisture-keeping, it is characterised in that described medicine group
Compound is extracted by each raw material of following parts by weight and is mixed to prepare: red wine 2-40 part, Sargassum
Acid sodium 1-20 part, Aloe 1-20 part, stem and leaf of Radix Ginseng total saponins 0.01-0.5 part, vitamin C
0.01-0.5 part, vitamin e 0.01-0.5 part, Semen Tritici aestivi germ oil 0.01-0.5 part, fish glue from skin
Former albumen 0.1-2 part, hyaluronic acid 0.1-2 part, hyaluronic acid 0.1-2 part.
Pharmaceutical composition the most according to claim 1, it is characterised in that described each raw material
Parts by weight proportioning as follows: red wine 5-20 part, sodium alginate 2-10 part, Aloe 2-10
Part, stem and leaf of Radix Ginseng total saponins 0.02-0.25 part, vitamin C 0.02-0.25 part, vitamin e
0.02-0.25 part, Semen Tritici aestivi germ oil 0.02-0.25 part, collagen protein of fish skin 0.2-1 part, glass
Uric acid 0.2-1 part, hyaluronic acid 0.2-1 part.
Pharmaceutical composition the most according to claim 1, it is characterised in that described compositions
Also comprise acceptable carrier and/or excipient on galenic pharmacy, for preparing the medicine of skin whitening
Thing, health product, cosmetics, such as facial film, astringent, frost, emulsion, gel.
Pharmaceutical composition the most according to claim 3, it is characterised in that described galenic pharmacy
Upper acceptable carrier and/or excipient are selected from sodium carboxymethyl cellulose, carbomer, polyacrylic acid
Sodium, glycerol, propylene glycol, sorbitol, HP-β-CD, polyoxyethylene hydrogenated Oleum Ricini
One or more in RH40, polyoxyethylene hydrogenated Oleum Ricini HS15.
5. according to the pharmaceutical composition described in any one of Claims 1-4, it is characterised in that
The application of described compositions is for preparing the medicine of skin whitening, health product, cosmetics, as
Facial film, astringent, frost, emulsion, gel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510124906.9A CN106137805A (en) | 2015-03-23 | 2015-03-23 | A kind of pharmaceutical composition for skin moisture-keeping and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510124906.9A CN106137805A (en) | 2015-03-23 | 2015-03-23 | A kind of pharmaceutical composition for skin moisture-keeping and preparation method thereof |
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| CN106137805A true CN106137805A (en) | 2016-11-23 |
Family
ID=58063281
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| CN201510124906.9A Pending CN106137805A (en) | 2015-03-23 | 2015-03-23 | A kind of pharmaceutical composition for skin moisture-keeping and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109662922A (en) * | 2017-10-17 | 2019-04-23 | 陈静 | A kind of whitening and moisturizing gel mask |
| WO2020226347A1 (en) * | 2019-05-03 | 2020-11-12 | 김옥희 | Cosmetic composition for skin moisturization, cosmetic using same, and preparation method therefor |
| CN113925789A (en) * | 2021-09-15 | 2022-01-14 | 王御惟 | Novel scalp active shampoo powder and production process thereof |
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| CN101966141A (en) * | 2010-10-14 | 2011-02-09 | 珈侬生化科技(中国)有限公司 | Composite containing ginseng extracts and ganoderma extracts and application thereof |
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| CN101530608A (en) * | 2008-09-04 | 2009-09-16 | 厦门金日制药有限公司 | Composition with functions of resisting radiation and improving skin moisture |
| CN101966141A (en) * | 2010-10-14 | 2011-02-09 | 珈侬生化科技(中国)有限公司 | Composite containing ginseng extracts and ganoderma extracts and application thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109662922A (en) * | 2017-10-17 | 2019-04-23 | 陈静 | A kind of whitening and moisturizing gel mask |
| WO2020226347A1 (en) * | 2019-05-03 | 2020-11-12 | 김옥희 | Cosmetic composition for skin moisturization, cosmetic using same, and preparation method therefor |
| CN113925789A (en) * | 2021-09-15 | 2022-01-14 | 王御惟 | Novel scalp active shampoo powder and production process thereof |
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